• Journal of the Korean Institute of Gas
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• v.24 no.3
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• pp.33-39
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• 2020

In general, in a batch reaction process in which products are made using flammable liquids, splash filling is used to clean the walls of the reactor by spraying flammable liquids, which are raw materials used for product, during cleaning of the reactor after work. During this process, mist of flammable liquid is generated, the lower limit of explosion is lowered, and fire·explosion may occur due to discharges caused by various types of complex charges, such as flow charge, collision charge, and ejection charge. Therefore, based on the recent accident case, to identify the risk when working in the form of splash filling with toluene in a batch process and perform an explosion impact analysis using the TNT equivalent method After that, we will analyze the accident results and suggest preventive measures such as constant purge system, improvement of cleaning method, and use of tantalum to prevent such accident.

• Journal of the Korean Institute of Gas
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• v.28 no.1
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• pp.11-18
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• 2024

If flammable liquid leaks, vapor evaporated from the pool can cause poisoning or suffocation to workers, leading to secondary accidents such as fires and explosions. To prevent such damage, ventilation facilities shall be installed when designing indoor workplaces. At this time, the behavior varies depending on the characteristics of the leaked chemical, so it is necessary to select a suitable vent location according to the material. Therefore, 3D CFD simulations were introduced to derive optimal vent position and ventilation efficiency was quantitatively evaluated by vent position. At this time, assuming a situation in which flammable liquids leak at indoor workplaces to form pools, the concentration of vapor evaporated from pools was compared to derive the optimal vent position. As a result of research on toluene with high vapor density, ventilation efficiency was confirmed to be the highest at the upper supply-lower exhaust, and it is judged that introducing it can achieve about 3.7 times ventilation effect at the same maintenance cost. Through this study, it is expected that the workplace will be able to secure workers' safety by applying simulation results and installing ventilation ports.

• Korean Chemical Engineering Research
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• v.50 no.4
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• pp.702-707
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• 2012

During the last few decades, toxic chemicals used in various industries have caused global pollution and the side products such as carbon dioxide and methane gas have contributed to global warming. Thus, it is desirable to develop new alternative solvents. It is well known that ionic liquids display a variety of environmentally friendly physical properties: nonvolatile, nonflammable, wide electrochemical windows, high inherent conductivities, wide thermal operating ranges, chemically inert, and limited miscibilities with organic solvents. Because of these characteristics, ionic liquids are promising candidates as solvents for synthetic chemistries, catalysis, and gas separations. In this study, we synthesized morpholiunium salts as N-ethyl-N-methylmorpholine Bromide, N-butyl-N-methylmorpholine Bromide, N-octyl-N-methylmorpholine Bromide, N-ethyl-N-methylmorpholine Tetrafluoroborate, N-butyl-N-methylmorpholine Tetrafluoroborate, N-octyl-N-methylmorpholine Tetrafluoroborate, N-ethyl-N-methylmorpholine Hexafluorophosphate, N-butyl-N-methylmorpholine Hexafluorophosphate, and N-octyl-N-methylmorpholine Hexafluorophosphate. The melting points, decomposition temperatures and electrochemical stabilities of the salts were measured by DSC, TGA, and CV, respectively. The salts with halide anion showed high melting points ($150{\sim}200^{\circ}C$), low decomposition temperatures ($200{\sim}230^{\circ}C$), narrow electrochemical stabilities (3.4~3.6 V). The synthesized salts with inorganic anions, on the other hand, presented low melting point ($50{\sim}110^{\circ}C$), high decomposition temperatures ($250{\sim}380^{\circ}C$), wide electrochemical stabilities (6.1~6.3 V). We also found that the properties depend on the length of the carbon chain.

• Journal of Climate Change Research
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• v.2 no.3
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• pp.203-219
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• 2011

Greenhouse gas(GHG) inventories were reported recently in various fields. It, however, has been rarely to mention about the accuracy and reliability of the GHG inventory results. Some reliable assessment methods were introduced to judge the accuracy of the GHG inventory results. It is, hence, critical to develop an evaluation methodology. This project was designed 1) to develop evaluation methodology for reliability of inventory results by GHG-CAPSS, 2) to check the feasibility of the developed evaluation methodology as a result of applying this methodology to two emission sources: liquid fossil fuel and landfill, and 3) to construct the technical roadmap for future role of GHG-CAPSS. Qualitative and quantitative assessment methodologies were developed to check the reliability and accuracy of the inventory results. Qualitative assessment methodology was designed to evaluate the accuracy and reliability of estimation methods of GHG emissions from emission and sink sources, activity data, emission factor, and quality management schemes of inventory results. On the other hand, quantitative assessment methodology was based on the uncertainty assessment of emission results. According to the results of applying the above evaluation methodologies to two emission sources, those seem to be working properly. However, it is necessary to develop source-specific rating systems because emission and sink sources exhibit source-specific characteristics of GHG emissions and sinks.

