• Title/Summary/Keyword: wettability property

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A Study on the Improvement of Interfacial Properties of Epoxy Composites (에폭시 복합재료의 계면특성 향상에 관한 연구)

  • Lim, K.B.;Lee, S.H.;You, D.H.;Yuk, J.H.;Hwang, M.H.;Kim, Y.S.;Lee, D.C.
    • Proceedings of the KIEE Conference
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    • 2002.11a
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    • pp.124-126
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    • 2002
  • In this study, composite materials were put to dry interfacial treatment by use of plasma technology. It has been presented that the optimum parameters for the best wettability of the samples at the time of generation of plasma were oxygen atmosphere, 0.1 torr of system pressure, 100 W of discharge power, and 3 minutes of discharge time. Also, the surface resistance rate, dielectric property and tensile strength were improved.

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Compatibility of POSS Composites with Silicone Monomers and Application to Contact Lenses Material

  • Lee, Min-Jae;Lee, Kyungmun;Sung, A-Young
    • Journal of the Korean Chemical Society
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    • v.64 no.6
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    • pp.354-359
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    • 2020
  • This research was conducted to analyze the compatibility of used monomers and produce the high functional contact lens material containing silicone monomers. Silicone monomer (Sil-OH), Trimethylsilylmethacrylate (TSMA) were used as additives for the basic combination of Polyhedral Oligomeric Silsesquioxane (POSS), methyl methacrylate (MMA) and methyl acrylate (MA). And also, the materials were copolymerized with ethylene glycol dimethacrylate (EGDMA) as the cross-linking agent, AIBN (thermal polymerization initiator) as the initiator. It is judged that the fabricated lenses of all combinations are optically excellent and thus used monomers have good compatibility. Measurement of the optical and physical characteristics of the manufactured hydrophilic lens material were varied in each case. Especially TSMA with POSS increases the oxygen permeability and Sil-OH with POSS increases the wettability by the addition of Sil-OH. These materials were considered to have compatibility each other, so it can be used in functional contact lens material.

Improvement of Interfacial Adhesion of Plasma Treated Single Carbon Fiber Reinforced CNT-Phenolic Nanocomposites by Electrical Resistance Measurement and Wettability (젖음성 및 전기저항 측정을 이용한 플라즈마 처리된 단일 탄소섬유 강화 탄소나노튜브-페놀수지 나노복합재료의 계면접착력 향상)

  • Wang, Zuo-Jia;Kwon, Dong-Jun;Gu, Ga-Young;Park, Jong-Kyoo;Lee, Woo-Il;Park, Joung-Man
    • Journal of Adhesion and Interface
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    • v.12 no.3
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    • pp.88-93
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    • 2011
  • Optimal dispersion and fabrication conditions of carbon nanotube (CNT) embedded in phenolic resin were determined by electrical resistance measurement; and interfacial property was investigated between plasma treated carbon fiber and CNT-phenolic composites by electro-micromechanical techniques. Wettability of carbon fiber was improved significantly after plasma treatment. Surface energies of carbon fiber and CNT-phenolic nanocomposites were measured using Wilhelmy plate technique. Since surface activation of carbon fiber, the advancing contact angle decreased from $65^{\circ}$ to $28^{\circ}$ after plasma treatment. It was consistent with static contact angle results of carbon fiber. Work of adhesion between plasma treated carbon fiber and CNT-phenolic nanocomposites was higher than that without modification. The interfacial shear strength (IFSS) and apparent modulus also increased with plasma treatment of carbon fiber.

