• Title/Summary/Keyword: $F^+-H^+$

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A study on the formation and removal of residue and damaged layer on the overched silicon surface during the contact oxide etching using $C_4$F$_8$/H$_2$ helicon were plasmas (C$_4$F$_8$/H$_2$ helicon were 플라즈마를 이용한 contact 산화막 식각 공정시 과식화된 실리콘 표면의 잔류막과 손상층 형성 및 이의 제거에 관항 연구)

  • 김현수;이원정;백종태;염근영
    • Journal of the Korean institute of surface engineering
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    • v.31 no.2
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    • pp.117-126
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    • 1998
  • In this study, the residue remaining on the silicon wafer during the oxide overetching using $C_4F_8/H_2$ helicon were plasmas and effects of various cleaning and annealing methods on the removal of the remaining residue were investigated. The addition of 30%$H_2$ to the C4F8 plasma increased the C/F ratio and the thickness of the residue on the etched silicon surface. Most of the residuse on the etched surfaces colud be removed by the oxygen plasmsa cleaning followed by thermal annealing over $450^{\circ}C$. Hydrogen-coataining residue formed on the silicon by 70%$C_4F_8/30%H_2$ helicon plasmas was more easily removed than hydrogen-free residue formed residue formed by $C_4F_8$ helicon wear plasmas. However, damage remaining on the silicon surface overetched using 70%$C_4F_8/30%H_2$ helicon plasmas was intensive and the degree of reocvery duing the post-annealing was lower.

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Refractive index control of F-doped SiOC : H thin films by addition fluorine (Fluorine 첨가에 의한 F-doped SiOC : H 박막의 저 굴절률 특성)

  • Yoon, S.G.;Kang, S.M.;Jung, W.S.;Park, W.J.;Yoon, D.H.
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.17 no.2
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    • pp.47-51
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    • 2007
  • F-doped SiOC : H thin films with low refractive index were deposited on Si wafer and glass substrate by plasma enhanced chemical vapor deposition (PECVD) as a function of rf powers, substrate temperatures, gas rates and their composition flow ratios ($SiH_4,\;CF_4$ and $N_2O$). The refractive index of the F-doped SiOC : H film continuously decreased with increasing deposition temperature and rf power. As $N_2O$ gas flow rate decreased, the refractive index of the deposited films decreased down to 1.3778, reaching a minimum value at rf power of 180W and $100^{\circ}C$ without $N_2O$ gas. The fluorine content of F-doped SiOC : H film increased from 1.9 at% to 2.4 at% as the rf power was increased from 60 W to 180 W, which results in the decrease of refractive index.

Analysis of Flavonoid 3' Hydroxylase and Dihydroflavonol 4-Reductase Activity in Lilium Cultivars (나리품종의 Flavonoid 3' Hydroxylase와 Dihydroflavonol 4-Reductase 효소학적 분석)

  • Yu, Sun-Nam
    • FLOWER RESEARCH JOURNAL
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    • v.17 no.4
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    • pp.308-315
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    • 2009
  • The activities of flower color biosynthesis-controlling enzymes, flavonoid 3'hydroxy lase (F3'H) and dihydroflavonol 4-reductase (DFR), were analyzed in Llium longijlorum and 11 lily cultivars using biochemical and enzymological methods. Dihydroquercetin (DHQ) product was synthesized by F3'H using dihydrokaempferol (DHK) as a substrate in Lilium longiflorum. F3'H activity was also detected in the eight cultivars tested. The substrate-specific activity of F3'H was observed because eridictiol (ERI), which uses naringenin (NAR) as a substrate, was not detected in the tested cultivars. Leucocyanidin (LCy) product was synthesized by DFR using DHQ as a substrate in Lilium longiflorum. DFR activity was also detected in 'Le Reve', 'Montreux', 'Monte Negro', 'Etude', 'Acapulco', and 'Star Gazer', but not in 'Siberia', 'Royal Race', 'Nove Cento', 'Elite', and 'Cannes'. Substrate-specific activity of DFR was observed because leucopelargonidin (LPg), which uses DHK as a substrate, was not detected in the tested cultivars.

