권호 표지

Journal of Soil and Groundwater Environment (한국지하수토양환경학회지:지하수토양환경)

Korean Society of Soil and Groundwater Environment (KoSSGE)

  • Bimonthly
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  • 1598-6438(pISSN)
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  • 2287-8831(eISSN)

Aim & Scope

The Journal of Soil and Groundwater Environment is the offi cial peer-reviewed publication of Korean Society of Soil and Groundwater Environment(KoSSGE). The journal was launched in 1996, and accepts original research articles, reviews, technical notes, technical reports, special features, discussions and editorials in the fi eld of soil and groundwater environments. The KoSSGE aims to contribute to the social benefi t including an effi cient development and a proper conservation of environmental resources through the journal publication. The journal promotes communication among academia, industry, government, and non-governmental organizations who are instrumental in the solution of soil and groundwater environmental problems. The journal is published bimonthly in February, April, June, August, October and December each year. Supplementary issues are published occasionally. The offi cial title of the journal is ‘Journal of Soil and Groundwater Environment’ and the abbreviated title is ‘J. Soil Groundwater Environ.’ All submitted manuscripts are peer-reviewed by three reviewers. The text may be written in Korean or English. The abstract, the titles of fi gure and table should be written in English. All of the articles in this journal are indexed in KCI and DOI/Crossref. The circulation is 450 numbers. Manuscript should be uploaded to the online-submission system through the Journal’s homepage (www.ijsge.org). The full text of the Journal is available through the URL www.ijsge.org, www.kossge.or.kr, society.kisti.re.kr, www.kci.go.kr, ieg.or.kr, and www.riss.kr. The journal was supported by the ‘Korean Federation of Science and Technology Societies’ Grant funded by the Korean Government, ‘Korean Federation of Water Science and Engineering Society(KFWSES)’.

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Volume 21 Issue 6

  1. Lee, Jae-young;Lee, Minhee;Yu, Mokryun 1
    https://doi.org/10.7857/JSGE.2016.21.6.001 PDF KSCI
    The programmable logic array to match the treatment technology to the soil contaminated site based on the site properties in Korea was developed. Based on the previous technology screening system of FRTR (Federal Remediation Technology Roundtable) in USA, total 9 evaluation factors indicating the site characteristics were used for the technology matching process and 8 factors among them were quantitatively weighed in the order of importance. The class interval for each evaluation factor was linearly distributed to give the weighed score and 8 scores were summed up to prioritize the treatment technology. The optimal treatment technology for a specific site was determined according to the total score acquired from 8 evaluation factors used in this technology matching process. The reliability test for the developed technology matching system was done by using information of two real cleanup sites in Korea, suggesting that this guideline will be available to determine the most effective treatment technology to cleanup the soil contaminated site and also to assist the government or the company to design a successful and cost-effective site cleanup plan in Korea.
  2. Yang, Kyung;Kim, Byung Chul;Yu, Gihyeon;Nam, Kyoungphile 14
    https://doi.org/10.7857/JSGE.2016.21.6.014 PDF KSCI
    This study evaluated the applicability of stabilization of arsenic (As)-contaminated soil with iron (Fe) oxides at the former Janghang smelter site. Three Fe oxides (magnetite, goethite, and hematite) were tested as stabilizing agents to one soil sample collected from the study site. Amendment of 5% of magnetite, goethite, or hematite for one week showed the 64, 58, and 36% of reduction of the SBRC (Solubility/Bioavailability Research Consortium)-extractable (bioaccessible) As, respectively. Duration of stabilization more than one week did not show an additional reduction in SBRC-extractable As. Amendment of 5% of magnetite, which showed the highest As stabilization efficiency, was applied to 24 soil samples collected from the same site for one week, and 72% of reduction in the bioaccessible As was observed. The potential carcinogenic human health risk at the study site caused by As was $1.7{\times}10^{-5}$, which could be reduced to $8.1{\times}10^{-6}$ by the amendment of 5% magnetite for one week.
