• Title/Summary/Keyword: $CO_2$ foam

Search Result 125, Processing Time 0.025 seconds

Solar CO2-Reforming of Methane Using a Double-Layer Absorber (더블 레이어 흡수기를 이용한 고온 태양열 메탄-이산화탄소 개질반응)

  • Kim, Dong-Yeon;Lee, Jin-Gyu;Lee, Ju-Han;Seo, Tae-Beom
    • 한국태양에너지학회:학술대회논문집
    • /
    • 2012.03a
    • /
    • pp.267-273
    • /
    • 2012
  • Solar reforming of methane with CO2 was successfully tested with a direct irradiated absorber on a parabolic dish capable of 5kWth solar power. And the new type of double-layer absorber-the front layer, porous metal foam which absorbs the radiation and transfers the heat from material to gas, and the back layer, catalytically-activated metal foam-was prepared, and its activity was tested by using electric furnace. Ni was applied as the active metal on the gamma-Al2O3 coated Ni metal foam for the preparation of the catalytically-activated metal foam layer. Compared to conventional direct irradiation of the catalytically activated metal foam absorber, this new type of double layer absorber is found to exhibit a superior reaction and thermal storage performance at the fluctuating incident solar radiation. In addition, unlike direct irradiation of the foam absorber, double layer absorber has better thermal resistance, which prevents the emergence of cracks caused by mechanical or thermal shock. The total solar power absorbed reached up to 3.25kW and the maximum CH4 conversion was almost 59%.

  • PDF

Solar CO2-Reforming of Methane Using a Double-Layer Absorber (더블 레이어 흡수기를 이용한 고온 태양열 메탄-이산화탄소 개질반응)

  • Kim, Dong-Yeon;Shin, Il-Yoong;Lee, Ju-Han;Seo, Tae-Beom
    • 한국태양에너지학회:학술대회논문집
    • /
    • 2011.11a
    • /
    • pp.80-86
    • /
    • 2011
  • Solar reforming of methane with CO2 was successfully tested with a direct irradiated absorber on a parabolic dish capable of 5kWth solar power. And the new type of double-layer absorber - the front layer, porous metal foam which absorbs the radiation and transfers the heat from material to gas, and the back layer, catalytically-activated metal foam - was prepared, and its activity was tested by using electric furnace. Ni was applied as the active metal on the gamma-Al2O3 coated Ni metal foam for the preparation of the catalytically-activated metal foam layer. Compared to conventional direct irradiation of the catalytically activated metal foam absorber, this new type of double layer absorber is found to exhibit a superior reaction and thermal storage performance at the fluctuating incident solar radiation. In addition, unlike direct irradiation of the foam absorber, double layer absorber has better thermal resistance, which prevents the emergence of cracks caused by mechanical or thermal shock. The total solar power absorbed reached up to 3.25kW and the maximum CH4 conversion was almost 59%.

  • PDF

Fabrication of Magnesium Alloy Foam Through $TiH_2$ and $CaCO_3$ ($TiH_2$$CaCO_3$를 이용한 마그네슘 합금의 제조)

  • Seo, Chang-Hwan;Seong, Hwan-Goo;Yang, Dong-Hui;Park, Soo-Han;Hur, Bo-Young
    • Journal of Korea Foundry Society
    • /
    • v.26 no.6
    • /
    • pp.267-271
    • /
    • 2006
  • Metal foam is a class of attractive materials, which exhibits unique combinations of physical, mechanical, thermal, electrical and acoustic properties. In particular, it is light and good at absorbing energy, which makes it attractive in automotive and aerospace applications weight is critical. In this paper, the Mg alloy foam was prepared by melt foaming method by addition of calcium as thickening agent, and $TiH_2$ or $CaCO_3$ powder as blowing agent. The macrostructural observation of foamed Mg showed that the pore structures of Mg alloy foam made by $CaCO_3$ as blowing agent were much better than that of foams made by $TiH_2$ as blowing agent. In addition, this paper showed the possible reason of fabrication magnesium alloy foam in proportion to blowing agent and the porosity range was about 40 to 76% as results value.

