Browse > Article
http://dx.doi.org/10.12989/mwt.2018.9.2.087

Binding of Methylene Blue to two types of water soluble polymer and its removal by polyelectrolyte enhanced ultrafiltration  

Mansour, Nadia Cheickh (Wastewater Treatment Laboratory, Water Research and Technologies Center)
Ouni, Hedia (Department of Chemistry, Faculty of Science at Yanbu, Taibah University Yanbu, Medina Mounawara)
Hafiane, Amor (Wastewater Treatment Laboratory, Water Research and Technologies Center)
Publication Information
Membrane and Water Treatment / v.9, no.2, 2018 , pp. 87-94 More about this Journal
Abstract
The interactions of water soluble polymers with dye are studied by ultrafiltration using a molecular weight cut off of 10 KDa regenerated cellulose ultrafiltration membrane. Two water-soluble polymers, namely Poly (Sodium-4 Styrenesulfonate) (PSS) and Poly (Vinyl Alcohol) (PVA) were selected for this study. The effects of process parameters, such as, polyelectrolyte concentrations, transmembrane pressure, ionic strength and pH of solution on dye retention and permeation flux were examined. PSS enhanced ultrafiltration achieved dye retention as high as 99% as a result of complexation between polyanion containing aromatic groups and cationic dye. This result was confirmed by the red shift. The retention of dye decreases as the salt concentration increases, a high retention was obtained at pH above 4. However, in case of PVA, relatively low retention (50%) was observed. Ionic strength and pH has no significant effect on the removal of MB. The permeate flux depended slightly on polyelectrolytes concentrations, transmembrane pressure, salt concentration and pH.
Keywords
dye; poly(Sodium-4 Styrenesulfonate) (PSS); poly(Vinyl Alcohol) (PVA); dye retention; polymer enhanced ultrafiltration;
Citations & Related Records
Times Cited By KSCI : 1  (Citation Analysis)
연도 인용수 순위
1 Dragan, S., Dragan, D., Cristea, M., Airine., A. and Ghimici, L. (1999), "Polyelectrolytes complexes II specific aspects of the formation of polycation/dye/polyanion complexes", Polym. Sci. A, 37(4), 409   DOI
2 Fradj, A.B., Ben Hamouda, S., Ouni, H., Lafi, R., Gaza, L. and Hafiane, A. (2014), "Removal of methylene blue from aqueous solutions by poly(acrylic acid) and poly(ammonium-acrylate) assisted ultrafiltration", Sep. Purif. Technol., 133, 76-81.   DOI
3 Girgis, E., Adel, D., Tharwat, C., Attallah, A. and Rao, K.V. (2015), "Cobalt ferrite nanotubes and porous nanorods of dye removal", Adv. Nano Res., 7(6), 111-121.
4 Hessel, C., Allegre, C., Maissers, M., Charbit, F. and Moulin, P. (2007), "Guidelines and legislation for dye house effluents", J. Environ. Manage., 83(2), 171-180.   DOI
5 Ingole, P.G., Sawat, S.Y., Ingole, N.P., Pawar, R.R., Bajaj, H.C., Singh, K., Cho, M.H. and Lee, H.K. (2016), "Preparation of activated carbon incorporated polysulfone membranes for dye separation", Membr. Water Treat., 7(6) 477- 493.   DOI
6 Iqbal, M. and Ashiq, M., (2007), "Adsorption of dyes from aqueous solutions on activated charcoal", J. Hazard. Mater., 139(1), 57-66.   DOI
7 Kadiogln, S.I., Yilmaz, L., Aydogan, N. and Ozbelge, H.O. (2010), "Removal of heavy metals from multicomponent metal mixtures by polymer enhanced ultrafiltration: Effects of pH, ionic strength and conformational changes in polymer structure", Sep. Sci. Technol., 45(10), 1363-1373.   DOI
8 Ku, Y., Lee, P. and Wang, W. (2005), "Removal of acidic dyestuffs in aqueous solution by nanofiltration", J. Membr. Sci., 250(1-2), 159-165.   DOI
9 Lin, S.H. and Peng, C.F. (1996), "Continuous treatment of textile wastewater by combined coagulation, electrochemical oxidation and activated sludge", Water Res., 30(3), 587-592.   DOI
10 Mohan, N., Balusubramamiau, N. and Ahmed Basha, C. (2007), "Electrochemical oxidation of textile wastewater and its reuse", J. Hazard. Mater., 147(1-2), 644-651.   DOI
11 Mondal, S., Ouni, H., Dhahbi, M. and De, S. (2012), "Kinetic modeling for dye removal using polyelectrolyte enhanced ultrafiltration", J. Hazard. Mater., 229, 381-389.
12 Moreira, R.F.P.M., Peruch, M.G. and Kuhnen, N.C. (1998), "Adsorption of textile dyes on alumina: Equilibrium studies and contact time", Braz. J. Chem. Eng., 15(1).
