Fluorescent White OLEDs with a High Color-rendering Index Using a Silicon-Cored Anthracene Derivative as a Blue Host

  • Kwak, Jeong-Hun (School of Electrical Engineering and Computer Science, Inter-university Semiconductor Research Center, Seoul National University) ;
  • Lyu, Yi-Yeol (Unitech Co., Ltd.) ;
  • Lee, Hyun-Koo (School of Electrical Engineering and Computer Science, Inter-university Semiconductor Research Center, Seoul National University) ;
  • Char, Kook-Heon (School of Chemical and Biological Engineering, Intelligent Hybrids Research Center, Seoul National University) ;
  • Lee, Chang-Hee (School of Electrical Engineering and Computer Science, Inter-university Semiconductor Research Center, Seoul National University)
  • Received : 2010.09.09
  • Accepted : 2010.09.20
  • Published : 2010.09.30

Abstract

Fluorescent white organic light-emitting diodes showing high color-rendering indices (CRIs) of up to 81 was demonstrated, with a silicon-cored anthracene derivative (PATSPA) doped with DPAVBi utilized as the deep-blue host and dye materials, and the commercial dyes rubrene and DCM2 utilized as the orange- and red-light-emitting dyes. The devices, consisting of three emissive layers, showed bright-white-light emission, but the ratio of the blue peak to the orange and red peaks changed with the current density and the thickness of the blue emissive layer. A high CRI was achieved with the use of a deep-blue emitter doped in a novel host and by optimizing the blue-layer thickness. The device with a blue-layer thickness of 10 nm showed the Commission Internationale de l'Eclairage (CIE) color coordinate of (0.33, 0.35), a high CRI of 81, and a moderate external quantum efficiency of 2% at a current density of $2.5\;mA/cm^2$.

Keywords

References

  1. C. W. Tang and S. A. Van Slyke, Appl. Phys. Lett. 51, 913 (1987). https://doi.org/10.1063/1.98799
  2. J. Shi and C. W. Tang, Appl. Phys. Lett. 70, 1665 (1997). https://doi.org/10.1063/1.118664
  3. U. Mitschke and P. Bauerle, J. Mater. Chem. 10, 1471 (2000). https://doi.org/10.1039/a908713c
  4. Y. Sun and S. R. Forrest, Appl. Phys. Lett. 91, 263503 (2002).
  5. Z. Shen, P. E. Burrows, V. Bulovic, S. R. Forrest, and M. E. Thompson, Science 276, 2009 (1997). https://doi.org/10.1126/science.276.5321.2009
  6. S. Reineke, F. Lindner, G. Schwartz, N. Seidler, K. Walzer, B. Lüssem, and K. Leo, Nature 459, 234 (2009). https://doi.org/10.1038/nature08003
  7. H.-I. Baek and C. H. Lee, J. Appl. Phys. 103 (12), 124504, (2008) https://doi.org/10.1063/1.2939573
  8. R. Galbadrakh, H. S. Bang, H. I. Baek, and C. H. Lee, J. Information Display 9 (3), 23 (2008) https://doi.org/10.1080/15980316.2008.9652059
  9. C. Adachi, M. A. Baldo, M. E. Thompson, and S. R. Forrest, J. Appl. Phys. 90, 5048 (2001). https://doi.org/10.1063/1.1409582
  10. S.-O. Jeon, K. S. Yook, C. W. Joo, J. Y. Lee, K.-Y. Ko, J.-Y. Park, and Y. G. Baek, Appl. Phys. Lett. 93, 063306 (2008) https://doi.org/10.1063/1.2969786
  11. Y. Kawamura, K. Goushi, J. Brooks, J. J. Brown, H. Sasabe, and C. Adachi, Appl. Phys. Lett. 86, 071104 (2005). https://doi.org/10.1063/1.1862777
  12. Y.-Y. Lyu, J. Kwak, O. Kwon, S.-H. Lee, D. Kim, C. H. Lee, and K. Char, Adv. Mater. 20, 2720 (2008). https://doi.org/10.1002/adma.200602885
  13. K. Okumoto, H. Kanno, Y. Hamaa, H. Takahashi, and K. Shibata, Appl. Phys. Lett. 89, 063504 (2006). https://doi.org/10.1063/1.2266452
  14. L. Ying, Y. Xu, W. Yang, L. Wang, H. Wu, and Y. Cao, Org. Elect. 10, 42 (2009). https://doi.org/10.1016/j.orgel.2008.10.001
  15. X.-M. Yu, H.-S. Kwok, W.-Y. Wong, and G.-J. Zhou, Chem. Mater. 18, 5097 (2006). https://doi.org/10.1021/cm061030p
  16. J. X. Sun, X. L. Zhu, H. J. Peng, M. Wong, and H.S. Kwok, Org. Elect. 8, 305 (2007). https://doi.org/10.1016/j.orgel.2006.11.006
  17. P. Freitag, S. Reineke, S. Olthof, M. Furno, B. Lussem, and K. Leo, Org. Elect. 11, 1676 (2010). https://doi.org/10.1016/j.orgel.2010.07.017
  18. Commission Internationale de l'Eclairage (CIE) publication 13.3, Method of Measuring and Specifying Color Rendering Properties of Light Sources (1995).