• Title/Summary/Keyword: ${\Delta}V_{10}$

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The Solvolysis of Benzoyl Chloride in Water-Acetone Mixtures Under High Pressure

  • Jee, Jong-Gi;Ree, Taik-Yue
    • Bulletin of the Korean Chemical Society
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    • v.8 no.1
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    • pp.31-39
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    • 1987
  • By using a complete rate constant($k_e$) which treats a solvent (water) as a reactant, and a conventional rate constant($k_c$), which ignores the solvent in describing the rate, the parameters ${\Delta}V^{\neq}_s,\;{\Delta}H^{\neq}_s\;and\;{\Delta}S^{\neq}_s$ were introduced. These quantities represent the volume change, the enthalpy change, and the entropy change accompanying the electrostriction which occurs when solvent molecules condense on the activated complex. The authors measured the rates of the solvolysis of benzoyl chloride in water-acetone mixtures at $15^{\circ}$ to $30^{\circ}C$ and 1 bar to 2500 bars. Applying the authors' theory to the experimental results, the parameters, ${\Delta}V^{\neq}_s,\;{\Delta}H^{\neq}_s\;and\;{\Delta}S^{\neq}_s$ were evaluated, and it was found that they are all negative, indicating that water dipoles condense on the activated complex. They also proposed the following equations: ${\Delta}H^{\neq}_c\;=\;{\Delta}H^{\neq}_e\;+\;{\Delta}H^{\neq}_s\;and\; {\Delta}S^{\neq}_c\;=\;{\Delta}S^{\neq}_e\;+{\Delta}S^{\neq}_s\;,\;where\;{\Delta}H^{\neq}_c\;and\;{\Delta}H^{\neq}_c\;and\;{\Delta}S^{\neq}_s $are the activation enthalpy change and the activation entropy change for the conventional reaction rate, respectively, and ${\Delta}H^{\neq}_e$ and ${\Delta}S^{\neq}_e$ are the corresponding quantities for the complete reaction rate. The authors proposed that for the $SN_1$ type, all the quantities, ${\Delta}V^{\neq}_s,\;{\Delta}S^{\neq}_s\;,{\Delta}H^{\neq}_s\;and\;{\Delta}S^{\neq}_s$ are comparatively large, and for the $SN_2$ type, these quantities are smaller than for the $SN_1$ type, and occasionally the case ${\Delta}S^{\neq}_e$ < 0 occurs. Using these criteria, the authors concluded that at high temperature, high pressure and for a high water content solvent, the SN_1$ type mechanism predominates whereas in the reversed case the $SN_2$M type predominates.

Mission Orbit Design of CubeSat Impactor Measuring Lunar Local Magnetic Field

  • Lee, Jeong-Ah;Park, Sang-Young;Kim, Youngkwang;Bae, Jonghee;Lee, Donghun;Ju, Gwanghyeok
    • Journal of Astronomy and Space Sciences
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    • v.34 no.2
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    • pp.127-138
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    • 2017
  • The current study designs the mission orbit of the lunar CubeSat spacecraft to measure the lunar local magnetic anomaly. To perform this mission, the CubeSat will impact the lunar surface over the Reiner Gamma swirl on the Moon. Orbit analyses are conducted comprising ${\Delta}V$ and error propagation analysis for the CubeSat mission orbit. First, three possible orbit scenarios are presented in terms of the CubeSat's impacting trajectories. For each scenario, it is important to achieve mission objectives with a minimum ${\Delta}V$ since the CubeSat is limited in size and cost. Therefore, the ${\Delta}V$ needed for the CubeSat to maneuver from the initial orbit toward the impacting trajectory is analyzed for each orbit scenario. In addition, error propagation analysis is performed for each scenario to evaluate how initial errors, such as position error, velocity error, and maneuver error, that occur when the CubeSat is separated from the lunar orbiter, eventually affect the final impact position. As a result, the current study adopts a CubeSat release from the circular orbit at 100 km altitude and an impact slope of $15^{\circ}$, among the possible impacting scenarios. For this scenario, the required ${\Delta}V$ is calculated as the result of the ${\Delta}V$ analysis. It can be used to practically make an estimate of this specific mission's fuel budget. In addition, the current study suggests error constraints for ${\Delta}V$ for the mission.

