• Title/Summary/Keyword: 공극네트워크

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Variation of Porosity and Gas Permeability of Gas Diffusion Layers Under Compression (가스확산층의 압축에 따른 공극률 및 기체투과율의 변화)

  • Lee, Yongtaek
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.37 no.8
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    • pp.767-773
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    • 2013
  • This study suggested the variations of porosity and gas permeability of gas diffusion layers (GDLs), which are easily deformed among the components of a highly compressed PEMFC stack. The volume change owing to compression was measured experimentally, and the variations in the porosity and gas permeability were estimated using correlations published in previous literature. The effect of polytetrafluoroethylene (PTFE) which is added to the GDLs to enhance water discharge was investigated on the variations of porosity and gas permeability. The gas permeability which strongly affects the mass transport through GDL, decreases sharply with increasing compression when the GDL has high PTFE loading. As a result, the mass transport through the pore network of GDL can be changed considerably according to the PTFE loading even with the same clamping force. The accuracy of modeling of transport phenomena through GDL can be improved due to the enhanced correlations developed based on the results of this study.

Prediction of Soil-Water Characteristic Curve and Relative Permeability of Jumunjin Sand Using Pore Network Model (공극 네트워크 모델을 이용한 주문진표준사의 함수특성곡선 및 상대투수율 예측에 관한 연구)

  • Suh, Hyoung Suk;Yun, Tae Sup;Kim, Kwang Yeom
    • Journal of the Korean Geotechnical Society
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    • v.32 no.1
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    • pp.55-62
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    • 2016
  • This study presents the numerical results of soil-water characteristic curve for sandy soil by pore network model. The Jumunjin sand is subjected to the high resolution 3D X-ray computed tomographic imaging and its pore structure is constructed by the web of pore body and pore channel. The channel radius, essential to the computation of capillary pressure, is obtained based on the skeletonization and Euclidean Distance transform. The experimentally obtained soil-water characteristic curve corroborates the numerically estimated one. The pore channel radius defined by minimum radii of pore throat results in the slightly overestimation of air entry value, while the overall evolution of capillary pressure resides in the acceptable range. The relative permeability computed by a series of suggested models runs above that obtained by pore network model at high degree of saturation.

Pore-network Study of Liquid Water Transport through Multiple Gas Diffusion Medium in PEMFCs (고분자 연료전지의 다공성층 내에서의 액상수분 이동에 관한 공극-네트워크 해석 연구)

  • Kang, Jung-Ho;Lee, Sang-Gun;Nam, Jin-Hyun;Kim, Charn-Jung
    • 한국전산유체공학회:학술대회논문집
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    • 2011.05a
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    • pp.46-53
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    • 2011
  • Water is continuously produced in polymer electrolyte membrane fuel cell (PEMFC), and is transported and exhausted through polymer electrolyte membrane (PEM), catalyst layer (CL), microporous layer (MPL), and gas diffusion layer (GDL). The low operation temperatures of PEMFC lead to the condensation of water, and the condensed water hinders the transport of reactants in porous layers (MPL and GDL). Thus, water flooding is currently one of hot issues that should be solved to achieve higher performance of PEMFC. This research aims to study liquid water transport in porous layers of PEMFC by using pore-network model, while the microscale pore structure and hydrophilic/hydrophobic surface properties of GDL and MPL were fully considered.

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산업제어시스템 보안 표준화 동향

  • Nah, Jae Hoon;Na, Jung Chan
    • Review of KIISC
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    • v.26 no.4
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    • pp.28-35
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    • 2016
  • 초기의 산업제어시스템은 독립적인 네트워크를 구성하고 있어서 외부 네트워크와는 분리되어 있어 안전하다는 의견을 갖고 있었으나, 악성코드에 의한 우회적 공격이 발생함으로 단순 공극(Air-gap) 정책으로는 대처하는 것에는 한계가 드러났다. 또한 정보통신(ICT: Information & Communication Technology) 기술의 발달로 산업제어네트워크는 비즈니스, 정보공유 그리고 유지보수를 위하여 외부 네트워크와 연결이 필요하게 되었다. 이로 인하여 ICT의 보안 취약점도 전수되는 상황이 되었다. 그러나 산업제어시스템은 독립적인 플랫폼과 제어기술로 구축되어 있어서, ICT의 기 개발된 보안 메카니즘이 그대로 적용될 수 없다는 것이 문제로 인식되고 있다. 산업제어시스템 보안을 위하여 단품의 보안 제품이나 서비스로 대응하는 것으로는 보안강도를 충족하지 못하는 것이 일반적이며, '심층 방어' 체계를 구축하여 종합적이고, 체계적인 보안대책이 필요하다. 이와 상응하여 산업제어시스템 영역에 최적의 보안 수준을 유지하기 위하여 장비의 호환성을 제공하기 위하여 표준화 필요성이 대두되고 있으며, 이에 현재 진행되고 있는 표준화 동향을 분석한다.

