• Title/Summary/Keyword: water chemical characteristics

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Fabrication of Metal-Semiconductor Interface in Porous Silicon and Its Photoelectrochemical Hydrogen Production

  • Oh, Il-Whan;Kye, Joo-Hong;Hwang, Seong-Pil
    • Bulletin of the Korean Chemical Society
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    • v.32 no.12
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    • pp.4392-4396
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    • 2011
  • Porous silicon with a complex network of nanopores is utilized for photoelectrochemical energy conversion. A novel electroless Pt deposition onto porous silicon is investigated in the context of photoelectrochemical hydrogen generation. The electroless Pt deposition is shown to improve the characteristics of the PS photoelectrode toward photoelectrochemical $H^+$ reduction, though excessive Pt deposition leads to decrease of photocurrent. Furthermore, it is found that a thin layer (< 10 ${\mu}m$) of porous silicon can serve as anti-reflection layer for the underlying Si substrate, improving photocurrent by reducing photon reflection at the Si/liquid interface. However, as the thickness of the porous silicon increases, the surface recombination on the dramatically increased interface area of the porous silicon begins to dominate, diminishing the photocurrent.

The Characteristics of Shearing Resistance of Silicate-Grouted Soils (물유리계 약액고결토의 전단저항특성)

  • 정형식;류재일
    • Geotechnical Engineering
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    • v.4 no.2
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    • pp.45-55
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    • 1988
  • Chemical grouting is one of the ground.improvement methods for the purpose of cutting o($\boxUl$ water and increasing the strength of soil. It has ben reported that the effect of strength increasement of groued roils is due to increase of cohesion. In this study, the effect of cohesion on the shearing resistance of grouted soil 9.as intr.estigated tall.ouch triaxial compression test. According to the result of this research, It is found that the improved cohesion increases rapidly up to the maximum value at a small strain and subsequent decrease of cohericn is due to the breaking of grout chemical at a larger strain.

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[ $SiO_2$ ] CMP Characteristic by Additive (첨가제에 따른 $SiO_2$ CMP 특성)

  • Lee, Woo-Sun;Ko, Pi-Ju;Choi, Kwon-Woo;Shin, Jae-Wook;Seo, Yong-Jin
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.07a
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    • pp.378-381
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    • 2003
  • The chemical mechanical polishing (CMP) has been widely accepted for the global planarization of multi-layer structures in semiconductor manufacturing However, cost of ownership (COO) and cost of consumables (COC) were relatively increased because of expensive slurry. In this paper, the effects of different slurry composition on the oxide CMP characteristics were investigated to obtain the higher removal rate and lower non-uniformity. We prepared the various kinds of slurry. In order to save the costs of slurry, the original slurry was diluted by de-ionized water (DIW). And then, alunima abrasives were added in the diluted slurry in order to promote the mechanical force of diluted slurry.

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Permeation Characteristics of Poly(Hydroxypropyl Methacrylate) membrane having Tertiary Amine Moiety (Tertiary Amine을 포함하는 Hydroxypropyl Methacrylate 고분자막의 투과특성)

  • Hon, Jae-Min;Shim, Jyong-Sup
    • Applied Chemistry for Engineering
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    • v.1 no.2
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    • pp.154-160
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    • 1990
  • Hydroxypropyl methacrylate polymeric membranes having tertiary amine moiety were prepared to control the release rate of insulin in response to the concentration of glucose. Hydroxypropyl methacrylate was copolymerized with N, N'-diethylaminoethylacrylate. Its water content was increased with decreasing the pH of the medium and was reversible with variation of the pH of the medium. The permeation coefficient of insulin through copolymer membrane was also increased with decreasing the pH of the medium. Combining this copolymer membrane and the glucose oxidase immobilized membrane as a sensor for glucose, composite membrane was prepared. The permeability of this composite membrane was increased with addition of glucose.

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Microstrictire-property-processing relationship in highly active $TiO_2$ photocatalysts prepared by the sol-gel method (솔젤법으로 제조된 고활성 $TiO_2$ 광촉매에서 미세구조-물성-공정조건의 상관성)

  • Shin, Hyun-Ki;Kim, Hern
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.9 no.5
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    • pp.493-497
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    • 1999
  • $TiO_2$ Powders were prepared by sol-gel method to testify the characteristics as the photocatalysts. The relationship between processing conditions (R-value (molar ratio of water to alkoxide)), heat treatment temperature, microstructures (crystalline phases), and properties (surface area, particle size) was examined. The optimal conditionsto improve the activity of photocatalyst for photobleaching of dyes in aqueous solution, Were determined.

