• 제목/요약/키워드: $DeN_2O$

검색결과 131건 처리시간 0.025초

Feasibility of Bioethanol Production from Cider Waste

  • Seluy, Lisandro G.;Comelli, Raul N.;Benzzo, Maria T.;Isla, Miguel A.
    • Journal of Microbiology and Biotechnology
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    • 제28권9호
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    • pp.1493-1501
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    • 2018
  • Wastewater from cider factories (losses during transfers, products discarded due to quality policies, and products returned from the market) exhibits a Chemical Oxygen Demand greater than $170,000mg\;O_2/l$, mainly due to the ethanol content and carbohydrates that are added to obtain the finished product. These effluents can represent up to 10% of the volume of cider produced, and they must be treated to meet environmental regulations. In this work, a process was developed, based on alcoholic fermentation of the available carbohydrates present in ciders. The impact of inhibitors at different pH, size and reuse of inoculums and different nutrient supplementation on the ethanol yield were evaluated. The use of a 0.5 g/l yeast inoculum and corn steep water as the nutrient source allowed for depletion of the sugars in less than 48 h, which increased the content of ethanol to more than 70 g/l.

능이버섯으로부터 Fibrin 분해활성이 있는 단백질의 분리 및 정제 (Isolation and Purification of Fibrinolytic Enzyme of Edible Mushroom, Sarcodon aspratus(Berk.)S. Ito)

  • 이종호;양정례;정청송;김희숙;조재선
    • 생명과학회지
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    • 제11권6호
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    • pp.561-567
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    • 2001
  • 능이버섯[Sarcodon aspratus(Berk.)S.Ito]의 fibrin 분해 활성물질을 분리정제하기 위하여(N $H_4$)$_2$S $O_4$침전법, DE52 anion exchange column chromatography, Sephacryl-S2000 gel filtration chromatography 및 Mono S cation FPLC를 행하였으며 정제된 효소의 특성을 측정하였다. 혈전용해 요소의 활성물질은 DE52 anion exchange colum chroma-tography에 NaCI의 농도가 0.2M 정도에서 용출되었으며 계속된 Sephacryl-S200 gel fitration chromatography 및 Mono S cation EPLC를 실시한 결과 단일 Peak를 얻었고 혈전용해효소의 특이활성은 55.2 U/mg protein으로 조효소액으로 비하여 11.3 배 증가하였으며 수율은 49.5%이었다. 또한 Mono S cation EPLC에서 얻은 활성획분을 12% SDS-PAGE로 전기영동한 결과 단일 band를 얻었으며 gel filtration의 결과와 비교함으로서 정제된 능이의 혈전용해 효소의 분자량은 29.300 Da인 것으로 확인되었다. 능이로 부터 정제한 혈전용해효소는 pH가 높아질수록 효소활성이 증가하였으며 pH 10.5의 알카리성에서도 안정하였으며 6$0^{\circ}C$이상의 온도에서는 효소활성이 급격히 실활하기 시작하였지만 8$0^{\circ}C$에서 25%의 상대활성을 보였다. 또한 본 효소는 C $u^{2+}$이온 $Co^{3+}$ 이온 등 중금속에 의하여 68%및 38%활성이 저해되었으며 $Ca^{2+}$이온 또는 $Mg^{2+}$의 초딤색 인 EDTA및 serine protease inhibitor이 PMSF에 의하여 활성이 저해되었었다. 이러한 결과들은 능이의 혈전용해효소가 Ca.sup 2+/또는M $g^{2+}$에 의하여 활성이 증가하는 serine protease임을 암시해 주고 있다.

