• Title/Summary/Keyword: 계면분리

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Characterization of Hexane Biodegradation by Rhodococcus sp. EH741 (Rhodococcus sp. EH741에 의한 Hexane 생분해 특성)

  • Lee, Eun-Hee;Cho, Kyung-Suk
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.2
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    • pp.144-149
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    • 2006
  • As a strain EH741, having an excellent hexane degradability, was isolated from bacterial consortium using hexane as a sole carbon and energy source. EH741 was identified as a Rhodococcus sp. and the addition of a surfactant Pluronic F68(PF68), for increasing hexane solubility couldn't enhance the specific growth rate of the isolate EH741 n the mineral salt medium supplemented with hexane as a sole carbon source(hexane-BH medium). In the hexane-BH medium, the maximum specific growth rate(${\mu}_{max}$) of this strain was $0.04h^{-1}$, and the maximum hexane degradation rate($V_{max}$) and saturation constant($K_s$) were$161{\mu}mol{\cdot}g-DCW^{-1}{\cdot}h^{-1}$ and 10.5 mM, respectively. Rhodococcus sp. EH741 was one of excellent microorgamisms for hexane biodegradation processes.

Effect of surfactant types in aqueous cleaning agents on their physical properties, cleaning ability and oil-water separation (수계세정제의 계면활성제 종류에 따른 물성, 세정성 및 유수분리 영향 연구)

  • Park, S. W.;Cha, A. J.;Kim, H. T.;Kim, H. S.;Bae, J. H.
    • Clean Technology
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    • v.9 no.1
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    • pp.9-21
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    • 2003
  • CFC-113 and 1,1,1-TCE which are ozone destruction substances are not used any more in the advanced countries because of Montreal protocol. MC and TCE are now used restrictively at small part of industrial fields in most of countries since they are known to be hazardous or carcinogenic materials. Thus, it is indispensible that the alternative cleaning agents which are environmental-friendly and safe, and show good cleaning ability should be developed or utilized for replacement of the halogenated cleaning agents. Aqueous cleaning agents are evaluated to be promising alternative ones among various alternatives in environmental and economical view point. This study has been carried out as a part of development program of aqueous cleaning agent. First of all, several types of surfactants which are the most important component in aqueous cleaning agents were chosen, and the physical properties, foaming ability, cleaning ability and oil-water separation efficiency of their aqueous solutions were measured and compared for selection of proper type of surfactant in aqueous cleaning agents.

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Growth of AlN Thin Film on Sapphire Substrates and ZnO Templates by RF-magnetron Sputtering (RF 마그네트론 스퍼터링법을 이용하여 사파이어 기판과 ZnO 박막 위에 증착한 AlN 박막의 특성분석)

  • Na, Hyun-Seok
    • Journal of the Korean Vacuum Society
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    • v.19 no.1
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    • pp.58-65
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    • 2010
  • AlN thin films were deposited on sapphire substrates and ZnO templates by rf-magnetron sputtering. Powder-sintered AlN target was adopted for source material. Thickness of AlN layer was linearly dependent on plasma power from 50 to 110 W, and it decreased slightly when working pressure increased from 3 to 10 mTorr due to short mean free path of source material sputtered from AlN target by Ar working gas. When $N_2$ gas was mixed with Ar, the thickness of AlN layer decreased significantly because of low sputter yield of nitrogen. AlN layer was also deposited on ZnO template. However, it showed weak thermal stability that the interface between AlN and ZnO was deteriorated by rapid thermal annealing treatment above $700^{\circ}C$. In addition, ZnO layer was largely attacked by MOCVD ambient gas of hydrogen and ammonia around $700^{\circ}C$ through inferior AlN layer deposited by sputtering. And AlN layers were fully peeled off above $900^{\circ}C$.

Characteristics and Properties of Fluoro/Silicone Rubber Blend System (불소/실리콘 고무 블렌드의 특성과 물성)

  • Lee, Jin-Kook;Song, Hwan-Jae;Kim, Mi-Ra
    • Journal of Adhesion and Interface
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    • v.9 no.3
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    • pp.14-19
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    • 2008
  • In this study, silicone rubber (SR40) and fluororubber (FKM) mixture blends were prepared by various weight percentages, and their properties were characterized. The crosslinking rate increased as the contents of SR40 due to the crosslinking agent in SR40. As contents of FKM increase in SR40/FKM blends, thermal decomposition temperature of blends increased. When SR40/FKM blend ratio was at 50/50, the thermal decomposition stabilization was higher than that of pure SR40. The contact angle of SR40/FKM blend increased as the increase of SR40 contents in blend. All composition of SR40/FKM blends showed typical phase separation morphology. As the contents of SR40 increase in SR40/FKM blend, the degree of separation in SR40/FKM blends also increased.

