• Title/Summary/Keyword: 감마분광분석

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Coincidence Summing Corrections in HPGe Gamma Ray Spectrometry in Marinelli-beakers with Efficiency (효율을 적용한 마리넬리 비이커에서 HPGe 감마선 분광분석법의 동시합성보정)

  • Jang, Eun-Sung;Lee, Hyo-Yeong
    • Journal of the Korean Society of Radiology
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    • v.12 no.5
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    • pp.557-563
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    • 2018
  • Coincidence summing correction effects are known to be greater as the efficiency of the detector increases and as the distance between the source and the detector increases. A point source($^{60}Co$) was used to vary the distance in the direction of the detector's center axis and in the radial direction to obtain the P/T ratio for Coincidence summing correction calibration. In this study, values for coincidence summing corrected calibration of the values in the central and radial directions were applied to the mixed volume source(450 ml CRM source) to compare the overall peak efficiency change according to P/T with Geant4. In addition, the efficiency obtained from the mapping method is applied to the seaweed, a marine sample, and the compatibility of the P/T ratio with the detector and sample very dose together. The efficiency corrected to 1,836 keV was applied to the energy zone affected by the efficiency of 500 keV and the relative error of the measured and corrected values was well matcched by the 3.2 % peak efficiency correction. As with 450 mL CRM source, the larger the volume, the lower the P/T ratio was by ${\pm}5%$. This is due to the increased scattering of gamma-rays emitted as the source becomes farther away from the detector, and this change in P/T has been confirmed to affect the Coincidence summing corrected peak efficiency.

Synthesis of Electroactive PAAc/PVA/PEG Hydrogel Soft Actuator by Radiation Processing and Their Dynamic Characteristics (방사선을 이용한 전기 활성 PAAc/PVA/PEG 하이드로겔 소프트 액추에이터의 제조 및 구동 특성 분석)

  • Shin, Yerin;Kim, So Yeon
    • Applied Chemistry for Engineering
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    • v.30 no.6
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    • pp.698-706
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    • 2019
  • Over the last few decades, there have been a lot of efforts to develop soft actuators, which can be external stimuli-responsive and applied to the human body. In order to fabricate medical soft actuators with a dynamic precision control, the 3D crosslinked poly(acrylic acid) (PAAc)/poly(vinyl alcohol) (PVA)/poly(ethylene glycol) (PEG) hydrogels were synthesized in this study by using a radiation technique without noxious chemical additives or initiators. After irradiation, all hydrogels showed high gel fraction over 75% and the ATR-FTIR spectra indicated that PAAc/PVA/PEG hydrogels were successfully synthesized. In addition, the gel fraction, equilibrium water content, and compressive strength were measured to determine the change in physical properties of PAAc/PVA/PEG hydrogels according to the irradiation dose and content ratio of constituents. As the irradiation dose and amount of poly(ethylene glycol) diacrylate (PEGDA) increased, the PAAc/PVA/PEG hydrogels showed a high crosslinking density and mechanical strength. It was also confirmed that PAAc/PVA/PEG hydrogels responded to electrical stimulation even at a low voltage of 3 V. The bending behavior of hydrogels under an electric field can be controlled by changing the crosslinking density, ionic group content, applied voltage, and ionic strength of swelling solution.

Modulatory Effect of Four Azulene Derivatives from the Fruiting Bodies of Lactarius hatsudake on Interferon-$\gamma$ Production (젖버섯아재비 자실체로부터 분리한 Azulene계 화합물이 Interferon-$\gamma$ 생성에 미치는 영향)

