• Journal of the Korean Society for Heat Treatment
• /
• v.13 no.5
• /
• pp.337-345
• /
• 2000

As a case hardening process for stainless steels, nitriding is more preferred and widely used than carburizing which deterioates corrosion resistance severely. In order to add the nitrogen into the stainless steels, passive film on the surface must be removed effectively before nitriding. Conventional gas nitriding process is performed in the temperature range of 500 to $600^{\circ}C$ with $NH_3$ gas, which often leads to sensitization of stainless steels. In this study, we tried to activate passive film of austenitic stainless steels by heating at low pressure. ($900^{\circ}C$, $5{\times}10^{-2}$ Torr.) Nitriding was performed at the solution treatment temperature of $1100^{\circ}C$ with nitrogen molecules instead of $NH_3$ gas. An attainable nitrogen content in a case depends on the nitrogen gas pressure at constant nitriding temperature. A case depth is proportional to the square root of solution time, which suggests that inward diffusion of nitrogen follows the Fick's 2nd law. Surface nitrogen atoms are dissolved as interstitial solutes, or precipitated in the form of MN, $M_2N$ nitrides, which increase the case hardeness. Dissolved nitrogen in the case enhances the cavitation resistance of austenitic stainless steels dramatically.

• Journal of the Institute of Electronics Engineers of Korea SC
• /
• v.43 no.4 s.310
• /
• pp.21-29
• /
• 2006

A fuzzy ARTMAP neural network and a fuzzy ART neural network are proposed to identify $H_2S,\;NH_3$, and their mixtures and to estimate their concentrations, respectively. Features are extracted from a tin oxide gas sensor operated in a thermal modulation plan. After dimensions of the features are reduced by a preprocessing scheme, the features are fed into the proposed fuzzy neural networks. By computer simulations, the proposed method is shown to be fast in learning and stable in concentration estimating compared with other methods.

• Electrical & Electronic Materials
• /
• v.9 no.1
• /
• pp.9-17
• /
• 1996

Plasma enhanced chemical vapor deposition (PECVD) allows low temperature processing and so it is widely used, but it causes instability of devices due to serious amount of impurities within the film. In this paper, electrical and chemical characteristics of the PECVD oxynitride film formed by different N$_{2}$O to N$_{2}$O+NH$_{3}$ gas ratio is studied. It has been found that hydrogen concentration of PECVD oxynitride film was decreased from 4.25*10$^{22}$ [cm$^{-2}$ ] to 1.18*10$^{21}$ [cm$^{-2}$ ] according to the increase of N$_{2}$O gas. It was also found that PECVD oxynitride films have low trap density in the oxide and interface in comparison with PECVD nitroxide films, and has higher refractive index and capacitance than oxide films. In particular, oxynitride film formed in gas ratio of N$_{2}$O/(N$_{2}$O+NH$_{3}$)= 0.88 shows increased capacitance and decreased leakage current due to small portion of hydrogen in oxide and the accumulation of nitrogen about 4[atm.%] at the interface.

• Journal of Korean Society of Environmental Engineers
• /
• v.30 no.12
• /
• pp.1287-1293
• /
• 2008

In this study, a blend of 2-amino-2-methyl-1-propanol (AMP) and ammonia (NH$_3$) was used to achieve high absorption rates for carbon dioxide (CO$_2$) as suggested at several literatures. The absorption rates of aqueous AMP and blended AMP+NH$_3$ solutions with CO$_2$ and nitrogen dioxide (NO$_2$) were measured using a stirred-cell reactor at 303 K. The effect of the added NH$_3$ to enhance absorption characteristics of AMP was studied. The performances were evaluated under various operating conditions. The absorption rates increased following the increase of the concentration of NH$_3$. The absorption rate of NH$_3$ blended into 30 wt.% AMP solution with NO$_2$ at 303 K was 12.6$\sim$32.6% higher than that of aqueous AMP solution without NH3. Also, the addition of 3 wt.% NH$_3$ to 30 wt.% AMP increased 48.2$\sim$41.6% values for the reactions with CO$_2$ and NO$_2$ at 303 K. Therefore, it clearly shows that the reaction rate of AMP with CO$_2$ and NO$_2$ can be increased by the addition of NH$_3$.

