• Title/Summary/Keyword: water relations

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The Optimization of Removal Process of Humic Acid by Polysulfone Hollow-fiber Membrane (폴리설폰 중공사막에 의한 부식산 제거공정의 최적화)

  • Song, Kun-Ho;Lee, Kwang-Rae;Lee, Chan-Ki
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.7
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    • pp.1273-1284
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    • 2000
  • In this study, ultrafiltration was performed to remove humic acid from aqueous solution. Since the effects of system variables on the ultrafiltration were tangled with non-linearly. Response Surface Methodology(RSM) was used to know optimum conditions of ultrafiltration process, relations among system variables, and the effects of system variables such as pressure difference across the membrane, concentration of humic acid, and feed flow rates. As concentrations of humic acid were 10ppm, 40ppm, and 70ppm in feed stream, permeation fluxes were 2.56, 2.27, and $2.10({\times}10^{-2}cc/cm^2{\cdot}min)$ respectively ; in other words, permeation fluxes of 10ppm, 40ppm and 70ppm feed concentration decreased by 17.7%, 26.7% and 32.2% of pure water permeation flux respectively. Concentration of humic acid in permeate side were 0.5ppm, 1.2 ppm, and 2.1ppm respectively. When pressure difference(${\Delta}P$) increased from 1atm to 2atm and 3atm, permeation fluxes of 40ppm feed concentration increased by 66% and 152% of permeation rate at 1atm respectively. However, concentrations of humic acid in permeate side increased from 0.5ppm to 1.5ppm and 3.5ppm. RSM showed that the optimum condition of system variables is 38.5~40ppm of humic acid concentration in feed stream, 30~30.7cc/min of feed flow rate, and 2atm of pressure difference.

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Measurements and Modeling of the Activity Coefficients and Solubilities of L-alanine in Aqueous Electrolyte Solutions (전해질 수용액에서 L-Alanine의 활동도계수와 용해도의 측정 및 모델링)

  • Lee, Bong-Seop;Kim, Ki-Chang
    • Korean Chemical Engineering Research
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    • v.48 no.4
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    • pp.519-533
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    • 2010
  • Activity oefficients and solubilities of L-Alanine in aqueous solutions containing each of four electrolytes(NaCl, KCl, $NaNO_3$ and $KNO_3$) were measured at 298.15 K. The measurements of activity coefficients were carried out in the electrochemical cell coupled with two ion-selective electrodes(cation and anion), and the solubilities were measured by the gravimetric analysis of saturated solutions in equilibrium with the solid phase of L-alanine. To model the activity coefficients and solubilities of amino acid in the amino acid/electrolyte aqueous solutions, thermodynamic relations of the residual Helmholtz free energy in the amino acid/electrolyte aqueous solutions were developed based on the perturbed-chain statistical associating fluid theory(PC-SAFT) combined with the primitive mean spherical approximation(primitive-MSA). In the present model, it is assumed that the zwitterions of L-alanine are associated with each other and cross-associated with water molecules, and also cross-associated with the cation and anion dissociated from an electrolyte(inorganic salt). The activity coefficients and solubilities of L-Alanine calculated from the theoretical model proposed in this work are found to be well agreeable with experimental data.

Optimal Density of Initial Inoculation of Rotifer and, Optimal Density of Chlorella for Sustainable Dai]y Harvest of Rotifer (윤충의 연속반복 수확을 위한 적정윤충접종밀도와 적정 Chlorella 농도에 대하여)

  • Moon Yoeng Bong
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.14 no.2
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    • pp.86-93
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    • 1981
  • For daily supply of rotifers to feed juvenile fish and/or larval crustaceans such as shrimp in their seedling culture procedures, the maximum daily increase of cultured rotifers in relations with the inoculation densities of rotifers and the concentrations of food organism, Chlorella sp. were initially investigated in an experimental culture unit. The best results were obtained from the 10 inds./ml of the rotifer inoculation density with $3\times10^6\;cells/ml$ of Chlorella showing the maximum daily increase of 73.0 inds./ml/day on the 7th day. Based on the best results of the initial experiments a trial was made for continuous daily harvests of rotifers. As in the initial experiments, the maximum daily increase of rotifer was observed on the 7th day, when the daily harvest was initiated and continued once a day for 6days. For the 6 days, the amount of the mean daily harvest was $1.42\times10^5$ individuals per culture flask ($3{\iota}\;filled\;with\;2{\iota}$culture water) shelving a possibility of continuous daily harvests.