13 Morena Villoslada, I., Torres, C., Gonzalez, F., Shibue, T. and Nishide, H. (2009), "Binding of methylene blue to polyelectrolytes containing sulfonate groups", Macromol. Chem. Phys., 210(13-14), 1167-1175.   DOI
14 Nidheesh, P.V., Gandhimathi, R. and Ramesh, S.T. (2013), "Degradation of dyes from aqueous solution by Fenton processes: A review", Environ. Sci. Pollut. Res., 20(4), 2099-2132.   DOI
15 Ouni, H. and Dhahbi, M. (2010b), "Spectrometric study of crystal violet in presence of polyacrylic acid and polyethylenimine and its removal by polyelectrolyte enhanced ultrafiltration", Sep. Purif. Technol., 72(3), 340-346.   DOI
16 Ouni, H. and Dhahbi, M. (2010a), "Removal of dyes from wastewater using polyelectrolyte enhanced ultrafiltration (PEUF)", Desalin. Water Treat., 22(1-3), 355-362.   DOI
17 Safarik, I., Ptackora, L. and Saforikova, M. (2002), "Adsorption of dyes on magnetically labeled baker's yeast cell", Eur. Cell. Mater., 3(2), 52-55.
18 Purkait, M.K., Das Guptu, S. and Pe, S. (2004), "Resistance enhanced in series model for micellar VF of eosin dye", J. Colloid Interfac. Sci., 270(2), 496-506.   DOI
19 Majewska-Nowak, K. (2008), "The effect of a polyelectrolyte on the efficiency of dye-surfactant solution treatment by ultrafiltration", Desalination, 221(1-3), 395-404.   DOI
20 Quadrifoglio, F. and Grescenzi, V. (1971), "The interaction of methyl orange and other azo dyes with polyelectrolytes and with colloidal electrolytes in dilute aqueous solution", J. Colloid Interfac. Sci., 35(3), 447-459.   DOI
21 Shen, J.J., Rena, L.L. and Zhuang, Y.Y. (2006), "Interaction between anionic dyes and cationic floculant (PAM-DMC) in synthetic solutions", J. Hazard. Mater., 136(3), 809-815.   DOI
22 Srisukphum, T., Cheimchaisri, C., Urase, T. and Yamamoto, K. (2009), "Experimentation and modeling of foulant interaction and reverse osmosis membrane fouling during textile wastewater reclamation", Sep. Purif. Technol., 68(1), 37-40   DOI
23 Tan, X., Kyaw, N.N., Teo, W.K. and Li, K. (2006), "Decolorization of dye containing aqueous solutions by the polyelectrolyte enhanced ultrafiltration (PEUF) process using a hollow fiber membrane module", Sep. Purif. Technol., 52(1), 110-116.   DOI
24 Zaghbani, N., Hafiane, A. and Dhahbi, M. (2008), "Removal of Safranin T from wastewater using micellar enhanced ultrafiltration", Desalination, 222(1-3), 348-356.   DOI
25 Torrades, F. and Garcia-Montano, J. (2014), "Using central composite experimental design to optimize the degradation of real dye wastewater by Fenton and photo-Fenton reactions", Dyes Pigments, 100, 184-189.   DOI
26 Yao, H., Isohashi, T. and Kimura, K. (2007), "Electrolyte induced mesoscopic aggregation of thiacarbon cyanine dye in aqueous: counter ion size specificity", J. Phys. Chem B, 111(25), 7176-7183   DOI
27 Zaghbani, N., Hafiane, A. and Dhahbi, M. (2007), "Separation of methylene blue from aqueous solution by micellar enhanced ultrafiltration", Sep. Purif. Technol., 55(1), 117-124.   DOI
28 Antonov, L., Gergov, G., Petrov, V., Kubista, M. and Nygrem, J. (1999), "UV-Vis spectroscopic and chemometric study on the aggregation of ionic dyes in water", Talanta, 49(1), 99-106.   DOI
29 Abdullah, F., Rauf, M.A. and Ashraf, S.S. (2007), "Photolytic oxidation of Safranin O with $H_2O_2$", Dyes Pigments, 72(3), 349-352.   DOI
30 Albanis, T.A., Hela, D.G., Sakellarides, T.M. and Danis, T.G. (2000), "Removal of dyes from aqueous solutions by adsorption on mixtures of fly ash and soil in batch and column techniques", Global Nest J., 2(3), 237-244.
31 Chakraborty, S., Dasgupta, J., Farooq, U., Sikder, J., Drioli, E. and Curcio, S. (2014), "Experimental analysis modeling and optimization of chromium (VI) removal from aqueous solutions by polymer enhanced ultrafiltration", Membr. Sci., 456, 139-154.   DOI
32 Dasgupta, J., Sikder, J., Mandal, T. and Adhikari, U. (2015), "Reactive red 120 retention through ultrafiltration enhanced by synthetic and natural polyelectrolytes", J. Hazard. Mater., 299, 192-205.   DOI