• Title/Summary/Keyword: white emission

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Device Characteristics of white OLED using the fluorescent and phosphorescent materials coupled with interlayer

  • Lee, Young-Hoon;Kim, Jai-Kyeong;Yoo, Jai-Woong;Ju, Byeong-Kwon;Kwon, Jang-Hyuk;Jeon, Woo-Sik;Chin, Byung-Doo
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08b
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    • pp.1437-1439
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    • 2007
  • We fabricated white organic light emitting device (WOLED) with the layered fluorescent blue material and phosphorescent green/red dye-doped materials. Addition of the non-doped phosphorescent host material between the fluorescent and phosphorescent light emitting layers provided the result of broadband white spectrum, with improved balance, higher efficiency, and lower power consumption. In our devices, there was no need of exciton-blocking layer between the each emission layer for the further confinement of the diffusion of excitons.

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White OLEDs with a Single Emissive Layer (단일발광층을 이용한 백색 OLED)

  • Chu, Hye-Yong;Lee, Jeong-Ik;Yang, Yong-Suk;Oh, Ji-Young;KoPark, Sang-Hee;Kim, Mi-Kyung;Hwang, Chi-Sun;Jung, Byung-Jun;Shim, Hong-Ku;Jang, Jin
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.05a
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    • pp.43-46
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    • 2004
  • We demonstrated efficient white light emitting OLEDs with a single emissive layer structure, which was blue-emitting 1,4-bis[2,2-diphenylvinyl]biphenyl (DPVBi) doped with blue luminescent amino-substituted distyrylarylene amine (DSA-amine) and red luminescent [2,6-bis[2-[5-(dibutylamino) phenyl]vinyl]-4H -pyran-4-ylidene]propanedinitrile (DADB). Through the optimization of the device structure, the white light emission with full visible spectral range was obtained. Its CIE color coordinates was (0.32,0.42) at 10 $mA/cm^2$ and the external quantum efficiency, the luminance efficiency and the luminance yield were 3.7 %, 3.3 lm/W and 9.0 cd/A, respectively.

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Fluorescent White OLEDs with a High Color-rendering Index Using a Silicon-Cored Anthracene Derivative as a Blue Host

  • Kwak, Jeong-Hun;Lyu, Yi-Yeol;Lee, Hyun-Koo;Char, Kook-Heon;Lee, Chang-Hee
    • Journal of Information Display
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    • v.11 no.3
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    • pp.123-127
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    • 2010
  • Fluorescent white organic light-emitting diodes showing high color-rendering indices (CRIs) of up to 81 was demonstrated, with a silicon-cored anthracene derivative (PATSPA) doped with DPAVBi utilized as the deep-blue host and dye materials, and the commercial dyes rubrene and DCM2 utilized as the orange- and red-light-emitting dyes. The devices, consisting of three emissive layers, showed bright-white-light emission, but the ratio of the blue peak to the orange and red peaks changed with the current density and the thickness of the blue emissive layer. A high CRI was achieved with the use of a deep-blue emitter doped in a novel host and by optimizing the blue-layer thickness. The device with a blue-layer thickness of 10 nm showed the Commission Internationale de l'Eclairage (CIE) color coordinate of (0.33, 0.35), a high CRI of 81, and a moderate external quantum efficiency of 2% at a current density of $2.5\;mA/cm^2$.

White Organic Light-emitting Diodes using the Tandem Structure Incorporating with Organic p/n Junction

  • Lee, Hyun-Koo;Kwon, Do-Sung;Lee, Chang-Hee
    • Journal of Information Display
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    • v.8 no.2
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    • pp.20-24
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    • 2007
  • Efficient white organic light-emitting diodes are fabricated with the blue and red electroluminescent (EL) units electrically connected in a stacked tandem structure by using a transparent doped organic p/n junction. The blue and red EL units consist of the light-emitting layer of 1,4-bis(2,2-diphenyl vinyl)benzene (DPVBi) and 4-dicyanomethylene-2-methyl-6-[2-(2,3,6,7-tetrahydro-1H,5H-benzo[i,j] quinolizin-8-yl)vinyl]-4H-pyran) (DCM2) doped tris(8-hydroxyquinoline) aluminum $(Alq_3)$, respectively. The organic p-n junction consists of ${\alpha}-NPD$ doped with $FeCl_3$ (15 % by weight ratio) and $Alq_3$ doped with Li (10 %). The EL spectra exhibit two peaks at 448 and 606 nm, resulting in white light-emission with the Commission Internationale d'Eclairage (CIE) chromaticity coordinates of (0.36, 0.24). The tandem device shows the quantum efficiency of about 2.2 % at a luminance of 100 $cd/m^2$, higher than individual blue and red EL devices.

