• Title/Summary/Keyword: (100) Orientation

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(100) orientation of PZT thin films coated on the LNO electrode using a different manufacturing process (제조 공정을 달리한 LNO 전극에 코팅된 PZT 박막의 배향성)

  • Seo, Byung-Jun;Moon, Byung-Kee;Kim, Kang-Eon;Chung, Su-Tae
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07b
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    • pp.916-919
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    • 2004
  • This paper studied about the (100) orientation of PZT thin films coated on the LNO electrode using a different thermal annealing. The thermal annealing method is divided into two things. The one is the method transferring heat to only the lower substrate and another is transferring heat to all directions. Orientation factor of PZT in the method of transferring heat to only the lower substrate was F=99% in the thermal annealing of the LNO. Orientation factor of PZT was F=67% in the method of transferring heat to all directions.

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Effects of Physico-chemical Factors of Sol on the Degree of Preferred Orientation in $Pb(Mg, Zn)_{1/3}Nb_{2/3}O_3$ Thin Films (Sol의 물리화학적 변수들이 $Pb(Mg, Zn)_{1/3}Nb_{2/3}O_3$ 박막의 우선 배향성에 미치는 효과)

  • 조문규;장현명;김광수
    • Journal of the Korean Ceramic Society
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    • v.32 no.3
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    • pp.305-312
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    • 1995
  • Thin films of Pb(Mg, Zn)1/3Nb2/3O3 were fabricated by spin coating the Pb-Mg-Zn-Nb-O complex alkoxide sols on(111) Pt-coated MgO (100) planes. It was observed that the content of H2O and the rheological characteristics of sol greatly influenced the orientation of perovskite grains after thin-film formation. A strong preferential orientation of (100)-type planes of the perovskite grains was obtained for the sol aged for 15 days with the molar ratio of H2O to total metal alkoxides=2. As small angle X-ray scattering experiment in the Porod region was performed to correlate the observed preferential orientation with the network structure of precursors at various stage of aging. It was shown that the degree of branching of the Pb-Mg-Zn-Nb-O precursor chain had a direct effect on the preferred oreintation, and weakly branched precursor systems led to highly oriented grains after thin-film formation.

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Grain Orientation and Electrical Properties of $Sr_2Nb_2O_7$ Ceramics and Thin Films (다결정 및 박막형 $Sr_2Nb_2O_7$의 입자배향과 전기적특성)

  • 손창헌;전상재;남효덕;이희영
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.11 no.4
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    • pp.274-280
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    • 1998
  • Polycrystalline $Sr_2Nb_2O_7$ ceramics with very high Curie temperature were sintered using the powder derived by the chemical coprecipitation method (CCP). The phase evolution and grain-orientation of sintered samples were examined by XRD, while sintering behavior, dielectric properties and polarization were studied by SEM and ferroelectric tester. Extremely high degree of grain-orientation was observed along the (0k0) direction, which resulted in anisotropic dielectric properties of the sintered samples, with the dielectric constant values approaching those for single crystal. Thin film fabrication of $Sr_2Nb_2O_7$ in the pyroniobate family was also attempted on $SiO_2$/Si(100), Pt/$SiO_2$/Si(100), Pt/Ti/$SiO_2$/Si(100) and Pt/$ZrO_2/SiO_2/Si_2(100)$ substrates, using metalorganic decomposition (MOD) process. Neodecanoate precursor solution was prepared by mixing strontium neodecanoate with niobium neodecanoate synthesized from niobium ethoxide. It was found that $Sr_2Nb_2O_7$ single phase appeared in XRD patterns the samples annealed above $950^{\circ}C$. The effect of substrate type on film microstructure and dielectric properties was observed.

