• Title/Summary/Keyword: water-soluble dye

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Binding of Methylene Blue to two types of water soluble polymer and its removal by polyelectrolyte enhanced ultrafiltration

  • Mansour, Nadia Cheickh;Ouni, Hedia;Hafiane, Amor
    • Membrane and Water Treatment
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    • v.9 no.2
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    • pp.87-94
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    • 2018
  • The interactions of water soluble polymers with dye are studied by ultrafiltration using a molecular weight cut off of 10 KDa regenerated cellulose ultrafiltration membrane. Two water-soluble polymers, namely Poly (Sodium-4 Styrenesulfonate) (PSS) and Poly (Vinyl Alcohol) (PVA) were selected for this study. The effects of process parameters, such as, polyelectrolyte concentrations, transmembrane pressure, ionic strength and pH of solution on dye retention and permeation flux were examined. PSS enhanced ultrafiltration achieved dye retention as high as 99% as a result of complexation between polyanion containing aromatic groups and cationic dye. This result was confirmed by the red shift. The retention of dye decreases as the salt concentration increases, a high retention was obtained at pH above 4. However, in case of PVA, relatively low retention (50%) was observed. Ionic strength and pH has no significant effect on the removal of MB. The permeate flux depended slightly on polyelectrolytes concentrations, transmembrane pressure, salt concentration and pH.

Dyeing Properties and Functionality of Hot-water Extract from Juniperus chinensis Heartwood (향나무 심재 열수추출물의 염색성과 기능성)

  • Nam, Ki Yeon;Lee, Jung Soon
    • Textile Coloration and Finishing
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    • v.25 no.3
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    • pp.181-193
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    • 2013
  • The purpose of this study is to investigate dyeing properties and functionality of cotton and silk fabrics dyed with hot-water extract from Juniperus chinensis heartwood. Water-soluble dye of Juniperus chinensis heartwood extracted with distilled water was expressed YR color series. Dye uptake of cotton continued to increase according to the increase of the dye concentration. Its variation trends were shown to be similar to the isothermal absorption curve of the Freundlich. Dye uptake of silk was better than cotton, increased depending on increasing concentration of the dye, dyeing time and temperature. Its variation trends were shown to be similar to the isothermal absorption curve of the Langmuir. As the pH increased, the dye uptake of fabrics reduced and showed increased on red tinge. Colors of the dyed fabrics were various, depending on dye concentration and the mordant type and mordant concentration. Washing fastness, light fastness and perspiration fastness were not good. However, rubbing and dry cleaning fastness showed relatively good grade. Dyed fabrics of ultraviolet-cut ability and deodorant ability were improved. And dyed fabrics showed antimicrobial abilities of 99.9% against Staphylococcus aureus.

Effects of the Addition of Water-soluble Polymers on Silk Dyeing (수용성 고분자를 이용한 견의 염색)

  • 황은경;김문식;이동수
    • Journal of Sericultural and Entomological Science
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    • v.40 no.2
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    • pp.136-142
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    • 1998
  • The low-pollution dyeing condition and dyeing method suitable for the silk fiber were investigated. Instead of surfactants, water-soluble polymers and electrolytes were added as auxiliary agents in the new process of dyeing. By the new method, the level dyeing and sufficient exhaustion were achieved. The K/S values of silk fabrics were little different among electrolytes added in the dye-bath.

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A Study on the Decomposition of Water Soluble Dyes by UV/TiO2 (UV/TiO2에 의한 수용성 염료의 분해에 관한 연구)

  • 정갑섭
    • Journal of Environmental Science International
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    • v.12 no.3
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    • pp.319-324
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    • 2003
  • The characteristics of photocatalytic decomposition of dye waste water by titanium dioxide was studied in a batch reactor under constant strength of ultra-violet ray. The decomposition rate of methyl orange by TiO$_2$ was pseudo-first order, anatase type TiO$_2$ was more effective than rutile type below the dosage of 5g. The decomposition rate was increased with decreasing initial pH, increasing reaction temperature and oxidant concentration. The decomposition rate of water soluble dyes was decreased in order of rhodamine B>eosin Y>methyl orange.

