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Removal of Nitrogen Oxides Using Hydrocarbon Selective Catalytic Reduction Coupled with Plasma (플라즈마가 결합된 탄화수소 선택적 촉매환원 공정에서 질소산화물(NOx)의 저감)

  • Ihm, Tae Heon;Jo, Jin Oh;Hyun, Young Jin;Mok, Young Sun
    • Applied Chemistry for Engineering
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    • v.27 no.1
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    • pp.92-100
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    • 2016
  • Low-temperature conversion of nitrogen oxides using plasma-assisted hydrocarbon selective catalytic reduction of (HC-SCR) was investigated. Plasma was created in the catalyst-packed bed so that it could directly interact with the catalyst. The effect of the reaction temperature, the shape of catalyst, the concentration of n-heptane as a reducing agent, the oxygen content, the water vapor content and the energy density on $NO_x$ removal was examined. $NO_x$ conversion efficiencies achieved with the plasma-catalytic hybrid process at a temperature of $250^{\circ}C$ and an specific energy input (SIE) of $42J\;L^{-1}$ were 83% and 69% for one-dimensional Ag catalyst ($Ag\;(nanowire)/{\gamma}-Al_2O_3$) and spherical Ag catalyst ($Ag\;(sphere)/{\gamma}-Al_2O_3$), respectively, whereas that obtained with the catalyst-alone was considerably lower (about 30%) even with $Ag\;(nanowire)/{\gamma}-Al_2O_3$ under the same condition. The enhanced catalytic activity towards $NO_x$ conversion in the presence of plasma can be explained by the formation of more reactive $NO_2$ species and partially oxidized hydrocarbon intermediates from the oxidation of NO and n-heptane under plasma discharge. Increasing the SIE tended to improve $NO_x$ conversion efficiency, and so did the increase in the n-heptane concentration; however, a further increase in the n-heptane concentration beyond $C_1/NO_x$ ratio of 5 did not improve the $NO_x$ conversion efficiency any more. The increase in the humidity affected negatively the $NO_x$ conversion efficiency, resulting in lowering the $NO_x$ conversion efficiency at the higher water vapor content, because water molecules competed with $NO_x$ species for the same active site. The $NO_x$ conversion efficiency increased with increasing the oxygen content from 3 to 15%, in particular at low SIE values, because the formation of $NO_2$ and partially oxidized hydrocarbon intermediates was facilitated.

An Experimental Study of Corrosion Characteristics and Compounds by Corrosion Factors in Iron Artifacts (철제유물 부식인자에 대한 부식양상 및 부식화합물 실험 연구)

  • Park, Hyung Ho;Lee, Jae Sung;Yu, Jae Eun
    • 보존과학연구
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    • s.33
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    • pp.33-43
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    • 2012
  • The corrosion phenomena of the iron artifacts was studied by morphology observation and instrumental analysis(EDS, XRD, Raman) with various corrosion factors in oder to verify to confirm the danger of corrosion factors. Corrosion compounds were collected by depositing pure Fe powder(99%) into a HCl, $HNO_3$, $H_2SO_4$, and $H_2O$ solution which contained the corrosion factors. Stereoscopic-microscope observations were then conducted determine the colors and shapes of the collected corrosion compounds, and SEM-EDS analysis was conducted to confirm the corrosion factors and the growth of these compounds. X-ray diffraction (XRD), Raman analyses were conducted to examine the crystal structure and compositions of the created corrosion compounds. The results of the experiment revealed that corrosion speed was faster in an acidic environment and corrosion of HCl and $H_2SO_4$ was greater than that of $HNO_3$. The corrosion compounds of HCl grew into a needle or chestnut-like shape after being affected by Cl- ion, and XRD and Raman analyses detected goethite and lepidocrocite. The corrosion compounds of $H_2SO_4$ was affected by S ion and grew into a slender-needle-like or cylindrical shape, and the XRD and Raman analyses detected goethite and lepidocrocite. The corrosion compounds of $HNO_3$ grew into a spherical or plate-like shape after being affected by O ion and the XRD and Raman analyses detected magnetite and lepidocrocite. Although the corrosion compounds of $H_2O$ grew into a spherical or plate-like shape after being affected by O ion, most of them were observed to have had spherical shapes, and the XRD and Raman analyses failed to detect corrosion compounds in them. It was found in the study that corrosion characteristics and compounds are diversely displayed according to the corrosion factor.