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Deposition Characteristics of AlN Thin Films Prepared by RF Magnetron Sputtering (RF 마그네트론 스퍼터링에 의해 제조된 AlN 박막의 증착 특성)

  • Song, Jong-Han;Chun, Myoung-Pyo;Choi, Duck-Kyun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.25 no.12
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    • pp.969-973
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    • 2012
  • AlN thin films were deposited on p-type Si(100) substrates by RF magnetron sputtering method. This study showed the change of the preferential orientation of AlN thin films deposition with the change of the deposition conditions such as sputtering pressure and Ar/N2 gas ratio in chamber. It was identified by X-ray diffraction patterns that AlN thin film deposited at low sputtering pressure has a (002) orientation, however its preferred orientation was changed from the (002) to the (100) orientation with increasing sputtering pressure. Also, it was observed that the properties of AlN thin films such as thickness, grain size and surface roughness were largely dependent on Ar/$N_2$ gas ratio and a high quality thin film could be prepared at lower nitrogen concentration. AlN thin films were investigated relationship between preferential orientation and deposition condition by using XRD, FE-SEM and PFM.

Structure Development of Uniaxially Drawn Poly(trimethylene terephthalate)/ Poly(ethylene terephthalnte) Blends (일축 연신에 의한 폴리(트리메틸렌 데레프탈레이트)/ 폴리(에틸렌 데레프탈레이트) 블렌드의 구조 변화)

  • 전병환;김환기;강호종
    • Polymer(Korea)
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    • v.28 no.1
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    • pp.67-76
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    • 2004
  • The effects of drawing temperature and draw down ratio on thermal properties, crystallinity and orientation of poly(trimethylene terephthalate)/poly(ethylene terephthalate) (PTT/PET) 100/0 ,90/10, and 80/20 blends have been investigated. The crystallinity and glass transition temperature increased while cold crystallization temperature and cold enthalpy decreased due to the development of orientation and stress induced crystallization by the cord drawing. Introducing PET to PTT decreased the crystallinity of PTT. However, it enhanced the orientation of PTT/PET blends drawn at below the glass transition temperature of PET. This lead to the increase of tensile modulus and tensile strength of PTT/PET blends. The shrinkage increased with increasing orientation, which might be minimized by the development of crystalline morphology of PTT in the course of cold drawing.

The Evolution of Preferred Orientation and Morphology of NiO Thin Films under Variation of Plasma gas and RF Sputtering Power (플라즈마 가스와 RF 파워에 따른 NiO 박막의 우선배향성 및 표면형상 변화)

  • Ryu Hyun-Wook;Choi Gwang-Ryo;Noh Whyo-Sup;Park Yong-Ju;Kwon Yong;Park Jin-Seong
    • Korean Journal of Materials Research
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    • v.14 no.2
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    • pp.121-125
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    • 2004
  • Nickel oxide (NiO) thin films were deposited on Si(100) substrates at room temperature by RF magnetron sputtering from a NiO target. The effects of plasma gas and RF power on the crystallographic orientation and surface morphology of the NiO films were investigated. X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM) and atomic force microscopy (AFM) were employed to characterize the deposited film. It was found that the type of plasma gases affected the crystallographic orientation, deposition rate, surface morphology, and crystallinity of NiO films. Highly crystalline NiO films with (100) orientation were obtained when it was deposited under Ar atmosphere. On the other hand, (l11)-oriented NiO films with poor crystallinity were deposited in $O_2$. Also, the increase in RF power resulted in not only higher deposition rate, larger grain size, and rougher surface but also higher crystallinity of NiO films.

Effect of Substrate Temperature on the Morphology of Diamond Films by MPCVD (기판 온도가 다이아몬드 박막의 Morphology에 미치는 영향)

  • Park, Yeong-Su;Kim, Sang-Hun;Kim, Dong-Ho;Lee, Jo-Won
    • Korean Journal of Materials Research
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    • v.4 no.4
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    • pp.385-392
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    • 1994
  • The morphology variat~on of diamond thin films, grown by microwave plasma chem~cal vapor deposition, was investigated. With increasing substrate temperature from $550^{\circ}C$ to $750^{\circ}C$, the film morphology was changed from {111} to {100}, and then to cauliflower. The nondiamond components in the film increased with increasing temperature. Micro Raman spectrum suggested that the nondiamond components might exist along the boundaries of d~amond particles. The texture of diamond films, analyzed by X-ray diffraction, was varied from random orientation to <100> , and finally to <110> with increasing substrate temperature.

