• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2010년도 하계학술대회 논문집
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• pp.301-301
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• 2010

현재 전 세계는 앞으로 사용 될 대체 에너지에 많은 관심 가지고 있다. 지금 사용하고 있는 에너지 연료는 한정되어 있기 때문에 대체에너지에 대한 연구가 활발히 진행 되고 있다. 그 중 압전체를 이용한 에너지 하베스팅은 많은 주목을 받고 있다. 주변 환경에서 필요한 에너지를 끌어 쓸 수 있는 대표적인 청정에너지 시스템 중 하나이기 때문이다. 최근 전원 공급원으로써 에너지 수확 시스템은 현 사회에 사용되고 있는 배터리로 전원을 사용하는 제품들을 소용량과 저전압 분야에서의 에너지 수확의 원리를 이용하여 전기전자제품의 사용시간 연장 및 응용분야 확대를 시도하는 연구가 활발히 수행되고 있다. 압전세라믹스를 이용한 에너지 하베스팅은 진동에너지를 전기에너지로 변환하는 것으로서 압전 특성이 높아야 한다. 일반적으로 압전 세라믹스는 PbO 성분이 들어가므로 환경적 오염 뿐만 아니라 인체에도 영향이 좋지 않으므로 많은 나라에서 이러한 성분을 제한하고 점차적으로 줄어들고 있는 시점에서 PbO를 사용하지 않고 Lead-Free 세라믹를 사용한 연구가 진행되고 있다. 이 논문에서는 일반적인 소결 방법을 이용하여 (Na,K)NbO3 세라믹에 CeO2를 첨가한 압전 세라믹을 제작하였다. 제작된 압전 세라믹스로 에너지 하베스팅 소자를 제작하고, 이 소자로 수확된 에너지로 DC-DC Converter 응용 특성에 대하서 연구하였다. 압전 세라믹스의 좋은 압전 특성을 출력하기 위하여 캔틸레버의 고유 진동수가 진동원의 주파수와 일치하는 공진을 일으켜야 한다. 따라서 구동회로는 주파수원을 찾아 설계하였고, 압전 세라믹스의 진동은 가진기를 이용하여 구동실험을 하였다. 지금까지 나와있던 에너지 하베스팅 회로와 비교하여 그 특성을 분석하고, 시뮬레이션 및 실험을 통하여 검증하였다.

• 광물과 암석
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• 제33권4호
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• pp.307-324
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• 2020

백두산 북동쪽으로 약 25 km 떨어져있는 지역의 마이오세 현무암(황송푸 현무암, 20 Ma)에 대한 주성분원소와 미량원소, Sr-Nd 동위원소 조성에 대한 연구가 수행되었다. 황송푸 현무암은 비현정질 암석으로 Na2O+K2O=3.5~4.7 wt.%, MgO=9.9~11.1 wt.%을 보인다. Mg 성분이 풍부한 감람석(Mg#=75~86)과 단사휘석(Mg#=72~85), Ca성분이 풍부한 사장석 미반정을 함유하고 있다. 이 현무암은 경희토류원소 부화가 나타나는 해양도현무암과 유사한 미량원소 패턴을 보이고, 높은 Cr(394~479 ppm)과 Ni(389~519 ppm) 성분, Nb-Ta 부화 이상치, Rb과 Ba을 포함하는 LILE가 부화되어 있는 특징을 보인다. 이러한 조직과 주성분원소/미량원소조성 데이터는 황송푸 현무암이 알칼리 마그마 계열에 속하는 원시적인 마그마임을 나타낸다. 황송푸 마그마는 상승하는 도중에 분별결정작용, 지각오염, 마그마혼합과 같은 분화작용을 거의 경험하지 않은 액상선 환경에서 고화된 암석으로 이는 황송푸 현무암이 부분용융이 일어났던 맨틀에서의 특성을 지니고 있음을 반영한다. 황송푸 현무암의 높은 (Gd/Yb)sample/(Gd/Yb)PM 비율(2.8~3.5)은 황송푸 현무암이 판내부 환경에서 형성된 마그마로써 석류석이 존재하는 맨틀에서 페리도타이트의 낮은 부분용융(3~5%)으로 형성되었다. BSE보다 모두 높은 143Nd/144Nd와 87Sr/86Sr 성분을 보이는 황송푸 현무암은 이 지역 아래 부화된 맨틀영역이 존재한다는 것을 의미한다. 황송포 현무암은 과거(ancient)의 태평양판 섭입대에 의해 공급되어 재활용된 해양지각 혹은 대륙지각으로 교대작용을 경험한 맨틀에서 부분용융에 의해 형성되었다.

