• Title/Summary/Keyword: water vapor absorption

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A Study on the Fundamental Properties of Ultra Rapid Hardening Mortar using Coal-Ash (잔골재 대체재로서 석탄회를 이용한 초속경 보수모르타르의 기초적 특성에 관한 연구)

  • Lee, Gun-Cheol;Oh, Dong-Uk;Kim, Young-Geun;Cho, Chung-Ki
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.6 no.1
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    • pp.128-135
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    • 2011
  • In this study, in order to develop ultra rapid hardening mortar(URHM) for tunnel repairs using bottom ash of low recycle ratio and Admixture as Eco concept, fundamental properties of URHM on temperature condition of construction field were performed. Test result, URHM of three types for fluidity and setting time were as in the following : B > C > A. Those for low temperatures were later than the standard condition. Compressive, bending and bond strength were similar with three types as follow. In compressive strength, initial strength of the low were smaller than the standard but the low in the long-term were similar with the standard. On the contrary to this, bending strength were similar in initial strength but the low in the long-term were smaller than the standard. The low in bond strength was average 35% less than the standard. Length changes was as in the following : A > C > B. the low is two times much as the standard but the case using blast furnace slag particles noticeably reduced length changes. Water absorption coefficient and water vapor resistance were as in the following : C > A > B. In case of URHM added bottom ash, water absorption coefficient and water vapor resistance were increased because bottom ash is porous material.

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A Numerical study on the Moisture Transport of Concrete Tunnel Linings with the Sprayable Waterproofing Membrane (뿜칠 방수 멤브레인이 시공된 터널 라이닝의 수분이동에 관한 수치해석 연구)

  • Lee, Chulho;Choi, Soon-Wook;Kang, Tae-Ho;Chang, Soo-Ho
    • Tunnel and Underground Space
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    • v.26 no.3
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    • pp.212-219
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    • 2016
  • The sprayable waterproofing membrane is installed between shotcrete to provide crack bridging and hence prevent flow of liquid water as a waterproofing system. Because of its material characteristics, the sprayable membrane can be constructed at more complex structure than sheet membrane. The main component of the sprayable waterproofing membrane is a polymer-based material, therefore, moisture can migrate through sprayable waterproofing membrane materials by capillary and vapor diffusion mechanisms. The moisture transport mechanisms can have an influence on the degree of saturation and may influence the pore pressure and risk of freeze-thaw damage on concrete linings and membrane. In this study, long-term hygrothermal behavior was simulated with considering moisture transport and long-term effects on saturation of tunnel linings. From the simulation, due to water absorption and vapor transport properties of sprayable membrane, change of relative humidity and water content in tunnel lining can be evaluated.

THE EXTRACTION OF THE THERMAL RADIATION ASSOCIATED WITH GREENHOUSE GASES FROM AIRS MEASUREMENTS

  • Kwon, Eun-Han;Kim, Yong-Seung;Lee, Sun-Gu
    • Proceedings of the KSRS Conference
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    • v.1
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    • pp.301-304
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    • 2006
  • For the purpose of investigating the contributions of various gases to climate change, the thermal radiation associated with greenhouse gases are extracted from AIRS (Atmospheric Infrared Sounder) infrared radiances over the tropical pacific region. AIRS instrument which was launched on the EOS-Aqua satellite in May 2002 covers the spectral range from 650 cm-1 to 2700 cm-1 with a spectral resolution of between 0.4 cm-1 and 1 cm-1. In order to extract the thermal radiation absorbed by individual gases, the interfering background radiances at the top of the atmosphere are simulated using the radiative transfer code MODTRAN (MODerate spectral resolution atmospheric TRANsmittance). The simulations incorporated the temperature and water vapor profiles taken from NCEP (National Centers for Environmental Prediction) reanalyses. The differences between the simulated background radiance and AIRS-measured radiance result in the absorption of upward longwave radiation by atmospheric gases (i.e. greenhouse effect). The extracted absorption bands of individual gases will allow us to quantify the radiative forcing of individual greenhouse gases and thus those data will be useful for climate change studies and for the validation of radiative transfer codes used in general circulation models.