  3. Shin, Esther;Koh, Eun-Hee;Ha, Kyoochul;Lee, Eunhee;Lee, Kang-Kun 22
    https://doi.org/10.7857/JSGE.2016.21.6.022 PDF KSCI
    Global climate change could have an impact on hydrological process of a watershed and result in problems with future water supply by influencing the recharge process into the aquifer. This study aims to assess the change of groundwater recharge rate by climate change and to predict the sustainability of groundwater resource in Pyoseon watershed, Jeju Island. For the prediction, the groundwater recharge rate of the study area was estimated based on two future climate scenarios (RCP 4.5, RCP 8.5) by using the Soil Water Balance (SWB) computer code. The calculated groundwater recharge rate was used for groundwater flow simulation and the change of groundwater level according to the climate change was predicted using a numerical simulation program (FEFLOW 6.1). The average recharge rate from 2020 to 2100 was predicted to decrease by 10~12% compared to the current situation (1990~2015) while the evapotranspiration and the direct runoff rate would increase at both climate scenarios. The decrease in groundwater recharge rate due to the climate change results in the decline of groundwater level. In some monitoring wells, the predicted mean groundwater level at the year of the lowest water level was estimated to be lower by 60~70 m than the current situation. The model also predicted that temporal fluctuation of groundwater recharge, runoff and evapotranspiration would become more severe as a result of climate change, making the sustainable management of water resource more challenging in the future. Our study results demonstrate that the future availability of water resources highly depends on climate change. Thus, intensive studies on climate changes and water resources should be performed based on the sufficient data, advanced climate change scenarios, and improved modeling methodology.
  4. Jung, Youn-Young;Koh, Dong-Chan;Han, Hye-Sung;Kwon, Hong-Il;Lim, Eun-Kyung 36
    https://doi.org/10.7857/JSGE.2016.21.6.036 PDF KSCI
    Variability in precipitation due to climate change causes difficulties in securing stable surface water resource, which requires understanding of relation between precipitation and stream discharge. This study simulated stream discharge in a small mountainous forested catchment using antecedent precipitation index (API) models which represent variability of saturation conditions of soil layers depending on rainfall events. During 13 months from May 2015 to May 2016, stream discharge and rainfall were measured at the outlet and in the central part of the watershed, respectively. Several API models with average recession coefficients were applied to predict stream discharge using measured rainfall, which resulted in the best reflection time for API model was 1 day in terms of predictability of stream discharge. This indicates that soil water in riparian zones has fast response to rainfall events and its storage is relatively small. The model can be improved by employing seasonal recession coefficients which can consider seasonal fluctuation of hydrological parameters. These results showed API models can be useful to evaluate variability of streamflow in ungauged small forested watersheds in that stream discharge can be simulated using only rainfall data.
  5. Park, Gyuryeong;An, Hyejin;Kim, Seon-ok;Wang, Sookyun 46
    https://doi.org/10.7857/JSGE.2016.21.6.046 PDF KSCI
    This experimental study was aimed to estimate interfacial tension of brine-$CO_2$ by using a pendant bubble method and image analysis. Measurements were performed for wide ranges of temperatures, pressures, and salinities covering reservoir conditions in Pohang basin, a possible candidate for $CO_2$ storage operation in Korea. The profiles of $CO_2$ bubbles in brine obtained from image analysis with the densities of brine and $CO_2$ from previous studies were applied to Laplace-Young equation for calculating interfacial twnsion in brine-$CO_2$ system. The experimental results reveals that the interfacial tension is significantly affected by reservoir conditions such as pressure, temperature and water salinity. For conditions of constant temperature and water salinity, the interfacial tension decreases as pressure increases for low pressures (P < $P_c$), and approaches to a constant value for high pressures. For conditions of constant pressure and water salinity, the interfacial tension increases as temperature increases for T < $T_c$, with an asymptotic trend towards a constant value for high temperatures. For conditions of constant pressure and temperature, the interfacial tension increases with increasing water salinity. The trends in changes of interfacial tension can be explained by the effects of the reservoir conditions on the density difference of brine and $CO_2$, and the solubility of $CO_2$ in brine. The information on interfacial tensions obtained from this research can be applied in predicting the migration and distribution of injecting and residual fluids in brine-$CO_2$-rock systems in deep geological environments during geological $CO_2$ sequestrations.