  • Xu, Guang Hua;Kim, Jae-Wha;Li, Gao;Yoo, Ick-Dong
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.36 no.2
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    • pp.151-156
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    • 2010
  • Investigation of secondary bioactive metabolites from the fruiting bodies of Lactarius hatsudake led to the isolation of four azulene derivatives by means of repeated column chromatography and preparative HPLC, and they were identified as 1-formyl-4-methyl-7-isopropyl azulene (1), lactaroviolin (2), 4-methyl-7-isopropyl-azulene-1-carboxylic acid (3), and 1-formyl-4-methyl-7-(1-hydroxy-1-methylethyl) azulene (4) by their physico-chemical properties and spectroscopic analysis. The isolated compounds were evaluated for the effects on modulation of cytokines in natural killer cell line (NK92 cells). Compounds 1 and 4 strongly inhibited IFN-$\gamma$ production in a dose-dependent manner, corresponding to 101.3 % and 92.7 % inhibition at 400 ${\mu}M$, and 11.9 % and 24.1 % at 100 ${\mu}M$, respectively, whereas compounds 2 and 3 showed weak inhibitory effect on INF-$\gamma$ production, corresponding to 45.9 % and 18.0 % inhibition at 400 ${\mu}M$.

Method development for quantitative analysis of naturally occurring radioactive nuclides in building materials (실내 건축자재 중 천연방사성핵종의 정량분석법 연구)

  • Lim, Jong-Myoung;Lee, Hoon;Kim, Chang-Jong;Jang, Mee;Park, Ji-Young;Chung, Kun Ho
    • Analytical Science and Technology
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    • v.30 no.5
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    • pp.252-261
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    • 2017
  • Naturally occurring radioactive materials (NORMs) increase radiation exposure to the public as these materials are concentrated through artificial manufacturing processes by human activities. This study focuses on the development of a method for the quantitative analysis of $^{232}Th$, $^{235}U$, and $^{238}U$ in building materials. The accuracy and precision of inductively coupled plasma mass spectrometry (ICP-MS) for determination of digestion processes was evaluated for certified reference materials (CRMs) digested using various mixed acid (e.g., aqua regia, hydrofluoric acid, and perchloric acid) digestions and a $LiBO_2$ fusion method. The method validation results reveal that a $LiBO_2$ fusion and $Fe(OH)_3$ co-precipitation should be applied as the optimal sample digestion process for the quantitative analysis of radionuclides in building materials. The radioactivity of $^{232}Th$, $^{235}U$, and $^{238}U$ in a total of 51 building material (e.g., board, brick, cement, paint, tile, and wall paper) samples was quantitatively analyzed using an established process. Finally, the values of $^{238}U$ and $^{232}Th$ radioactivity were comprehensively compared with those from the indirect method using ${\gamma}$-spectrometry.

BLR Density Variations of the Seyfert 1 Galaxies NGC 4151 and NGC 5548 (Seyfert 1 은하 NGC 4151, NGC 5548의 BLR 밀도 변화)

  • Son, Dong-Hoon;Hyung, Siek
    • Journal of the Korean earth science society
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    • v.25 no.6
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    • pp.495-501
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    • 2004
  • Using numerous ground-based or space-based telescopes by many astronomers, AGN spectroscopic monitoring campaigns have been carried out over many years to study the variability of continua and emission lines. We investigate the SWP IUE spectra of a large aperture configuration for the Seyfert 1 galaxies NGC 4151 and NGC 5548. We estimate the BLR electron number densities and their variation from the line ratios of C III] 1909 to Si III] 1892. With the ratios of C IV 1550 to C III] 1909 which give us the information on the ionization parameter of BLR, we try to find the physical conditions of the BLR and activities of he super massive black hole surroundings. The BLR density variations scale as 4 and 8 for NGC 4151 and NGC 5548, respectively. Based on the BLR size and C III] line profiles, we found both black hole masses as about $10^7$ $M_{\odot}$.

Automatic Determination of the Energy Pulse-height Relationship in NaI(TI) Spectra (NaI(T1) 검출기 스펙트럼의 에너지-채널 관계 자동결정)

  • Lee, M.S.
    • Journal of Radiation Protection and Research
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    • v.22 no.3
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    • pp.143-151
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    • 1997
  • As the pulse heights from a NaI(Tl) detector vary with the temperature of the measuring environment a significant change in temperature may affect the energy calibration of the spectrometer. The auto-adjustment of the channel corresponding to a pulse heights can be achieved by introducing an external reference source to compensate the temperature dependency of pulse heights, but unfavorable increases of the Compton continuum are caused due to the external source. In this study, the total absorption peaks dominant in the typical environmental gamma spectrum-239 keV from $^{212}Pb$, 351 keV from $^{214}Pb$, 1460 keV from $^{40}K$ and 2614 keV from $^{208}Tl$ for examples - were used as reference in the correction of energy calibration. With these peaks, the program to calibrate the energy of the s spectrum was developed using Microsoft Visual Basic language. The program developed here was applied to the environmental spectra measured at intervals of 30 minutes in the temperature range of from $-20^{\circ}C$ to $10^{\circ}C$ to demonstrate the validity and applicability. As a result of the test, the correction scheme appeared to be effective in the temperature changes encountered in the usual environment.