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A Study on Chemical Neutralization and Production of Planting Porous Concrete Using Low-Grade Iron Ore (저 품위 철광석을 사용한 식생용 투수 콘크리트의 중성화 및 제작에 관한 연구)

  • Eun, Hee-Chang;Lee, Min-Su;Bae, Choong-Yeol
    • Journal of Industrial Technology
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    • v.27 no.A
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    • pp.31-38
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    • 2007
  • Recently produced concrete has a tendency to overcome environmental defects. Porous and planting Eco-concrete requires the neutralization process and enough void in concrete to contain water, to pass air freely, and provides necessary nutrients to vegetation roots. The biological environment in concrete is not suitable for planting because the concrete possesses strong alkali constituent of pH 11-13. This study evaluated the strength and serviceability of concrete as well as the chemical characteristics of concrete mixed by low-grade iron ore left in the abandoned mine and treated by Ammonium monohydrogen phosphate, $(NH_4)_2HPO_4$. Test variables include two kinds of coarse aggregates such as crushed stones and low-grade iron ore, the duration time and the period for neutralization treatment by Ammonium monohydrogen phosphate, $(NH_4)_2HPO_4$, and the proportion ratio of cement, blast furnace slag and silica fume.

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Passivation of organic light emitting diodes with a-$SiN_x$ thin films grown by catalyzer enhanced chemical vapor deposition

  • Jeong, Jin-A;Kang, Jae-Wook;Kim, Han-Ki
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08a
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    • pp.659-662
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    • 2007
  • The characteristics of a $SiN_x$ passivation layer grown by a specially designed catalyzer enhanced chemical vapor deposition (CECVD) system and electrical and optical properties of OLEDs passivated with the $SiN_x$ layer are described. Despite the low substrate temperature, the single $SiN_x$ passivation layer, grown on the PC substrate, exhibited a low water vapor transmission rate of $2{\sim}6{\times}10^{-2}\;g/m^2/day$ and a high transmittance of 87 %. In addition, current-voltage-luminescence results of an OLED passivated with a 150 nm-thick $SiN_x$ film compared to nonpassivated sample were identical indicating that the performance of an OLED is not critically affected by radiation from tungsten catalyzer during the $SiN_x$ deposition.

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Improvement of Physical Characteristics of Paper with Micro Pulp (마이크로 펄프를 이용한 종이의 물성 개선)

  • Kim, Hak-Sang;Kim, Bong-Yong
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.40 no.1
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    • pp.9-14
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    • 2008
  • Beating and using chemical agents are common methods to improve physical properties. But the beating is high energy consumption process and chemical agent addition may cause deteriorate waste water quality. Therefore, it is necessary to use more environment-friendly methods. In this study, micro pulp was used in the handsheet making to get improving effects of physical properties without beating treatment and chemicals. Stiffness, thickness and air permeability were increased and strength properties of paper were also improved to some extents by only the micro pulp addition.

Effects of Marbling and Maturity on Physico-Chemical Properties of Hanwoo Meat during Cold Storage (근내지방도와 성숙도가 저장기간에 따른 한우육의 이화학적 특성 변화에 미치는 영향)

  • 문성실;주선태;이정일;박구부
    • Food Science of Animal Resources
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    • v.21 no.1
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    • pp.47-55
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    • 2001
  • This experiment was conducted to investigate the effects of marbling and maturity on physicochemical properties of Hanwoo meat during cold storage. A total of 18 carcasses were collected by marbling and maturity score at the commercial slaughter house. Loins of carcasses were selected and moved to laboratory and used to measure physico-chemical characteristics during 7 weeks storage at $0^{\circ}C$. The pH of samples was tended to be increased until 3 weeks storage. The water holding capacity of samples was not affected by marbling and maturity score. Lightness value of all samples was not changed, whereas redness value of high marbling samples was significantly(p<0.05) higher than that of low marbling samples. Purge loss of high marbling samples was significantly(p<0.05) lower than that of low marbling samples. These results indicate that high marbling and low maturity has better meat quality than low marbling and high maturity in Hanwoo.

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Fluorescence Enhancement of Ethidium Bromide by DNA Bases and Nucleosides

  • Pyun, Chong-Hong;Park, Su-Moon
    • Bulletin of the Korean Chemical Society
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    • v.10 no.2
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    • pp.142-147
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    • 1989
  • Fluorescence enhancements of ethidium bromide (EB) by solution species of low molecular weights such as DNA base molecules and nucleosides in water are reported. The degree of enhancements was determined by intensity as well as lifetime measurements for EB fluorescence. Experiments including solvent effects on absorbance and fluorescence spectra of EB, effects of protonation on the EB absorbance spectrum, and determination of equilibrium constants for EB-DNA bases have been performed to help explain the fluorescence enhancement. The results suggest that the excited state stabilization in the hydrophobic environment, the loss of torsional/vibrational energy of amino groups, and the change in the electronic transition characteristics are all responsible for the fluorescence enhancement.