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A Molecular Dynamics Simulation Study of Ranciéite-takanelite Solid Solution Crystal Structures (란시아이트-다카네라이트 고용체 결정구조에 대한 분자동역학 시뮬레이션 연구)

  • Han, Suyeon;Kwon, Kideok D.
    • Korean Journal of Mineralogy and Petrology
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    • v.33 no.1
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    • pp.19-28
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    • 2020
  • Ranciéte is a hexagonal phyllomanganate mineral containing random Mn(IV) vacancies with hydrated Ca2+ cations charged balanced as interlayer cations. Its Mn2+ analogue is called takanelite, and ranciéite and takanelite are regarded as end-members of a solid solution series of (Ca2+,Mn2+)Mn4O9·nH2O. Because the minerals are found as very small particles associated with other minerals, the crystal structures of the solid solution series have yet to be defined. In this research, we conducted classical molecular dynamics (MD) simulations of ranciéite and takanelite by varying the Mn2+/Ca2+ interlayer cation ratio to find relations between the interlayer cations and mineral structures. MD simulation results of chalcophanite group minerals are compared with experimental results to verify our method applied. Then, lattice parameters of ranciéite and takanelite models are presented along with detailed interlayer structures as to the distribution and coordination of cations and water molecules. This study shows the potentials of MD simulations in entangling complicated phyllomanganates structures.

Sediment Characteristics of the Beach and Subtidal Zone in Shindu Marine Protected Area (신두 해양생태계보호구역 해빈과 조하대의 퇴적물 특성)

  • Shin, Young Ho;Seo, Jong Cheol
    • Journal of the Korean Geographical Society
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    • v.49 no.6
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    • pp.812-832
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    • 2014
  • We analyzed physical and chemical properties of sediments from 20 subtidal points and 9 beach points to define sedimentary environment between summer and winter of Shindu Marine Protected Area. Means of particle size in summer were generally finer than winter's. There was distinctively spatial pattern that particle sizes became increasingly fine as west direction and apart from beach in summer, but this pattern was not shown in winter. Coarse sediments were prevailed in winter. To explain these patterns, we propose possible two causes which are spatially different water depth condition related with seasonal wave climate or fine sediment input from an estuary located in south of this area during summer rainy season. Contents of exchangeable cations of sediment in summer were shown $Na^+$>$Ca^{2+}$>$Mg^{2+}$>$K^+$ in order, but those of winter were shown $Na^+$>$Mg^{2+}{\fallingdotseq}Ca^{2+}$>$K^+$. Contents of $Na^+$, $Mg^{2+}$, and $K^+$ were related with contents of fine sediment and showed high correlation in each other. These relations were not shown between $Ca^{2+}$ and others. Our results show that there are spatio-temporal unique sedimentary environments between subtidal zone, beach, and dune near Shindu Marine Protected Area. Therefore, we should consider these spatio-temporal patterns for environmentally sound management of Shindu coastal system.

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Ecophysiological Interpretations on the Water Relations Parameters of Trees (XI) -The Comparison of Hydraulic Conductivity of Branch Junctions in Twenty-one Deciduous Broad-Leaved Species (수목(壽木)의 수분특성(水分特性)에 관한 생리(生理)·생태학적(生態學的) 해석(解析)(XI) - 낙엽(落葉) 활엽수(闊葉樹) 21종(種)의 분지부(分枝部)의 수분통도성(水分通道性) 비교(比較) -)

  • Han, Sang Sup;Kim, Sun Hee;Yi, Myong Jong
    • Journal of Korean Society of Forest Science
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    • v.87 no.2
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    • pp.220-229
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    • 1998
  • This study was performed to compare the characteristics of hydraulic conductivity such as relative conductivity(RC), leaf specific conductivity(LSC), Huber value(HV), specific conductivity(SC), and diameter of vessels(${\mu}m$) and number of vessels($No./mm^2$) in branch junctions of the twenty-one deciduous broad-leaved species. The hydraulic conductivities of branch junctions decreased with increasing junction angle between stem and branch, and with decreasing diameter of branch. The RC and LSC of branch junctions related to branching types(ㅏ, Y, ${\Psi}$ type) were much lower in ㅏ and ${\Psi}$ types than in Y type. The diameter and number of vessels remarkably reduced in branch junctions as compared with the stem and branch.

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Study on Fish Diversity by Impervious Cover of Gyeongan-Stream Watershed (경안천 유역의 불투수면에 따른 어류다양성 연구)

  • Choi, Sun Hee;Kwon, Sun Soon;Lee, Sang Don
    • Journal of Wetlands Research
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    • v.14 no.4
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    • pp.561-569
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    • 2012
  • This study estimates landscape indices of the Gyeongan-stream watershed from 1975 to 2000 by classifying the land cover into impervious cover and pervious cover depending on its state using a landscape analysis program. For the indicator of biodiversity this study uses Total Core Area(TCA) among landscape indices. The estimated TCA is then used along with an Impervious Cover Model(ICM) to compare the number of fish species that appear in the Gyeongan-stream watershed. In the relations between TCA and the impervious cover ratio, it has been found that as the impervious cover ratio increases, TCA decreases accordingly. It shows that as the ratio of impervious cover in the landscape increases due to urbanization and development, the critical area that individual species need for isolation from outside has decreased. Also, the monitoring of the number of fish species that appear in the Gyeongan-stream watershed shows that in the areas with low impervious cover ratio there are more fish species appearing that inhabit in clean, uncontaminated water. It has been identified that the Gyeongan-stream watershed falls into the category of Impacted Stream and that its state is worsening, and since the watershed in this area responds to the impervious cover ratio very sensitively, its fish diversity it is required to improve the state of the basin through its proper and careful management.