Enhancement of Electrochemical and Mechanical Properties of 3D Graphene Nanostructures by Dopamine-coating (도파민 코팅을 이용한 3차원 그래핀 나노 구조체의 전기화학적/기계적 특성 향상 연구)

  • Lee, Guk Hwan;Luan, Van Hoang;Han, Jong Hun;Kang, Hyun Wook;Lee, Wonoh
    • Composites Research
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    • v.32 no.6
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    • pp.388-394
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    • 2019
  • Inherited the excellent electrical and mechanical properties based on the low dimensional structure of graphene, three-dimensional graphene nanostructures have gathered great attention as electrochemical energy storage electrodes owing to their high porosity and large specific surface area. Also, having the catecholamine structure, dopamine has been regarded as a multifunctional material to possess high affinity to various organic/inorganic materials and to modify a hydrophobic surface to a hydrophilic one. In this work, through coating dopamine on the three-dimensional graphene nanostructure, we tried to increase the specific capacitance by enhancing the wettability with electrolyte and to improve the mechanical compressive property by strengthening the nano-architecture. As a result, the dopamine-coated nanostructure exhibited significant improvement on the specific capacitance (51.5% increase) and compressive stress (59.6% increase).

Fundamental Study for Developing Silicone Rubber Impression Material (실리콘 고무인상재 개발을 위한 기초연구)

  • Oh, Young-Il;Han, Kyung-A;Kim, Kyung-Nam;Cho, Lee-Ra;Chung, Kyung-Ho
    • Elastomers and Composites
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    • v.35 no.1
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    • pp.19-28
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    • 2000
  • The fundamental study of additional silicone impression material has been performed by comparing the other import products. In order to estimate the possibility of usage of the impression material developed in this study, the several techniques such as IR, EDX, DSC, TGA, rubber rheometer, and contact angle measurement were used. According to the results, there were not any product satisfying all properties required in the impression material. The impression material developed in this study showed best mechanical properties among the all impression materials. However. the wetting property should be studied more by an introduction of a hydrophilic surfactant or modification of a base polymer.

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Photocatalyst Surface Properties of the Oxide Thin Films According to the Plasma Etching Process (플라즈마 에칭공정에 따른 산화물 박막의 광촉매 표면 특성)

  • Lee, Chang-Hyun;Seo, Sung-Bo;Oh, Ji-Yong;Jin, Ik-Hyeon;Sohn, Sun-Young;Kim, Hwa-Min
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.28 no.5
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    • pp.300-305
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    • 2015
  • $WO_3$, $SiO_2$, and $TiO_2$ films with hydrophilic property are deposited by rf-magnetron sputtering. Their wettability is strongly depends on the presence or absence of the oxygen plasma etching on the glass substrates. The $TiO_2$ film of 50 nm-thick on the plasma etched glass shows a water contact angle (WCA) below $5^{\circ}$ which means a super-hydrophilic surface. However, WCA values are gradually degraded when the films are exposed under atmosphere, especially $WO_3$. In order to improve hydrophilic property, the degraded films can be again recovered by UV illumination for 10 sec using UV-light and the $TiO_2$ film shows a super-hydrophilic surface about $3^{\circ}$.

Bio-Inspired Surface Modification of 3-Dimensional Polycaprolactone Scaffold for Enhanced Cellular Behaviors

  • Jo, Seon-Ae;Gang, Seong-Min;Park, Su-A;Lee, Hae-Shin
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.202-202
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    • 2011
  • The research of 3-dimensional (3-D) scaffold for tissue engineering has been widely investigated as the importance of the 3-D scaffold increased. 3-D scaffold is needed to support for cells to proliferate and maintain their biological functions. Furthermore, its architecture defines the shape of the new bone and cartilage growth. Polycaprolactone (PCL) has been one of the most promising materials for fabricating 3-D scaffold owing to its excellent mechanical property and biocompatibility. However, there are practical problems for using it, in vitro and in vivo; extracellular matrix components and nutrients cannot penetrate into the inner space of scaffold, due to its hydrophobic property, and thus cell seeding and attachment onto the inner surface remain as a challenge. Thus, the surface modification strategy of 3-D PCL scaffold is prerequisite for successful tissue engineering. Herein, we utilized a mussel-inspired approach for surface modification of 3-D PCL scaffold. Modification of 3-D PCL scaffolds was carried out by simple immersion of scaffolds into the dopamine solution and stimulated body fluid, and as a result, hydroxyapatite-immobilized 3-D PCL scaffolds were obtained. After surface modification, the wettability of 3-D PCL scaffold was considerably changed, and infiltration of the pre-osteoblastic cells into the 3-D scaffold followed by the attachment onto the surface was successfully achieved.