Dyeing of Silk and Ramie Fabric with Natural Dye(1) - The traditional dyeing method of safflower - (천연 염료에 의한 견 및 모시 염색(1) - 전통 방법에 의한 홍화 염색 -)

  • 정인모;우순옥
    • Journal of Sericultural and Entomological Science
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    • v.37 no.2
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    • pp.161-166
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    • 1995
  • Safflower is natural red dye largely used for dyeing on protein and cellulose fabric. It contains safflower yellow and carthamin red. Safflower yellow is water-soluble dye, while carthamin red is soluble in alkaline condition. Therefore the former was extracted by cold water. Cartamon obtained by adding acidic solution to carthamin red shows the original hue of safflower. In this study, the condition of extraction with bean stem ash solution and dyeing behavior of carthamon in safflower were examined by using the traditional dyeing method. The relationship between the dye-uptake(K/S) of silk and ramie fabric and the various extractions and dyeing conditions was investigated.

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Dyeing Property and Functionality of Silk Fabrics Dyed with Rhododedron brachycarpum Extracts (만병초 추출물에 의한 견직물의 염색성 및 기능성)

  • Kim, Sangyool
    • Journal of Fashion Business
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    • v.23 no.3
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    • pp.23-34
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    • 2019
  • The aim of this study is to explore the possibility utilizing Rhododedron brachycarpum as a new natural dye resource. It was dyed in silk fabric according to different dyeing conditions such as dye concentration, dye bath temperature, dyeing time and dye bath pH. The effect of the mordanting conditions were estimated as dyeability and color changes. Additionally, the colorfastness, antibacterial property, ultraviolet protection properties of the dyed and mordanted silk fabrics were examined. The water-soluble dye of Rhododedron brachycarpum extracted with distilled water was expressed as Yellow Red color. The dye-abilities of silk generally increased depending on the increasing values of dye concentration, dye bath temperature and dyeing duration. The highest K/S values were obtained at a dye concentration of 100% (v/v), a dye bath temperature of $90^{\circ}C$, a dyeing duration 120 minutes and a dyeing of pH 2. The light fastness of dyed and Cu mordanted silk fabrics were found to be 4 grade while Al, Fe mordanted silk fabrics were found to be 2~3 grade. The dry cleaning and rubbing fastness were excellent or good. The fade of washing fastness was not good, however, the stain of washing fastness was excellent. The dyed and Al, Cu mordanted silk fabrics indicated 99.9% reduction rate. The dyed and the mordanted fabrics showed very good ultraviolet protection factors.

Syntheses of the derivatives of chitin and chitosan, and their physicochemical properties (키틴 및 키토산 유도체의 합성과 그 물리화학적 특성)

  • Byun, Hee-Guk;Kang, Ok-Ju;Kim, Se-Kwon
    • Applied Biological Chemistry
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    • v.35 no.4
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    • pp.265-271
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    • 1992
  • Derivatives (microcrystalline chitin, carboxymethylchitin, acetylchitin, N-acetylchitosan, ethylchitosan and chitosansulfate) of chitin and chitosan were synthesized, and the physicochemical properties of the derivatives were compared with those of chitin and chitosan. Carboxymethylchitin was soluble in water or acetic acid, whereas chitosan and ethylchitosan were soluble in acetic acid alone. The water binding capacity of N-acetylchitosan was two fold higher than that of chitin. Lipid binding capacity of carboxymethylchitin was the highest, holding 1800%, and that of chitin was the lowest, holding 511% among the derivatives. Carboxymethylchitin among the derivatives showed the highest emulsifying capacity, however chitin and chitosan didn't produce emulsions. Dye binding capacity of acetylchitin was the highest, holding 0.93 mg dye/g sample (Blue R-250) and 0.96 mg dye/g sample (Red No. 2). It was concluded that carboxymethylchitin is a good emulsifier and N-acetylchitosan, chitosansulfate and chitosan are suitable for use as dye absorbents.