The Evaluation of Application to MODIS LAI (Leaf Area Index) Product (MODIS LAI (엽면적지수) Product의 활용성 평가)

  • Ha, Rim;Shin, Hyung-Jin;Park, Geun-Ae;Hong, Woo-Yong;Kim, Seong-Jun
    • Journal of the Korean Association of Geographic Information Studies
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    • v.11 no.2
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    • pp.61-72
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    • 2008
  • Leaf area index (LAI) is a key biophysical variable influencing land surface processes such as photosynthesis, transpiration and energy balance, and is a required input to estimate evapotranspiration in various ecological and hydrological models. The development of more correct and useful LAIs estimation techniques is required by these importance, but LAIs had been assumed in most LAI research through simple relations with the normalized difference vegetation index (NDVI) because the field measurement is difficult on wide area. This paper is to evaluate the MODIS LAI Product's practical use by comparing with LAIs that is derived from NOAA AVHRR NDVIs and the 2 years (2003-2004) measured LAIs of Korea Forest Research Institute in Gyeongancheon watershed (561.12 $Km^2$). As a result, the MODIS LAIs of deciduous forests showed higher values about 14 % and 15~30 % than the measured LAIs and NOAA LAIs. In the year of 2003, the MODIS LAIs in coniferous forests were 5 % higher than the measured LAIs, and showed about 7 % differences comparing with the NOAA LAIs except April. These differences come from the insufficient field data measured in partial points of the target area, and the extracted reference data from MODIS LAIs include the limits of spatial resolution and the error of incorrect land cover classification. Thus, using the MODIS data by the proper correction with the measured data can be useful as an input data for ecological and hydrological models which offers the vegetation information and simulates the water balance of a given watershed.

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A Calculation Method of in vivo Energy Consumption in Estimation of Harvesting Date for High Potato Solids (고 고형분함량 감자의 수확시기 예측모형을 위한 식물체내 에너지 소모량 추정)

  • Jung, Jae-Youn;Suh, Sang-Gon
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.55 no.4
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    • pp.284-291
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    • 2010
  • A simulation modeling for predicting the harvesting date with high potato solids consists of development of mathematical models. The mathematical model on potato growth and its development should be obtained by using agricultural elements which analyze relations of solar radiation quantity, temperature, photon quantity, carbon dioxide exchange rate, water stress and loss, relative humidity, light intensity, and wind etc. But more reliable way to predict harvesting date against climatic change employs in vivo energy consumption for growth and induction shape in a slight environmental adaptation. Therefore, to calculate in vivo energy loss, we take a concept of estimate of the amount of basal metabolism in each tuber on the basis of $Wm={\int}^m_tf(x)dt$ and $Tp=\frac{Tm{\cdot}Wm^{Tp}}{Wm^{Tm}}$. In the validation experiments, results of measuring solid accumulation of potato harvested at simulated date agreed fairly well with the actual measured values in each regional field during the growth period of 2005-2009. The calculation method could be used to predict an appropriate harvesting date for a production of high potato solids according to weather conditions.

Effects of Temperature, Food Concentration, and Shell Size on Filtering Rate and Pseudofeces Production of Unio douglasiae on Microcystis aeruginosa (수온, 먹이농도, 패각 크기가 Microcystis aeruginosa에 대한 말조개의 여과율 및 배설물 생산에 미치는 영향)

  • Lee, Yeon-Ju;Kim, Baik-Ho;Kim, Nan-Young;Um, Han-Yong;Hwang, Soon-Jin
    • Korean Journal of Ecology and Environment
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    • v.41 no.spc
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    • pp.61-67
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    • 2008
  • This study was conducted to evaluate filtering rate (FR) and pseudofeces production (PFP) of a freshwater filter-feeding bivalve, Unio douglasiae, on a toxic cyanobacterium (Microcystis aeruginosa). The experiments were conducted under the various conditions of water temperature $(5{\sim}35^{\circ}C)$, mussel size $(5.6{\sim}13.3cm)$ and food con centrations $(49{\sim}491{\mu}g\;Chl-{\alpha}L^{-1})$. Among the applied temperature, the maximum FR $(0.41L\;gAFDW^{-1}hr^{-1})$ and PFP (0.47mg $gAFDW^{-1}hr^{-1}$) were observed at 15 and $25^{\circ}C$, respectively. Both weight-based FR and PFP were not correlated with the mussel size, and the values lied in a limited range with some degree of variation. Likewise, no significant relations between FR and PFP was observed in the mussel size. The FR values were negatively correlated with food concentration, while PFP showed positive correlation. Among the applied food concentrations, the maximum FR (0.34L $gAFDW^{-1}hr^{-1}$) and PFP (0.06mg $gAFDW^{-1}hr^{-1}$) appeared in $113{\mu}g\;Chl-{\alpha}L^{-1}$ and $491{\mu}g\;Chl-{\alpha}L^{-1}$, respectively. These results indicate that the grazing of Unio douglasiae are affected by various parameters, and it may be applied as an effective biofilter to inhibit Microcystis bloom under appropriate application. However, further studies on the fate of excreted pseudofeces are needed to understand their possibility of stimulating nuisant algal growth.