• Bulletin of the Korean Chemical Society
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• 제10권2호
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• pp.132-133
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• 1989

To probe the geometrical effects of cyclopropyl moiety on the stabilization of an adjacent cation center, chemical shift of 2-p-fluorophenyl-8,9-dehydro-2-adamantyl cation (3) was compared with that of 5-p-fluorophenyl-2,4-dehydro-5-homoadamantyl cation (4). Difference between the chemical shift of 8,9-dehydro-2-adamantyl cation 3 and that of 2,4-dehydro-5-adamantyl cation 4 is 5.1 ppm (${\Delta}{\Delta}{\delta}$). We conclude, therefore, that ion 3 is about 3.82 kcal more stadble than ion 4 of which rigid carbon skeleton requires significant distortion of the cyclopropane ring from the ideal bisected conformation. The energy difference between these cations can be calculated by Taft-Relationship$^8$ on the basis of chemical shift.

• Kyungpook Mathematical Journal
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• 제59권1호
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• pp.47-63
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• 2019

For $y{\in}{\mathbb{R}}$, a sequence $x=(x_n){\in}{\ell}^{\infty}$, and a non-negative regular matrix A, Bartoszewicz et. al., in 2015, defined the notion of the A-density ${\delta}_A(y)$ of the indices of those $x_n$ that are close to y. Their main result states that if the set of limit points of ($x_n$) is countable and density ${\delta}_A(y)$ exists for any $y{\in}\mathbb{R}$ where A is a non-negative regular matrix, then ${\lim}_{n{\rightarrow}{\infty}}(Ax)_n={\sum}_{y{\in}{\mathbb{R}}}{\delta}_A(y){\cdot}y$. In this note we first show that the result can be extended to a more general class of matrices and then consider a conjecture which naturally arises from our investigations.

• The Journal of Advanced Prosthodontics
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• 제6권6호
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• pp.427-433
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• 2014

PURPOSE. Surface color is one of the main criteria to obtain an ideal esthetic. Many factors such as the type of the material, surface specifications, number of firings, firing temperature and thickness of the porcelain are all important to provide an unchanged surface color in dental ceramics. The aim of this study was to evaluate the color changes in dental ceramics according to the material type and glazing methods, during the multiple firings. MATERIALS AND METHODS. Three different types of dental ceramics (IPS Classical metal ceramic, Empress Esthetic and Empress 2 ceramics) were used in the study. Porcelains were evaluated under five main groups according to glaze and natural glaze methods. Color changes (${\Delta}E$) and changes in color parameters (${\Delta}L$, ${\Delta}a$, ${\Delta}b$) were determined using colorimeter during the control, the first, third, fifth, and seventh firings. The statistical analysis of the results was performed using ANOVA and Tukey test. RESULTS. The color changes which occurred upon material-method-firing interaction were statistically significant (P<.05). ${\Delta}E$, ${\Delta}L$, ${\Delta}a$ and ${\Delta}b$ values also demonstrated a negative trend. The MC-G group was less affected in terms of color changes compared to other groups. In all-ceramic specimens, the surface color was significantly affected by multiple firings. CONCLUSION. Firing detrimentally affected the structure of the porcelain surface and hence caused fading of the color and prominence of yellow and red characters. Compressible all-ceramics were remarkably affected by repeated firings due to their crystalline structure.

• 대한화학회지
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• 제55권3호
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• pp.379-384
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• 2011

[ $25^{\circ}C$ ] 순수 물에서 음이온성 계면활성제인 DBS(sodium dodecyl benzenesulfonate)와 SDS(sodium dodecylsulfate) 그리고 비이온성 계면활성제인 Brij 30(polyoxyethylene(4) lauryl ether) 사이의 혼합미셀화에 대한 임계미셀농도(CMC)와 반대이온의 결합상수값(B)을 전도도법과 표면장력계법으로 측정하였다. 이와 같이 측정한 CMC값에 비이상적 혼합미셀화 모델을 적용함으로써 여러 가지 열역학적 함수값($X_i,\;{\gamma}i,\;C_i,\;a_i^M,\;{\beta}$ 및 ${\Delta}H_{mix}$)들을 계산하여 상호 비교분석하였다. 그 결과, SDS는 DBS보다 Brij 30과 더욱 강한 상호작용을 이루었으며, SDS/Brij 30 혼합계면활성제가 이상적 혼합미셀화로부터 가장 큰 음의 벗어남을 보였다. 그리고 SDS/DBS 혼합계면활성제는 거의 이상적 혼합미셀화를 이루는 것으로 나타났다.