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POLYNOMIAL COMPLEXITY OF PRIMAL-DUAL INTERIOR-POINT METHODS FOR CONVEX QUADRATIC PROGRAMMING

  • Liu, Zhongyi;Sun, Wenyu;De Sampaio, Raimundo J.B.
    • Journal of applied mathematics & informatics
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    • 제27권3_4호
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    • pp.567-579
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    • 2009
  • Recently, Peng et al. proposed a primal-dual interior-point method with new search direction and self-regular proximity for LP. This new large-update method has the currently best theoretical performance with polynomial complexity of O($n^{\frac{q+1}{2q}}\;{\log}\;{\frac{n}{\varepsilon}}$). In this paper we use this search direction to propose a primal-dual interior-point method for convex quadratic programming (QP). We overcome the difficulty in analyzing the complexity of the primal-dual interior-point methods for convex quadratic programming, and obtain the same polynomial complexity of O($n^{\frac{q+1}{2q}}\;{\log}\;{\frac{n}{\varepsilon}}$) for convex quadratic programming.

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A Study on Efficient Data De-Identification Method for Blockchain DID

  • Min, Youn-A
    • International Journal of Internet, Broadcasting and Communication
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    • 제13권2호
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    • pp.60-66
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    • 2021
  • Blockchain is a technology that enables trust-based consensus and verification based on a decentralized network. Distributed ID (DID) is based on a decentralized structure, and users have the right to manage their own ID. Recently, interest in self-sovereign identity authentication is increasing. In this paper, as a method for transparent and safe sovereignty management of data, among data pseudonymization techniques for blockchain use, various methods for data encryption processing are examined. The public key technique (homomorphic encryption) has high flexibility and security because different algorithms are applied to the entire sentence for encryption and decryption. As a result, the computational efficiency decreases. The hash function method (MD5) can maintain flexibility and is higher than the security-related two-way encryption method, but there is a threat of collision. Zero-knowledge proof is based on public key encryption based on a mutual proof method, and complex formulas are applied to processes such as personal identification, key distribution, and digital signature. It requires consensus and verification process, so the operation efficiency is lowered to the level of O (logeN) ~ O(N2). In this paper, data encryption processing for blockchain DID, based on zero-knowledge proof, was proposed and a one-way encryption method considering data use range and frequency of use was proposed. Based on the content presented in the thesis, it is possible to process corrected zero-knowledge proof and to process data efficiently.

Chemical and Electrochemical Intercalation of Lithium in 2D-FeMoO$_4Cl^1$

  • 조진호;장순호;노동윤;손경아
    • Bulletin of the Korean Chemical Society
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    • 제10권1호
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    • pp.27-30
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    • 1989
  • Lithium has been intercalated into $FeMoO_4Cl$, and deintercalated from $LixFeMoO_4Cl$ both electrochemically and chemically. The inserted $Li^+$ ions are stabilized in the distorted octahedral field in interlayer space of $FeMoO_4Cl$. The crystal symmetry is reduced from tetragonal to monoclinic due to the reduction of ferric to ferrous ions in $LixFeMoO_4Cl$ upon lithium intercalation. From the magnetic and structural data, it has been concluded that the high-spin electronic configuration of $Fe^{2+}(d_{xz}^2{d_{y2}^1}{d_1}{2d_z^12}{\cdot}_y2)$, corresponding to $^5E_g$, group term in $D_{4h}$ symmetry, can be stabilized by the elongation of $FeO_4Cl_{2-}$octahedra in a weak ligand field.

Crystal Structure and Thermal Stability Study on Tetrabutylammonium Hexamolybdate [n-Bu4N]2[Mo6O19](TBAM)