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Optimization of Culture Condition of Nocardia sp. L-417 Strain for Biosurfactant Production (Biosurfactant의 생산을 위한 Nocardia sp. L-417균주의 배양조건 최적화)

  • 이태호;김순한;임이종
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.27 no.2
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    • pp.252-258
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    • 1998
  • The strain producing biosurfactant was isolated from soil smples. The isolated strain was identified as the genus Nocardia through its morphological, cultural and physiolgical characteristics. A high concentration of the biosurfactant by Nocardia sp. L-417 was obtained after 4 days of cultivation in the culture medium containing 3% n-hexadecane, 0.1% $NaNO_3$, 0.02% $K_2HOP_4$, 0.01% $H_2PO_4$, 0.01% $MgSO_4$.$7H_2O$, 0.01% $CaCl_2$, 0.02% yeast extract, and 0.02% tryptone. The optimum pH and temperature for biosurfactant production were pH 6.0 and $30^{\circ}C$, respectively. Furthermore, most biosurfactans were produced during the exponential growth phase, and this fact indicated that the biosurfactans production was growth-associated. The biosurfactant showed the good emulsification activities on various emulsifying substrates such as bunker A, paraffin, corn oil which are used widely in industries.

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Study on the Stability of Emulsion Stabilized with Polyoxyethylene Dodecyl Ethers (폴리옥시에틸렌 도데실 에테르 유체로된 유화계의 안정도에 관한 연구)

  • 이충남
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.11 no.1
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    • pp.21-31
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    • 1985
  • The effect of dispersed phase on the stability of emulsion system with polyoxyethylene dodecyl ethers and their variation of ethylene oxide moles was studied by such methods as interfacial tension measurement, centrifugation and droplet size variation with time. The experiments showed that, in interfacial tension measurement, long chain alkanols into dispersed phaes are more effectively adsorbed onto interface, while long chain alkanes nearly not, and in centrifugation, dispersed phase with alkanols is less separated than that with alkanes. On the other hand, alkanes help more stabilyzing emulsion than alkanols in droplet size variation. And the addition of NaCl or Urea, and variation of E.O. moles have very slight effects on the stability with alkanes than with alkanols. Moreover, the longer carbon chain length is, dispersed phase is more effective on emulsion stability. Supposed from these facts is that more stable emulsion can be made with alkanes which retard molecular diffusion by water solubility decrease rather than alkanols which raise resistance to coalescence by rigid interfacial mixed monolayers formation. In conclusion, the stabilities of these emulsions are proved to be more influenced by molecular diffusion than coalescence.

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초음파 처리 시간 변화에 따른 나노 구조 P3HT층을 가진태양전지의 특성

  • Lee, Yong-Hun;Kim, Dae-Hun;Kim, Tae-Hwan
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.398.2-398.2
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    • 2014
  • 유기태양전지는 낮은 공정 단가, 저온공정 및 기계적 유연성과 같은 다양한 장점을 지니고 있어서 실리콘 기반의 태양전지를 대체하기 위해서 많은 연구가 진행되고 있다. 유기태양전지는 실리콘 기반의 태양전지에 비해서 낮은 광전변환효율을가지고 있기 때문에 효율을 높이기 위한 다양한 연구가 진행되고 있다. 그 중에서 엑시톤 분리 효율을 높이기 위한 방안으로 나노 구조가 많이 연구되고 있다. 하지만 나노 구조를 제작하기 위해서는 식각 과정을 거치거나, 금속 템플레이트를 사용하여 공정상 복잡하고 어려움을 갖는다. 본 연구에서는 간단한 용액 공정을 이용하여 초음파 처리시간 변화에 따른 나노 구조를 가지는 광활성층을 제작하였다. 전자주게 물질인 P3HT를 혼합 용매에 녹여서 초음파 처리를 통해서 나노 구조를 제작하였고, 초음파 처리 시간에 따른 구조의 변화를 광류미네에센스 측정과 원자간 힘 현미경으로 관찰하였다. 나노 구조를 가지는 태양 전지는 엑시톤을 분리할 수 있는 전자주게와 전자받게의 계면이 증가함으로 엑시톤 분리 효율이 향상되는 장점을 가진다. 초음파 처리 사긴 변화에 따른 나노 구조 P3HT 층을 가진 태양전지의 전류밀도-전압 측정을 통해 효율의 변화를 비교하였다. 15분 동안 초음파 처리를 하였을 때, 가장 높은 효율을 가지는 것을 확인할 수 있었고, 나노 구조를 가지지 않는 유기태양전지에 비해서 20% 정도 효율이 향상되는 결과를 볼 수 있었다.