• 한국신재생에너지학회:학술대회논문집
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• 2010.06a
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• pp.225.2-225.2
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• 2010

전 세계는 온실 가스의 방출을 줄이기 위하여 기존의 화석연료를 대체할 수 있는 에너지를 찾기 위해 연구개발에 박차를 가하고 있다. 이러한 계속적인 연구에서, 전 세계의 국가들은 태양열, 풍력, 지열 및 수소에너지와 같이 화석연료를 대체할 다양한 가스를 조사해왔다. 대체에너지 중 수소 연료는 실제로 배출가스가 없기 때문에 가장 유망한 대안이라고 할 수 있다. 연료전지자동차용 연료로 수소를 사용하기 위해서는 저장합금, 액체 및 압축 상태로 저장할 수 있다. 이 중 세계 대부분의 자동차 메이커 들은 수소를 압축하는 방식을 채택하고 있으며, 주행거리를 확보하기 위하여 고압상태로 수소가스를 저장하는 방식을 사용한다. 수소연료전지 자동차용으로 고압의 수소를 저장할 수 있고, 자동차에 탑재할 수 있도록 가벼운 용기의 개발이 진행되고 있다. 이 중 Type3와 Type4 형태의 용기가 시범적으로 적용되고 있으며, 이러한 용기의 안전성을 확보하기 위한 기준들이 국 내외에서 개발되고 있다. 현재 국제기준 중 UN ECE의 WG.29에서 선진국들을 중심으로 수소연료전지 자동차용 용기의 안전성 평가를 위한 기준을 개발하고 있다. 본 연구에서는 ISO. 15869의 기술기준에 대한 안전성 분석과 미국의 SAE J2579의 기술 보고서에서 제시한 새로운 개념의 안전성 평가 기법을 기준으로 제정되고 있는 UN ECE WG.29의 draft초안을 비교하고, 향후 수소연료전지 자동차용 용기를 위한 국내기준의 방향을 제시하고자 한다.

• Journal of the Korean Institute of Gas
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• v.8 no.3 s.24
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• pp.8-15
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• 2004

This paper presents von Mises stress, deformation, and rotating distortion moment characteristics of inner tank bottom plate as a function of a cryogenic temperature difference along the radial distance from the center area to the corner one. The calculated results show that the filling level of LNG at the beginning of the cool-down process is very important for the design safety analysis of the inner tank. Obviously the thermal loading by a temperature difference between the LNG vapor gas of $-80^{\circ}C$ and a LNG temperature of $-162^{\circ}C$ affects to the thermal related characteristics of the bottom plates and annular one. From the computed results, the temperature difference by a vapor gas and liquid of LNG may lead to the thermal instability of the bottom plate. This phenomenon may cause the system failure of an inner tank.

• Journal of the Korean Society of Propulsion Engineers
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• v.14 no.4
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• pp.10-15
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• 2010

Light gas guns have a large number of applications in various fields of engineering. A two-stage light-gas gun can produce an extremely high pressure in a very short interval of time. In general, the two-stage light-gas gun is made up of a high pressure tube, a compression tube and a launch tube, each stage being separated by diaphragms. This can be employed efficiently in the application of ultra-high pressure liquid jets. In the present study, experiments are carried out to investigate the projectile velocity and pressure behavior in the tubes according to the pressure changes at the frist diaphragm opening. In the present study result was found that the rupture pressure of the first diaphragm has a dominant influence on piston acceleration.

• Journal of the Korean Society of Propulsion Engineers
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• v.14 no.4
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• pp.1-9
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• 2010

Fuel shutoff valve of a gas generator controls propellant mass flowrate of a rocket engine, by using pilot pressure and spring force. The developing fuel shutoff valve can be self sustained even though pilot pressure is removed in an actuator. Therefore, it is necessary to analyze the characteristics of the forces with respect to the opening and closing of the valve in order to evaluate its performance. In light of this, the valve has been designed to adjust the control pressure for the opening of the poppet and to determine the working fluid pressure at which the valve starts to close. This paper also has been designed dynamic model using the AMESim and predicted flow coefficient of the valve by Fluent CFD analysis. Various results from the prediction and the analysis have been compared with experiments. Finally, dynamic characteristics of the valve have been verified with experimental results.

• Journal of the Korean Institute of Gas
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• v.20 no.5
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• pp.1-8
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• 2016

The autoignition temperature (AIT) of a substance is the lowest temperature at which the vapor ignites spontaneously from the heat of the environment. The AIT is important index for the safe handling of flammable liquids which constitute the solvent mixtures in the process. This study measured the AITs of n-butanol+p-xylene mixture by using ASTM E659 apparatus. The AITs of n-butanol and p-xylene which constituted binary system were $340^{\circ}C$ and $557^{\circ}C$, respectively. The experimental AITs of n-butanol+p-xylene mixture were a good agreement with the calculated AITs by the proposed equations with a few A.A.D.(average absolute deviation).

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• v.y2005m4
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• pp.123-127
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• 2005

LRE(liquid rocket engine) performance design code with several modules for each engine component has been developed for a preliminary design purpose. Thrust chamber, non-cryogenic centrifugal pump, single stage axial impulse turbine, gas generator and exhaust pipe for extra thrust have been considered. For simplicity, pump exit pressures are fixed, which eliminates pressure balancing problem between thrust chamber and turbopump unit. In this paper, calculated performance parameters with system flow charts and the design methodologies for each component are briefly presented and the results are compared with tile real engine specification.