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Investigation of $xV_2O_5-B_2O_3$ and $xV_2O_5-B_2O_3-yNa_3O$ Glasses by $^{11}B MAS$ NMR

  • Kim, Sun-ha;Han, Oc-Hee;Kang, Jae-Pil
    • Journal of the Korean Magnetic Resonance Society
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    • v.9 no.1
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    • pp.61-66
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    • 2005
  • $^{11}B MAS NMR$ spectra of binary glass system $xV_2O5-B_2O_3$ and ternary glass system $xV_2O5-B_2O_3-yNa_2O$ (x = $V_2O_5 mol%/$B_2O_3$ mol%, y = $Na_2O$ mol$/$B_2O_3$ mol%) were acquired. $BO_3$ units are dominant components in the spectra of $xV_2O_5-B_2O_3$glass systems while both $BO_3$ and $BO_4$ unit appear in comparable amounts in the spectra of $xV_2O_5-B_2O_3-yNa_2O$ glass systems. More $BO_3$ units were monitored for higher $V_2O_5$ contents while more $BO_4$ unit for higher $Na_2O$ contents. Quadrupole parameters such as $e^2qQ$ and $\eta$ obtained form spectral simulation indicate that $e^2qQ$ has a maximum value at x = y 1 and $\eta$ decreases and increases as x or y grows, respectively. Our results suggest that $V_2O_5$ and $Na_2O$ play opposite roles in the ternary glasses.

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Application of the Response Surface Methodology and Process Optimization to the Electrochemical Degradation of Rhodamine B and N, N-Dimethyl-4-nitrosoanilin Using a Boron-doped Diamond Electrode (Boron-doped Diamond 전극을 이용한 Rhodamine B와 N, N-Dimethyl-4-nitrosoanilin의 전기화학적 분해에 반응표면분석법의 적용과 공정 최적화)

  • Kim, Dong-Seog;Park, Young-Seek
    • Journal of Environmental Health Sciences
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    • v.36 no.4
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    • pp.313-322
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    • 2010
  • The aim of this research was to apply experimental design methodology to optimization of conditions of electrochemical oxidation of Rhodamine B (RhB) and N, N-Dimethyl-4-nitrosoaniline (RNO, indicative of the OH radical). The reactions of electrochemical oxidation of RhB degradation were mathematically described as a function of the parameters of current ($X_1$), NaCl dosage ($X_2$) and pH ($X_3$) and modeled by the use of the central composite design. The application of response surface methodology (RSM) yielded the following regression equation, which is an empirical relationship between the removal efficiency of RhB and RNO and test variables in a coded unit: RhB removal efficiency (%) = $94.21+7.02X_1+10.94X_2-16.06X_3+3.70X_1X_3+9.05X_2X_3-{3.46X_1}^2-{4.67X_2}^2-{7.09X_3}^2$; RNO removal efficiency (%) = $54.78+13.33X_1+14.93X_2- 16.90X_3$. The model predictions agreed well with the experimentally observed result. Graphical response surface and contour plots were used to locate the optimum point. The estimated ridge of maximum response and optimal conditions for the RhB degradation using canonical analysis was 100.0%(current, 0.80 A; NaCl dosage, 2.97% and pH 6.37).

Magnetic Propertes of $Nd_{x}{(Fe_{0.9}Co_{0.1})}_{90-x}B_{6}Nb_{3}Cu_{1}(x=\;3,\;4,\;5)$ Nanocrystalline Alloys ($Nd_{x}{(Fe_{0.9}Co_{0.1})}_{90-x}B_{6}Nb_{3}Cu_{1}(x=\;3,\;4,\;5)$ 초미세결정립합금의 자기특성)

