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Magnetization Switching of MTJs with CoFeSiB/Ru/CoFeSiB Free Layers (CoFeSiB/Ru/CoFeSiB 자유층을 갖는 자기터널 접합의 스위칭 자기장)

  • Lee, S.Y.;Lee, S.W.;Rhee, J.R.
    • Journal of the Korean Magnetics Society
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    • v.17 no.3
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    • pp.124-127
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    • 2007
  • Magnetic tunnel junctions (MTJs), which consisted of amorphous CoFeSiB layers, were investigated. The CoFeSiB layers were used to substitute for the traditionally used CoFe and/or NiFe layers with an emphasis given on understanding the effect of the amorphous free layer on the switching characteristics of the MTJs. CoFeSiB has a lower saturation magnetization ($M_s\;:\;560\;emu/cm^3$) and a higher anisotropy constant ($K_u\;:\;2800\;erg/cm^3$) than CoFe and NiFe, respectively. An exchange coupling energy ($J_{ex}$) of $-0.003\;erg/cm^2$ was observed by inserting a 1.0 nm Ru layer in between CoFeSiB layers. In the Si/$SiO_2$/Ta 45/Ru 9.5/IrMn 10/CoFe 7/$AlO_x$/CoFeSiB 7 or CoFeSiB (t)/Ru 1.0/CoFeSiB (7-t)/Ru 60 (in nm) MTJs structure, it was found that the size dependence of the switching field originated in the lower $J_{ex}$ using the experimental and simulation results. The CoFeSiB synthetic antiferromagnet structures were proved to be beneficial for the switching characteristics such as reducing the coercivity ($H_c$) and increasing the sensitivity in micrometer size, even in submicrometer sized elements.

Development of a Dietary Education Program for Korean Young Adults in Single-Person Households (청년 1인가구를 위한 식생활교육 프로그램 개발)

  • Joung, Se Ho;Lee, Jung Woo;Bae, Da Young;Kim, Yoo Kyung
    • Journal of Korean Home Economics Education Association
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    • v.33 no.1
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    • pp.151-167
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    • 2021
  • This study reports on the development of a dietary education program for Korean young adults in single-person households. The 7th National Health and Nutrition Survey (2016-2018) was used to compare and analyze the dietary behavior of single-person households and multi-person households, and an online survey was conducted on 350 young adults (age 19-39 years) living in Seoul. According to the analysis, single-person households had higher rates of breakfast and eating out than multi-person households, and significantly lower average intake of energy and nutrients (p<0.05). In particular, in the case of single-person households, the lower the frequency of cooking at home, the higher the rate of breakfast and the higher the frequency of eating out and delivery food (p<0.05). Based on the survey, a dietary education program for young adults single-person households was developed by applying the DESIGN six-step procedure and social cognitive theory as a conceptual model. The first session consisted of the health and economic benefits of home-cooked meals, the second session of the importance of the breakfast and the effect of exercise in life, the third session of the importance of balanced nutrition and the principles of a healthy diet, the fourth session of food safety and storage, and the fifth session of social dining. Each session was composed of a combination of theoretical lectures to motivate 'more making and eating healthy home-cooked meals' and cooking practice for improving behavioral performance.

MD Simulation Study for Preferred Structure of Glycerol Backbone in 1,2-dioleoyl-sn-glycero-3-phosphocholine (DOPC) Molecule According to Solvent Properties (용매 특성에 따른 1,2-dioleoyl-sn-glycero-3-phosphocholine (DOPC) 분자에서 글리세롤 골격 구조에 대한 MD 시뮬레이션 연구)

  • Yang, Ji-yun;Huh, Eugene;Ahn, Ik-sung;Mhin, Byung-jin
    • Journal of the Korean Chemical Society
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    • v.65 no.3
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    • pp.179-184
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    • 2021
  • In this study, the molecular dynamics simulation of 1,2-dioleoyl-sn-glycero-3-phosphocholine (DOPC) single molecule was conducted by changing the solvent properties in order to investigate the change in the glycerol backbone structure in phospholipids according to the solvent properties. DOPC has three different conformations according to glycerol C1-C2 bond: A(θ3 = trans, θ4 = gauche), B(θ3 = gauche, θ4 = gauche-), C(θ3 = gauche-, θ4 = trans). Changes in the glycerol backbone structure of the DOPC were examined using the solvent's dielectric constant and surface tension constant as variables. As a result, the population of the B structure increased as the dielectric constant increased. The reason is that the solvation energy of the B structure is larger than that of A. In addition, as the surface tension constant increased, the population of the B structure increased because the surface area of B was smaller than that of A. The results of these studies are expected to be used in the study of phospholipid structure in the future.