Relation between Autogenous Shrinkage of Concrete and Relative Humidity, Capillary Pressure, Surface Energy in Pore (공극 내 상대습도, 모세관압력, 표면에너지 변화에 따른 콘크리트 자기수축)

  • Lee, Chang-Soo;Park, Jong-Hyok
    • Journal of the Korea Concrete Institute
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    • v.20 no.2
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    • pp.131-138
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    • 2008
  • Humidity and strain were estimated for understanding the relation between humidity change by self-desiccation and shrinkage in high-performance concrete with low water binder ratio. Internal humidity change and shrinkage strain were about 10%, 4% and $320\times10^{-6}$, $120\times10^{-6}$ respectively on concrete with water binder ratio 0.3, 0.4 and from the results, humidity change and shrinkage represented the strong linear relation regardless of mixture. For specifying the relation on internal humidity change and autogenous shrinkage strain, shrinkage model was established which is driven by capillary pressure in pore water and surface energy in hydrates on the assumption of a single network and extended meniscus in pore system of concrete. This model and experimental results had a similar tendency so it would be concluded that the internal humidity change by self-desiccation in HPC originated in small pores less than 20 nm, therefore controlling plan on autogenous shrinkage might be focused on surface tension of water and degree of saturation in small pore.

Autogenous Shrinkage of High-Performance Concrete Containing Mineral Admixture (광물질 혼화재를 함유한 고성능 콘크리트의 자기수축)

  • Lee, Chang-Soo;Park, Jong-Hyok;Kim, Yong-Hyok;Kim, Young-Ook
    • Journal of the Korean Society of Hazard Mitigation
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    • v.7 no.3
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    • pp.19-31
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    • 2007
  • Humidity and strain were estimated for understanding the relation between humidity change by self-desiccation and shrinkage in high-performance concrete with low water binder ratio and containing fly ash and blast furnace slag. Internal humidity change and shrinkage strain were about 10%, 10%, 7%, 11%, 11% and $320{\times}10^{-6}$, $270{\times}10^{-6}$, $231{\times}10^{-6}$, $371{\times}10^{-6}$, $350{\times}10^{-6}$ respectively on OPC30, O30F10, O30F20, O30G40, O30G50 and from the results, fly ash made humidity change and strain decrease but slag increase comparing with ordinary portland cement. Considering only relation internal humidity and shrinkage by self-desiccation, humidity change and shrinkage represented the strong linear relation regardless of mineral admixture. For specifying the relation on internal humidity change and autogenous shrinkage strain, shrinkage model was established which is driven by capillary pressure in pore water and surface energy in hydrates on the assumption of a single network and extended meniscus in pore system of concrete. This model and experimental results had a similar tendency so it would be concluded that the internal humidity change by self-desiccation in HPC originated in small pores less than 20nm, therefore controlling plan on autogenous shrinkage might be focused on surface tension of water and degree of saturation in small pore.

Development of a Pipe Network Fluid-Flow Modelling Technique for Porous Media based on Statistical Percolation Theory (통계적 확산이론에 기초한 다공질체의 유동관망 유동해석 기법 개발)

  • Shin, Hyu-Soung
    • The Journal of Engineering Geology
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    • v.23 no.4
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    • pp.447-455
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    • 2013
  • A micro-mechanical pipe network model with the shape of a cube was developed to simulate the behavior of fluid flow through a porous medium. The fluid-flow mechanism through the cubic pipe network channels was defined mainly by introducing a well-known percolation theory (Stauffer and Aharony, 1994). A non-uniform flow generally appeared because all of the pipe diameters were allocated individually in a stochastic manner based on a given pore-size distribution curve and porosity. Fluid was supplied to one surface of the pipe network under a certain driving pressure head and allowed to percolate through the pipe networks. A percolation condition defined by capillary pressure with respect to each pipe diameter was applied first to all of the network pipes. That is, depending on pipe diameter, the fluid may or may not penetrate a specific pipe. Once pore pressures had reached equilibrium and steady-state flow had been attained throughout the network system, Darcy's law was used to compute the resultant permeability. This study investigated the sensitivity of network size to permeability calculations in order to find out the optimum network size which would be used for all the network modelling in this study. Mean pore size and pore size distribution curve obtained from field are used to define each of pipe sizes as being representative of actual oil sites. The calculated and measured permeabilities are in good agreement.

