• 제목/요약/키워드: $T_m-shift$

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1-(phenoxymethyl)benzotriazole 유도체 중 methylene 양성자의 chemical shift 에 관한 자유에너지 관계의 조성과 용매 의존성 (Solvent Dependence and Component of Linear Free Energy Relationship on the Chemical Shift of Methylene Proton in 1-(phenoxymethlyl)benzotriazole Derivatives)

  • 성낙두
    • 대한화학회지
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    • 제33권5호
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    • pp.538-544
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    • 1989
  • 1-(phenoxymethyl)benzotriazole(1)과 1-(thiophenoxymethyl)benzotriazole(2) 유도체중의 X 치환기가 전자를 끄는 세기(${\rho}<0$)와 methylene group의 인접 Y원자에 의한 local diamagnetic effect(Y=O(1)>S(2)), 그리고 용매의 극성파라미터($E_T$=Kcal/mol:acetone;42.2>chloroform;39.0)가 클수록 methylene group의 수소원자($H_m$)와 용매사이에 B-형의 수소결합성이 증가되었으며 (1)의 methylene group 에 대한 substituent chemical shift($CH_2-SCS$)에 미치는 자유 에너지 직선관계(LFER)의 조성은 아세톤 용액 중에서 장(F)(또는 유발(I))-효과 보다 공명(R)-효과가 더 크게 나타나는 용매 의존적인 경향이었다.

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A NEW CRITERION FOR MOMENT INFINITELY DIVISIBLE WEIGHTED SHIFTS

  • Hong T. T. Trinh
    • 대한수학회논문집
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    • 제39권2호
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    • pp.437-460
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    • 2024
  • In this paper we present the weighted shift operators having the property of moment infinite divisibility. We first review the monotone theory and conditional positive definiteness. Next, we study the infinite divisibility of sequences. A sequence of real numbers γ is said to be infinitely divisible if for any p > 0, the sequence γp = {γpn}n=0 is positive definite. For sequences α = {αn}n=0 of positive real numbers, we consider the weighted shift operators Wα. It is also known that Wα is moment infinitely divisible if and only if the sequences {γn}n=0 and {γn+1}n=0 of Wα are infinitely divisible. Here γ is the moment sequence associated with α. We use conditional positive definiteness to establish a new criterion for moment infinite divisibility of Wα, which only requires infinite divisibility of the sequence {γn}n=0. Finally, we consider some examples and properties of weighted shift operators having the property of (k, 0)-CPD; that is, the moment matrix Mγ(n, k) is CPD for any n ≥ 0.

온도 및 구속응력을 고려한 토목섬유의 크리프거동에 관한 연구 (A Study on Creep Behavior of Geosynthetics Considering Effect of Temperature and Confining Stress)

  • 방윤경;김홍택
    • 한국지반공학회논문집
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    • 제19권5호
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    • pp.291-299
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    • 2003
  • 본 연구에서는, 토목섬유의 크리프시험시 온도 및 토목섬유에 가해지는 구속응력을 제어할 수 있도록 고안된 온도제어 구속크리프시험(Temperature Dependent Confined Creep Test)을 수행하였다. 시험결과를 토대로, 시험온도 및 구속응력의 크기가 토목섬유의 크리프특성에 미치는 영향을 정량적으로 분석하였으며, 장기적인 크리프변위를 예측하기 위하여 시간-온도 중첩원리를 이용한 합성곡선을 작도하여, 1$\times$$10^7$min.(Geomembrane D)∼1$\times$$10^{10}$min.(Geogrid T)까지의 크리프변위를 예측하였다. 본 합성곡선에 의해, 토목섬유에 가해지는 구속하중에 따른 토목섬유의 이동계수(shift factor)를 도출하였다. 온도제어 구속크리프시험은 시트형 지오그리드와 지오멤브레인을 대상으로 하였으며, 시험온도는 5∼4$0^{\circ}C$의 범위로, 구속하중의 크기는 0∼9t/$cm^2$의 범위로 하였다.

