Proceedings of the Korean Fiber Society Conference (한국섬유공학회:학술대회논문집)
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1994.10a
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A new theoretical fabric shear model has been presented and a quantitative study has been conducted on the shear properties of polyethylene(terephthalate)(PET) fabrics of four different fabric densities and five different weight reduction. The fabric shear properties were measured with KES-F handle measurement system. From the theoretical and experimental studies, following results can be summarized : 1) The fabric shear behavior is strongly dependent on the fabric density and free volume available for the constituent yarns and their filament. 2) Shear hysteresis at the small shear angle(2HG) is dependent more on the yarn tensile properties than on the fabric structure. 3) Shear hysteresis at the shear angle, 5(2HG5) is dependent more on the interaction between two crossing yarns which is directly related on the fabric structure than on the yarn tensile properties.
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Anionic water dispersible copolyesters were synthesized by the polycon-densation of dimethyl isophathalate/5-sodium sulfo dimethyl isophathalate with ethylene glycol/diethylene glycol. Structrual analyses such as NMR, Irm WAXD analyses were done and copolyesters were found to be correctly synthesized. Relation between feed ratio and composition ratio of EG/DEG in copolyesters was confirmed by NMR analysis. Solubility test was done to find out optimum conditon of DMS feed ration of 10 mol% in dimethyl esters. Water resistance of copolyesters decreased with the increase of DMS or DEG molar feed ratio.
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Anionic water dispersible copolyesters were synthesized and characterized. Viscosity of the copolyester is lower than that of routine acrylic water dispersible polymers. Adhesive force of the copolyester was much higher than that of water dispersible acrylic polymers. Particle size of the copolyesters in water decreased with the increase of DMS or DEG feed ratio. With the conclusive study of the data of particle size and potential, it was found that the dispersion stability of copolyesters in water increased with the increase of DMS or DEG feed ratio. Judging from the results of potential and particle size of copolyesters, there seems to be competition between two dispersion stability factors, i.e. electrostatic stabilization and steric stabilization and as a result, morphological change of particles occurrs. Tg decreased with the increase of DEG molar feed ratio or oil contents.