Purification and Characterization of Cellulolytic Enzymes from Aspergillus niger (Aspergillus niger가 생산(生産)하는 섬유소(纖維素) 분해효소(分解酵素)의 정제(精製) 및 특성(特性))

  • Park, Kwan-Hwa;Oh, Tae-Kwang;Shin, Jae-Doo
    • Applied Biological Chemistry
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    • v.24 no.3
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    • pp.186-193
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    • 1981
  • Three fractions of carboxymethyl-cellulase (F-I, F-II, and F-III) and ${\beta}-glucosidase$ form Aspergillus niger were partially purified by ammonium sulfate fractionation. Sephadex G-150 and DEAE-Sephadex column chromatography. The optimum conditions such as pH and temperature and thermal inactivation properties of the enzymes were investigated. Arrhenius plots of F-II and F-III appeared as straight lines, whereas that of F-I was biphasic. The Z-values of F-II and F-III were $8^{\circ}C$ and $10^{\circ}C$ respectively, while that of F-I was $4^{\circ}C$ over $60{\sim}70^{\circ}C$ and $383^{\circ}C$ over $70{\sim}98^{\circ}C$. Three fractions and the crude extract of carboxymethyl-cellulase exhibited a similar optimum pH 4.3 and temperature of $60^{\circ}C$, while Z-value of crude extract $(21.5^{\circ}C)$ was much higher than that of the purified enzyme. Maximum activity of both purified and crude extract of ${\beta}-glucosidase$ was shown at pH 4.7 and $60^{\circ}C$, and z-value of the enzyme was $7^{\circ}C$.

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Analysis of Technology Association Rules Between CPC Codes of the 'Internet of Things(IoT)' Patent (CPC 코드 기반 사물인터넷(IoT) 특허의 기술 연관성 규칙 분석)

  • Shim, Jaeruen
    • The Journal of Korea Institute of Information, Electronics, and Communication Technology
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    • v.12 no.5
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    • pp.493-498
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    • 2019
  • This study deals with the analysis of the technology association rules between CPC codes of the Internet of Things(IoT) patent, the core of the Fourth Industrial Revolution ICT-based technology. The association rules between CPC codes were extracted using R, an open source for data mining. To this end, we analyzed 369 of the 605 patents related to the Internet of Things filed with the Patent Office until July 2019, with a complex CPC code, up to the subclass-level. As a result of the technology association rules, CPC codes with high support were [H04W ${\rightarrow}$ H04L](18.2%), [H04L ${\rightarrow}$ H04W](18.2%), [G06Q ${\rightarrow}$ H04L](17.3%), [H04L ${\rightarrow}$ G06Q](17.3%), [H04W ${\rightarrow}$ G06Q](9.8%), [G06Q ${\rightarrow}$ H04W](9.8%), [G06F ${\rightarrow}$ H04L](7.9%), [H04L ${\rightarrow}$ G06F](7.9%), [G06F ${\rightarrow}$ G06Q](6.2%), [G06Q ${\rightarrow}$ G06F](6.2%). After analyzing the technology interconnection network, the core CPC codes related to technology association rules are G06Q and H04L. The results of this study can be used to predict future patent trends.

Chemical Beam Deposition of $MgF_2$ Thin Films (화학선 증착법에 의한 $MgF_2$ 박막제조)

  • 박보현;백성기
    • Journal of the Korean Ceramic Society
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    • v.33 no.3
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    • pp.299-306
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    • 1996
  • We invesgated the fesibility of thin films deposition by pyrolysis of metalorganic precursors using chemical beam deposition (CBD) process. We attempted to understand the effects of deposition variables such as substrate temperature operating pressure effusion cell temperature and H2 partial pressure on the properties of MgF2 grown by CBD. Mg(tfac)2 was used as a precursor. MgF2 thin films were always grown in an amorphous state and crystallized bypost-annealing. he higher the substrate temperature and the lower the operating pressure the less the impurities I the deposited MgF2 thin films. H2 gas has to be supplied for the pyrolitic reaction of Mg(tfac)2 decomposition. MgF2 films annealed in H2 have lower C impurity than those annealed in O2. But their crysatllinity was independent of annealing atmosphere. The optimum conditions for the prepara-tion of MgF2 films by CBD process were as following : The substrate temperature 55$0^{\circ}C$ the operating pressure 10-4 torr; effusion cell temperature 21$0^{\circ}C$ the percentage of H2 100% Post-annealing in H2 gas was required to remove residual carbon and to form MgF2 crystalline phase.

