• Title/Summary/Keyword: [p, q]-order

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Adsorption Properties of Cadmium onto Granite Soil and Calcium Sand (화강풍화토 및 칼슘샌드에 의한 카드뮴 흡착특성 연구)

  • Lee, Myoung-Eun;Kwon, Min-Seok;Ahn, Yong-Tae;Chung, Jae-Woo
    • Journal of the Korea Organic Resources Recycling Association
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    • v.22 no.2
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    • pp.27-34
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    • 2014
  • Kinetic and isotherm properties of the cadmium adsorption onto calcium sand and granite soil were evaluated by batch experiments. The pHs of calcium sand and granite soil were 9.51 and 6.33, respectively, showing that the precipitation of heavy metals can be occurred due to the increase of pH when the calcium sand is used as an adsorbent. The pseudo-second-order model described the adsorption kinetics satisfactory with correlation coefficients over 0.999. The equilibrium adsorption capacities of calcium sand and granite soil were 2.10 and 2.16 mg/g, respectively. The adsorption isotherm followed the Freundlich isotherm model, indicating the cadmium adsorbed onto the heterogeneous surfaces of adsorbents.

Effects of Isokinetic Strength Exercise of the Hemiparetic Knee Joint on Lower Extremity Sensorimotor and Gait Functions in Patients With Chronic Stroke: Open Kinetic Chain Versus Closed Kinetic Chain

  • An, Chang-man;Roh, Jung-suk
    • Physical Therapy Korea
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    • v.26 no.2
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    • pp.49-60
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    • 2019
  • Background: After stroke, in order to improve gait function, it is necessary to increase the muscle strength and to enhance the propriocetive function of the lower extremity. Objects: This study aimed to compare the effects of open kinetic chain (OKC) versus closed kinetic chain (CKC) isokinetic exercise of the hemiparetic knee using the isokinetic equipment on lower extremity sensorimotor function and gait ability in patients with chronic stroke. Methods: Thirty participants with chronic hemiplegia (> 6 months post-stroke) were randomly divided into 2 equal groups: CKC group and OKC group. Patients from both groups attended conventional physiotherapy sessions 3 times a week for 6 weeks. Additionally, subjects from the CKC group performed isokinetic exercise using the CKC attachment, while those from the OKC group performed isokinetic exercise using the OKC attachment. The isokinetic knee and ankle muscles strength, position sense of the knee joint, and spatiotemporal gait parameters were measured before and after interventions. Results: The knee muscles peak torque/body weight (PT/BW) and hamstring/quadriceps (H/Q) ratio significantly increased in both groups (p<.01). In particular, ankle plantarflexors PT/BW, position sense of the knee, gait velocity, and spatial gait symmetry significantly improved in the CKC group (p<.01, p<.05, p<.01, and p<.01, respectively). Conclusion: CKC isokinetic exercise can be an effective therapeutic intervention for the improvement of sensorimotor function of the lower extremity and gait functions, such as gait velocity and symmetry. CKC position in isokinetic strength training is effective to improve functional ability in patients with chronic stroke.

Chromium(VI) Removal from Aqueous Solution using Acrylic Ion Exchange Fiber (아크릴계 이온교환섬유를 이용한 수중 크롬(VI) 제거)

  • Nam, Aram;Park, Jeong-Ann;Do, Taegu;Choi, Jae-Woo;Choi, Ungsu;Kim, Kyung Nam;Yun, Seong-Taek;Lee, Sanghyup
    • Journal of Korean Society of Environmental Engineers
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    • v.39 no.3
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    • pp.112-117
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    • 2017
  • Ion exchange fiber, PADD was synthesized by the reaction between PAN based acrylic fiber and DETA with $AlCl_3{\cdot}6H_2O$, and was analyzed by FT-IR and SEM to investigate its characteristics. The experimental results of Cr(VI) removal by PADD were better fitted with Langmuir adsorption isotherm, and the maximum uptake value ($Q_{max}$) was calculated to be 6.93 mmol/g. The kinetic data can be well described by Lagergen pseudo-second order rate model. The Cr(VI) adsorption capacity of PADD was 4.11 mmol/g at pH 2, which shows the effect of pH changes on the removal of Cr(VI). The adsorption selectivity of Cr(VI) was higher than phosphate and As(V). Total ion exchange capacity of PADD was 4.70 mmol/g, which was measured by acid-base back titration.