  • 조용수;김만중;천정남;김택기;박우식;김윤배
    • Journal of the Korean Magnetics Society
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    • v.5 no.5
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    • pp.880-894
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    • 1995
  • Magnetic properties of $Nd_{x}{(Fe_{0.9}Co_{0.1})}_{90-x}B_{6}Nb_{3}Cu_{1}(x=\;3,\;4,\;5)$ rrelt-spun alloys with 6 at% B content were studied aiming for finding out a new $\alpha$-Fe based Nd-Fe-B nanocrystalline alloy with good hard magnetic properties. $Nd_{x}{(Fe_{0.9}Co_{0.1})}_{90-x}B_{6}Nb_{3}Cu_{1}$ melt-spun alloys prepared by RSP crystallized to nanocrystalline phase. An optimally annealed $Nd_{3}{(Fe_{0.9}Co_{0.1})}_{87}B_{6}Nb_{3}Cu_{1}$ melt-spun alloys had larger volume ratio of $\alpha$-Fe(Co) than that of higher Nd content alloy and showed high remanence of about 1.6 T. On the contrary, the increase of Nd content in $Nd_{x}{(Fe_{0.9}Co_{0.1})}_{90-x}B_{6}Nb_{3}Cu_{1}$ alloys gave rise to gradual increase of an amount of $Nd_{2}{(Fe,\;Co)}_{14}B$ phase and improved coercivity. An optimally annealed $Nd_{5}{(Fe_{0.9}Co_{0.1})}_{85}B_{6}Nb_{3}Cu_{1}$ alloy showed the most improved hard mag¬netic properties. The remanence, coercivityand energy product of the alloy were 1.35 T, 219 kA/m (2.75 kOe), and $129\;kJ/m^{3}$ (16.2 MGOe), respectively.

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Moieties of Complement iC3b Recognized by the I-domain of Integrin αXβ2

  • Choi, Jeongsuk;Buyannemekh, Dolgorsuren;Nham, Sang-Uk
    • Molecules and Cells
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    • v.43 no.12
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    • pp.1023-1034
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    • 2020
  • Complement fragment iC3b serves as a major opsonin for facilitating phagocytosis via its interaction with complement receptors CR3 and CR4, also known by their leukocyte integrin family names, αMβ2 and αXβ2, respectively. Although there is general agreement that iC3b binds to the αM and αX I-domains of the respective β2-integrins, much less is known regarding the regions of iC3b contributing to the αX I-domain binding. In this study, using recombinant αX I-domain, as well as recombinant fragments of iC3b as candidate binding partners, we have identified two distinct binding moieties of iC3b for the αX I-domain. They are the C3 convertase-generated N-terminal segment of the C3b α'-chain (α'NT) and the factor I cleavage-generated N-terminal segment in the CUBf region of α-chain. Additionally, we have found that the CUBf segment is a novel binding moiety of iC3b for the αM I-domain. The CUBf segment shows about a 2-fold higher binding activity than the α'NT for αX I-domain. We also have shown the involvement of crucial acidic residues on the iC3b side of the interface and basic residues on the I-domain side.

A Study on Mossbauer Spectra of the ${Ni_{1+x}}{Ti_x}{Fe_{2-2x}}O_4$ System (${Ni_{1+x}}{Ti_x}{Fe_{2-2x}}O_4$계의 $\M"{o}ssbauer$ 스펙트럼 연구)

  • Baek, Seung-Do;Ko, Jeong-Dae;Hong, Sung-Rak
    • Korean Journal of Materials Research
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    • v.11 no.1
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    • pp.3-7
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    • 2001
  • $M\"{o}ssbauer$ spectra of the $Ni_{1+x}Ti_xFe_{2-2x}O_4$ systems ($0{\leqq}x{\leqq}0.7$), which appear as single phase spinel structure, were examined at RT. The $M\"{o}ssbauer$ spectra reveal two sextet for $0{\leqq}x{\leqq}0.3$, two sextet and a doublet for $0.4{\leqq}x{\leqq}0.6$, and a doublet for x=0.7 As x increases, the area ratio of B-site and A-site($A_B/A_A$) of the sextet decreases, and the area ratio of the doublet and the total areas($A_{doublet}/A_{tot.}$) increases. The isomer shift(I.S.) of A-site slightly increases and magnetic hyperfine fields($H_{hf}$) of two sites decrease as the increasing x. From these results, we have obtained the cation distributions of the samples and concluded that the increasing x leads to the decrease of covalency of $Fe^{3+}-O^{2-}$ bond in A-sites and A-B superexchange interactions.eractions.