Experimental Study on the Spalling Properties of Ultra High Strength Concrete containing Amorphous Metallic Fiber (비정질강섬유를 혼입한 초고강도콘크리트의 폭렬특성에 관한 실험적 연구)

  • Choe, Gyeong-Cheol;Kim, Gyu-Yong;Kim, Hong-Seop;Hwang, Eui-Chul;Nam, Jeong-Soo
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.23 no.3
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    • pp.111-118
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    • 2019
  • This study examined the effect of amorphous metallic (AM) fibers on the spalling properties of ultra high strength concrete. Six specimens with concrete strengths of 100 MPa and 150 MPa were evaluated with mix proportions of polypropylene (PP) fibers of 0.15% by concrete volume, and proportions of AM fibers of 0.3% and 0.5% by concrete volume. These specimens were then heated in accordance with the ISO-834 heating curve. The movement of water vapor through a pore network formed by molten PP fibers was found to be a dominant factor controlling the spalling of high-strength concrete. Spalling control was not found to be significantly affected by the addition of 0.3% AM fibers; however, when 0.5% AM fibers was added, cracking was limited and so were paths for water vapor migration, increasing the likelihood of a moisture clog and creating the differential internal pressure often blamed for concrete spalling.

Development of Epoxy/Boron Nitride Composites for High Heat Dissipation of Metal Copper Clad Laminate (MCCL) (Metal Copper Clad Laminate (MCCL)의 고방열 특성을 위한 Epoxy/BN 복합체 개발)

  • Choi, Ho-Kyoung;Choi, Jae-Hyun;Choi, Bong-Goo;Yoon, Do-Young;Choi, Joong-So
    • Korean Chemical Engineering Research
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    • v.58 no.1
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    • pp.64-68
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    • 2020
  • In this study, metal copper clad laminate can be prepared using epoxy composite filled with thermally conductive fillers. In order to improve the thermal conductivity of epoxy composites, it is important factor to form conductive networks through appropriate packing of conductive fillers in epoxy composite matrix and to decrease the amount of thermally resistant junctions involving a epoxy composite matrix layer between adjacent filler units. This is because epoxy has a thermal conductivity of only 0.2-0.3W, so in order to maintain high thermal conductivity, thermally conductive fillers are connected to each other, so that the gap between particles can be reduced to reduce thermal resistance. The purpose of this study is to find way to achieve highly thermally conductive in the epoxy composite matrix filled with Al2O3 and Boron Nitride(BN) filler by filler loading and uniform dispersion. As a results, the use of Al2O3/BN hybrid filler in epoxy matrix was found to be effective in increasing thermal conductivity of epoxy composite matrix due to the enhanced connectivity offered by more continuous thermally conductive pathways and uniform dispersion without interfacial voids in epoxy composite matrix. In addition, surface treatmented s-BN improves the filler dispersion and adhesion between the filler and the epoxy matrix, which can significantly decrease the interfacial thermal resistance and increase the thermal conductivity of epoxy composite matrix.

Development Trend of Nanofiber Filter (나노섬유 필터의 개발 동향)

  • Kang Inn-Kyu;Kim Young-Jin;Byun Hong-Sik
    • Membrane Journal
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    • v.16 no.1
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    • pp.1-8
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    • 2006
  • Nanofiber is a broad phrase generally referring to a fiber with diameter less than 1 micron. Various polymers have been successfully electrospun into nanofibers in recent years. These nanofibers, due to their high surface area and porosity, have a great potential for use as filter medium, adsorption layers in protective clothing, etc. Nanofiber filters will enable new levels of filtration performance in the field of air filtration. In particular, nanofibers provide marked increases in filtration efficiency at relatively small pressure drop in permeability. Therefore, nanofiber filters could be substituted for conventional filter market due to the easy application of process and the possibility of coating to micron-sized non-woven sheets. This review is discussed on the trend of researche and development related to nanofiber filter including future marketability.