• Title/Summary/Keyword: $N_2O$ emission

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Nitrous Oxide Emissions from Red Pepper, Chinese Cabbage, and Potato Fields in Gangwon-do, Korea

  • Seo, Youngho;Kim, Gunyeob;Park, Kijin;Kim, Kyunghi;Jung, Yeong-Sang
    • Korean Journal of Soil Science and Fertilizer
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    • v.46 no.6
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    • pp.463-468
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    • 2013
  • The level of nitrous oxide ($N_2O$), a long-lived greenhouse gas, in atmosphere has increased mainly due to anthropogenic source, especially application of nitrogen fertilizers. Quantifying $N_2O$ emission from agricultural field is essential to develop national inventories of greenhouse gases (GHGs) emission. The objective of the study was to develop emission factor to estimate direct $N_2O$ emission from agricultural field in Gangwon-do, Korea by measuring $N_2O$ emissions from potato (Solanum tuberosum), red pepper (Capsicum annum L.), and Chinese cabbage (Brassica campestris L.) cultivation lands from 2009 to 2012. Accumulated $N_2O$ emission was $1.48{\pm}0.25kg$ $N_2O-N\;ha^{-1}$ for red pepper, $1.27{\pm}0.27kg$ $N_2O-N\;ha^{-1}$ for potato, $1.49{\pm}0.06kg$ $N_2O-N\;ha^{-1}$ for Chinese cabbage cultivated in spring, and $1.14{\pm}0.22kg$ $N_2O-N\;ha^{-1}$ for fall Chinese cabbage. Emission factor of $N_2O$ calculated from accumulated $N_2O$ emission, nitrogen fertilization rate, and background $N_2O$ emission was $0.0051{\pm}0.0016kg$ $N_2O-N\;ha^{-1}$ N for cropland in Gangwon province. More extensive study is deserved to be conducted to develop $N_2O$ emission factor for upland crops in Korea through examining the emission factors from various regions and crops because $N_2O$ emission is influenced by many factors including climate characteristics, soil properties, and agricultural practices.

Developing N2O Emission Factor in Red Pepper Fields to Quantify N2O Emission of Agricultural Field

  • Kim, Gun-Yeob;Park, Woo-Kyun;Lee, Jong-Sik;Jeong, Hyun-Cheol;Lee, Sun-Il;Choi, Eun-Jung;Kim, Pil-Joo;Seo, Young-Ho
    • Korean Journal of Soil Science and Fertilizer
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    • v.47 no.6
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    • pp.598-603
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    • 2014
  • The level of nitrous oxide ($N_2O$), a long-lived greenhouse gas, in atmosphere has increased mainly due to anthropogenic sources, especially application of nitrogen fertilizers. Quantifying $N_2O$ emission in the agricultural field is essential to develop National inventories of greenhouse gases (GHGs) emission. The objective of this study was to develop emission factor to estimate direct $N_2O$ emission from agricultural field by measuring $N_2O$ emissions in the red pepper cultivating field from 2010 to 2012. Emission factor of $N_2O$ calculated from accumulated $N_2O$ emission, nitrogen fertilization rate, and background $N_2O$ emission was $0.0086{\pm}0.00043kg$ $N_2O-N\;kg^{-1}$ N resulted from three year experiment of the research sites. More extensive studies need to be conducted to develop $N_2O$ emission factors for other upland crops in the various regions of Korea because $N_2O$ emission is influenced by many factors including climate characteristics, soil properties, and agricultural practices.