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Measurement of Skin Dose Distribution for the Mobile X-ray Unit Collimator Shielding Device (이동형 X선 장치 차폐도구 제작을 통한 표면선량 분포 측정)

  • Hong, Sun-Suk;Kim, Deuk-Yong
    • Korean Journal of Digital Imaging in Medicine
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    • v.12 no.1
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    • pp.5-8
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    • 2010
  • Opened a court in February 10, 2006, a rule of safety management of the diagnosis radiation system was promulgated for safety of the radiation worker, patients and patients' family members. The purpose of this rule is to minimize the risk of being exposed to radiation during the process of handling X-ray. For this reason, we manufactured shielding device of mobile X-ray unit collimator for diminution of skin dose. Shielding device is made to a thickness of Pb 0.375mm. For portable chest radiography, we measured skin dose 50cm from center ray to 200cm at intervals of 20cm by Unfors Xi detector. As a result, a rule of safety management of the diagnosis radiation system has been strengthened. But there are exceptions, such as ER, OR, ICU to this rule. So shielding device could contribute to protect unnecessary radiation exposure and improve nation's health.

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Orthogonality Measurement of Square Plane Mirrors for Laser Interferometry (레이저 간섭계의 직각 평면거울에 대한 직각도 오차 측정)

  • 김태호;김승우
    • Journal of the Korean Society for Precision Engineering
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    • v.15 no.12
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    • pp.169-179
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    • 1998
  • Plane mirror type laser interferometers are popularly being used in many modern ultraprecision machines, as they can perform simultaneous measurements of multiple axis positions with nanometer resolution capabilities. One important issue in this application of laser interferometers is to provide a good level of alignment between the reflecting mirrors and the laser beams so that measurement errors due to undesirable coupling effects can be avoided in multiple axis measurements In this investigation, a thorough metrological analysis is given to develop an suitable mathematical model for a precision x-y stage in which the orthogonality misalignment between the reflecting mirrors significantly affects overall x-y mea-surement results. Then a noble calibration method is suggested in which two-dimensional displacement sensors of moire gratings of concentric circles are used to realize the reversal principle of orthogonality evaluation in situ. Finally, actual experimental results are discussed to verify that the suggested method can effectively calibrate the orthogonality error with an uncertainty of 0.2667 arcsec.

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A NEW CHARACTERIZATION OF PRÜFER v-MULTIPLICATION DOMAINS

  • CHANG, GYU WHAN
    • Korean Journal of Mathematics
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    • v.23 no.4
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    • pp.631-636
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    • 2015
  • Let D be an integral domain and w be the so-called w-operation on D. In this note, we introduce the notion of *(w)-domains: D is a *(w)-domain if $(({\cap}(x_i))({\cap}(y_j)))_w={\cap}(x_iy_j)$ for all nonzero elements $x_1,{\ldots},x_m$; $y_1,{\ldots},y_n$ of D. We then show that D is a $Pr{\ddot{u}}fer$ v-multiplication domain if and only if D is a *(w)-domain and $A^{-1}$ is of finite type for all nonzero finitely generated fractional ideals A of D.

Economic Design of Synthetic Control Charts (합성 관리도의 경제적 설계)

  • 임태진;김용덕
    • Journal of Korean Society for Quality Management
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    • v.31 no.2
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    • pp.117-130
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    • 2003
  • This paper investigates the economic design of synthetic control charts. The synthetic control chart has been proven to be statistically superior to the $\bar{X}$-control chart, but its economic characteristics have not been known. We develop an economic model of the synthetic control chart, based on Duncan's model. The synthetic chart has one more decision variable, the lower control limit for the conforming run length. In addition to this, the significance level and the power of the synthetic chart are more complicated than those of the $\bar{X}$-chart. These features make the optimization problem more difficult. We propose an optimization algorithm by adapting the congruent gradient algorithm. We compare the optimal cost of the synthetic chart with that of (equation omitted)-control chart, under the same input parameter set of Duncan’s. For all cases investigated, the synthetic chart shows superior to the $\bar{X}$-chart. The synthetic control chart is easy to implement, and it has better characteristics than the $\bar{X}$-chart in economical sense as well as in statistical sense, so it will be a good alternative to the traditional control charts.