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Studies on Transfer Printing of Cotton and Polyester/Cotton Blended Fabrics Treated with Water Soluble Polyurethane Resin (수용성 폴리우레탄 수지 처리된 면 및 폴리에스테르/면 혼방직물의 전사날염에 관한 연구)

  • 황종호;전병익
    • Textile Coloration and Finishing
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    • v.11 no.5
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    • pp.13-21
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    • 1999
  • In this study, selected cotton fabrics and polyester/cotton(P/C) blended fabrics are treated with a soluble polyurethane(SPU) and then, printed by heat transfer to determine the effect of SPU treatment on dye uptake of the samples. The results obtained are as follows: 1) In heat transfer, dye-uptake gets higher in Vopotion to temperature and time. The optimum printing temperature and printing time of C.I. Disperse Orange 3 and C.I. Disperse Violet 1 are $200^\circ{C}$ and 50sec. 2) Dye-uptake gets higher according to SPU concentration ; both cotton and P/C fabrics show the highest at $100g/\ell$. 3) In color, as temperature, time and SPU concentration increase, P/C fabrics show more yellowish orange color than cotton fabrics in case of C.I. Disperse Orange 3 and P/C fabrics show more reddish violet color than cotton fabrics in case of C.I. Disperse Violet 1. 4) All fastness of cotton and P/C fabrics treated with SPU are good, but color fastness to washing and water of cotton fabrics treated with SPU are not good.

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Bioprocess of Triphenylmethane Dyes Decolorization by Pleurotus ostreatus BP Under Solid-State Cultivation

  • Yan, Keliang;Wang, Hongxun;Zhang, Xiaoyu;Yu, Hongbo
    • Journal of Microbiology and Biotechnology
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    • v.19 no.11
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    • pp.1421-1430
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    • 2009
  • With an aim to evaluate dye decolorization by white rot fungus on natural living conditions, reproducing by solid-state fermentation, the process of triphenylmethane dyes decolorization using the white rot fungus P. ostreatus BP, cultivated on rice straw solid-state medium, has been demonstrated. Three typical dyes, including malachite green, bromophenol blue, and crystal violet, were almost completely decolorized by the fungus after 9 days of incubation. During the process of dye decolorization, the activities of enzyme secreted by the fungus, and the contents of soluble components, such as phenolic compounds, protein, and sugar, changed regularly. The fungus could produce ligninolytic, cellulolytic, and hemicellulolytic enzymes and laccase was the most dominant enzyme in solid-state medium. Laccase, laccase isoenzyme, and the laccase mediator could explain the decolorization of malachite green, bromophenol blue, and crystal violet by the fungus in solid-state medium, respectively. It is worth noting that the presence of the water-soluble phenolic compounds could stimulate the growth of fungus, enhance the production of laccase, and accelerate dye decolorization.

Dyeing of Cotton Fabric with Natural Dye (I) ―Safflower― (천연염료에 의한 면섬유 염색 (I) ―홍 화―)

  • Nam, Sung Woo;Chung, In Mo;Kim, In Hoi
    • Textile Coloration and Finishing
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    • v.7 no.2
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    • pp.47-54
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    • 1995
  • Safflower is natural red dye largely used for dyeing on cotton. It contains yellowish safflower yellow and reddish carthamin, whose constitution is known. Safflower yellow is water-soluble dye and carthamin is solved in alkaline condition. Carthamon obtained by adding acidic solution to a carthamin shows the original hue of safflower. In present study, the dyeing behavior of natural dye known as safflower are examined in an aqueous acidic medium by use of the different dyeing methods such as traditional, modern and purifide-powder method. The relationship between the dye-uptake of cotton fabric investigated by the three methods and the various dyeing conditions is discussed.

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