  • Zhao, Pu Su;Zhao, Zhan Ru;Jian, Fang Fang;Lu, Lu De
    • 대한화학회지
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    • 제47권6호
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    • pp.553-558
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    • 2003
  • $[n-Bu_4N]_2[Mo_6O_{19}]$(TBAM)의 결정구조는 X-ray 분석기로 결정되었다. 그 결정은 monoclinic 계이며 ${\alpha}$=16.314(5), b=17.288(5), c=17.776(4) ${\AA}$, ${\beta}$=101.47(3) 그리고 z=4의 결정파라미터를 갖는 sapce group 이 C2/c인 결정이다 $[Mo_6O{19}]^{2-}$ 음이온에서, Mo 원자는 팔면체의 여섯 개 모서리를 차지하며 각 Mo 원자는 여석개의 산소원자에 배위되어 찌그러진 팔면체 배위 기하학을 지닌다. Mo-Ot(말단기), Mo-Ob(연결된), 그리고Mo-Oc(중앙)의 평균거리는 각각 1.680 ${\AA}$, 1.931 ${\AA}$ 및 2.325 ${\AA}$ 이다. $[n-Bu_4N]^+$ 양이온에서 N원자는 약간 찌그러진 사면체 모형을 갖는다. 격자안에서 폭 넓은 C-H ${\cdots}$ O 수소결합이 있으며, 그것에 의하여 분자들을 연결하고 결정구조를 안정화 한다. 열분석에 의하여 제목의 열적분핸ㄴ 두개의 전이가 일어나며 356.0와 803.5 $^{\circ}$에서 각각 무게를 잃는다. 그리고 분해된 생성물은 $Mo_2O_2$로 추정된다. 따라서, 제목의 화합물은 높은 열적 안정성을 갖는다.

Ca3Mn2O7 세라믹스의 전기전도 및 자기적 특성 (Transport and Magnetic Properties of Ca3Mn2O7 ceramic)

  • 정우환
    • 한국세라믹학회지
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    • 제42권9호
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    • pp.613-617
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    • 2005
  • We present the results of a combined magnetization, dc and magneto-transport study of the n = 2 Ruddlesden-Popper compound $Ca_3Mn_2O_7$ The negative thermoelectric powder is observed. The magnetic measurement data show that there is sharp magnetic transition at 134 K. However, the de and magnetoresistance of $Ca_3Mn_2O_7$ show no particular transport. Transport properties of the compound $Ca_3Mn_2O_7$ are interpreted in terms of activated hopping of small polarons in non-adiabatic regime. Polarons are most probably formed around $Mn^{3+}$ sites created by oxygen sub-stoichiometry.

Effects of Hybrid and Maturity on Maize Stover Ruminal Degradability in Cattle Fed Different Diets

  • Arias, S.;Di Marco, O.N.;Aello, M.S.
    • Asian-Australasian Journal of Animal Sciences
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    • 제16권11호
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    • pp.1619-1624
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    • 2003
  • The effect of maize hybrid (Suco and Dekalb 765, DK 765), maturity stage (milk, $R_3$ and 1/2 milk line, $R_5$) and animal diet (Diet 1: 70% lucerne hay+30% maize silage; Diet 2: 50% maize silage+20% sunflower meal+30% maize grain) on ruminal stover dry matter (DM) degradability was studied. Additionally, morphological and chemical plant composition was evaluated. Fodder samples ground at 2 mm were incubated in three Holstein steers (400 kg body weight) using the in situ technique. Ruminal degradation kinetics was studied and the effective degradability (ED) was estimated for an assumed kp of 5%/h. The in situ data was analyzed in a complete randomized block design with the animals as blocks. Significant interactions between hybrid${\times}$diet and maturity${\times}$diet on kinetic digestion parameters were detected. In Diet 1, hybrids did not differ in degradable fraction, kd or ED, although a minor difference (p<0.05) in the soluble fraction was found (25.5 and 23.2% for Suco and DK 765, respectively). In Diet 2, the DK 765 had greater degradable fraction (p<0.001) but smaller (p<0.01) kd than Suco, without differences in the soluble fraction or in ED. Anticipating the harvest increased ED of stover from 37.5% in $R_5$ to 44.6% in $R_3$ (average values across hybrids and diets) due to the increase (p<0.001) in the soluble fraction ($R_5$: 22.6%, $R_3$: 28.8%). It is concluded that hybrids had similar stover in situ DM degradability and that soluble fraction represent the main proportion of degradable substrates. Advancing the date of harvesting may not improve the in situ DM degradability of whole maize plant silage since the increase in stover quality is counteracted by the depression in the grain-to-stover ratio. The diet of the animal consuming silage might not improve stover utilization either.