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A Study on the Environmental Radioactive Strontium Analysis (환경중 방사성 스트론튬 분석 방법 연구)

  • Lee, Goung-Jin;Hwang, Jung-Lae;Chung, Woon-Kwan
    • Journal of Radiation Protection and Research
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    • v.24 no.3
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    • pp.155-160
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    • 1999
  • In the natural, there exist several kinds of radioactive isotopes. From atmospheric weapon tests and then some isotopes are naturally radioactivity above all things, nuclear power plant operation and man-made radioactive isotopes concern steadily growing in the environment. During the fission process of nuclear weapon tests and nuclear power plant operation, more than 200 radioactive isotopes are generated. Among them, $^{90}Sr$ and $^{137}Cs$ has been regarded as very important isotopes due to characteristics. In this paper, a quantitative analysis method of environment low level $^{90}Sr$ is studied. Radioactivity level of the environmental $^{90}Sr$ is very low, and it emits continuous beta spectrum, and $^{90}Sr$ exists together with $^{89}Sr$, $^{90}Y$ and other radioactive isotopes. It very difficult to make the quantitative analysis of $^{90}Sr$. For the analysis of low level radioactive strontium, enrich and chemical separation of strontium from the other radioactive isotopes are needed. For the estimation of strontium recovery ratio, so called SGAT(Strontium Gravimetric Analysis Technique) was generally used among the domestic research groups, and chemical procedures were developed appropriation for the SGAT, Recently, by using ICP(Inductively Coupled atomic Plasma emission spectrophotometer), amounts of stable atoms can be measured easily and accurately to the extend of ppm or ppb. In this paper, new chemical procedures are developed to exploits the ICP technique. New developed method has simpler chemical treatment procedures and then it gives more accurate results compared with the traditional SGAT.

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Cooling Time Determination of Spent Nuclear Fuel by Detection of Activity Ratio $^{l44}Ce /^{l37}Cs$ (방사능비 $^{l44}Ce /^{l37}Cs$ 검출에 의한 사용후핵연료 냉각기간 결정)

  • Lee, Young-Gil;Eom, Sung-Ho;Ro, Seung-Gy
    • Nuclear Engineering and Technology
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    • v.25 no.2
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    • pp.237-247
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    • 1993
  • Activity ratio of two radioactive primary fission products which had sufficiently different half-lives was expressed as functions of cooling time and irradiation histories in which average burnup, irradiation time, cycle interval time and the dominant fissile material of the spent fuel were included. The gamma-ray spectra of 36 samples from 6 spent PWR fuel assemblies irradiated in Kori unit-1 reactor were obtained by a spectrometric system equipped with a high purity germanium gamma-ray detector. Activity ratio $^{l44}$Ce $^{l37}$Cs, analyzed from each spectrum, was used for the calculation of cooling time. The results show that the radioactive fission products $^{l44}$Ce and $^{l37}$Cs are considered as useful monitors for cooling time determination because the estimated cooling time by detection of activity ratio $^{l44}$Ce $^{l37}$Cs agreed well with the operator declared cooling time within relative difference of $\pm$5 % despite the low counting rate of the gamma-ray of $^{l44}$Ce (about 10$^{-3}$ count per second). For the samples with several different irradiation histories, the determined cooling time by modeled irradiation history showed good agreement with that by known irradiation history within time difference of $\pm$0.5 year. From this result, it would be expected to be possible to estimate reliably the cooling time of spent nuclear fuel without the exact information about irradiation history. The feasibility study on identification of and/or sorting out spent nuclear fuel by applying the technique for cooling time determination was also performed and the result shows that the detection of activity ratio $^{l44}$Ce $^{l37}$Cs by gamma-ray spectrometry would be usefully applicable to certify spent nuclear fuel for the purpose of safeguards and management in a facility in which the samples dismantled or cut from spent fuel assemblies are treated, such as the post irradiation examination facility.mination facility.