  6. Lim, Tae-Yong;Lee, Sang-Woo;Yun, Seong-Taek;Kim, Soon-Oh 56
    https://doi.org/10.7857/JSGE.2016.21.6.056 PDF KSCI
    Generally, the contribution of crop-intake pathway (CIP) is remarkable in human health assessment (HHA) of heavy metal contamination. Although the crop exposure concentrations (Cp) should directly be used for calculating the average daily dose (ADD) of CIP, the soil exposure concentration (Cs) multiplied by soil-crop bio-concentration factor (BCF) has frequently been used instead of using Cp values. Thus, the BCF values are significant in the HHA, and care should be taken to ensure the reasonable acquisition of BCF values. Meanwhile, the BCF values are known to be significantly affected by analytical methods. Nevertheless, they have been calculated from the concentrations of soil and crop analyzed by only one method: total digestion (aqua regia extraction). For this reason, this study was initiated to seek appropriate soil analysis methods for effective computation of the ADD of CIP. The concentrations of 5 metal contaminants (As, Cd, Cu, Pb, and Zn) in 127 soil samples obtained from 4 abandoned metal mine areas were analyzed by several methods including total digestion and partial digestions using 0.1/1 N HCl, 1M $NH_4NO_3$, 0.1 M $NaNO_3$, and 0.01M $CaCl_2$. The heavy metal concentrations in 127 crop samples (rice grains) were analyzed by total digestion as well. Using the concentrations of soils and crops, the BCF values of each contaminant were calculated according to the kind of soil extraction methods applied. Finally, the errors between Cp and $C_s{\times}BCF$ were computed to evaluate the relevance of each method. The results indicate that the partial extraction using 0.1 N and 1 N HCl was superior or equivalent to total digestion. In addition, the 0.1M $NaNO_3$ method combined with total digestion is recommended for improving the reliability of BCF values.
  7. Koo, Min-Ho;Park, Eungyu;Jeong, Jina;Lee, Heonmin;Kim, Hyo Geon;Kwon, Mijin;Kim, Yongsung;Nam, Sungwoo;Ko, Jun Young;Choi, Jung Hoon;Kim, Deog-Geun;Jo, Si-Beom 67
    https://doi.org/10.7857/JSGE.2016.21.6.067 PDF KSCI
    Gaussian process regression (GPR) is proposed as a tool of long-term groundwater quality predictions. The major advantage of GPR is that both prediction and the prediction related uncertainty are provided simultaneously. To demonstrate the applicability of the proposed tool, GPR and a conventional non-parametric trend analysis tool are comparatively applied to synthetic examples. From the application, it has been found that GPR shows better performance compared to the conventional method, especially when the groundwater quality data shows typical non-linear trend. The GPR model is further employed to the long-term groundwater quality predictions based on the data from two domestically operated groundwater monitoring stations. From the applications, it has been shown that the model can make reasonable predictions for the majority of the linear trend cases with a few exceptions of severely non-Gaussian data. Furthermore, for the data shows non-linear trend, GPR with mean of second order equation is successfully applied.
  8. Lee, Jin-Yong 80
    https://doi.org/10.7857/JSGE.2016.21.6.080 PDF KSCI
    Earthquakes of M5.1, M5.8 and M4.5 occurred in September 12 and 19 respectively in Gyeongju, Gyeongbuk Province. Theses earthquakes inflated fears of people and highlighted necessity of detailed countermeasures because we have considered our country is safe to earthquakes. In the meanwhile, earthquake also impacts groundwater and thus it was recently reported that the Gyeongju Earthquakes affected groundwater there. This study evaluates daily groundwater data collected from five national groundwater monitoring stations (Geoncheon, Sannae, Oedong, Yangbuksin, Cheonbuk) in Gyeongju. The analysis revealed that only groundwater level of bedrock monitoring well hosted in andesite exhibited earthquake impact while no wells in the other four stations hosted in sedimentary rocks showed substantial responses to the earthquakes. This may be derived from the difference of seismic velocity of hosting rocks as well as epicenter distance. Special interest on groundwater monitoring is required to predict earthquakes as precursory phenomena.