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Reliability Evaluation Through Moisture Sorption Characterization of Electronic Packaging Materials (전자 패키징 소재의 수착 특성화를 통한 신뢰성 평가)

  • Park, Heejin
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.37 no.9
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    • pp.1151-1158
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    • 2013
  • Knowledge of the moisture sorption properties of a material is essential for optimal material development and analysis of the delamination failure caused by vapor pressure at the interlayer during the manufacturing process of integrated packaging devices. In this paper, both temperature dependent absorption and desorption properties according to temperature and humidity model are parameterized and the effects of water activities and temperature are discussed. The activation energy obtained from the parameterized diffusivity determines the acceleration factor for the equivalency of moisture sorption levels, which enables the effect of moisture diffusivity on the equivalent elapsed testing time required for evaluating the reliable life time to be estimated. The acceleration factor evaluated at the reliability testing standard of the flexible packaging module is exampled.

Effect of Carbon Dioxide in the Air on Zinc-air Cell (대기중의 이산화탄소가 공기-아연전지에 미치는 영향)

  • Kim, Nam-In;Park, Ki-Hong;Choi, Yong-Kook;Lee, Woo-Tae
    • Applied Chemistry for Engineering
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    • v.10 no.2
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    • pp.177-182
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    • 1999
  • The electrolyte was brought into contact with air and potassium carbonate concentration was measured with various contact time in order to check the effect of carbon dioxide in the air on zinc-air cell. The relationship between potassium carbonate concentration in electrolyte and battery capacity was also studied. The potassium carbonate concentration increased due to carbon dioxide absorption with increasing contact time with air, but the cell capacity linearly decreased with increasing potassium carbonate concentration in the electrolyte. The rate of carbon dioxide absorption was mainly affected by the pore size of hydrophobic membrane. Our study showed that adapting the pore of hydrophobic membrane decreased the loss of cell discharge performance due to the presence of carbon dioxide or water vapor in the atmosphere.

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Enhanced Photoelectrochemical Reaction of MoS2 Nanosheets Vertically Grown on TiO2 Nanowires (MoS2 나노시트의 TiO2 나노선에 수직 성장을 통한 광전기화학반응 향상)

  • Seo, Dong-Bum;Kim, Eui-Tae
    • Korean Journal of Materials Research
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    • v.31 no.2
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    • pp.92-96
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    • 2021
  • We report the growth and enhanced photoelectrochemcial (PEC) water-splitting reactivity of few-layer MoS2 nanosheets on TiO2 nanowires. TiO2 nanowires with lengths of ~1.5 ~ 2.0 ㎛ and widths of ~50~300 nm are synthesized on fluorine-doped tin oxide substrates at 180 ℃ using hydrothermal methods with Ti(C4H9O)4. Few-layer MoS2 nanosheets with heights of ~250 ~ 300 nm are vertically grown on TiO2 nanowires at a moderate growth temperature of 300 ℃ using metalorganic chemical vapor deposition. The MoS2 nanosheets on TiO2 nanowires exhibit typical Raman and ultraviolet-visible light absorption spectra corresponding to few-layer thick MoS2. The PEC performance of the MoS2 nanosheet/TiO2 nanowire heterostructure is superior to that of bare TiO2 nanowires. MoS2/TiO2 heterostructure shows three times higher photocurrent than that of bare TiO2 nanowires at 0.6 V. The enhanced PEC photocurrent is attributed to improved light absorption of MoS2 nanosheets and efficient charge separation through the heterojunction. The photoelectrode of the MoS2/TiO2 heterostructure is stably sustained during on-off switching PEC cycle.

Estimation of Precipitable Water from the GMS-5 Split Window Data (GMS-5 Split Window 자료를 이용한 가강수량 산출)

  • 손승희;정효상;김금란;이정환
    • Korean Journal of Remote Sensing
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    • v.14 no.1
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    • pp.53-68
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    • 1998
  • Observation of hydrometeors' behavior in the atmosphere is important to understand weather and climate. By conventional observations, we can get the distribution of water vapor at limited number of points on the earth. In this study, the precipitable water has been estimated from the split window channel data on GMS-5 based upon the technique developed by Chesters et al.(1983). To retrieve the precipitable water, water vapor absorption parameter depending on filter function of sensor has been derived using the regression analysis between the split window channel data and the radiosonde data observed at Osan, Pohang, Kwangiu and Cheju staions for 4 months. The air temperature of 700 hPa from the Global Spectral Model of Korea Meteorological Administration (GSM/KMA) has been used as mean air temperature for single layer radiation model. The retrieved precipitable water for the period from August 1996 through December 1996 are compared to radiosonde data. It is shown that the root mean square differences between radiosonde observations and the GMS-5 retrievals range from 0.65 g/$cm^2$ to 1.09 g/$cm^2$ with correlation coefficient of 0.46 on hourly basis. The monthly distribution of precipitable water from GMS-5 shows almost good representation in large scale. Precipitable water is produced 4 times a day at Korea Meteorological Administration in the form of grid point data with 0.5 degree lat./lon. resolution. The data can be used in the objective analysis for numerical weather prediction and to increase the accuracy of humidity analysis especially under clear sky condition. And also, the data is a useful complement to existing data set for climatological research. But it is necessary to get higher correlation between radiosonde observations and the GMS-5 retrievals for operational applications.