Initial Troponin Level as a Predictor of Prognosis in Patients with Intracerebral Hemorrhage

  • Chung, Pil-Wook;Won, Yu-Sam;Kwon, Young-Joon;Choi, Chun-Sik;Kim, Byung-Moon
    • Journal of Korean Neurosurgical Society
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    • 제45권6호
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    • pp.355-359
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    • 2009
  • Objective : It has been suggested that elevated cardiac troponin T (cTnT) level is a marker of increased risk of mortality in acute ischemic stroke and subarachnoid hemorrhage (SAH). However, the association of serum cTnT level and prognosis of intracerebral hemorrhage (ICH) has been sparsely investigated. The aim of this study was to identify the relationship between cTnT level and the outcome in patients with spontaneous ICH. Methods : We retrospectively investigated 253 patients identified by a database search from records of patients admitted in our department for ICH between January 1, 2003 and December 31, 2007. The patients were divided into 2 groups; the patients in group 1 (n=225) with serum cTnT values of 0.01 ng/mL or less, and those in group 2 (n=28) with serum cTnT values greater than 0.01 ng/mL. Results : The serum cTnT level was elevated in 28 patients. There were significant differences in sex, hypertension, creatine kinase-myocardial band, midline shift, side of hematoma, and presence of intraventricular hemorrhage between the 2 groups. Logistic regression analysis identified the level of consciousness on admission, cTnT and midline shift as independent predictors of hospital mortality. Conclusion : Theses results suggest that increased serum cTnT level at admission is associated with in-hospital mortality and the addition of a serum cTnT assay to routine admission testing should be considered in patients with ICH.

Device Coupling Effects of Monolithic 3D Inverters

  • Yu, Yun Seop;Lim, Sung Kyu
    • Journal of information and communication convergence engineering
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    • 제14권1호
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    • pp.40-44
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    • 2016
  • The device coupling between the stacked top/bottom field-effect transistors (FETs) in two types of monolithic 3D inverter (M3INV) with/without a metal layer in the bottom tier is investigated, and then the regime of the thickness TILD and dielectric constant εr of the inter-layer distance (ILD), the doping concentration Nd (Na), and length Lg of the channel, and the side-wall length LSW where the stacked FETs are coupled are studied. When Nd (Na) < 1016 cm-3 and LSW < 20 nm, the threshold voltage shift of the top FET varies almost constantly by the gate voltage of the bottom FET, but when Nd (Na) > 1016 cm-3 or LSW > 20 nm, the shift decreases and increases, respectively. M3INVs with TILD ≥ 50 nm and εr ≤ 3.9 can neglect the interaction between the stacked FETs, but when TILD or εr do not meet the above conditions, the interaction must be taken into consideration.

시계열분석을 이용한 한국 명태어업의 어획량 예측 : AIC (Prodiction of Walleye Pollock , Theragra Chalcogramma , Landings in Korea by Time Series Analysis : AIC)

  • 박해훈;윤갑동
    • 수산해양기술연구
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    • 제32권3호
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    • pp.235-240
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    • 1996
  • Forecasts of monthly landings of walleye pollock, Theragra chalcogramma, in Korea were carried out by the seasonal Autoregressive Integrated Moving Average(ARlMA) model. The Box - Cox transformation on the walleye pollock catch data handles nonstationary variance. The equation of Box - Cox transformation was Y'=($Y^0.31$_ 1)/0.31. The model identification was determined by minimum AIC(Akaike Information Criteria). And the seasonal ARlMA model is presented (1- O.583B)(1- $B^1$)(l- $B^12$)$Z_t$ =(l- O.912B)(1- O.732$B^12$)et where: $Z_t$=value at month t ; $B^p$ is a backward shift operator, that is, $B^p$$Z_t$=$Z_t$-P; and et= error term at month t, which is to forecast 24 months ahead the walleye pollock landings in Korea. Monthly forecasts of the walleye pollock landings for 1993~ 1994, which were compared with the actual landings, had an absolute percentage error(APE) range of 20.2-226.1 %. Thtal observed annual landings in 1993 and 1994 were 16, 61OM/T and 1O, 748M/T respectively, while the model predicted 10, 7 48M/T and 8, 203M/T(APE 37.0% and 23.7%, respectively).

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Characteristics of the Multi-Hydrogen Bonded Systems: DFT Description on the Solvated Electrons

  • Xu, Jun
    • Bulletin of the Korean Chemical Society
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    • 제34권11호
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    • pp.3265-3268
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    • 2013
  • The multi-hydrogen bonded systems with the solvated electrons are investigated at the B3LYP/6-311++$G^{**}$ basis set level. The symmetrical linear geometrical characteristic is common for the dimer systems, while for the tetramer system, the tetrahedron configuration is generated. The NBO charge analyses demonstrate that the multi-hydrogen-multi-electron (mH-ne) coupling exist in these anion systems, as is supported by the electrostatic potential and the molecular orbital analyses. The positive chemical shift value of the central hydrogen ($H_c$) and the negative chemical shift value of the terminal hydrogen ($H_t$) indicate that the $H_c$ is electronegative while the $H_t$ is electropositive, respectively. Strong coupling between two central hydrogen atoms is demonstrated by the large spin-spin coupling constants. The solvated electron donates significant contributions for the stability of these systems.