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Micro-patterning for Biomimetic Functionalization of Surface

  • Jeon, Deok-Jin;Lee, Jun-Yeong;Yeo, Jong-Seok
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.272-273
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    • 2013
  • Some living thingsuse micro- or nano- structures for living in nature. Scientists and engineers made efforts to mimic them, and they succeeded in making new types of applications. They used 'Namib desert beetle' to self-filling device by moisture harvesting and 'lotus leaf' to self-cleaning device by water repelling. 'Namib desert beetle' and lotus leaf have micro-patterns on their surface, which consists of hydrophobic or hydrophilic materials [1]. Moreover, micro-patterns on the surface make self-filling or self-cleaning property enhanced because of the surface roughness. Surface roughness enhances wettability [2]. Micro-pattern is a significant factor to make the surface be functional, so we want to make new types of functional surface by micro-patterning. In this work,we make several functional micro-patterns (radial, line, and dot arrays) using maskless lithography and analyze the characteristics of each micro-pattern. In order to analyze and understand surface characteristics, micro-patterns with varying sizes are investigated. All experiments are proceeded on mr-DWL5 photo resists coated on silicon wafers in same condition. All the experiments have demonstrated good performances about hydrophobic or hydrophilic property corresponding to their material and structural combinations. In radial micro-pattern, although the surface is flat, water drops on hydrophilic radial pattern can be convergent to a middle point and water drops on hydrophobic radial pattern can be divergent from the middle point. In line array micro-pattern, water drops can roll off along only one direction in parallel with the line arrays. Such phenomena might be mainly caused by the local change of surface roughness. From these results, controlling the movement and direction of water drops is made feasible without introducing a slope, which can potentially be used for new types of applications.

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Interfacial Durability and Acoustic Properties of Transparent xGnP/PVDF/xGnP Graphite Composites Film for Acoustic Actuator (음향 작동기를 위한 투명한 xGnP/PVDF/xGnP 그래핀 복합재료 필름의 계면 내구성 및 음향 특성)

  • Gu, Ga-Young;Wang, Zuo-Jia;Kwon, Dong-Jun;Park, Joung-Man
    • Composites Research
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    • v.25 no.3
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    • pp.70-75
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    • 2012
  • Interfacial durability and electrical properties of CNT, ITO or xGnP coated PVDF nanocomposites were investigated for acoustic actuator applications. The xGnP coated PVDF nanocomposite exhibited better electrical conductivity than CNT and ITO case due to the unique electrical property of xGnP, and this nanocomposite also showed good sound characteristics. Interfacial adhesion durability between either neat CNT or plasma treated CNT and plasma treated PVDF were measured by static contact angle, surface energy, work of adhesion, and spreading coefficient tests. The optimum acoustic actuation performance of xGnP coated PVDF nanocomposite was measured using sound level meter with changing radius of curvature and coating conditions. As compared to CNT and ITO, the xGnP was known as more appropriate acoustic actuator due to the characteristic electrical property. It is the most appropriate condition when the radius of curvature is 15 degree. Although sound characteristics were different with various coating thicknesses, it is possible to manufacture transparent actuator with good sound quality.

A Study on the Silver Nanoparticle Deposition for Optical Amplification (광 증폭용 플라즈모닉 나노구조 제작을 위한 은 나노입자 증착 연구)

  • Kang, J.S.;Kim, J.H.;Jeong, M.Y.
    • Journal of the Microelectronics and Packaging Society
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    • v.25 no.1
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    • pp.11-15
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    • 2018
  • In this study, we deposited silver nanoparticles on the nanocone array structure which was fabricated by the UV nanoimprint process for optical signal amplification. The deposition of the silver nanoparticles was based on the evaporation behavior of the solution droplet according to wettability of surface and the deposition pattern changed from the center of the droplet to the edge depending on the difference of thermal energy. The optical property of silver nanoparticles that were deposited on imprinted nanohole patterns was simulated by the Finite difference time domain (FDTD) analysis method, and it was confirmed that energy was concentrated around the silver nanoparticle of the finally fabricated structure.