Properties of Y3Al5O12:Ce3+,Pr3+ Single Crystal for White Laser Lightings (백색 레이저 조명용 Y3Al5O12:Ce3+,Pr3+ 단결정 특성)

  • Kang, Taewook;Lim, Seokgyu;Kim, Jongsu;Lee, Bong
    • Journal of the Semiconductor & Display Technology
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    • v.17 no.4
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    • pp.37-41
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    • 2018
  • $Y_3A_{l5}O_{12}:Ce^{3+},Pr^{3+}$ single crystal phosphor was prepared by floating zone method. single crystal was confirmed to have a Ia-3d (230) space group of cubic structure and showed regular morphology. The optical properties, single crystal exhibited a emission band from green, yellow wide wavelength and 610nm, 640nm red wavelength vicinity. The luminance maintenance rate was decreased by phonon with increasing temperature, but high luminance is maintained more than powder phosphor. In addition, $Y_3A_{l5}O_{12}:Ce^{3+},Pr^{3+}$ single crystal phosphor was applied to a high power blue laser diode, we implemented high power white laser lightings. and it was confirmed that thermal properties over time, due to the effective heat transfer of complete crystal structure. We confirmed that excellent radiant heat properties than powder phosphor was applied to a high power white laser diode.

Synthesis and Luminescence of Sr2Si5N8:Eu2+ Red Phosphor for High Color-Rendering White LED (고연색 LED용 적색 Sr2Si5N8:Eu2+ 형광체의 합성 및 발광특성 연구)

  • Lee, Sung Hoon;Kim, Jong Su;Kang, Tae Wook;Ryu, Jong Ho;Lee, Sang Nam
    • Journal of the Semiconductor & Display Technology
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    • v.16 no.4
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    • pp.11-15
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    • 2017
  • Red phosphors, $Sr_2Si_5N_8:Eu^{2+}$, were synthesized as a single-phase crystal structure by optimizing carbon and $Eu^{2+}$ contents in a carbothermal reduction nitridation method. With increasing $Eu^{2+}$ contents, the photoluminescence spectra were red-shifted from 600 nm peak for 1 mol% for to 700 nm for 7 mol%. It was suggested that this red shift is attributed to the energy transfer from one low-energy sited $Eu^{2+}$ (1) to other high-energy sited $Eu^{2+}$ (2). Finally, the best red sample (620 nm emission peak and 80 nm half width for 3 mole% of $Eu^{2+}$) was packaged on a Blue LED together with two additional green and yellow phosphors, the fabricated White LED showed a high color-rendering index of 90 and white color coordinates of x= 0.321 and y = 0.305.

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Emission Characteristics of White Organic Light-Emitting Diodes Using Blue Fluorescent and Red Phosphorescent Materials (청색 형광과 적색 인광 물질을 사용한 백색 OLED의 발광 특성)

  • Park, Chan-Suk;Ju, Sung-Hoo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.28 no.11
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    • pp.704-710
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    • 2015
  • We studied white organic light-emitting diodes using blue fluorescent and red phosphorescent materials. White single OLEDs were fabricated using SH-1 : BD-2 (3 vol.%) and CBP : $Ir(mphmq)_2(acac)$ (2 vol.%) as emitting layer (EML). The white single OLED using SH-1 : BD-2 (3 vol.% 8 nm) / CBP : $Ir(mphmq)_2(acac)$ (2 vol.% 22 nm) as emitting layer showed maximum current efficiency of 8.8 cd/A, Commission Internationale de l'Eclairage (CIE) coordinates of (0.403, 0.351) at $1,000cd/m^2$, and variation of CIE coordinates with ($0.402{\pm}0.012$, $0.35{\pm}0.002$) from 500 to $3,000cd/m^2$. The white tandem OLED using SH-1 : BD-2 (3 vol.% 12 nm) / CBP : $Ir(mphmq)_2(acac)$ (2 vol.% 18 nm) showed maximum efficiency of 19.6 cd/A, CIE coordinates of (0.354, 0.365) at $1,000cd/m^2$, and variation of CIE coordinates with ($0.356{\pm}0.016$, $0.364{\pm}0.002$) from 500 to $3,000cd/m^2$. Maximum current efficiency of the white tandem OLED was more twice as high as the single OLED. Our findings suggest that tandem OLED was possible to produce improved efficiency and excellent color stability.