Ni Foam-Supported Ni Nanoclusters for Enhanced Electrocatalytic Oxygen Evolution Reaction

  • Hoeun Seong;Jinhee Kim;Kiyoung Chang;Hyun-woo Kim;Woojun Choi;Dongil Lee
    • Journal of Electrochemical Science and Technology
    • /
    • v.14 no.3
    • /
    • pp.243-251
    • /
    • 2023
  • Developing oxygen evolution reaction (OER) electrocatalysts is essential to accomplish viable CO2 and water electrolysis. Herein, we report the fabrication and OER performance of Ni-foam (NF)-immobilized Ni6 nanoclusters (NCs) (Ni6/NF) prepared by a dip-coating process. The Ni6/NF electrode exhibited a high current density of 500 mA/cm2 for the OER at an overpotential as low as 0.39 V. Ni6/NF exhibited high durability in an alkaline solution without corrosion. Electrokinetic studies revealed that OER can be easily initiated on Ni6 NC with fast electron-transfer rates. Finally, we demonstrated stable CO2-to-CO electroreduction using an NC-based zero-gap CO2 electrolyzer operated at a current density of 100 mA/cm2 and a full-cell potential of 2.0 V for 12 h.

Carbon-capture Performance of foam Concrete Using Stainless Steel Slag (스테인리스 스틸 AOD 슬래그를 이용한 폼 콘크리트의 탄소포집 성능)

  • Kim, Byung Jun;Yoo, Sung Won;Choi, Young Cheol
    • Journal of the Korea institute for structural maintenance and inspection
    • /
    • v.24 no.4
    • /
    • pp.18-25
    • /
    • 2020
  • The purpose of this study is to investigate the mechanical and carbon-capture properties of foam concrete containing stainless steel argon oxygen decarbonization(AOD) slag. AOD slag was used as a binder, and foam concrete having a foaming ratio of 69 ± 0.5 % and a slurry density of 573.2 to 578.6 kg / ㎥ was produced. In order to examine the effect of carbonation, blended specimen was cured by two types : normal curing and CO2 curing. As a result of the experiment, the specimens incorporating AOD slag showed higher compressive strength than Plain after CO2 curing. According to the analysis of the image of foam concrete, it was confirmed that the ST30 has a lower total pore volume and average pore size than plain, resulting in high compressive strength. The SEM analysis confirmed the formation of calcite by carbonation of AOD slag. Through the thermogravimetric analysis, the increase of CO2 uptake was confirmed by the incorporation of AOD slag. Foam concrete has a higher porosity than normal concrete, so it is expected that carbon-capture performance can be improved by using a AOD slag.

CoMn Oxide/Carbon-nanofiber Composite Electrodes for Supercapacitors (코발트망간 산화물/탄소나노섬유 복합전극의 수퍼케폐시터 특성)

  • Kim, Yong-Il;Yoon, Yu-Il;Ko, Jang-Myoun
    • Journal of the Korean Ceramic Society
    • /
    • v.45 no.8
    • /
    • pp.493-496
    • /
    • 2008
  • Composite electrodes consisting of $CoMnO_2$ and carbon nanofibers(vapor grown carbon nanofiber, VGCF) with high electrical conducivity($CoMnO_2$/VGCF) were prepared on a porous nickel foam substrate as a current collector and their supercapacitive properties were investigated using cyclic voltammetry in 1 M KOH aqueous solution. The $CoMnO_2$/VGCF electrode exhibited high specific capacitance value of 630 F/g at 5 mV/s and excellent capacitance retention of 95% after $10^4$ cycles, indicating that the used VGCF played the important roles in reducing the interfacial resistance in the composite electrode to improve supercapacitive performance.

Nano-Morphology Design of Nickel Cobalt Hydroxide on Nickel Foam for High-Performance Energy Storage Devices (고성능 에너지 저장 소자를 위한 니켈 구조체에 담지된 니켈 코발트 수산화물의 나노 형상 제어)

  • Shin, Dong-Yo;Yoon, Jongcheon;Ha, Cheol Woo
    • Korean Journal of Materials Research
    • /
    • v.31 no.12
    • /
    • pp.710-718
    • /
    • 2021
  • Recently, due to high theoretical capacitance and excellent ion diffusion rate caused by the 2D layered crystal structure, transition metal hydroxides (TMHs) have generated considerable attention as active materials in supercapacitors (or electrochemical capacitors). However, TMHs should be designed using morphological or structural modification if they are to be used as active materials in supercapacitors, because they have insulation properties that induce low charge transfer rate. This study aims to modify the morphological structure for high cycling stability and fast charge storage kinetics of TMHs through the use of nickel cobalt hydroxide [NiCo(OH)2] decorated on nickel foam. Among the samples used, needle-like NiCo(OH)2 decorated on nickel foam offers a high specific capacitance (1110.9 F/g at current density of 0.5 A/g) with good rate capability (1110.9 - 746.7 F/g at current densities of 0.5 - 10.0 A/g). Moreover, at a high current density (10.0 A/g), a remarkable capacitance (713.8 F/g) and capacitance retention of 95.6% after 5000 cycles are noted. These results are attributed to high charge storage sites of needle-like NiCo(OH)2 and uniformly grown NiCo(OH)2 on nickel foam surface.