  9. Koh, Il-Ha;Kim, Jungeun;Kim, Gi Suk;Park, Mi Sun;Kang, Dae Moon;Ji, Won Hyun 87
    https://doi.org/10.7857/JSGE.2016.21.6.087 PDF KSCI
    Biochar, which has high alkalinity, has widely studied for amendment of soil that contaminated with heavy metals. The aim of this study is assessment of amendment for arsenic and heavy metals contaminated acidic agricultural soil using biochar that derived from buffalo weed (A. trifida L. var. trifida). Pot experiments were carried out including analysis of soil solution, contaminants fractionation, soil chemical properties and plant (lettuce) uptake rate. Arsenic and heavy metals concentrations in soil solution showed relatively low in biochar added experiments when compared to the control. In the heavy metals fractionation in soil showed decrease of exchangeable fraction and increase of carbonates fraction; however, arsenic fractionations showed constant. Soil chemical properties indicated that biochar could induce recovery of soil quality for plant growth in terms of soil alkalinity. However, phosphate concentration in biochar added soil decreased due to Ca-P precipitation by exchangeable calcium from biochar. Arsenic and heavy metals uptake rate of plant in the amended experiment decreased to 50% when compared to the control. Therefore biochar derived from buffalo weed can be used as amendment material for agricultural soil contaminated with arsenic and heavy metals. Precipitation of As-Ca and metal-carbonates are major mechanisms for soil amendment using char.
  10. Jeen, Sung-Wook;Jun, Seong-Chun;Kim, Rak-Hyeon;Hwang, Hyoun-Tae 101
    https://doi.org/10.7857/JSGE.2016.21.6.101 PDF KSCI
    To properly manage and remediate groundwater contaminated with chlorinated hydrocarbons such as trichloroethylene (TCE), it is necessary to assess natural attenuation processes of contaminants in the aquifer along with investigation of contamination history and aquifer characterization. This study evaluated natural attenuation processes of TCE at an industrial site in Korea by delineating hydrogeochemical characteristics along the flow path of contaminated groundwater, by calculating reaction rate constants for TCE and its degradation products, and by using geochemical and reactive transport modeling. The monitoring data showed that TCE tended to be transformed to cis-1,2-dichloroethene (cis-1,2-DCE) and further to vinyl chloride (VC) via microbial reductive dechlorination, although the degree was not too significant. According to our modeling results, the temporal and spatial distribution of the TCE plume suggested the dominant role of biodegradation in attenuation processes. This study can provide a useful method for assessing natural attenuation processes in the aquifer contaminated with chlorinated hydrocarbons and can be applied to other sites with similar hydrological, microbiological, and geochemical settings.
  11. Hahn, Jeongsang;Kiem, Youngseek;Lee, Juhyun;Lee, Byoungho;Hahn, Chan 114
    https://doi.org/10.7857/JSGE.2016.21.6.114 PDF KSCI
    An increase of groundwater flux in BHE system creates that ground temperature (locT) becomes lower in summer and higher in winter time. In other words, it improves significantly the performance of BHE system. The size of thermal plume made up by advection driven-flow under the balanced energy load is relatively small in contrast to the unbalanced energy load where groundwater flow causes considerable change in the size of thermal plume as well ground temperature. The ground temperatures of the up gradient and down gradient BHEs under conduction only heat transport are same due to no groundwater flow. But a significant difference of the ground temperature is observed between the down gradient and up gradient BHE as a result of groundwater flow-driven thermal interference took placed in BHE field. As many BHEs are designed under the obscure assumption of negligible groundwater flow, failure to account for advection can cause inefficiencies in system design and operation. Therefore including groundwater flow in the design procedure is considered to be essential for thermal and economic sustain ability of the BHE system.
  12. Son, Younggyu 128
    https://doi.org/10.7857/JSGE.2016.21.6.128 PDF KSCI
    Acoustic emission spectra was analyzed to investigate the distribution of sound pressure in a 36 kHz sonoreactor. The sound pressure of fundamental frequency (f: 36 kHz), harmonics (2f: 72 kHz, 3f: 108 kHz, 4f: 144 kHz, 5f: 180 kHz, 6f: 216 kHz), and subharmonics (1.5f: 54 kHz, 2.5f: 90 kHz, 3.5f: 126 kHz, 4.5f: 162 kHz, 5.5f: 198 kHz, 6.5f; 234 kHz) was measured at every 5 cm from the ultrasonic transducer using a hydrophone and a spectrum analyzer. It was revealed that the input power of ultrasound, the application of mechanical mixing, and the concentration of SDS affected the sound pressure distributions of the fundamental frequency and total detected frequencies frequencies significantly. Moreover a linear relationship was found between the average total sound pressure and the degree of sonochemical oxidation while there was no significant linear relationship between the average sound pressure of fundamental frequency and the degree of sonochemical oxidation.