• 대한수학회지
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• 제50권3호
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• pp.557-578
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• 2013

For an ideal $\mathcal{I}$ of a preadditive category $\mathcal{A}$, we study when the canonical functor $\mathcal{C}:\mathcal{A}{\rightarrow}\mathcal{A}/\mathcal{I}$ is local. We prove that there exists a largest full subcategory $\mathcal{C}$ of $\mathcal{A}$, for which the canonical functor $\mathcal{C}:\mathcal{C}{\rightarrow}\mathcal{C}/\mathcal{I}$ is local. Under this condition, the functor $\mathcal{C}$, turns out to be a weak equivalence between $\mathcal{C}$, and $\mathcal{C}/\mathcal{I}$. If $\mathcal{A}$ is additive (with splitting idempotents), then $\mathcal{C}$ is additive (with splitting idempotents). The category $\mathcal{C}$ is ample in several cases, such as the case when $\mathcal{A}$=Mod-R and $\mathcal{I}$ is the ideal ${\Delta}$ of all morphisms with essential kernel. In this case, the category $\mathcal{C}$ contains, for instance, the full subcategory $\mathcal{F}$ of Mod-R whose objects are all the continuous modules. The advantage in passing from the category $\mathcal{F}$ to the category $\mathcal{F}/\mathcal{I}$ lies in the fact that, although the two categories $\mathcal{F}$ and $\mathcal{F}/\mathcal{I}$ are weakly equivalent, every endomorphism has a kernel and a cokernel in $\mathcal{F}/{\Delta}$, which is not true in $\mathcal{F}$. In the final section, we extend our theory from the case of one ideal$\mathcal{I}$ to the case of $n$ ideals $\mathcal{I}_$, ${\ldots}$, $\mathca{l}_n$.

• Korean Journal of Mathematics
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• 제6권2호
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• pp.221-229
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• 1998

Let $k$ be a real abelian field and $k_{\infty}$ be its $\mathbb{Z}_p$-extension for an odd prime $p$. Let $A_n$ be the Sylow $p$-subgroup of the ideal class group of $k_n$, the $nth$ layer of the $\mathbb{Z}_p$-extension. By using the main conjecture of Iwasawa theory, we have the following: If $p$ does not divide $\prod_{{{\chi}{\in}\hat{\Delta}_k},{\chi}{\neq}1}B_{1,{\chi}{\omega}^{-1}$, then $A_n$ = {0} for all $n{\geq}0$, where ${\Delta}_k=Gal(k/\mathbb{Q})$ and ${\omega}$ is the Teichm$\ddot{u}$ller character for $p$. The converse of this statement does not hold in general. However, we have the following when $k$ is of prime conductor $q$: Let $q$ be an odd prime different from $p$. and let $k$ be a real subfield of $\mathbb{Q}({\zeta}_q)$. If $p{\mid}{\prod}_{{\chi}{\in}\hat{\Delta}_{k,p},{\chi}{\neq}1}B_{1,{\chi}{\omega}}-1$, then $A_n{\neq}\{0\}$ for all $n{\geq}1$, where ${\Delta}_{k,p}$ is the $Gal(k_{(p)}/\mathbb{Q})$ and $k_{(p)}$ is the decomposition field of $k$ for $p$.

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2003년도 춘계학술강연 및 발표대회
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• pp.23-23
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• 2003

분말야금된 소결체의 가장 큰 특징 중의 하나는 피할 수 없는 소결체의 기공이다. 이러한 기공이 기계적 특성에 미치는 영향에 관해서는 많은 연구가 오래 전부터 진행되었었다. 그러나 기존의 연구는 거의 대부분 일반 분말야금에 의한 것이고 분말사출성형된 소결체의 기공율과 기계적 특성 광계는 거의 연구가 이루어 지지 않았다. 본 연구에서는 기공율의 조절이 용이한 분말사출성형 공정을 이용하여 소결 초기부터 완전 치밀화에 가까운 조직까지 다양한 소경율의 시편을 만들어 기계적 특성에 미치는 순수기공의 영향은 조사하기 위해 다음과 같이 조사하고자 하였다. 사출성형에 사용된 재료는 고강도 이며 내식성이 뛰어난 17-4 PH STS이고 평균 입경은 10mm였다. 열분해와 소결은 수소 분위기에서 행하였으며 소결온도는 900~$1350^{\circ}C$였다. 연구수행을 통해 다음과 같은 결론을 얻었다. 1. 기공율과 기계적 특성의 관계는 닫힌 기공이 지배하는 고밀도 영역과 열린 기공이 지배하는 저밀도 영역을 분리하여 해석해야한다. 2. 저밀도 영역에서의 기공율과 강도의 관계는 넥 성장에 따른 load bearing area의 증가로 나타낼 수 있고 아래와 같다. $\frac{\delta}{\delta_o}=1-\frac{P}{P_i}$ 3. 고밀도 영역에서의 기공율과 강도의 관계는 소결 현상과 초기 충진율을 고려한 ideal pore모델을 도입하였고 아래와 같이 나타났다. $\frac{\delta}{\delta_o}=1-1.95(P_i\;{\cdot}\;P)^{2/3}$