Assessment of N2O Emission Factor of Autumn Chinese Cabbage Fields at Three Different Geographical Location in South Korea

  • Kim, Gun-Yeob;Park, Woo-Kyun;Jeong, Hyun-Cheol;Lee, Sun-il;Kim, Pil-Joo;Seo, Young-Ho;Na, Un-sung
    • Korean Journal of Soil Science and Fertilizer
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    • v.48 no.3
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    • pp.163-169
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    • 2015
  • The level of nitrous oxide ($N_2O$), a long-lived greenhouse gas, in atmosphere has increased mainly due to anthropogenic sources, especially application of nitrogen fertilizers. Quantifying $N_2O$ emission in the agricultural field is essential to develop national inventories of greenhouse gases (GHGs) emission. The objective of this study was to develop an emission factor to estimate the direct $N_2O$ emission from an agricultural field cultivated with the Chinese cabbage during autumn season in 2010-2012. Emission factor of $N_2O$ calculated over three years experiment using accumulated $N_2O$ emission, nitrogen fertilization rate, and background $N_2O$ emission was $0.0058{\pm}0.00254kg\;N_2O-N\;kg^{-1}\;N$. More extensive studies need to be conducted to develop $N_2O$ emission factors for other upland crops in the various regions of Korea because $N_2O$ emission is influenced by many factors including climate characteristics, soil properties, and agricultural practices as well as crop species.

The Development of N2O Emission Factor at Municipal Solid Waste Incinerator (도시고형폐기물 소각시설의 N2O 배출계수 개발)

  • Ko, Jae Churl;Choi, Sang Hyun
    • Clean Technology
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    • v.25 no.1
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    • pp.40-45
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    • 2019
  • In this study, nitrous oxide ($N_2O$) emission concentration was measured 3 times continuously for 24 hours from August 27, 2018 to October 22, 2018 and non-dispersive infrared (NDIR) spectrometer was used to calculate $N_2O$ concentration of exhaust gas from municipal solid waste (MSW) incinerator. As a result of $N_2O$ emission characteristics, it is estimated that $N_2O$ emission concentration is due to the difference of furnace temperature, oxygen concentration rather than the chemical component of waste. The measured $N_2O$ emission concentration of MSW incinerator was obtained in the range of 53.6 ~ 59.5 ppm and the total average concentration was measured 55.6 ppm. Therefore, the amount of $N_2O$ emissions calculated from the $N_2O$ concentration was $98.05kg\;day^{-1}$ on average and the amount of $N_2O$ distribution in the range of $90.41{\sim}108.44kg\;day^{-1}$ was obtained. As a result, the $N_2O$ emission factor of the MSW incinerator was estimated to be $1,066.13g_{N_2O}\;ton_{waste^{-1}}$. The estimated $N_2O$ emission factor of the MSW incinerator was 20 times higher than calculated emission factor used in the Tier 2 method. Consequently, it is considered that the method of calculating the amount of $N_2O$ emission in the MSW incineration facilities using waste type and incineration amount needs to be supplemented to ensure accuracy.

Effect of Ammonium Concentration on the Emission of $N_2O$ Under Oxygen-Limited Autotrophic Wastewater Nitrification

  • Kim, Dong-Jin;Kim, Yu-Ri
    • Journal of Microbiology and Biotechnology
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    • v.21 no.9
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    • pp.988-994
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    • 2011
  • A significant amount of nitrous oxide ($N_2O$), which is one of the serious greenhouse gases, is emitted from nitrification and denitrification of wastewater. Batch wastewater nitrifications with enriched nitrifiers were carried out under oxygen-limited condition with synthetic (without organic carbon) and real wastewater (with organic carbon) in order to find out the effect of ammonium concentration on $N_2O$ emission. Cumulated $N_2O$-N emission reached 3.0, 5.7, 6.2, and 13.5 mg from 0.4 l of the synthetic wastewater with 50, 100, 200, and 500 mg/l ${NH_4}^+$-N, respectively, and 1.0 mg from the real wastewater with 125 mg/l ${NH_4}^+$-N. The results indicate that $N_2O$ emission increased with ammonium concentration and the load. The ammonium removal rate and nitrite concentration also increased $N_2O$ emission. Comparative analysis of $N_2O$ emission from synthetic and real wastewaters revealed that wastewater nitrification under oxygen-limited condition emitted more $N_2O$ than that of heterotrophic denitrification. Summarizing the results, it can be concluded that denitrification by autotrophic nitrifiers contributes significantly to the $N_2O$ emission from wastewater nitrification.