  13. Yun, Do Youn;Ahn, Jun-Young;Kim, Cheolyong;Kim, Tae Yoo;Hwang, Inseong 135
    https://doi.org/10.7857/JSGE.2016.21.6.135 PDF KSCI
    MgO recently has been regarded as the alternative material for replacement of cement. The aim of this study is to investigate the effects of accelerated carbonation on the strength development of MgO-based binder which is binary mixtures of magnesium oxide (MgO) with portland cement (PC) or ground granulated blast furnace slag (GGBS) or fly ash (FA). The compressive strengths of all binders were higher in the 20% $CO_2$ condition and for longer curing time. The strength were generally higher as the following order: MgO/PC > MgO/GGBS > MgO/FA system. The binder composed of 20% MgO and 80% PC showed highest compressive strength (38.0MPa) which was higher than PC. The correlation analysis of the porosity and compressive strength showed that compressive strength was higher when porosity was lower. The hydration and carbonation products of MgO including brucite ($Ca(OH)_2$), magnesite ($MgCO_3$) and nesquehonite ($MgCO_3{\cdot}3H_2O$) presumably filled the pores and contributed to strength development. Thermogravimetric analyses elucidated that 0.34 kg of $CO_2$ could be stored the 50% MgO/50% PC binder which performed the maximum $CO_2$ uptake at 20% $CO_2$ condition.
  14. Han, Yikyeong;Lee, Minhee 146
    https://doi.org/10.7857/JSGE.2016.21.6.146 PDF KSCI
    The field feasibility tests for a phytoextraction process were performed to identify the effect of citric acid as a chelate on the uranium (U) transfer into the plant for the naturally U contaminated soil in Duckpyeongri, Korea. For the feasibility tests, lettuce and Chinese cabbage were cultivated for 49 days on four testing grounds ($1m{\times}1m{\times}0.5m$ in each) in 2016. The citric acid solution was added to two testing grounds (one for lettuce and the other for Chinese cabbage) increasing the U transfer in two crop plants and their results were compared to those without the citric acid solution. When without the citric acid solution, the U concentration of plant after the cultivation was low (< $45{\mu}g/kg$ for leaves and < $450{\mu}g/kg$ for roots). However, with the addition of 50 mM citric acid solution, the U concentration of lettuce leaves and roots increased by 24 times and 1.8 times, and the U concentration of Chinese cabbage leaves and roots increased by 86.7 times and 5.4 times. The absolute accumulated U amount (${\mu}g$) in lettuce and Chinese cabbage also increased by 8.7 times and 50 times, compared to those without citric acid solution. Less than 8% of the U amount of exchangeable/carbonate phases was removed by using the lettuce and Chinese cabbage when the citric acid solution was not applied. However 52% and 66% of the U amount in exchangeable/carbonate phases were removed by the lettuce and the Chinese cabbage when the citric acid solution was added. The effect of the citric acid on the U transfer capability into the plants was quantitatively investigated by the field feasibility test, suggesting that U existing as exchangeable/carbonate phase in soil can be successfully removed by the phytoextraction process using Chinese cabbage with citric acid.
  15. Park, So-Yeon;Yoo, Seoung-Hoon 156
    https://doi.org/10.7857/JSGE.2016.21.6.156 PDF KSCI
    The Korean government is planning to invest a lot of funds for conservation of the soil. Accordingly, it needs quantitative information on the soil. This paper attempts to analyze the total value of soil quantitatively: the total economic value of soil can be divided into use value and non-use value. To this end, we apply a replacement cost method (RCM) and contingent valuation method (CVM). Especially, CVM is most widely used to measure the non-use value such as environment goods. We employed the one-and-one-half-bounded dichotomous choice (OOHBDC) for willingness to pay (WTP) elicitation and a spike model. The monthly mean WTP was estimated to be KRW 3,949 per household for the next 10 years, which is statistically significant at the 1% level. Expanding the value to the relevant population gives us KRW 897.9 billion per year and as of the end of 2015, the non-use value of soil was assessed to be KRW 838.6 billion. Meanwhile, use value is subdivided into direct use value and indirect use value. This value was calculated KRW 3,277 trillion and KRW 51.8 trillion, respectively. As a result, total economic value of soil is estimated to be KRW 3,330 trillion in Korea.