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The Effect of Pr Additive on Magnetostriction of Amorphous Fe-B Alloy (Pr 첨가가 Fe-B 비정질합금의 자왜에 미치는 영향)

  • 조용수;김윤배;김창석;김택기
    • Journal of the Korean Magnetics Society
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    • v.4 no.2
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    • pp.126-129
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    • 1994
  • In order to invetigate the effect of Pr additive on the magnetostriction of amorphous Fe-B alloys, amorphous $Fe_{86-x}B_{14}Pr_{x}(2{\leq}x{\leq}8\;at.%)$ alloys were prepared by a rapid solidification process. As the Pr content increased in the as-prepared amorphous $Fe_{84}B_{14}Pr_{2}$ alloy annealed at $300^{\circ}C$ for 2 hr increased to 70 ppm. Ac power loss and permeability$(f=50\;kHz,\;B_{m}=0.1\;T)$ of the annealed amorphous $Fe_{84}B_{14}Pr_{2}$ alloy were 15 W/kg and $5.5{\times}10^{3}$, respectively.

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Preparation of $\textrm{Fe}_{5}\textrm{Si}_{x}\textrm{B}_{5-x}$(x=0, 1, 2, 3) Powder by Mechanical Alloying (기계적합금법에 의한 $\textrm{Fe}_{5}\textrm{Si}_{x}\textrm{B}_{5-x}$(x=0, 1, 2, 3)분말의 제조)

  • Kim, Taek-Soo;Hwang, Yeon;Lee, Hyo-Sook
    • Korean Journal of Materials Research
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    • v.8 no.2
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    • pp.141-146
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    • 1998
  • Ball mill을 이용하여 Ar 분위기에서 기계적 합금법으로 $Fe_{ 5}$$Si_{x}$ $B_{5-x}$ 분말을 제조하고, 제조된 분말을 연속 진공 열처리 시킨 후 Si첨가에 따른 결정구조 및 자기적성질을 조사하였다. 250시간 볼밀처리한 Fe$_{5}$ $B_{5}$ 합금에서 전체적으로 비정질 구조가 형성되었으나 일부분에 결정질이 존재하고 있었으며, $800^{\circ}C$에서 2시간 열처리하면 FeB와 $Fe_{2}$B 상이 혼재된 구조를 얻었다. 250시간 볼밀처리한 $Fe_{5}$ $Si_{2}$$B_{3}$합금에서 전체적으로 비정질 구조를 얻을 수 있었고, 이 시료를 2시간, $800^{\circ}C$로 열처리 하였을 때 $Fe_{2}$B상은 사라지고, 대부분 FeB의 균질한 상을 나타내었다. $Fe_{5}$ $B_{5}$ /조성에서는 분말 입자크기가 약 $1\mu\textrm{m}$이었으나, Si이 첨가되면 분말 입자크기가 약 $10\mu\textrm{m}$로 커졌다. Si의 첨가에 의해서 비정질상의 형성을 촉진시켜 단일 FeB상의 합성시간을 단축시킬 수 있었다.

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PRECISE RATES IN THE LAW OF THE LOGARITHM FOR THE MOMENT CONVERGENCE OF I.I.D. RANDOM VARIABLES

  • Pang, Tian-Xiao;Lin, Zheng-Yan;Jiang, Ye;Hwang, Kyo-Shin
    • Journal of the Korean Mathematical Society
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    • v.45 no.4
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    • pp.993-1005
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    • 2008
  • Let {$X,\;X_n;n{\geq}1$} be a sequence of i.i.d. random variables. Set $S_n=X_1+X_2+{\cdots}+X_n,\;M_n=\max_{k{\leq}n}|S_k|,\;n{\geq}1$. Then we obtain that for any -1$\lim\limits_{{\varepsilon}{\searrow}0}\;{\varepsilon}^{2b+2}\sum\limits_{n=1}^\infty\;{\frac {(log\;n)^b}{n^{3/2}}\;E\{M_n-{\varepsilon}{\sigma}\sqrt{n\;log\;n\}+=\frac{2\sigma}{(b+1)(2b+3)}\;E|N|^{2b+3}\sum\limits_{k=0}^\infty\;{\frac{(-1)^k}{(2k+1)^{2b+3}$ if and only if EX=0 and $EX^2={\sigma}^2<{\infty}$.