Assessment of Integrated N2O Emission Factor for Korea Upland Soils Cultivated with Red Pepper, Soy Bean, Spring Cabbage, Autumn Cabbage and Potato

  • Kim, Gun-Yeob;Na, Un-Sung;Lee, Sun-Il;Jeong, Hyun-Cheol;Kim, Pil-Joo;Lee, Jong-Eun;Seo, Young-Ho;Lee, Jong-Sik;Choi, Eun-Jung;Suh, Sang-Uk
    • Korean Journal of Soil Science and Fertilizer
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    • v.49 no.6
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    • pp.720-730
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    • 2016
  • Greenhouse-gas emission factors are widely used to estimate emissions arising from a defined unit of a specific activity. Such estimates are used both for international reporting to the United Nations Framework Convention on Climate Change (UNFCCC) and for myriad national and sub-national reporting purposes (for example, European Union Emissions Trading Scheme; EU ETS). As with the other so-called 'Kyoto protocol GHGs', the Intergovernmental Panel on Climate Change (IPCC) provides a methodology for national and sub-national estimation of $N_2O$ emissions, based on the sector from which the emissions arise. The objective of this study was to develop a integrated emission factor to estimate the direct $N_2O$ emission from an agricultural field cultivated with the red pepper, soy bean, spring cabbage, autumn cabbage and potato in 2010~2012. Emission factor of $N_2O$ calculated using accumulated $N_2O$ emission, N fertilization rate, and background $N_2O$ emission over three year experiment was $0.00596{\pm}0.001337kg$ $N_2O-N(N\;kg)^{-1}$. More extensive studies need to be conducted to develop $N_2O$ emission factors for other upland crops in the various regions of Korea because $N_2O$ emission is influenced by many factors including climate characteristics, soil properties, and agricultural practices.

Effect of Nitrogen Application Rates on Nitrous Oxide Emission during Crop Cultivations in Upland Soil

  • Lee, Jong-Eun;Yun, Yeo-Uk;Choi, Moon-Tae;Jung, Suck-Kee;Nam, Yun-Gyu;Pramanik, Prabhat;Kim, Pil-Joo
    • Korean Journal of Environmental Agriculture
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    • v.31 no.3
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    • pp.205-211
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    • 2012
  • BACKGROUND: Generally, nitrogen (N) fertilization higher than the recommended dose is applied during vegetable cultivation to increase productivity. But higher N fertilization also increases the concentrations of nitrate ions and nitrous oxide in soil. In this experiment, the impact of N fertilization was studied on nitrous oxide ($N_2O$) emission to standardize the optimum fertilization level for minimizing $N_2O$ emission as well as increasing crop productivity. Herein, we developed $N_2O$ emission inventory for upland soil region during red pepper and Chinese milk vetch cultivation. METHODS AND RESULTS: Nitrogen fertilizers were applied at different rates to study their effect on $N_2O$ emission during red pepper and Chinese milk vetch cultivation. The gas samples were collected by static closed chamber method and $N_2O$ concentration was measured by gas chromatography. The total $N_2O$ flux was steadily increased due to increasing N fertilization level, though the overall pattern of $N_2O$ emission dynamics was same. Application of N fertilization higher than the recommended dose increased the values of both seasonal $N_2O$ flux (94.5% for Chinese cabbage and 30.7% for red pepper) and $N_2O$ emission per unit crop yield (77.9% for Chinese cabbage and 23.2% for red pepper). Nitrous oxide inventory revealed that the $N_2O$ emission due to unit amount of N application from short-duration vegetable field in fall (autumn) season (6.36 kg/ha) was almost 70% higher than that during summer season. CONCLUSION: Application of excess N-fertilizers increased seasonal $N_2O$ flux especially the $N_2O$ flux per unit yield during both Chinese cabbage and red pepper cultivation. This suggested that the higher N fertilization than the recommended dose actually facilitates $N_2O$ emission than boosting plant productivity. The $N_2O$ inventory for upland farming in temperate region like Korea revealed that $N_2O$ flux due to unit amount of N-fertilizer application for Chinese cabbage in fall (autumn) season was comparatively higher than that of summer vegetables like red pepper. Therefore, the judicious N fertilization following recommended dose is required to suppress $N_2O$ emission with high vegetable productivity in upland soils.