Parameter Estimation of the Aerated Wetland for the Performance of the Polluted Stream Treatment (오염하천 정화를 위한 호기성 인공습지의 운영인자 평가)

  • Kim, Dul-Sun;Lee, Dong-Keun
    • Clean Technology
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    • v.25 no.4
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    • pp.302-310
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    • 2019
  • A constructed wetland with the aerobic tank and anaerobic/anoxic tank connected in series was employed in order to treat highly polluted stream water. The aerobic tank was maintained aerobic with a continuous supply of air through the natural air draft system. Five pilot plants having different residence times were employed together to obtain parameters for the best performances of the wetland. BOD and COD removals at the aerobic tank followed the first order kinetics. COD removal rate constants were slightly lower than BOD. The temperature dependence of COD (θ = 1.0079) and BOD (θ = 1.0083) was almost the same, but the temperature dependence (θN) of T-N removal was 1.0189. The SS removal rate was as high as 98% and the removal efficiency showed a tendency to increase with increasing hydraulic loading rate (Q/A). The main mechanism of BOD and COD removal at the anaerobic/anoxic tank was entirely different from that of the aerobic tank. BOD and COD were supplied as the carbon source for biological denitrification. T-P was believed to be removed though the cation exchange between orthophosphate and gravels within the anaerobic and anoxic tanks. The wetland could successfully be operated without being blocked by the filtered solid which subsequently decomposed at an extremely fast rate.

An Empirical Formula of Bearing Capacity on Prebored and Precast Steel Piles (강관 매입말뚝의 지지력 공식 제안)

  • Park, Jong-Jeon;Kim, Do-Hyun;Jung, Gyung-Ja;Jeong, Sang-Seom
    • Journal of the Korean Geotechnical Society
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    • v.37 no.6
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    • pp.5-20
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    • 2021
  • In this study, a modified empirical formula for estimating the bearing capacity of the steel pipe prebored and precast pile was proposed by performing 20 cases of real-scale field pile loading tests. The proposed formula will be based on expanded SPT N-value in order to consider the realistic condition of the surrounding soil. The formula is proposed based on a statistic approach of the data points from the field pile loading test, in order to ensure safe engineering practice while finding a reliable formula. The statistical analysis of the data points from the loading test indicated that the existing formula has been underestimated the bearing capacity of the prebored and precast pile. The proposed formula estimates 15% and 20% higher pile End bearing capacity (qt=230Pdriven(kN/m2)) and the shaft resistance (fmax=3.0NsE(kN/m2)) compared to the existing formula. The accuracy and the stability of the proposed formula was verified by comparing the estimated results with additional field test data. The verification process showed that the proposed formula was estimated to be more accurate than the existing formula.

High Speed Mo2N/Mogate MOS Integrated Circuit (동작속도가 빠른 Mo2N/Mo 게이트 MOS 집적회로)

  • 김진섭;이우일
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.22 no.4
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    • pp.76-83
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    • 1985
  • Mo2N/Mo double layer which is to be used for gate of the RMOS (refractory metal oxide semiconductor) and interconnection material has been formed by means of low temperature r.f. reactive sputtering in Ar and N2 mixture. The sheet .esistance of 1 000$\AA$Mo2 N/4000$\AA$Mofilm was about 1.20-1.28 ohms/square, which is about an order of magnitude lower than that of polysilicon film. The workfunction difference naE between MO2N/MO layer and (100) p-Si with 6-9 ohm'cm resistivity obtained from C-V plots was about -0.30ev, and the fixed charge density Qss/q in the oxide was about 2. Ix1011/cm2. To evaluate the signal transfer delay time per inverter stage, an integrated ring oscillator circuit consisting of 45-stage inverters was fabricated using the polysilicon gate NMOS process. The signal transfer delay time per inverter stage obtained in this experiment was about 0.8 nsec

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Identification and Characterization of Two New S-Adenosylmethionine-Dependent Methyltransferase Encoding Genes Suggested Their Involvement in Stipe Elongation of Flammulina velutipes

  • Huang, Qianhui;Mukhtar, Irum;Zhang, Yelin;Wei, Zhongyang;Han, Xing;Huang, Rongmei;Yan, Junjie;Xie, Baogui
    • Mycobiology
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    • v.47 no.4
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    • pp.441-448
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    • 2019
  • Two new SAM-dependent methyltransferase encoding genes (fvsmt1 and fvsmt2) were identified from the genome of Flammulina velutipes. In order to make a comprehensive characterization of both genes, we performed in silico analysis of both genes and used qRT-PCR to reveal their expression patterns during the development of F. velutipes. There are 4 and 6 exons with total length of 693 and 978 bp in fvsmt2 and fvsmt1, respectively. The deduced proteins, i.e., FVSMT1 and FVSMT2 contained 325 and 230 amino acids with molecular weight 36297 and 24894 Da, respectively. Both proteins contained a SAM-dependent catalytic domain with signature motifs (I, p-I, II, and III) defining the SAM fold. SAM-dependent catalytic domain is located either in the middle or at the N-terminal of FVSMT2 and FVSMT1, respectively. Alignment and phylogenic analysis showed that FVSMT1 is a homolog to a protein-arginine omega-N-methyltransferase, while FVSMT2 is of cinnamoyl CoA O-methyltransferase type and predicted subcellular locations of these proteins are mitochondria and cytoplasm, respectively. qRT-PCR showed that fvsmt1 and fvsmt2 expression was regulated in different developmental stages. The maximum expression levels of fvsmt1 and fvsmt2 were observed in stipe elongation, while no difference was found in mycelium and pileus. These results positively demonstrate that both the methyltransferase encoding genes are involved in the stipe elongation of F. velutipes.