• 한국전기전자재료학회논문지
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• 제32권5호
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• pp.418-425
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• 2019

A piezoelectric ceramic fiber composite (PCFC) was successfully fabricated using $0.69Pb(Zr_{0.47}Ti_{0.53})O_3-0.31[Pb(Zn_{0.4}Ni_{0.6})_{1/3}Nb_{2/3}]O_3$ (PZT-PZNN) for use in small-scale wind energy harvesters. The PCFC was formed using an epoxy matrix material and an array of Ag/Pd-coated PZT-PZNN piezo-ceramic fibers sandwiched by Cu interdigitated electrode patterned polyethylene terephthalate film. The energy harvesting performance was evaluated in a custom-made wind tunnel while varying the wind speed and resistive load with two types of flutter wind energy harvesters. One had a five-PCFC array vertically clamped with a supporting acrylic rod while the other used the same structure but with a five-PCFC cantilever array. Stainless steel (thickness: $50{\mu}m$) was attached onto one side of the PCFC to form the PZT-PZNN cantilever. The output power, in general, increased with an increase in the wind speed from 2 m/s to 10 m/s for both energy harvesters. The highest output power of $15.1{\mu}W$ at $14k{\Omega}$ was obtained at a wind speed of 10 m/s for the flutter wind energy harvester with the PZT-PZNN cantilever array. The results presented here reveal the strong potential for wind energy harvester applications to supply sustainable power to various IoT micro-devices.

• 자원환경지질
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• 제56권6호
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• pp.745-764
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• 2023

In the Republic of Congo, Banded iron formations (BIFs) occur in two areas: the Chaillu Massif and the Ivindo Basement Complex, which are segments of the Archean Congo craton outcropping in the northwestern and southwestern parts of the country. They show interesting potential with significant mineral resources reaching 2 Bt and grades up to 60% Fe. BIFs consist mostly of oxide-rich facies (hematite/magnetite), but carbonate-rich facies are also highlighted. They are found across the country within the similar geological sequences composed of amphibolites, gneisses and greenschists. The Post-Archean Australian Shale (PAAS)-normalized patterns of BIFs show enrichment in elements such as SiO₂, Fe₂O₃, CaO, P₂O₅, Cr, Cu, Zn, Nb, Hf, U and depletion in TiO₂, Al₂O₃, MgO, Na₂O, K₂O, Sc, Th, Ba, Zr, Rb, Ni, V. REE diagrams show slight light REEs (rare earth elements; LREEs) compared to heavy REEs (HREEs), and positive La and Eu anomalies. The lithological associations, as well as the very high (Eu/Eu^*)_SN ratios> 1.8 shown by the BIFs, suggest that they are related to Algoma-type BIFs. The positive correlations between Zr and TiO₂, Al₂O₃, Hf suggest that the contamination comes mainly from felsic rocks, while the absence of correlations between MgO and Cr, Ni argues for negligeable contributions from mafic sources. Pr/Pr^* vs. Ce/Ce^* diagram indicates that the Congolese BIFs were formed in basins with redox heterogeneity, which varies from suboxic to anoxic and from oxic to anoxic conditions. They were formed through hydrothermal vents in the seawater, with relatively low proportions of detrital inputs derived from igneous sources through continental weathering. Some Congolese BIFs show high contents in Cr, Ni and Cu, which suggest that iron (Fe) and silicon (Si) have been leached through hydrothermal processes associated with submarine volcanism. We discussed their tectonic setting and depositional environment and proposed that they were deposited in extensional back-arc basins, which also recorded hydrothermal vent fluids.