Xanthium strumarium suppresses degranulation and pro-inflammatory cytokines secretion on the mast cells (비만세포에서의 창이자의 탈과립 및 pro-inflammatory cytokines 분비량에 미치는 영향)

  • Lyu, Ji-Hyo;Yoon, Hwa-Jung;Hong, Sang-Hoon;Ko, Woo-Shin
    • The Journal of Korean Medicine Ophthalmology and Otolaryngology and Dermatology
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    • v.21 no.3
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    • pp.82-93
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    • 2008
  • Objective: Previously, the methanol extracts of the semen of Xanthium strumsrium could involved anti-inflammatory effects in lipopolysaccharide (LPS)-stimulated Raw 264,7 cells, We evaluated the anti-allergic effects of X. strumarium on rat basophilic leukemia (RBL-2H3) cells, Methodes : To investigate the effect of X. strumarium on the phorbol 12-myristate 13-acetate (PMA) and calcium ionophore A23187-induced RBL-2H3 cells. The effects of X. strumarium on the degranulation and the pro-inflammatory cytokines secretion and expression from RBL-2H3 cells were evaluated with $\beta$-hexosaminidase assay, ELISA, and RT-PCR analysis, In addition, we examined the effects of X. strumarium on nuclear factor (NF)-${\kappa}B$ activation and $I{\kappa}B-\alpha$ degradation using Western blot analysis. Results : X. strumarium inhibited degranulation and secretions and expressions of pro-inflammatory cytokines, such as tumor necrosis factor-alpha ($TNF-\alpha$), interleukin (IL)-4 and cyclooxygenase (COX)-2, on stimulated RBL-2H3 cells, however, X. strumarium not affect cell viability. In stimulated RBL-2H3 cells, the protein expression level of nuclear factor-kappa B (NF-${\kappa}B$) was decreased in the nucleus by X. strumarium. In addition, X. strumarium suppressed the degradation of inhibitory protein $I{\kappa}B-{\alpha}$ protein in RBL-2H3 cells. Conclusion : These results suggest that X. strumarium inhibits the degranulation and secretion of pro-inflammatory cytokines through blockade of NF-${\kappa}B$ activation and I $I{\kappa}B-{\alpha}$ degradation.

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THE RULE OF TRAJECTORY STRUCTURE AND GLOBAL ASYMPTOTIC STABILITY FOR A FOURTH-ORDER RATIONAL DIFFERENCE EQUATION

  • Li, Xianyi;Agarwal, Ravi P.
    • Journal of the Korean Mathematical Society
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    • v.44 no.4
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    • pp.787-797
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    • 2007
  • In this paper, the following fourth-order rational difference equation $$x_{n+1}=\frac{{x_n^b}+x_n-2x_{n-3}^b+a}{{x_n^bx_{n-2}+x_{n-3}^b+a}$$, n=0, 1, 2,..., where a, b ${\in}$ [0, ${\infty}$) and the initial values $X_{-3},\;X_{-2},\;X_{-1},\;X_0\;{\in}\;(0,\;{\infty})$, is considered and the rule of its trajectory structure is described clearly out. Mainly, the lengths of positive and negative semicycles of its nontrivial solutions are found to occur periodically with prime period 15. The rule is $1^+,\;1^-,\;1^+,\;4^-,\;3^+,\;1^-,\;2^+,\;2^-$ in a period, by which the positive equilibrium point of the equation is verified to be globally asymptotically stable.