• Korean Chemical Engineering Research
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• v.48 no.5
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• pp.598-602
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• 2010

In this paper, we carried out CFD modelling and simulation for the membrane system to separate H2 gas from the multi-component feed gas. The membrane system is of the annulus tubular type consisting of the external lumen side for the feed gas and the internal permeation side for the sweeping gas. The operating temperature and pressure of the lumen side inlet flow are $374^{\circ}C$ and 7 bar respectively and those of the sweeping gas are $374^{\circ}C$ and 3 bar, and considering these conditions, Pd membrane system was employed. CFD simulations were performed for the co-current flow and counter-current flow membrane system based on the flow directions between the feed and the sweeping gas. Comparisons and discussions were made for the H2 partial pressure, H2 mole fraction and H2 flux for both cases. Furthermore, we executed CFD simulations for the each case of the various inlet flow rates of the feed gas at the lumen side. Accordingly, we reviewed the effects of the flow rate and residence time on the performance of the membrane system.

• Applied Chemistry for Engineering
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• v.9 no.4
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• pp.561-564
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• 1998

The radial distribution functions of a linear spheroidal type gas molecule $C_2H_4$ were calculated by using the Stockmayer molecular molel, which assumed the $C_2H_4$ molecule as simple quadrupolar molecule. To examine the validity of the calculated radial distribution of $C_2H_4$ gas, the density dependent pressures of $C_2H_4$ gas at several temperatures were calculated and compared with literarily known experimental pressure data of $C_2H_4$ gas. The temperatures examined was 50, 100 and $150^{\circ}C$ and the densities were up to $0.02/{\AA}^3$ (maximum pressure = 1500 atm). The radial distribution function expression used was derived by Yoon, Hacura, and Baglin (YHB) with Baker and Henderson's perturbation theory. The calculated results by a computer showed that the $C_2H_4$ pressures calculated agreed well with the experimental values within ${\pm}5%$ of error range. This indicated that the YHB radial distribution function expression is good enough to obtain various physical quantities sensitive to density such as pressure with resonable accuracy.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.30 no.2 s.245
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• pp.101-109
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• 2006

The narrow band-averaged transmissivity of $CO_2-H_2O$ mixtures is expressed by multiplying the transmissivities of $CO_2\;and\;H_2O$. Applying the multiplication property of narrow band transmissivities for gas mixtures of $CO_2-H_2O$ of the narrow band based WSGGM (weighted sum of gray gases model), the number of gray gases, required for accurate representation of the absorption characteristics by using the narrow band based WSGGM, is significantly increased. To reduce the computational loads by reducing the number of gray gases, we propose a gray gas regrouping process where the gray gases used for .the WSGGM are regrouped into a specified number of groups according to the magnitudes of absorption coefficients. To evaluate the proposed WSGGM for gas mixtures, the radiative transfer problems through 3-dimensional gas media are considered. The radiative source terms and the radiative heat fluxes obtained by using the proposed method are fairly well compared to previous results obtained by using the SNB model and other models. The regrouping technique results in an excellent computational efficiency with minor loss of accuracy.

• 한국연소학회:학술대회논문집
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• 2001.11a
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• pp.90-96
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• 2001

Catalytic ignition of $H_2/O_2/CO_2$ mixtures over platinum catalyst is experimentally investigated by using microcalorimetry. For comparison, $N_2$ and Ar is also used as diluent gas. The gas mixture flows toward platinum foil heated by electric current at atmosphere pressure and ambient temperature. The ignition temperature range 350-445K according to the fuel ratio, dilution ratio and diluent gas. It increases as the fuel ratio and dilution ratio increase. $H_2/O_2$ mixture with $CO_2$ ignites at higher temperature than with other diluents by 30-50K. Several experimental evidences show the inhibition effects of $CO_2$ in $H_2-O_2$ heterogeneous reaction is considerable

• Proceedings of the Korea Crystallographic Association Conference
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• 2007.11a
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• pp.28-28
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• 2007