Effects of Various Packaging Systems on the Quality Characteristic of Goat Meat

  • Morales-delaNuez, A.;Moreno-Indias, I.;Falcon, A.;Arguello, A.;Sanchez-Macias, D.;Capote, J.;Castro, N.
    • Asian-Australasian Journal of Animal Sciences
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    • 제22권3호
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    • pp.428-432
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    • 2009
  • 40 goat kid ribcages were held for 7 days in storage conditions ($4^{\circ}C$) and used to determine the effects of three different packaging methods (atmospheric air, vacuum and modified atmosphere package (MAP) 10:70:20 mixture of $N_2:O_2:CO_2$) on meat quality of the chops. L* was affected by the packaging method being lighter than MAP chops. The coordinate a* significantly increased during storage time. For MAP-packed chops and those kept in atmospheric air, b* increased markedly during storage time whereas it remained unaffected throughout storage when in vacuum packages. Final pH values ranged from 5.6 to 5.8 and no effects were found for either storage time or packaging method. WHC means were lowest for the three packaging methods on day 7 of storage and highest on day 1. Storage time increased water loss in vacuum treatments. Trained panel colour acceptability was lower at 3, 5 and 7 days than on day 1 of storage for atmospheric air treatment and vacuum packaging, while for the MAP treatment average values on days 5 and 7 were lower than those observed on days 1 or 3. Trained panel odour was lower for atmospheric air and vacuum packages at 3, 5, and 7 days storage than at 1 day, while no differences were found in trained panel odour acceptability for MAP packages. With reference to consumers, the MAP proposed in the present study is the chosen method for storing goat meat, rather than vacuum or atmospheric air packaging.

Effect of Hydrocarbon Additives on SNCR DeNOx Characteristics under Oxidizing Diesel Exhaust Gas Conditions

  • Nam, Changmo
    • 한국환경과학회지
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    • 제27권10호
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    • pp.809-820
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    • 2018
  • DeNOx experiments for the effects of hydrocarbon additives on diesel SNCR process were conducted under oxidizing diesel exhaust conditions. A diesel-fueled combustion system was set up to simulate the actual cylinder and head, exhaust pipe and combustion products, where the reducing agent $NH_3$ and $C_2H_6/diesel$ fuel additives were separately or simultaneously injected into the exhaust pipe, used as the SNCR flow reactor. A wide range of air/fuel ratios (A/F=20~40) were maintained, based on engine speeds where an initial NOx level was 530 ppm and the molar ratios (${\beta}=NH_3/NOx$) ranged between 1.0~2.0, together with adjusting the amounts of hydrocarbon additives. Temperature windows were normally formed in the range of 1200~1350K, which were shifted downwards by 50~100K with injecting $C_2H_6/diesel$ fuel additives. About 50~68% NOx reduction was possible with the above molar ratios (${\beta}$) at the optimum flow #1 ($T_{in}=1260K$). Injecting a small amount of $C_2H_6$ or diesel fuel (${\gamma}=hydrocarbon/NOx$) gave the promising results, particularly in the lower exhaust temperatures, by contributing to the sufficient production of active radicals ($OH/O/HO_2/H$) for NOx reduction. Unfortunately, the addition of hydrocarbons increased the concentrations of byproducts such as CO, UHC, $N_2O$ and $NO_2$, and their emission levels are discussed. Among them, Injecting diesel fuel together with the primary reductant seems to be more encouraging for practical reason and could be suggested as an alternative SNCR DeNOx strategy under diesel exhaust systems, following further optimization of chemicals used for lower emission levels of byproducts.