On the Optimal Adaptive Estimation in the Semiparametric Non-linear Autoregressive Time Series Model

  • So, Beong-Soo
    • Journal of the Korean Statistical Society
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    • v.24 no.1
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    • pp.149-160
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    • 1995
  • We consider the problem of optimal adaptive estiamtion of the euclidean parameter vector $\theta$ of the univariate non-linerar autogressive time series model ${X_t}$ which is defined by the following system of stochastic difference equations ; $X_t = \sum^p_{i=1} \theta_i \cdot T_i(X_{t-1})+e_t, t=1, \cdots, n$, where $\theta$ is the unknown parameter vector which descrives the deterministic dynamics of the stochastic process ${X_t}$ and ${e_t}$ is the sequence of white noises with unknown density $f(\cdot)$. Under some general growth conditions on $T_i(\cdot)$ which guarantee ergodicity of the process, we construct a sequence of adaptive estimatros which is locally asymptotic minimax (LAM) efficient and also attains the least possible covariance matrix among all regular estimators for arbitrary symmetric density.

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FINDING THE NATURAL SOLUTION TO f(f(x)) = exp(x)

  • Paulsen, William
    • Korean Journal of Mathematics
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    • v.24 no.1
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    • pp.81-106
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    • 2016
  • In this paper, we study the fractional iterates of the exponential function. This is an unresolved problem, not due to a lack of a known solution, but because there are an innite number of solutions, and there is no agreement as to which solution is "best." We will approach the problem by rst solving Abel's functional equation ${\alpha}(e^x)={\alpha}(x)+1$ by perturbing the exponential function so as to produce a real xed point, allowing a unique holomorphic solution. We then use this solution to nd a solution to the unperturbed problem. However, this solution will depend on the way we rst perturbed the exponential function. Thus, we then strive to remove the dependence of the perturbed function. Finally, we produce a solution that is in a sense more natural than other solutions.

Speed Up Test on conventional Line by using Korean High Speed Train(HSR-350x) (한국형 고속 전철을 활용한 기존선 속도향상 고찰)

  • Kim Ki-Hwan;Park Choon-Soo;Kim Seok-Won
    • Proceedings of the KSR Conference
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    • 2004.06a
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    • pp.334-338
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    • 2004
  • KTX has started commercial service from Seoul to Busan and Mokpo since April 1, 2004. The service line is composed of new-high speed line and conventional line. Before KTX is runs, the maximum operational speed on conventional line was 140km/h. In order to reduce the traveling time, operation speed of KTX must be increased on the conventional line. So, we performed test running with prototype HSR-350x and verification of safety was made in $10\%$ speed-up. Korean High Speed Train HSR-350x) was developed by G7 - R&D project. In this study, in safety aspect, several technical reviews are introduced and the possibility for reduction of traveling time is investigated on the conventional line by using HSR-350x.

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Material Design for the Fabrication of Barrier Ribs with High Aspect Ratio of Plasma Display Panel by X-ray Lithography

  • Ryu, Seung-Min;Yang, Dong-Yol;So, Jae-Yong;Park, Lee-Soon
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.989-992
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    • 2008
  • X-ray lithography is one of the most powerful processes in the fabrication of nano/micro structures with a high aspect ratio. This process enables the fabrication of ultra-thin barrier ribs for PDP using X-ray sensitive paste. In this paper, organic material including photo-monomers, photo-oligomers, binder polymer and additives as well as inorganic powders with different size were optimized to fabricate high aspect ratio barrier rib pattern for PDP.

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