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Effect of Added NH$_3$ to AMP on Absorption Rate for Simultaneous Removal of CO$_2$/NO$_2$ in Composite Absorption Process  

Seo, Jong-Beom (Department of Environmental Engineering, Pusan National University)
Choi, Won-Joon (Greenhouse Gas Research Center, Korea Institute of Energy Research)
Moon, Seung-Jae (Department of Reduction of Greenhouse Gas, Response to Climate Change)
Lee, Gou-Hong (Environmental Science Technology, Ulsan Metropolitan City Hall)
Oh, Kwang-Joong (Department of Environmental Engineering, Pusan National University)
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Abstract
In this study, a blend of 2-amino-2-methyl-1-propanol (AMP) and ammonia (NH$_3$) was used to achieve high absorption rates for carbon dioxide (CO$_2$) as suggested at several literatures. The absorption rates of aqueous AMP and blended AMP+NH$_3$ solutions with CO$_2$ and nitrogen dioxide (NO$_2$) were measured using a stirred-cell reactor at 303 K. The effect of the added NH$_3$ to enhance absorption characteristics of AMP was studied. The performances were evaluated under various operating conditions. The absorption rates increased following the increase of the concentration of NH$_3$. The absorption rate of NH$_3$ blended into 30 wt.% AMP solution with NO$_2$ at 303 K was 12.6$\sim$32.6% higher than that of aqueous AMP solution without NH3. Also, the addition of 3 wt.% NH$_3$ to 30 wt.% AMP increased 48.2$\sim$41.6% values for the reactions with CO$_2$ and NO$_2$ at 303 K. Therefore, it clearly shows that the reaction rate of AMP with CO$_2$ and NO$_2$ can be increased by the addition of NH$_3$.
Keywords
Carbon Dioxide; Nitrogen Dioxide; Simultaneous Absorption; 2-amino-2-methyl-1-propanol(AMP); Ammonia;
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Times Cited By KSCI : 1  (Citation Analysis)
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1 Choi, W. J., Seo, J. B., Kim, J. W., Moon, S. J., Park, S. W., and Oh, K. J., "Removal of carbon dioxide and sulfur dioxide by absorption into aqueous AMP/AMMONIA solutions," 1st ASCON-IEEChE, 751-754(2008)
2 Xu, S., Otto, F. D., and Mather, A. E., "Physical properties of aqueous AMP solutions," J. Chem. Eng. Data, 36, 71-75(1991)   DOI
3 IPelk, J. E., Concannon, P. J., Manley, D. B., and Poling, B. E., "Product distributions in the $CO_2-NH_3-H_2O$ system from liquid conductivity measurements," Ind. Eng. Chem. Res., 31, 2209-2215(1992)   DOI
4 Gray, P. and Yoffe, A. D., "The reactivity and structure of nitrogen dioxide," Chem. Rev., 55, 1069-1154(1955)   DOI
5 Mandal, B. P., Guha, M., Biswas, A. K. and Bandyopadhyay, S. S., "Removal of carbon dioxide by absorption in mixed amines: modelling of absorption in aqueous MDEA/MEA and AMP/MEA solutions," Chem. Eng. Sci., 56, 6217-6224(2001)   DOI   ScienceOn
6 Hatch, T. F. and Pigford, R. L., "Simultaneous absorption of carbon dioxide and ammonia in water," Ing. Eng. Chem. Funda., 1(3), 209(1962)   DOI
7 Xu, S., Wang, Y. W., Otto, F. D., and Mather, A. E., "Representation of equilibrium solubility properties of $CO_2$ with aqueous solutions of 2-amino-2-methyl-1-propanol," Chem. Eng. Proc., 31, 7-12(1992)   DOI   ScienceOn
8 Oh, K. J., Kim, D. U., Shon, B. H., and Lee, J. J., "A study on the solubility of carbon dioxide in aqueous solution of 2-amino-2-methyl-1-propanol (AMP) and piperazine," 221st ACS National Meeting, Fuel Chem. Div. Prep., 46, 65-66(2001)
9 Denbigh, K. G. and Prince, A. J., "Kinetics of nitrous gas absorption in aqueous nitric acid," J. Am. Chem. Soc., 69, 790-801(1947)   DOI
10 오광중, 최원준, 이재정, 유정석, 조상원, 손병현, "AMP (2-amino-2-methyl-1-propanol)에 MDEA(N-methyldiethanolamine) 을 첨가한 흡수제의 $CO_2$$H_2S$의 흡수특성," 대한환경공학회지, 23(8), 1337-1347(2001)
11 Choi, W. J., Cho, K. C., Lee, S. S., Shim, J. G., Hwang, H. R., Park, S. W., and Oh, K. J., "Removal of carbon dioxide by absorption into blended amines: kinetics of absorption into aqueous AMP/HMDA, AMP/MDEA, and AMP/piperazine solutions," Green Chemistry, 9, 594-598(2007)   DOI   ScienceOn
12 Brooks, L. A. and Audrieth, L. F., "Ammonia carbamate," Inorg. Synth., 2, 85(1946)   DOI
13 Kucheryavyi, V. I. and Gorlovskij, D. M., "Densities of coexisting phases in the equilibrium gas-liquid system $NH_3-CO_2-CO-(NH_2)_2-H_2O$ at high temperatures and pressures," Zh. Prikl. Khim., 43, 1675-681(1970)
14 최원준, 이재정, 정종현, 유정석, 문길호, 오광중, "첨가제에 따른 혼합흡수제를 이용한 $CO_2/H_2S$의 흡수 및 재생," 대한환경공학회지, 26(5), 536-542(2004)