• 한국전기전자재료학회논문지
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• 제20권7호
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• pp.594-599
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• 2007

[ $CulnS_2$ ] thin films were synthesized by sulfurization of Cu/In Stacked elemental layer deposited onto glass Substrates by vacuum furnace annealing at temperature $200^{\circ}C$. And structural and electrical properties were measured in order to certify optimum conditions for growth of the ternary compound semiconductor $CuInS_2$ thin films with non-stoichiometry composition. $CuInS_2$ thin film was well made at the annealed $200^{\circ}C$ of SLG/Cu/In/S stacked elemental layer which was prepared by thermal evaporator, and chemical composition of the thin film was analyzed nearly as the proportion of 1 : 1 : 2. Physical properties of the thin film were investigated at various fabrication conditions substrate temperature, annealing and temperature, annealing time by XRD, FE-SEM and Hall measurement system. The compositional deviations from the ideal chemical formula for $200^{\circ}C$ material can be conveniently described by non-molecularity$({\Delta}x=[Cu/In]-1)$ and non-stoichiometry $({\Delta}y=[{2S/(Cu+3In)}-1])$. The variation of ${\Delta}x$ would lead to the formation of equal number of donor and accepters and the films would behave like a compensated material. The ${\Delta}y$ parameter is related to the electronic defects and would determine the type of the majority charge carriers. Films with ${\Delta}y>0$ would behave as p-type material while ${\Delta}y<0$ would show n-type conductivity. At the sane time, carrier concentration, hall mobility and resistivity of the thin films was $9.10568{\times}10^{17}cm^{-3},\;312.502cm^2/V{\cdot}s\;and\;2.36{\times}10^{-2}\;{\Omega}{\cdot}cm$, respectively.

• 한국수학교육학회지시리즈B:순수및응용수학
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• 제25권1호
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• pp.31-38
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• 2018

In [4], the authors show that if ${\mathbb{X}}$ is a ${\mathbb{k}}-configuration$ in ${\mathbb{P}}^2$ of type ($d_1$, ${\ldots}$, $d_s$) with $d_s$ > $s{\geq}2$, then ${\Delta}H_{m{\mathbb{X}}}(md_s-1)$ is the number of lines containing exactly $d_s-points$ of ${\mathbb{X}}$ for $m{\geq}2$. They also show that if ${\mathbb{X}}$ is a ${\mathbb{k}}-configuration$ in ${\mathbb{P}}^2$ of type (1, 2, ${\ldots}$, s) with $s{\geq}2$, then ${\Delta}H_{m{\mathbb{X}}}(m{\mathbb{X}}-1)$ is the number of lines containing exactly s-points in ${\mathbb{X}}$ for $m{\geq}s+1$. In this paper, we explore a standard ${\mathbb{k}}-configuration$ in ${\mathbb{P}}^2$ and find that if ${\mathbb{X}}$ is a standard ${\mathbb{k}}-configuration$ in ${\mathbb{P}}^2$ of type (1, 2, ${\ldots}$, s) with $s{\geq}2$, then ${\Delta}H_{m{\mathbb{X}}}(m{\mathbb{X}}-1)=3$, which is the number of lines containing exactly s-points in ${\mathbb{X}}$ for $m{\geq}2$ instead of $m{\geq}s+1$.

• 대한조선학회논문집
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• 제47권6호
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• pp.782-786
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• 2010

Thrust deduction related to the prediction of power performance of a ship is rather resistance increase, and as a preliminary study for it forces upon a circular cylinder in a uniform flow of ideal fluid due to singularities located behind it are investigated. The circle theorem is used to get the complex velocity potential for the flow field under consideration, and the Blasius theorem is applied to obtain forces upon the circular cylinder. As singularities sinks, point vortices and dipoles and their combinations are treated. $\varepsilon$, standing for the strength of a singularity, and $\delta$, representing the distance between the cylinder and the singularity, are important small parameters for the resistance and lateral forces. For sinks or point vortices it is shown that the dimensionless forces upon the cylinder is O($\epsilon$) if $\epsilon$= O($\delta$) is assumed, and the same holds for dipoles if $\epsilon$= O(${\delta}^3$) is supposed. Forces upon the cylinder by a symmetric pair of sinks are greater than a single sink located at the central plane since there is an additional term due to cross effects, and the same is also valid for the case of dipole. Combination of dipole and a point vortex is also considered and a few new aspects are clarified.