  16. Lee, Hong-gil;Kim, Ji-in;Noh, Hoe-Jung;Park, Jeong-Eui;Kim, Tae Seung;Yoon, Jeong Ki 169
    https://doi.org/10.7857/JSGE.2016.21.6.169 PDF KSCI
    The Standards, Measurement and Testing Programme (SM&T-formerly BCR) extraction procedure was applied to fractionate Cr, Cu, Ni, Pb and Zn in 23 top soil samples into: (i) exchangeable phase; (ii) reducible phase; (iii) oxidisable(sulfides and organics bound) phase; and (iv) residual phase. Fractions of Cr and Ni were in the order of residual > oxidisable > reducible > exchangeable phase. The oxidisable phase was identified as dominant for Cu and Pb. Zn had the highest ratio of exchangeable phase in comparision to the other metals. The bioavailability and mobility were assessed to be the greatest for Zn, followed by a decreasing order of Pb, Cu, Ni and Cr. All metal average concentrations in topsoil samples was higher in industrial sites than in agricultural sites. Our results revealed higher concentrations in topsoil samples (0~15 cm) than in sub soils (15~30 cm, 30~60 cm) for most metals at six sites (No. 5, 6, 17, 19, 20, 23). The fractions of exchangeable, reducible ad oxidisable phases showed relatively high correlation with soil pH, Fe/Mn oxide concentrations and organic matter contents, respectively.
  17. Kwon, Ji Cheol;Lee, Goontaek;Kim, Tae Seung;Yoon, Jeong-Ki;Kim, Ji-in;Kim, Yonghoon;Kim, Joonyoung;Choi, Jeongmin 179
    https://doi.org/10.7857/JSGE.2016.21.6.179 PDF KSCI
    In addition to the measurement of the concentration of soil contaminants, the new idea of indicative parameters was proposed to validate the remedial works through the monitoring for the changes of soil characteristics after applying the clean up technologies. The parameters like CFU (colony forming unit), pH and soil texture were recommended as indicative parameters for land farming. In case of soil washing, water content and the particle size distribution of the sludge were recommended as indicative parameters. The sludge is produced through the particle separation process in soil washing and it is usually treated as a waste. The parameters like water content, organic matter content, CEC (cation exchange capacity) and CFU were recommended as indicative parameters for the low temperature thermal desorption method. Besides the indicative parameter, sampling methods in stock pile and the optimal minimum amount of composite soil sample were proposed. The rates of sampling error in regular grid, zigzag, four bearing, random grid methods were 17.3%, 17.6%, 17.2% and 16.5% respectively. The random grid method showed the minimum sampling error among the 4 kinds of sampling methods although the differences in sampling errors were very little. Therefore the random grid method was recommended as an appropriate sampling method in stock pile. It was not possible to propose a value of optimal minimum amount of composite soil sample based on the real analytical data due to the dynamic variation of $CV_{fund{\cdot}error}$. Instead of this, 355 g of soil was recommended for the optimal minimum amount of composite soil sample under the assumption of ISO 10381-8.
  18. Ahn, Jun-Young;Kim, Cheolyong;Kim, Tae Yoo;Jun, Seong-Chun;Hwang, Inseong 192
    https://doi.org/10.7857/JSGE.2016.21.6.192 PDF KSCI
    A field investigation was conducted on an aquifer contaminated with trichloroethylene (TCE) for application of in situ reactive zone treatment using nanosized zero-valent iron (NZVI). The aquifer was an unconfined aquifer with a mean hydraulic conductivity of $5.14{\times}10^{-4}cm/sec$, which would be favorable for NZVI injection. Seasonal monitoring of TCE concentration revealed a presence of non-aqueous phase liquid form of TCE near IW (injection well). The hydrochemical data characterized the site groundwater to be a $Ca-HCO_3$ type. The average value of Langelier Saturation Index of the groundwater was -1.33, which implied that the site was favorable for corrosion of NZVI. Dissolved oxygen (DO) concentration varied between 2.5~11.5 mg/L, which indicated that DO would greatly compete with TCE as an electron acceptor. The hydrogeological and hydrochemical characterization reveals that the time around November would be appropriate for NZVI injection when water level and temperature are relatively high and DO concentration is low.