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The Analysis of radioactivity Concentration in drainage when using a radioactive Iodine (방사성옥소 사용 시 배수 중 방사능농도 분석)

  • Lee, Kyung-Jae;Sul, Jin-Hyung;Park, Young-Jae;Lee, In-Won
    • The Korean Journal of Nuclear Medicine Technology
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    • v.22 no.1
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    • pp.28-34
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    • 2018
  • Purpose With regard to the use of radioiodine in domestic medical institution, the case of exceeding the allowance of nuclear safety Act about radioactive concentration in drainage was found. Through understanding the cause of exceeding case and analyzing radioactive concentration in drainage, evaluating the relationship of the public waters in surroundings and usefulness. Materials and Methods From November 1, 2014 to April 30th, 2015, the research is aiming at domestic twenty hospitals for six months. By using a HPGe gamma-ray spectrometer(Canberra DSA-1000) and GENIE-2000 Analysis software for comparative analysis, measuring a radioactive concentration of radioiodine in drainage. Consequently, we confirm the excess of radioactive concentration of radioiodine in seven medical institutions. Results Conducting a survey of twenty hospitals and average radioactive concentration of radioiodine in drainage appears $42,100Bq/m^3$. The features of domestic hospitals where show a high radioactive concentration are a number of medical treatment patient when using radioactive iodine and the absence of private rest room. During I-131 whole body scan, the pretreatment procedure of urinating is considered emission of residual Iodine. In public waters, the cause of exceeding detect on radioactive concentration in drainage suppose a diagnostic radioactive iodine. Conclusion We confirm the importance of enhanced education, providing a safety control instructions and installing a private rest rooms for patients who injected a low capacity radioiodine. Also, constructing institutional and legal management system is considered about the Emission management standard in drainage.

Natural Radioactivity of Soils by Bed Rocks Distributed in the Keum River Area (금강유역 기반암 토양의 자연방사능 특성)

  • Lee, Kil-Yong;Yoon, Yoon-Yeol;Cho, Soo-Young;Lee, Jung-Hwa;Lee, Jin-Soo;Koh, Kyung-Seok;Kim, Yong-Je
    • Journal of Soil and Groundwater Environment
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    • v.14 no.2
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    • pp.10-16
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    • 2009
  • Characteristics of natural radioactivity were investigated for soils collected from seven sites of different bed rocks distributed in the Keum River area of Korea by the use of a Gamma-ray spectrometry. Specific activity (SA) and SA ratio (SAR) of typical naturally occurring radioactive nuclide such as $^{226}$Ra, $^{228}$Ac and $^{40}$K were determined for the soil samples. The SA values of $^{226}$Ra, $^{228}$Ac and $^{40}$K in 41 soils of 7 sites are 26.7-485 (74.2 ${\pm}$ 72.2), 30.9-157 (90.7 ${\pm}$ 32.7) and 203-1558 (990 ${\pm}$ 203) Bq/kg, respectively. The SA of $^{226}$Ra has very different values by the soils and the sites. Especially the SA of $^{226}$Ra in a soil sample of Ogcheon site is 485 Bq/kg while most SA of 41 soil samples are < 100 Bq/kg. SA of $^{228}$Ac has a little different values with the soils and sites, however the SA of $^{40}$K has almost constant values in all soil samples. The SAR values of $^{26}$Ra/$^{228}$Ac, $^{226}$Ra/$^{40}$K and $^{228}$Ac/$^{40}$K in 41 soils of 7 sites are 0.343-6.11 (0.865 ${\pm}$ 0.883), 0.0258-0.759 (0.0814 ${\pm}$ 0.1l17) and 0.0373-0.178 (0.0945 ${\pm}$ 0.0373), respectively. The SARs of $^{226}$Ra/$^{228}$Ac and $^{226}$Ra/$^{40}$K have very different values by the soils and the sites, however the SAR of $^{228}$Ac/$^{40}$K has a little difference by the soil and sites.