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Structure and Bonding of Ni(C6H4-nFn)(CO)2 (C6H4=benzyne, n=1-4) Complexes (Ni(C6H4-nFn)(CO)2 (C6H4=benzyne, n=1-4) 착물의 구조 및 화학결합)

  • Ghiasi, Reza;Hashemian, Saeedeh;Irajee, Oranoos
    • Journal of the Korean Chemical Society
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    • v.55 no.2
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    • pp.183-188
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    • 2011
  • The electronic structure and properties of Ni$(C_6H_{4-n}F_n)(CO)_2$ ($C_6H_4$=benzyne, n=1-4) complexes have been investigated using hybrid density functional B3LYP theory. Both aromatic natures and nucleus independent chemical shift (NICS) of the benzyne rings have been analyzed. Among mono-, di-, and tri-fluorinated complexes, 3-F, 3,6-F, and 4-H are the most stable isomers, respectively. NICS values calculated at the several points above the ring centers are consistent with those based on the relative energies of the complexes. The atoms in molecules (AIM) analysis indicates that Ni-C bond distance is well correlated with the electron density of a ring critical point (${\rho}_{rcp}$) in all species.

Flavanone 3β-Hydroxylases from Rice: Key Enzymes for Favonol and Anthocyanin Biosynthesis

  • Kim, Jeong Ho;Lee, Yoon Jung;Kim, Bong Gyu;Lim, Yoongho;Ahn, Joong-Hoon
    • Molecules and Cells
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    • v.25 no.2
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    • pp.312-316
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    • 2008
  • Flavanone $3{\beta}$-hydroxylases (F3H) are key enzymes in the synthesis of flavonol and anthocyanin. In this study, three F3H cDNAs from Oryza sativa (OsF3H-1 ~3) were cloned by RT-PCR and expressed in E. coli as gluthatione S-transferase (GST) fusion proteins. The purified recombinant OsF3Hs used flavanone, naringenin and eriodictyol as substrates. The reaction products with naringen and eriodictyol were determined by nuclear magnetic resonance spectroscopy to be dihydrokaempferol and taxifolin, respectively. OsF3H-1 had the highest enzymatic activity whereas the overall expression of OsF3H-2 was highest in all tissues except seeds. Flavanone $3{\beta}$-hydroxylase could be a useful target for flavonoid metabolic engineering in rice.

GRADED INTEGRAL DOMAINS AND PRÜFER-LIKE DOMAINS

  • Chang, Gyu Whan
    • Journal of the Korean Mathematical Society
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    • v.54 no.6
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    • pp.1733-1757
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    • 2017
  • Let $R={\oplus}_{{\alpha}{\in}{\Gamma}}R_{\alpha}$ be an integral domain graded by an arbitrary torsionless grading monoid ${\Gamma}$, ${\bar{R}}$ be the integral closure of R, H be the set of nonzero homogeneous elements of R, C(f) be the fractional ideal of R generated by the homogeneous components of $f{\in}R_H$, and $N(H)=\{f{\in}R{\mid}C(f)_v=R\}$. Let $R_H$ be a UFD. We say that a nonzero prime ideal Q of R is an upper to zero in R if $Q=fR_H{\cap}R$ for some $f{\in}R$ and that R is a graded UMT-domain if each upper to zero in R is a maximal t-ideal. In this paper, we study several ring-theoretic properties of graded UMT-domains. Among other things, we prove that if R has a unit of nonzero degree, then R is a graded UMT-domain if and only if every prime ideal of $R_{N(H)}$ is extended from a homogeneous ideal of R, if and only if ${\bar{R}}_{H{\backslash}Q}$ is a graded-$Pr{\ddot{u}}fer$ domain for all homogeneous maximal t-ideals Q of R, if and only if ${\bar{R}}_{N(H)}$ is a $Pr{\ddot{u}}fer$ domain, if and only if R is a UMT-domain.

RADIUS OF FULLY STARLIKENESS AND FULLY CONVEXITY OF HARMONIC LINEAR DIFFERENTIAL OPERATOR

  • Liu, ZhiHong;Ponnusamy, Saminathan
    • Bulletin of the Korean Mathematical Society
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    • v.55 no.3
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    • pp.819-835
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    • 2018
  • Let $f=h+{\bar{g}}$ be a normalized harmonic mapping in the unit disk $\mathbb{D}$. In this paper, we obtain the sharp radius of univalence, fully starlikeness and fully convexity of the harmonic linear differential operators $D^{\epsilon}{_f}=zf_z-{\epsilon}{\bar{z}}f_{\bar{z}}({\mid}{\epsilon}{\mid}=1)$ and $F_{\lambda}(z)=(1-{\lambda)f+{\lambda}D^{\epsilon}{_f}(0{\leq}{\lambda}{\leq}1)$ when the coefficients of h and g satisfy harmonic Bieberbach coefficients conjecture conditions. Similar problems are also solved when the coefficients of h and g satisfy the corresponding necessary conditions of the harmonic convex function $f=h+{\bar{g}}$. All results are sharp. Some of the results are motivated by the work of Kalaj et al. [8].