Experimental analysis of the sedimentation processes in the movable weir by changing the channel slope considering weir operation (가동보 운영 및 하상경사 변화에 의한 보 상류 퇴사과정의 실험적 분석)

  • Lee, Kyung Su;Jang, Chang-Lae
    • Journal of Korea Water Resources Association
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    • v.51 no.8
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    • pp.729-737
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    • 2018
  • This study investigates the sediment processes the Improved-pneumatic-movable weir through laboratory experiments considering changing channel slopes. Experimental results show that the delta migrates towards the weir and the delta height increases as time passes. Moreover, as the delta approaches the weir, the delta migration speed decreases. As the dimensionless delta location increases, the effective height of dimensionless delta and the dimensionless reservoir capacity increases. Therefore, under the same slope conditions, the sediment deposition volume of the delta is small as the channel slope is mild. This means that the channel slope affects the development of the delta in the upstream of the Improved-pneumatic-movable weir. At the beginning of the experiment, the foreset slope is mild. However, the foreset slope of the delta increases with water depth as the delta migrates downstream. Moreover, as the slope is mild, the ratio of delta front length to delta height is close to 1, and the dimensionless delta height and the dimensionless delta migration speed decrease. As the delta height increases, the water depth, the velocity approaching to the weir and the delta migration speed decrease.

Dielectric Properties of XLPE/Semiconductor Sheet in Power Cables (전력케이블용 XLPE/반도전층의 유전 특성)

  • 이관우;이경용;최용성;박대희
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.17 no.8
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    • pp.904-909
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    • 2004
  • We studied the dielectric properties and voltage dependence on slice XLPE sheet from 22 kV and 154 kV power cables. Interface structures are XLPE/semiconductor and XLPE/water/semiconductor capacitance and tan6 of 22 kV, 154 kV were 52/42 pF and $7.4\times{10}/^{-4}, 2.15\times{10}^{-4}$, respectively in these results, the trend was increased with the increase of temperature the tan$\delta$ of XLPE/semiconductive layer and XLPE/water/ semiconductive layer were increased as compared with that of XLPE Temperature reliability of tan$\delta$ was small.

Seismic Performance Evaluation of Inverted V Braced Steel Frames with Considering P-Δ Effects: A Case Study (P-Δ 효과를 고려한 역 V형 철골 가새골조의 내진성능평가: 사례연구)

  • Lee, Cheol-Ho;Kim, Jeong-Jae
    • Journal of the Earthquake Engineering Society of Korea
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    • v.8 no.3
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    • pp.97-103
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    • 2004
  • Most of the columns in centrally braced steel frame buildings are usually designed as the gravity columns to reduce connection cost. For a rational seismic performance evaluation of centrally braced steel frame buildings, it is important to properly incorporate in the analysis  the P-${\Delta}$ effects arising from the gravity columns. An effective scheme for the P-${\Delta}$ effects modeling due to the gravity columns was illustrated based on the concept of fictitious leaning column. Seismic performance evaluation of inverted V braced steel frames with or without P-${\Delta}$ effects modeling was conducted by following the FEMA 273 NSP (Nonlinear Static Procedure). The problem in estimating dynamic P-${\Delta}$ modification factor (C3) in FEMA 273 was discussed. The results of this study indicated that the P-${\Delta}$ effects should be included in the seismic performance evaluation of centrally braced steel frames. This study also showed that the inverted V braced frames, retrofitted by applying the tie bars to redistribute the inelastic demand over the height of the building, exhibit significantly improved seismic performance.