Effects of Red Ginseng-Ejung-tang and White Ginseng-Ejung-tang Water Extract on Hydrogen Peroxide Production in RAW 264.7 Cells (백삼(白蔘)과 홍삼(紅蔘)이 포함된 이중탕(理中湯)의 마우스 대식세포 내 hydrogen peroxide 생성에 미치는 영향)

  • Park, Wan-Su
    • Journal of Physiology & Pathology in Korean Medicine
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    • v.25 no.1
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    • pp.78-83
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    • 2011
  • The purpose of this study is to investigate whether the intracellular hydrogen peroxide productions of mouse macrophage RAW 264.7 are modulated by Red Ginseng-Ejung-tang water extract (ER) and White Ginseng-Ejung-tang water extract (EG). Red Ginseng-Ejung-tang were composed of Red Ginseng, Atractylodes rhizome white, Zingiberis Rhizoma Siccus, and Glycyrrhizae Radix. White Ginseng-Ejung-tang were composed of White Ginseng, Atractylodes rhizome white, Zingiberis Rhizoma Siccus, and Glycyrrhizae Radix. The intracellular hydrogen peroxide productions were measured by dihydrorhodamine 123 assay with spectrofluorometer (excitation 485 nm; emission 535 nm). For 4, 20, 24, 44, 48, 68, and 72 h incubation, ER significantly increased hydrogen peroxide productions of RAW 264.7 at the concentration of 25, 50, 100, and $200{\mu}g/mL$ (P <0.05). EG for 4, 20, 24, 44, and 48 h incubation significantly increased hydrogen peroxide productions of RAW 264.7 at the concentration of 25, 50, 100, and $200{\mu}g/mL$ (P <0.05). For 68 and 72 h incubation, EG at the concentration of 50, 100, and $200{\mu}g/mL$ significantly increased hydrogen peroxide productions in RAW 264.7 (P <0.05). These results suggest that ER and EG have the immune-enhancing properties related with their increasing effects on the intracellular hydrogen peroxide production of macrophage.

Electroluminescent Properties of White Light-Emitting Device Using Photoconductive Polymer and Anthracene Derivatives (광전도성 고분자와 안트라센 유도체를 이용한 백색 전계발광소자의 발광 특성)

  • Lee Jeong-Hwan;Choi Hee-Lack;Lee Bong
    • Korean Journal of Materials Research
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    • v.15 no.8
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    • pp.543-547
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    • 2005
  • Organic electroluminescence devices were made from 1,4-bis-(9-anthrylvinyl)benzene (AVB) and 1,4-bis-(9-aminoanthryl)benzene (AAB) anthracene derivatives. Device structure was ITO/AVB/PANI(EB)/Al (multi-layer device) and ITO/AAB:DCM/Al(single-layer device). In these devices, AVB, polyaniline(emeraldine base) (PANI(EB)) and AAB were used as the emitting material. 4-(dicyanomethylene)-2-methyl-6-p-(dimethylamino)styryl-4H -pyran(DCM) was used as red fluorescent dopant. We studied change of fluorescence wavelength with concentration of DCM doped in AAB. The ionization potential (IP) and optical band gap (Eg) were measured by cyclic voltammetry and UV-visible spectrum. We compared with difference of emitting wavelength between photoluminescence and electroluminescence spectrum. In case of the multi-layer device, PANI and AVB EL spectra have similar wave pattern to each PL spectrum and when PAM and AVB were used at the same time, and multi-layer device showed that a balanced recombination and radiation kom PANI and AVB. In case of the single-layer device, with the increase of DCM concentration, the blue emission decreases and red emission increases. This indicates that DCM was excited by the energy transfer from AAB to DCM or the direct recombination at the dopant sites due to carrier trapping, or both. The device with $1.0wt\%$ DCM concentration gave white light.

Ce:YAG remote phosphor coating for white LED with silica sol binder (Silica sol 바인더를 적용한 백색 LED용 Ce:YAG remote 형광체 코팅)

  • Gim, Su Jin;Park, Ha Na;Choi, Jae Ho;Jung, Yoon Sung;Kim, Hyeong-Jun
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.31 no.5
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    • pp.212-217
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    • 2021
  • The applicability of the white LED from the blue LED of the coating film as a binder for surface and curved coatings were confirmed. The particle size of YAG is D50: 9~10 ㎛, and the crystal structure is garnet (Y3Al5O12), cubic. The coating film had no cracks, at the same time, the silica sol was uniformly coated with YAG phosphor, and the YAG content and thickness in the coating film showed a tendency to increase up to 40 ㎛ in proportion to the increase in the amount added. Furthermore, as the YAG content increased, the PL emission intensity increased and the color coordinate shift toward the end of the chromatic locus curve was confirmed.