Selective Inhibition of Ammonia Oxidation and Nitrite Oxidation Linked to $N_2O$ Emission with Activated Sludge and Enriched Nitrifiers

  • Ali, Toor Umair;Kim, Minwook;Kim, Dong-Jin
    • Journal of Microbiology and Biotechnology
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    • v.23 no.5
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    • pp.719-723
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    • 2013
  • Nitrification in wastewater treatment emits a significant amount of nitrous oxide ($N_2O$), which is one of the major greenhouse gases. However, the actual mechanism or metabolic pathway is still largely unknown. Selective nitrification inhibitors were used to determine the nitrification steps responsible for $N_2O$ emission with activated sludge and enriched nitrifiers. Allylthiourea (86 ${\mu}M$) completely inhibited ammonia oxidation and $N_2O$ emission both in activated sludge and enriched nitrifiers. Sodium azide (24 ${\mu}M$) selectively inhibited nitrite oxidation and it led to more $N_2O$ emission than the control experiment both in activated sludge and enriched nitrifiers. The inhibition tests showed that $N_2O$ emission was mainly related to the activity of ammonia oxidizers in aerobic condition, and the inhibition of ammonia monooxygenase completely blocked $N_2O$ emission. On the other hand, $N_2O$ emission increased significantly as the nitrogen flux from nitrite to nitrate was blocked by the selective inhibition of nitrite oxidation.

A Revised Estimate of N2O Emission Factor for Spring Chinese cabbage fields in Korea (국내 봄배추 재배지의 아산화질소 배출계수 개발에 관한 연구)

  • Kim, Gun-Yeob;Park, Woo-Kyun;Jeong, Hyun-Cheol;Lee, Sun-il;Choi, Eun-Jung;Kim, Pil-Joo;Seo, Young-Ho;Na, Un-sung
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.17 no.4
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    • pp.326-332
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    • 2015
  • Greenhouse-gas emission factors are widely used to estimate emissions arising from a defined unit of a specific activity. Such estimates are used both for international reporting to the United Nations Framework Convention on Climate Change (UNFCCC) and for a myriad of national and subnational reporting purposes. The Intergovernmental Panel on Climate Change (IPCC) provides a methodology for national and sub-national estimation of known greenhouse gas emissions including $N_2O$ for each sector from which the emissions arise. The objective of this study was to develop an emission factor to estimate the direct $N_2O$ emission from an agricultural field cultivated with Chinese cabbage during spring season in 2010-2012. An estimated emission factor of $N_2O$ calculated over three years from field experiment accounting for cumulative $N_2O$ emission, nitrogen fertilization rate, and background $N_2O$ emission was $0.0056{\pm}0.00254$ (95% CI) Kg $N_2O-N/kg$ N. More extensive studies are needed to develop $N_2O$ emission factors for other upland crops in various regions of Korea because $N_2O$ emission is influenced by many factors including climate characteristics, soil properties agricultural practices and crop species.

Emission Control Technologies for N2O from Adipic Acid Production Plants (아디픽산 제조공정으로부터 발생되는 N2O에 대한 배출제어기술)

  • Kim, Moon-Hyeon
    • Journal of Environmental Science International
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    • v.20 no.6
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    • pp.755-765
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    • 2011
  • Nitrous oxide ($N_2O$) is one of six greenhouse gases listed up in the Kyoto Protocol, and it effects a strong global warming because of its much greater global warming potential (GWP), by 310 times over a 100-year time horizon, than $CO_2$. Although such $N_2O$ emissions from both natural and anthropogenic sources occur, the latter can be controlled using suitable abatement technologies, depending on them, to reduce $N_2O$ below acceptable or feasible levels. This paper has extensively reviewed the anthropogenic $N_2O$ emission sources and their related compositions, and the state-of-the-art non-catalytic and catalytic technologies of the emissions controls available currently to representative, large $N_2O$ emission sources, such as adipic acid production plants. Challengeable approaches to this source are discussed to promote establishment of advanced $N_2O$ emission control technologies.