Maximum Degree Vertex-Based Algorithm for Maximum Clique Problem (최대 클릭 문제에 관한 최대차수 정점 기반 알고리즘)

  • Lee, Sang-Un
    • Journal of the Korea Society of Computer and Information
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    • v.20 no.1
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    • pp.227-235
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    • 2015
  • In this paper, I propose a linear time algorithm devised to produce exact solution to NP-complete maximum clique problem. The proposed algorithm firstly, from a given graph G=(V,E), sets vertex $v_i$ of the maximum degree ${\Delta}(G)$ as clique's major vertex. It then selects vertex $v_j$ of ${\Delta}(G)$ among vertices $N_G(v_i)$ that are adjacent to $v_i$, only to determine $N_G(v_i){\cap}N_G(v_j)$ as candidate cliques w and $v_k$. Next it obtains $w=w{\cap}N_G(v_k)$ by sorting $d_G(v_k)$ in the descending order. Lastly, the algorithm executes the same procedure on $G{\backslash}w$ graph to compare newly attained cliques to previously attained cliques so as to choose the lower. With this simple method, multiple independent cliques would also be attainable. When applied to various regular and irregular graphs, the algorithm proposed in this paper has obtained exact solutions to all the given graphs linear time O(n).

Mg Delta-Doping Effect on a Deep Hole Center Related to Electrical Activation of a p-Type GaN Thin Film

  • Park, Hyo-Yeol;Jeon, Kyoung-Nam;Kim, Keun-Joo
    • Transactions on Electrical and Electronic Materials
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    • v.11 no.1
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    • pp.37-41
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    • 2010
  • The authors investigated the photoluminescence (PL) and the electron paramagnetic resonance (EPR) from an magnesium (Mg)-doped GaN thin film with a delta-doped layer. The regularly doped sample shows a PL peak at 2.776 eV for the as-grown sample, and the peak shifts to 2.904 eV and increases in intensity for the annealed sample. The delta-doped sample also shows the same PL peak as does the regularly doped sample. However, only the annealed delta-doped layer shows a sharp EPR with a small isotropic Lande g-factor, $g_{II}$, of 2.029. This resonance is attributed to the delta-doped layer, which forms a hole-bound Mg-N atomic structure instead of the $Mg_{Ga}-V_N$ defect complex, indicating that the delta-doped sample was not optically activated to form PL centers but was instead electrically activated to form a hole-bound state.

Equivalent 10-Hz Flicker Index Calculation Using Half-cycle Sliding Window and Recursive RMS Method (반주기 슬라이딩 윈도우와 재귀적 실효치 계산을 이용한 국내 플리커 평가지수 산출기법)

  • Cho, Soo-Hwan
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.60 no.11
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    • pp.2017-2020
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    • 2011
  • Flicker, which is also known as voltage fluctuation, is an electromagnetic phenomenon generated by large scale nonlinear loads, such as arc furnaces and welding machines. Since a severe and continuous flicker can cause to some damages to electrically sensitive loads as well as human's visual irritations, it needs to be appropriately managed by being accurately measured, quantified and assessed. In Korea, an equivalent 10-Hz flicker index, shortly ${\Delta}V10$, is used to determine the permission limit of flicker. This paper presents an efficient calculation of the flicker index by using a half-cycle sliding window and a recursive method, showing a concrete calculating procedure of ${\Delta}V10$ from the viewpoint of signal processing.

Natural Convection Heat Transfer in Rectangular Air Enclosures With Adiabatic and Isothermal Horizontal Boundary Conditions (단열 및 등온수평 경계조건을 갖는 직각 밀폐용기내 공기의 자연대류 열전달)

  • 이진호;김무현;모정하
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.14 no.1
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    • pp.207-213
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    • 1990
  • Natural convection heat transfer in rectangular air enclosure was studied interferometrically and numerically for the use of adiabatic and constant temperature horizontal boundary conditions. In the isothermal horizontal boundary case with the temperature difference ratio, .DELTA. $T_{v/}$.DELTA. $T_{H}$ .simeq. 1 temperature distribution in the enclosure is strongly stratified and the average Nusselt Number is higher than that of adiabatic horizontal boundary case.ase.