Environmental and Economic Impact of EV and FCEV Penetration into the Automobile Industry: A CGE Approach (전기 및 수소차 보급 확산의 환경적·경제적 영향분석: 계산가능일반균형모형(CGE)의 적용)

  • Han, Taek-Whan;Lim, Dongsoon;Kim, Jintae
    • Environmental and Resource Economics Review
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    • v.28 no.2
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    • pp.231-276
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    • 2019
  • This paper analyzed the impact of the penetration of EV(electric vehicle) and FCEV(fuel cell electric vehicle) into the automobile industry, using a static CGE approach. There are contrasting view on the economic impact of EV/FCEV penetration: negative economic impact due to shrunken intermediate inputs versus positive impact because of input saving technical progress. Regarding environment, there is no clear consensus whether EV or FCEV will contribute to the reduction of $CO_2$ emissions in Korea. This study attempts to provide an answer to these questions. By giving shocks to the input coefficients of automobile industries and automobile using sectors, as well as to the final demands for energies. we integrated the Bass diffusion model into the CGE framework, The result suggests that the EV penetration has adverse impact on the $CO_2$ emission while the FCEV penetration has positive impact. On the other hand, both EV and FCEV have positive impacts on GDP. When considering automobile manufacturing sectors only, adverse impacts on $CO_2$ are demonstrated both for EV and FCEV. However, since the size of $CO_2$ increase is small, these results does not alter the overall effects.

Evaluation of Toxicity of Heavy Metals and Surfactants Using Vibrio Fischeri and Daphnia Magna (발광박테리아(Vibrio fischeri)와 물벼룩(Daphnia magna)을 이용한 중금속 및 계면활성제의 혼합독성 평가)

  • Paik, Dohyeon;Lee, Narae;Lee, Sangmin;Hong, Sungchul
    • Journal of the Korean Society of Urban Environment
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    • v.18 no.4
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    • pp.429-437
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    • 2018
  • In this study, the mixed toxicity of heavy metals (Cu, Pb, Hg) and surfactants (SLS, ALS) was evaluated by using Vibrio fischeri and Daphnia magna. The sensitivity of ecotoxicity to heavy metals was sensitive to daphnia but the case of surfactants were more sensitive to Vibrio fischeri. Experimental results of Vibrio fischeri show that the toxicity value P(O) was lower than the predicted value P(E), and the antagonistic effect was observed when the heavy metal and the surfactant were mixed. It seems that SLS and ALS, which are anionic surfactants, have anionic form on the hydrophilic head, so that they have an antagonistic effect that they are bonded with heavy metal ion which is a cation type and the actual toxicity is lowered. In Daphnia magna, the results showed that antagonistic, additive and synergistic effects were in order as concentrations increased. As the concentration increases, Daphnia magna, which is highly sensitive to heavy metals, seems to have a synergistic effect with a rapid increase in mortality.

Review on Discontinuum-based Coupled Hydro-Mechanical Analyses for Modelling a Deep Geological Repository for High-Level Radioactive Waste (고준위방사성폐기물 심층처분장 모델링을 위한 불연속체 기반 수리-역학 복합거동 해석기법 현황 분석)

  • Kwon, Saeha;Kim, Kwang-Il;Lee, Changsoo;Kim, Jin-Seop;Min, Ki-Bok
    • Tunnel and Underground Space
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    • v.31 no.5
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    • pp.309-332
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    • 2021
  • Natural barrier systems surrounding the geological repository for the high-level radioactive waste should guarantee the hydraulic performance for preventing or delaying the leakage of radionuclide. In the case of the behavior of a crystalline rock, the hydraulic performance tends to be decided by the existence of discontinuities, so the coupled hydro-mechanical(HM) processes on the discontinuities should be characterized. The discontinuum modelling can describe the complicated behavior of discontinuities including creation, propagation, deformation and slip, so it is appropriate to model the behavior of a crystalline rock. This paper investigated the coupled HM processes in discontinuum modelling such as UDEC, 3DEC, PFC, DDA, FRACOD and TOUGH-UDEC. Block-based discontinuum methods tend to describe the HM processes based on the fluid flow through the discontinuities, and some methods are combined with another numerical tool specialized in hydraulic analysis. Particle-based discontinuum modelling describes the overall HM processes based on the fluid flow among the particles. The discontinuum methods that are currently available have limitations: exclusive simulations for two-dimension, low hydraulic simulation efficiency, fracture-dominated fluid flow and simplified hydraulic analysis, so it could be improper to the modelling the geological repository. Based on the concepts of various discontinuum modelling compiled in this paper, the advanced numerical tools for describing the accurate coupled HM processes of the deep geological repository should be developed.