교대근무자의 카페인 섭취가 수면의 질에 미치는 영향 (Effect of Ingested Caffeine on the Sleep Quality among Shift Workers)

  • 김혜성;이종은
    • 한국직업건강간호학회지
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    • 제29권4호
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    • pp.306-315
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    • 2020
  • Purpose: This study was conducted to identify the effects of caffeine intake by shift workers on sleep, considering various variable related to the sleep health of shift workers. Methods: A descriptive survey study was conducted with 128 employees who worked shifts. Respondents were surveyed on their of caffeine intake behavior, schedule type, quality of sleep, health promotion behavior, and occupational stress. Differences in their quality of sleep were assessed using the t-test and analysis of variance, while factors influencing the effect of caffeine intake on the quality of sleep were analyzed using hierarchical logistic regression. Results: The average Pittsburgh Sleep Index, Korean Version score of those surveyed was 7.3±3.25, indicating that their quality of sleep was low. On the other hand, their aveage daily intake of caffeine was 1.6±0.99 cups (1 cup =150 mL) and 116.4±77.58 mg/dL of caffeine. When the various variables that could have affected the quality of sleep were corrected, an increase in the amount of caffeine consumed was found to lead to a decrease in the quality of sleep (p=.015). Conclusion: Caffeine intake by shift workers has a significant bearing on their quality of sleep; therefore, such intake should be adjusted to improve their sleep health.

비선형수열의 상호상관함수 분석 (Analysis of cross-correlation functions of non-linear sequences)

  • 조성진;임지미
    • 한국정보통신학회논문지
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    • 제17권5호
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    • pp.1138-1144
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    • 2013
  • 최대주기를 갖는 수열들의 상호상관함수에 대한 연구는 수십년간 이루어져 왔다. 본 논문에서는 n=2m을 만족하고 최대주기 $2^n-1$을 가지면서 Niho type의 데시메이션 $d=2^{m-2}(2^m+3)$에 대하여 비선형수열$S_a^r(t)=Tr_1^m\{[Tr_m^n(a{\alpha}^t+{\alpha}^{dt})]^r\}$의 상호상관함수 값을 구한다. 특히, $d{\equiv}1(mod\;2^m-1)$을 만족하는 d를 Niho type의 데시메이션 이라고 한다. 그리고 위상이동차 ${\tau}=(2^m+1)k(0{\leq}k{\leq}2^m-2)$인 경우에 대하여 $S_a^r(t)$의 상호상관함수 값의 분포를 분석하고 실험 결과를 제시한다.

THE SPIN REORIENTATION AND THE MAGNETI ANISOTROPY IN $R_{2}Fe_{17-x}M_{x}C_{y}$ (R=Er, Tm, M=Al, Ga)

  • Ohno, K.;Urakabe, T.;Agata, M.;Saito, T.;Shinagawa, K.;Tsushima, T.
    • 한국자기학회지
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    • 제5권5호
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    • pp.437-441
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    • 1995
  • In order to consider the change of the magnetic anisotropy energy by the Al or Ga substitution for Fe, spin reorientation temperature $T_{SR}$ and Curie temperature $T_{c}$ in $R_{2}Fe_{17-x}M_{x}$ (R=Er, Tm, M=Al, Ga) have been studied both experimentally and theoretically. As a result, $T_{SR}$ and $T_{c}$ for $R_{2}Fe_{17-x}M_{x}$ shift toward higher temperature side with x ($0{\leq}x{\leq}2.0$). The ${\Delta}T_{c}$ the difference of the $T_{c}'s$ between $Er_{2}Fe_{17-x}Al_{x}$ and $Tm_{2}Fe_{17-x}Al_{x}$, is always about 10 K independent of Al-content. But in the case of Ga substitution, the ${\Delta}T_{c}$ increases with Ga-content ; especially, the ${\Delta}T_{c}$ for x=2.0 is 43 K. This value of the ${\Delta}T_{c}$ is not explained by only the difference of the de Gennes fator G between $Er^{3+}$ and $Tm^{3+}$, but it is thought that the values of $J_{ErFe}$ and $J_{TmFe}$ themselves are not equal. ($J_{AB}$ : the exchange interaction between A and B.)

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