Piezoelectric and Dielectric Properties on PSN-PMN-PZT Composition according to CeO2 Addition (PSN-PMN-PZT 조성의 CeO2첨가에 따른 압전.유전특성 변화)

  • Yoon, Man-Soon;Chio, Yong-Gil;Ur, Soon-Chul
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.19 no.9
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    • pp.838-842
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    • 2006
  • 0.03Pb$(Sb_{0.5}Nb_{0.5})O_{3}-0.03Pb(Mn{1/3}Nb{2/3)O_{3}-(0.94-x)PbTiO_{3}-xPbZrO_{3}$ ceramics doped with $CeO_{2}$ were synthesized by conventional bulk ceramic processing technique. Phases analysis, microstructures and piezoelectric properties were investigated as a function of $CeO_{2}$ content (0.03, 0.05, 0.1 0.3, 0.5 and 0.7 wt%). Microstructures and phases information were characterized using a scanning electron microscope (SEM) and an X-ray diffractometer (XRD). Mechanical quality factor ($Q_{m}$) and coupling factor(kp) were obtained from the resonance measurement method. Both $Q_{m}$ and $k_{p}$ were shown to reach to the maximum at 0.1 wt% $CeO_{2}$. In order to evaluate the stability of resonance frequency and effective electromechanical coupling factor ($K_{eff}$) as a function of $CeO_{2}$, the variation of resonance and anti-resonance frequency were also measured using a high voltage frequency response analyzer under various alternating electric fields from 10 V/mm to 80 V/mm. It was shown that the stability of resonance frequency and effective electromechanical coupling factor were increased with increasing the $CeO_{2}$ contents.

Chl a Fluorescence Characterization and Biomarker Selection from Ricciocarpos natans under Cadmium Stress (카드뮴 독성 평가를 위한 은행이끼의 엽록소형광 분석 및 환경지표 선발)

  • Oh, Soonja;Koh, Seok Chan
    • Journal of Environmental Science International
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    • v.22 no.11
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    • pp.1403-1413
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    • 2013
  • The effects of cadmium ions ($Cd^{2+}$) on the Chl a fluorescence of Ricciocarpos natans were investigated in order to determine whether Chl fluorescence can be used as a biomarker to estimate the physiological responses of plants to cadmium stress. In all plants treated with $Cd^{2+}$, the image of Fv/Fm, which represents the maximum photochemical efficiency of PSII, changed as the $Cd^{2+}$ concentration increased, when treated for 48 h or more. Changes of ${\Phi}_{PSII}$ and $Q_P$ images were recognized even at 10 ${\mu}M$ $Cd^{2+}$. The Chl a O-J-I-P fluorescence transient was also affected even at 10 ${\mu}M$ $Cd^{2+}$. The fluorescence yield decreased considerably in steps J, I and P in plants treated with $Cd^{2+}$, although a typical polyphasic rise was observed in non-treated plants. The Chl fluorescence parameters, Fm, Fv/Fo, Sm, SFIabs, PIabs and ETo/CS, decreased as the $Cd^{2+}$ concentration increased, while the Mo and Kn parameters increased. Peroxidase activity decreased significantly and catalase activity increased as the $Cd^{2+}$ concentration increased. Because of its sensitivity to $Cd^{2+}$ Ricciocarpos natans is useful in experiments investigating the responses of plants to cadmium exposure. Several parameters (Fm, Fv/Fo, Sm, SFIabs, PIabs, ETo/CS, Mo and Kn) can be applied to determine quantitatively the physiological states of plants under cadmium stress.

Pichia pastoris: A Recombinant Microfactory for Antibodies and Human Membrane Proteins

  • Goncalves, A.M.;Pedro, A.Q.;Maia, C.;Sousa, F.;Queiroz, J.A.;Passarinha, L.A.
    • Journal of Microbiology and Biotechnology
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    • v.23 no.5
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    • pp.587-601
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    • 2013
  • During the last few decades, it has become evident that the compatibility of the yeast biochemical environment with the ability to process and translate the RNA transcript, along with its capacity to modify a translated protein, are relevant requirements for selecting this host cell for protein expression in several pharmaceutical and clinical applications. In particular, Pichia pastoris is used as an industrial host for recombinant protein and metabolite production, showing a powerful capacity to meet required biomolecular target production levels in high-throughput assays for functional genomics and drug screening. In addition, there is a great advantage to using P. pastoris for protein secretion, even at high molecular weights, since the recovery and purification steps are simplified owing to relatively low levels of endogenous proteins in the extracellular medium. Clearly, no single microexpression system can provide all of the desired properties for human protein production. Moreover, chemical and physical bioprocess parameters, including culture medium formulation, temperature, pH, agitation, aeration rates, induction, and feeding strategies, can highly influence product yield and quality. In order to benefit from the currently available wide range of biosynthesis strategies using P. pastoris, this mini review focuses on the developments and technological fermentation achievements, providing both a comparative and an overall integration analysis. The main aim is to highlight the relevance and versatility of the P. pastoris biosystem to the design of more cost-effective microfactories to meet the increasing demands for recombinant membrane proteins and clinical antibodies for several therapeutic applications.