• Journal of Surface Science and Engineering
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• v.31 no.5
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• pp.266-277
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• 1998

The effects of $H_2S$ gas ratio, temperature and time on the case depth, hardness, and sulfide and nitride formation on the surface of sulfnitrided SCM440 steel have been studied by micro-pulse plasma technique. The thickness of compound layer of sulfide and nitride increased with the increase of time, temperautre and $H_2S$ gas ratio. But surface hardness decreased with the increase of soft sulfide layer because the hard nitride layer formed beneath the sulfide. The thickness of sulfide layer was about 10$\mu\textrm{m}$ abpve 0.0088% of $H_2S$ gas. The highest surface hardness of the compound layer was Hv835 at $530^{\circ}C$, 1hr and 0.06% of $H_2S$ gas. X-ray diffraction indicated that the surface products were $Fe_{1_x}S$, $Fe_{2.5}N$ and $Fe_4N$. It was confirmed by EPMA that sulfide only existed in the surface.

• The Transactions of The Korean Institute of Electrical Engineers
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• v.61 no.4
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• pp.585-589
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• 2012

The characteristics of interface layer and the effect of mole fraction of inlet gas mixture($B_2H_6/H_2/N_2/TiCl_4$) on the microstructure of Ti(B,N) films were studied by microwave plasma hot filament CVD process. Ti(B,N) films were deposited on a substrate(STD-61) to develop a high performance of resistance wear coating tool. Ti(B,N) films were obtained at a gas pressure of 1 torr, bias voltage of 300 V and substrate temperature of $480^{\circ}C$ in $B_2H_6/H_2/N_2/TiCl_4$gas system. It was found that TiN, $TiB_2$, TiB and hexagonal boron nitride(h-BN) phases exist in thin layer on the STD-61.

• Journal of Surface Science and Engineering
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• v.50 no.2
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• pp.85-90
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• 2017

The carbon steel formed the thick, somewhat porous, loosely adherent iron oxide scale when oxidized at $500-800^{\circ}C$ for 15 h in air. It formed the thicker, more porous, nonadherent scale consisting of FeS plus iron oxides in $Ar/1%SO_2$-mixed gas. It formed the much thicker, more porous, nonadherent scale consisting of FeS plus iron oxides in Ar/0.1% $H_2S$-mixed gas. However, the aluminized carbon steel formed the thin, protective $Al_2O_3$ surface scale even in $Ar/1%SO_2$-, and $Ar/0.1%H_2S$-mixed gas. Aluminizing drastically improved the corrosion resistance in (O, S, H)-containing gas.

• Journal of Sensor Science and Technology
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• v.17 no.2
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• pp.147-150
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• 2008

Multiple ZnO nanorod device detecting $NO_2$ gas was fabricated by sol-gel growth method and gas response characteristics were measured as a chemical gas sensor. The device is mainly composed of sensing electrode and sensing nano material. To acquire high sensitivity of the device for $NO_2$ gas it was heated by a heat chuck up to $400^{\circ}C$ The sensing part was easily made using the CMOS compatible process, for example, the large area and low temperature nano material growth process, etc. The sensors were successfully demonstrated and showed high sensitive response for $NO_2$ gas sensing.

• Journal of Surface Science and Engineering
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• v.40 no.6
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• pp.245-249
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• 2007

Amorphous IZO films were deposited on PET substrate by DC magnetron sputtering without substrate heating. In order to investigate effect of reactive gas addition on film properties, 0.2-0.4% of $H_2$ or $O_2$ gas was introduced during the deposition. Deposited IZO films were evaluated with mechanical property, electrical property, and water permeability. In the case of $H_2$ gas addition, mechanical property showed clear degradation compared to $O_2$ gas. In the case of $O_2$ gas, water permeability of the IZO film was increased compared to $H_2$ gas which could be attributed to the low adhesion of the film caused by bombardment of high energy negative oxygen ion. As a result, it is confirmed that water permeability of the film could be strongly affected by adhesion of the film.