• Journal of Animal Environmental Science
• /
• v.4 no.2
• /
• pp.161-166
• /
• 1998

Controlling malodor originating from livestock feces has become a major issue, due to its influence on the health of man and livestock, together with its influences on atmospheric pollution. In this study, Five types of biofilters filled with saw-dust, night soil, fermented compost, leaf mold and a mixture(a compound of night soil, fermented compost and leaf mold at the same rates, respectively) were manufactured and tested. To study the effect of the biofilter on reducing malodor in a composting facility and swine building, a pilot scale composting facility enclosed with polyethylene film was constructed. Swine feces was composted in the facility and malodorous gas generated from the decomposition of organic matter in the feces was gathered by vacuum pump. Each biofilter achieved 87∼96% NH3 removal efficiency. This performance was maintained throughout 10 days of operation. The highest NH3 removal efficiency was achieved by leaf mold on the first day of operation period. It reduced the concentration of NH3 by about 96%. Night soil and fermented compost showed nearly equal performance of 93 to 94% for 10 days from the beginning of operation. The mixture achieved the lowest NH3 removal efficiency. It reduced NH3 concentration by about 89∼94% for 10 days from the beginning of operation. However NH3 removal efficiency of each biofilter declined with the passage of operational time. After 30 days from the beginning of operation, NH3 removal efficiency of each biofilter of each biofilter was below 60%, respectively. The concentration of H2S and CH3-SH originating from compost were equal to or less than 5mg/l and 3mg/l, respectively. After passing throughout the biofilter, the concentration of H2S and CH3-SH were not detected.

• Journal of environmental and Sanitary engineering
• /
• v.16 no.2
• /
• pp.17-23
• /
• 2001

The objective of this study was to investigate the component ratio of gas generated at closed GD landfill site in MY city and the decomposition status of landfill gas, and was to examine and analyze the properties of the landfill gas. In addition, to provide basic data required to stabilize landfill earlier in the future, the study was to measure gas by landfill gas gauge and to analyze the properties of landfill gas based on documents. As a result of analyzing the properties, acquired follow results. 1. The main elements of landfill gas, $CH_4$ and $CO_2$ were respectively 25.02% and 22.325 on the average. 2. $NH_3$ and $H_2S$ were respectively 1.07 4.97 and 0.75 1.15 on the average. 3. Generated gas was different depending on water, pH properties of MSW(Munticipal Solid Wastes) and their decomposition rate. Furthermore, when measured the temperature of room to inspect landfill gas, the temperature was $22{\;}-{\;}30^{\circ}C$ in the average.

• Journal of the Semiconductor & Display Technology
• /
• v.13 no.4
• /
• pp.21-25
• /
• 2014

The silicon nitride ($SiN_x$) film for surface passivation and anti-reflection coating of crystalline silicon solar cell is very important and it is generally deposited by plasma enhanced chemical vapor deposition (PECVD). PECVD can be divided into low and high frequency method. In this paper, the $SiN_x$ film deposited by low and high frequency PECVD method was studied. First, to optimize the $SiN_x$ film deposited by low frequency PECVD method, the refractive index was measured by varying the process conditions like $SiH_4$, $NH_3$, $N_2$ gas rate, and RF power. When $SiH_4$ gas rate was increased and $NH_3$ gas rate was decreased, the refractive index was increased. The refractive index was also increased with RF power decline. Second, to compare the characteristics of the low and high frequency PECVD $SiN_x$ film, the refractive index was measured by varying $NH_3/SiH_4$ gas ratio and RF power and the minority carrier lifetime of before and after high temperature treatment process was also measured. The refractive index of both low and high frequency PECVD $SiN_x$ film was decreased with increase in $NH_3/SiH_4$ gas ratio and RF power. After high temperature treatment process, the minority carrier lifetime of both low and high frequency PECVD $SiN_x$ film was increased and increased degree was similar. The minority carrier lifetime of low frequency PECVD $SiN_x$ was increased from $11.03{\mu}m$ to $28.24{\mu}m$ and that of high frequency PECVD $SiN_x$ was increased from $11.60{\mu}m$ to $27.10{\mu}m$.