• 한국전기전자재료학회논문지
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• 제27권11호
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• pp.696-701
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• 2014

In this study, in order to develop coupled vibration mode piezoelectric devices for Acoustic Emission (abbreviated as AE) sensor application with outstanding displacement and piezoelectric properties have been simulated by ATILA FEM program. And, From the results of ATILA simulation, the AE sensor specimen, obtained superior electromechanical coupling factor and displacement, when the size of specimen is $3.45mm{\Phi}{\times}3.45mm$ with ratio of diameter/thickness(${\Phi}/T$)= 1.0. Therefore, AE sensor was fabricated by (Na,K,Li)(Nb,Ta) $O_3$(abbreviated as NKL-NT) system piezoelectric ceramics using coupled vibration mode. The piezoelectric properties of NKL-NT ceramics was exhibited that piezoelectric constant($d_{33}$), piezoelectric voltage constant($g_{33}$) and electro mechanical coupling factor($k_p$) have the excellent values of 261[pC/N], 40.10[$10^{-3}Vm/N$], and 0.44, respectively. The manufactured piezoelectric device with ratio of ${\Phi}/T$= 1.0 indicated the optimum values of resonant frequency(fr)= 556.5[kHz], antiresonant frequency(fa)=631.1[kHz], and effective electromechanical coupling factor(keff)= 0.473. The maximum sensitivity of the coupled vibration mode AE sensor was 55[dB] at the resonant frequency of 75[kHz]. The results show that the coupled vibration mode piezoelectric device is a promising candidate for the application AE sensor piezoelectric device.

• 한국전기전자재료학회논문지
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• 제25권6호
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• pp.420-425
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• 2012

Lead-free piezoelectric ceramic/epoxy composites with '0-3' connectivity were prepared by cold-pressing with a temperature controlled curing method. A ceramic powder with a composition of $(Na_{0.51}K_{0.47}Li_{0.02})(Nb_{0.8}Ta_{0.2})O_3$ was synthesized by a conventional solid state reaction route. The dielectric and piezoelectric properties of ceramic/epoxy composites were characterized as a function of the volume fraction (${\phi}$) of piezoelectric ceramics, which was varied from 70 to 95 vol%. The results indicated that the piezoelectric properties of composites were significantly affected by the volume fraction of ceramics. In terms of the piezoelectric properties, specimens showed the best performance at ${\phi}$= 85 vol%, resulting in the piezoelectric constant $d_{33}$ of 39 pC/N and the figure of merit as a piezoelectric energy harvester ($d_{33}{\cdot}g_{33}$) of 1.24 $pm^2/N$.

• 센서학회지
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• 제24권4호
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• pp.228-231
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• 2015

Ultrasonic motors provide high torques and quick responses compared to their magnetic counterparts; therefore, they are widely used in small-scale applications such as mobile phones, microrobots, and auto-focusing modules in digital cameras. To determine the feasibility of lead-free piezoceramics for ultrasonic motor applications, we fabricated a ring-type piezoceramic with a KNN-based lead-free piezoceramic (referred to as CZ5), intended for use in an auto-focusing module of a digital camera. The vibration of the lead-free stator was observed at 45.1 kHz. It is noteworthy that the fully assembled lead-free ultrasonic motor exhibited a revolution speed of 5-7 rpm, even though impedance matching with neighboring components was not considered. This result suggests that the tested KNN-based piezoceramic has great potential for use in ultrasonic motor applications, requiring minimal modifications to existing lead-based systems.

• 한국재료학회:학술대회논문집
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• 한국재료학회 2011년도 추계학술발표대회
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• pp.20.2-20.2
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• 2011

BMNO dielectric materials with a pyrochlore structure have been chosen and they have quite high dielectric constants about 210 for the bulk material. In the case of thin films, 200-nm-thick BMNO films deposited at room temperature showed a low leakage current density of about $10^{-8}\;A/cm^2$ at 3 V and a dielectric constant of about 45 at 100 kHz. Because high dielectric constant BMNO thin films kept an amorphous phase at a high temperature above $900^{\circ}C$. High dielectric constant BMNO thin films grown at room temperature have many applications for flexible electronic devices. However, because the dielectric constant of the BMNO films deposited at room temperature is still low, percolative BMNO films (i.e., those were grown in a pure argon atmosphere) sandwiched between ultra-thin BMNO films grown in an oxygen and argon mixture have greater dielectric constants than standard BMNO films. However, they still showed a leakage problem at a high voltage application. Accordingly, a new nano-structure that uses BMNO was required to construct the films with a dielectric constant higher than that of its bulk material. The fundamental reason that the BMNO-Bi nano-composite films grown by RF-Sputtering deposition had a dielectric constant higher than that of the bulk material was addressed in the present study. Also we used the graphene as bottom electrode instead of the Cu bottom electrode. At first, we got the high leakage current density value relatively. but through this experiment, we could get improved leakage current density value.