Effects of Heat-treatment Temperature on Mechanical Properties of Reticulated Carbon Foams (망상형 탄소폼의 열처리 온도가 기계적 물성에 미치는 영향)

  • Han, Yoon-Soo;Lee, Sung-Min;Kim, Hyung-Tae
    • Journal of the Korean Ceramic Society
    • /
    • v.49 no.3
    • /
    • pp.236-240
    • /
    • 2012
  • The reticulated carbon foam have been used for their excellent properties in terms of thermal management which is getting important in industrial field currently. In this study, we measure the mechanical properties of the reticulated carbon foam which is heat-treated at various temperature from the prepared low-density phenol foam. Simultaneously, we observe microstructures with high resolution transmission microscope and measure the residual oxygen content of carbon foams to figure out the relationship between the apparent change of properties such as weight loss and linear shrinkage during heat treatment. In conclusion, the carbon foam heat-treated at $1400^{\circ}C$ shows the highest strength, and the mechanical behavior is believed to be strongly related to the creation of nano-size graphite crystals from the amorphous carbon during heat treatment. On the other hand, it is turned out that the weight loss occurred at the temperature under $1400^{\circ}C$ comes from the elimination of oxygen in the form of $CO_2$ or CO, but no evidence is found on weight loss mechanism at the temperature above $1400^{\circ}C$.

Electrochemical Properties of 3D Cu-Sn Foam as Anode for Rechargeable Lithium-Ion Battery (3D-foam 구조의 구리-주석 합금 도금층을 음극재로 사용한 리튬이온배터리의 전기화학적 특성 평가)

  • Jung, Minkyeong;Lee, Gibaek;Choi, Jinsub
    • Journal of the Korean institute of surface engineering
    • /
    • v.51 no.1
    • /
    • pp.47-53
    • /
    • 2018
  • Sn-based lithium-ion batteries have low cost and high theoretical specific capacity. However, one of major problem is the capacity fading caused by volume expansion during lithiation/delithiation. In this study, 3-dimensional foam structure of Cu-Sn alloy is prepared by co-electrodeposition including large free space to accommodate the volume expansion of Sn. The Cu-Sn foam structure exhibits highly porous and numerous small grains. The result of EDX mapping and XPS spectrum analysis confirm that Cu-Sn foam consists of $SnO_2$ with a small quantity of CuO. The Cu-Sn foam structure electrode shows high reversible redox peaks in cyclic voltammograms. The galvanostatic cell cycling performances show that Cu-Sn foam electrode has high specific capacity of 687 mAh/g at a current rate of 50 mA/g. Through SEM observation after the charge/discharge processes, the morphology of Cu-Sn foam structure is mostly maintained despite large volume expansion during the repeated lithiation/delithiation reactions.

Modeling of Foam Separator for Sea Water Treatment (해수 포말분리공정의 해석 및 모델)

  • HUR Hyun-Chul;SEO Jae-Koan;PARK Eun-ju;KIM Sung-Koo
    • Korean Journal of Fisheries and Aquatic Sciences
    • /
    • v.32 no.2
    • /
    • pp.165-169
    • /
    • 1999
  • Experiments were conducted to evaluate a experimental model developed for the protein removal by foam separation. The foam separator was operated in well-mixed tank which would be considered as a completely mixed condition. The feasibility of foam separation to remove protein from sea water was investigated. Protein removal characteristics of the foam separator were obtained by batch experiments. To find the effect of the operating parameter to protein removal rate, the foam separation was carried with variation of initial protein concentration and superficial air velocity. The result indicated that the protein removal efficiency was increased with increasing protein concentration and superficial air velocity. The relationship between operation parameters and protein removal rate were evaluated by non-linear regression as the form of exponential function, Using both relationships, the simplified model was determined. The simplified foam separator operation model was verified by the batch operation. The simulation results showed a good relationship with the experimental data.

  • PDF