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Separation of Xanthorhodopsin from Salinibacter ruber and Its in vitro Reconstruction (Salinibacter ruber로부터 잔토로돕신의 분리와 in vitro에서 재구축)

  • Kong, Min-Kyung;Yim, Joung-Han;Lee, Pyung-Cheon
    • Clean Technology
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    • v.17 no.3
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    • pp.280-282
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    • 2011
  • Capture and conversion of abundant solar energy using biotechnology will be essential for the development of sustainable and future energy. Photosynthesis is used for the production of biofuels such as biohydrogen. In this study, lightharvesting xanthorhodopsin consisting of retinal and salinixanthin was isolated from a photosynthetic microorganism Salinibacter ruber by aqueous two phase extraction. To stabilize the light-harvesting machine, artificial xanthorhodopsin-liposome system was reconstructed to have photoelectron absorption activity.

Recent Research Trends of Mixed Matrix Membranes for CO2 Separation (이산화탄소 분리용 혼합 매질 분리막 최신 연구 동향)

  • Chi, Won Seok;Lee, Jae Hun;Park, Min Su;Kim, Jong Hak
    • Membrane Journal
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    • v.25 no.5
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    • pp.373-384
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    • 2015
  • In the past few decades, polymeric membrane has played an important role in gas separation applications. For the separation of $CO_2$, one of greenhouse gases, high permselectivity, long-term stability and scale-up are needed. However, conventional polymeric membranes have shown a trade-off relation between permeability and selectivity while inorganic materials are highly permeable but expensive. Mixed matrix membranes (MMMs) combining the advantages of both polymeric and inorganic materials have become a possible breakthrough for the next-generation gas separation membranes. The MMMs could be either symmetric or asymmetric but the latter is more preferred to improve the permeance. Important factors influencing the MMM fabrication include homogeneous distribution of inorganic particles and good interfacial contact between inorganic filler and organic matrix. Recently, metal organic frameworks (MOFs) have received much attention as a new class of porous crystalline materials and a potential candidate for $CO_2$ separation. Zeolitic imidazolate frameworks (ZIFs), a sub-branch of MOFs, are the most widely used in MMMs due to small particle size and appropriate pore size for $CO_2$ separation. One of the major issues associated with the incorporation of porous particles in a polymeric membrane is to control the microstructure of the porous particle materials such as particle size, orientation, and boundary conditions etc. In this review, major challenges surrounding MMMs and the strategies to tackle these challenges are given in detail.

Evaluation of Debonding Defects in Railway Concrete Slabs Using Shear Wave Tomography (전단파 토모그래피를 활용한 철도 콘크리트 궤도 슬래브 층분리 결함 평가)

  • Lee, Jin-Wook;Kee, Seong-Hoon;Lee, Kang Seok
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.26 no.3
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    • pp.11-20
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    • 2022
  • The main purpose of this study is to investigate the applicability of the shear wave tomography technology as a non-destructive testing method to evaluate the debonding between the track concrete layer (TCL) and the hydraulically stabilized based course (HSB) of concrete slab tracks for the Korea high-speed railway system. A commercially available multi-channel shear wave measurement device (MIRA) is used to evaluate debonding defects in full-scaled mock-up test specimen that was designed and constructed according to the Rheda 200 system. A part of the mock-up specimen includes two artificial debonding defects with a length and a width of 400mm and thicknesses of 5mm and 10mm, respectively. The tomography images obtained by a MIRA on the surface of the concrete specimens are effective for visualizing the debonding defects in concrete. In this study, a simple image processing method is proposed to suppress the noisy signals reflected from the embedded items (reinforcing steel, precast sleeper, insert, etc.) in TCL, which significantly improves the readability of debonding defects in shear wave tomography images. Results show that debonding maps constructed in this study are effective for visualizing the spatial distribution and the depths of the debondiing defects in the railway concrete slab specimen.