Durability Test of PEMFC Membrane by the Combination of Chemical/Mechanical Degradation (화학적/기계적 열화 병행방법에 의한 PEMFC 고분자막 내구성 평가)

  • Lim, Daehyeon;Oh, Sohyeong;Jung, Sunggi;Jeong, Jihong;Park, Kwonpil
    • Korean Chemical Engineering Research
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    • v.59 no.3
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    • pp.339-344
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    • 2021
  • In order to improve the PEMFC (Proton Exchange Membrane Fuel Cell) durability, it is important to accurately evaluate the durability of the membrane in a short time. Recently, DOE (Department of Energy) reported a protocol that combines the chemical and mechanical durability of membranes to evaluate them effectively. This protocol applies chemical/mechanical deterioration to the membrane by repeating wet/dry while OCV (Open Circuit Voltage) holding. The problem of this protocol is that it is highly affected by electrode degradation due to change cycles in OCV and that the evaluation time is long. By using oxygen instead of air as the cathode gas while leaving the other conditions of the DOE protocol as it is, the durability evaluation time could be reduced from 408 hours to 144 hours. By reducing the number of voltage change cycles to 1/3, the electrode degradation due to the voltage change cycle was reduced to 1/12 when oxygen was used compared to air at the end, thereby enabling more accurate evaluation of polymer membrane durability.

The Relationship Analysis of the Korean Science Curriculum with the Chemistry Domains of the 8th Grade TIMSS 2019 (TIMSS 2019의 8학년 화학 영역과 우리나라 과학 교육과정의 비교 분석)

  • Kim, Hyun-Kyung
    • Journal of the Korean Chemical Society
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    • v.64 no.6
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    • pp.371-378
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    • 2020
  • The purpose of this study is to analyze the relationship between the eight topics in TIMSS 2019 8th grade chemistry domains and the Korea 2009 Revised Science Curriculum and the 2015 Revised Science Curriculum. For this purpose, four elementary and four secondary teachers participated in physics, chemistry, biology and earth science majors, and two science education experts participated in analyzing in which grades the content elements of the TIMSS 2019 science framework are covered in the Korean science curriculum. The study also analyzed whether the content of the Korean science curriculum matches the 246 items of 8th grade in the TIMSS 2019 assessment and reflects in which grades the eight topics are covered. The results of this study are as follows. First, among the TIMSS 2019 evaluation topics, topics not covered at all in the Korean middle school curriculum were periodic table, matter and energy in chemical reactions, the role of electrons in chemical bonds. Second, the topic of "the periodic table as an organizing principle for the known elements" needs to be introduced in the Korean middle school curriculum, and topics such as "familiar exothermic and endothermic reactions" and "factors affecting the reaction rates" need to be discussed in consideration of the flow of international curricula. Third, the next science curriculum should be structured so that the sequence of chemistry contents and scope, especially core concepts to be included in the elementary, secondary, and higher education curriculum is linked to continuity.

Estimation and Analysis of Wave Spectrum Parameter using HeMOSU-2 Observation Data (HeMOSU-2 관측 자료를 이용한 파랑 스펙트럼 매개변수 추정 및 분석)

  • Lee, Uk-Jae;Ko, Dong-Hui;Kim, Ji-Young;Cho, Hong-Yeon
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.33 no.6
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    • pp.217-225
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    • 2021
  • In this study, wave spectrum data were calculated using the water surface elevation data observed at 5Hz intervals from the HeMOSU-2 meteorological tower installed on the west coast of Korea, and wave parameters were estimated using wave spectrum data. For all significant wave height ranges, the peak enhancement parameter (γopt) of the JONSWAP spectrum and the scale parameter (α) and shape parameter (β) of the modify BM spectrum were estimated based on the observed spectrum, and the distribution of each parameter was confirmed. As a result of the analysis, the peak enhancement parameter (γopt) of the JONSWAP spectrum was calculated to be 1.27, which is very low compared to the previously proposed 3.3. And in the range of all significant wave heights, the distribution of the peak enhancement parameter (γopt) was shown as a combined distribution of probability mass function (PMF) and probability density function (PDF). In addition, the scale parameter (α) and shape parameter (β) of the modify BM spectrum were estimated to be [0.245, -1.278], which are lower than the existing [0.300, -1.098], and the result of the linear correlation analysis between the two parameters was β = -3.86α.

Freeze-Thaw Resistance of Alkali Activated Ternary Blended Cement Incorporated with Ferronickel Slag (알칼리 활성화제를 첨가한 페로니켈슬래그 혼입 삼성분계 콘크리트의 동결융해 저항성)

  • Cho, Won-Jung;Park, Kwang-Pil;Ann, Ki-Yong
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.10 no.2
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    • pp.159-167
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    • 2022
  • The present study assessed the micro structure and durability characteristics of ternary blended cement with different types of alkali activators. Ground granulated blast furnace slag(GGBS) and ferronickel slag(FNS) was replaced until 50 % of the weight of cement. In addition, potassuim hydroxide and sodium hydroxide were used for comparing the properties of different type of alkali activator. Ternary blended cement with alkali activators showed higher peak portlandite peak than that of OPC(Ordinary Portlande Cement) and non activated ternary blended cement. Also, there was no new hydration products in ternary blended cement or/and alkali activators. Based on the mercury intrustion porosimetry(MIP) test result, ternary blended cement increased macro pore while alkali activated ternary blended cement modified pore structure and increased microp pore as compared to OPC as control. Combination with alkali activators is desirable to enhance the compressive strength and freeze thaw resistance.