• Journal of the Microelectronics and Packaging Society
• /
• v.8 no.1
• /
• pp.13-18
• /
• 2001

Carbon nanotubes (CNTs) were grown on Ni-coated glass substrates by catalytic chemical vapor depositors (CVD) using RF plasma under $600^{\circ}C$. Various types of CNTs were obtained by different growth temperature, etching period and thickness of Ni catalyst. $NH_3$ or $H_2$ gas was used as a etching gas, then $C_2H_2$ gas was flowed as carbon source. Vertically aligned CNTs with diameter of 150 nm and length of 3 $\mu\textrm{m}$ were observed by SEM. CNTs synthesized by catalytic CVD using RF plasma should be expected to FED emitter.

• Journal of the Korea Organic Resources Recycling Association
• /
• v.17 no.3
• /
• pp.27-39
• /
• 2009

The main objective of this study is to investigate the characteristics of combustion by analyzing fuel gases from a combustion equipment with various combustion conditions for refuse-derived fuels (RDFs). CO gas is a parameter for indicating of incomplete combustion during a combustion process. The lowest CO gas was produced when the experiment conditions were m=2 under air-fuel condition and $800^{\circ}C$. $CO_2$ gas is a final product after complete combustions. The highest amount of $CO_2$ gas was produced when the experiment conditions were m=2 under air-fuel condition and $800^{\circ}C$. The highest level of $SO_2$ gas was produced in S.1 sample containing the highest sulfur. The highest level of NOx gas was produced in S.1 sample with the highest nitrogen content and air-fuel condition of m=2 under temperature of $800^{\circ}C$. HCl gas that is generated by reacting with metals catalyst through oxygen catalyst reaction during combustion process is a precursor of dioxin formation. The higher level of HCl gas was produced in the sample with higher chlorine content. The lowest level of HCl gas was produced when the experiment conditions were air-fuel condition of m=2 and $800^{\circ}C$. The lowest level of $NH_3$ gas was generated when the experiment condition was m=2 under air-fuel condition and after 3 minutes. Air-fuel condition is more important to create $NH_3$ gas than operating temperatures. Higher level of $H_2S$ gas was generated in S.1 sample with the higher sulfur content and was created in RDFs that contain higher mixture ratios of sewage sludge and food wastes. A result of combustion, gases and gases levels from the combustion of S.1 and S.2 were very similar to the combustion of a stone coal. As results of this research, when evaluating the feasibility of the RDFs, the RDFs could be used as auxiliary and main fuels.

• Journal of the Korean Crystal Growth and Crystal Technology
• /
• v.8 no.3
• /
• pp.387-387
• /
• 1998

This paper reports on a thermodynamic analysis for the GaN thick film growth by vapor phaseepitaxy method. The thermodynamic calculation was performed using a chemical stoichiometric algorism. Thesimulation variables include the growth temperature in a range 400~1500 K, the gas ratios $(GaCl_3)/(GaCl_3+NH_3)$and $(N_2)/(GaCl_3+NH_3)$. The theoretical calculation predicts that the growth temperature of GaN be in thelower range of 450~750 K than the experimental results. The difference in the growth temperature betweenthe simulation and the experiments indicates that the vapor phase epitaxy of GaN is kinetically limited,presumably, due to the high activation energy of thin film growth.