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A Study on the Characteristics of MgO Thin Films Prepared by Electron Beam (전자빔 증착법에 의해 형성된 MgO 박막의 증착 및 특성)

  • Lee, Choon-Ho;Kim, Sun-Il;Shin, Ho-Shik
    • Journal of the Korean Ceramic Society
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    • v.39 no.12
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    • pp.1171-1176
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    • 2002
  • The growth characteristics on the MgO thin films prepared by the e-beam evaporation method have been investigated. We observed the film of preferred orientation and surface morphology with various parameters such as substrate temperature, deposition rate on Si(100) and slide glass respectively. Consequently, it was shown that MgO(111) preferred orientation films can be obtained as the deposition rate was increased on Si(100) substrate. MgO(220) peak was found as the substrate temperature was increased. Whereas, in case of slide glass the orientation is changed from (200) to (111) by substrate temperature. Also we investigated the relationship between the film characteristics and the orientation of MgO thin films.

A Study on Clothing Shopping Orientation and Cloghin Buying Behavior of female workers (직장여성의 쇼핑성향과 의복구매특성에 관한 연구 - 전라남도 여교사를 중심으로 -)

  • 이영미;이옥희
    • Journal of the Korean Home Economics Association
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    • v.40 no.2
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    • pp.87-100
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    • 2002
  • The purpose of this study was to investigate the demographics and general clothing buying behavior according to clothing shopping orientation of female workers. A questionnaire was developed to measure clothing shopping orientation, fashion information sources, stores selection criteria, clothing purchasing frequency of a year, purchasing expenditure of clothing, the demographics. The questionnaire was administered to 775 female teacher in Chonnam. The data was analyzed using percentage, frequency, mean, factor analysis, Cluster Analysis, $\chi^2$-_test and ANOVA, Duncan test. The results of the study were as follows: 1. The female teachers were classified into four groups by the cluster analysis; indifferent shopping group, rational shopping group, conspicuous shopping group, recreational shopping group. 2. In the case of fashion information sources, significant differences were found according to shopping orientation subdivision in mass media information, information by consumer, information by marketer. 3. The stores selection criteria were significantly different depending on shopping orientation subdivision in goods and atmosphere of shop, promotion, convenience of shop's location. 4. The clothing purchasing frequency of a year were significantly different depending on shopping orientation subdivision. 5. The significant differences were found according to shopping orientation subdivision in purchasing expenditure of clothing. 7. In the demographic characteristics, significant differences were found according to shopping orientation subdivision in age, marriage, the length of one's work, income.

Dependence of Turn-On Voltage and Surface State Density on the Silicon Crystallographic Orientation (실리콘 결정의 방향성에 따른 Turn-On 전사과 추면대융단파의 상대성에 관한 연구)

  • 성영권;성만영;조철제;고기만;이병득
    • The Transactions of the Korean Institute of Electrical Engineers
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    • v.33 no.4
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    • pp.157-163
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    • 1984
  • The object of this paper is to investigte the gate controlled diode structure for ionic concentration measurement. It includes device fabrication, characterization, device physics and modeling of the gate controlled diode structure. The differences of turn on voltages and surface generation currents in the (100) and (111) silicon crystallographic orientation of the sample device were observed. Therefore the dependence of these two factors of the silicon crystallographic orientation was investigated. It was observed that drifts arose after extended immersion of the sample device in acid or base solutions. The surface generation-recombination velocity of both (100) and (111) increased. The increase in the interfacial traps for both surface, determined by the turn on voltage was directly proportional to the surface generation-recombination velocity increase.

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