Experimental Study on Compression/Absorption High-Temperature Hybrid Heat Pump with Natural Refrigerant Mixture (천연혼합냉매를 이용한 압축/흡수식 고온히트펌프의 실험적 연구)

  • Kim, Ji-Young;Park, Seong-Ryong;Baik, Young-Jin;Chang, Ki-Chang;Ra, Ho-Sang;Kim, Min-Sung;Kim, Yong-Chan
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.35 no.12
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    • pp.1367-1373
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    • 2011
  • This research concerns the development of a compression/absorption high-temperature hybrid heat pump that uses a natural refrigerant mixture. Heat pumps based on the compression/absorption cycle offer various advantages over conventional heat pumps based on the vapor compression cycle, such as large temperature glide, temperature lift, flexible operating range, and capacity control. In this study, a lab-scale prototype hybrid heat pump was constructed with a two-stage compressor, absorber, desorber, desuperheater, solution heat exchanger, solution pump, liquid/vapor separator, and rectifier as the main components. The hybrid heat pump system operated at 10-kW-class heating capacity producing hot water whose temperature was more than $90^{\circ}C$ when the heat source and sink temperatures were $50^{\circ}C$. Experiments with various $NH_3/H_2O$ mass fractions and compressor/pump circulation ratios were performed on the system. From the study, the system performance was optimized at a specific $NH_3$ concentration.

Screening of Agricultural and Food Processing Waste Materials as New Sources for Biodegradable Food Packaging Application

  • Wang, Long-Feng;Reddy, Jeevan Prasad;Rhim, Jong-Whan
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.20 no.1
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    • pp.7-15
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    • 2014
  • Agar-based composite films were prepared with variety of food processing and agricultural processing waste materials in order to screen natural lingo-cellulosic resources for the value-added utilization of the under-utilized materials. The effect of these waste materials (10 wt% based on agar) on mechanical properties, moisture content (MC), water vapor permeability (WVP), water absorption behavior of biocomposite films were investigated. Biocomposite films prepared with various fibers resulted in significant increase or decrease in color and percent transmittance. The MC, WVP, and surface hydrophobicity of biocomposite films increased significantly by incorporation of fibers, while the water uptake ratio and solubility of the film decreased. SEM images of biocomposite film showed better adhesion between the fiber and agar polymer. Among the tested cellulosic waste materials, rice wine waste, onion and garlic fibers were promising for the value-added utilization as a reinforcing material for the preparation of biocomposite food packaging films.

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Influence of Methylcellulose on Properties of Wheat Gliadin Film Cast from Aqueous Ethanol

  • Song, Yihu;Li, Lingfang;Zheng, Qiang
    • Food Science and Biotechnology
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    • v.18 no.4
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    • pp.910-916
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    • 2009
  • Present work was focused on the influence of methylcellulose (MC) on steady rheology of wheat gliadin solution and the properties of glycerol plasticized gliadin films. The presence of MC below 0.99 wt% improved viscosity and flow activation energy of the 10 wt% gliadin solution significantly. In the casting films containing 0.2 g glycerol/g dry protein, the MC component aggregated in the gliadin matrix. The blend films containing less than 7.7 wt% MC exhibited higher Young's modulus (E) and tensile strength (${\sigma}_b$) and lower elongation at break (${\epsilon}_b$) in comparison with the pure gliadin film, which was related to the intermolecular interaction between MC and gliadins, the brittle fracture of the aggregated MC component, and the increase in glass transition temperature ($T_g$) of the gliadin phase. Increasing MC content led to a slight increase in water vapor permeability (WVP) without significant influence on the moisture absorption (MA).