• Title/Summary/Keyword: water chemical characteristics

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Experimental Study on Bonding Properties of Reinforced Concrete with Water-Cement Ratio and Blending of Mineral Admixture (물-시멘트비 및 혼화재 혼입에 따른 철근콘크리트의 부착 특성에 관한 연구)

  • Choi, Yoon-Suk;Kim, Myung-Yu;Yang, Eun-Ik;Yi, Seong-Tae
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.05b
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    • pp.225-228
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    • 2006
  • To clarify the one body behavior of reinforcing bar and concrete, it is important to investigate bond characteristics between two materials. Bond strength is decided by applied force and interface area between reinforcing bar and concrete. And, the resultant force of chemical adhesive force, frictional force, and mechanical interaction are to be main factors. Property of concrete influences on chemical adhesive force and frictional force; bond strength is decreased by corrosion of reinforcing bar, as the result, durability is also decreased. In this study, to confirm bond characteristics with property of concrete, w/c ratio and blending of mineral admixture were selected as the main test parameters. The results obtained from this study will be used as the basic data for bond characteristics with corrosion.

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Evaluation of membrane fouling characteristics due to manganese and chemical cleaning efficiency in microfiltration membrane process (막여과 정수처리공정에서 망간에 의한 막오염 특성 및 화학세정효율 평가)

  • Kang, Joon-Seok;Park, Seogyeong;Song, Jiyoung;Jeong, Ahyoung;Lee, Jeong-Jun;Kim, Han-Seung
    • Journal of Korean Society of Water and Wastewater
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    • v.31 no.6
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    • pp.539-549
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    • 2017
  • In water treatment process using microfiltration membranes, manganese is a substance that causes inorganic membrane fouling. As a result of analysis on the operation data taken from I WTP(Water Treatment Plant), it was confirmed that the increase of TMP was very severe during the period of manganese inflow. The membrane fouling fastened the increase of TMP and shortened the service time of filtration or the cleaning cycle. The TMP of the membrane increased to the maximum of $2.13kgf/cm^2$, but it was recovered to the initial level ($0.17kgf/cm^2$) by the 1st acid cleaning step. It was obvious that the main membrane fouling contaminants are due to inorganic substances. As a result of the analysis on the chemical waste, the concentrations of aluminum(146-164 mg/L) and manganese(110-126 mg/L) were very high. It is considered that aluminum was due to the residual unreacted during coagulation step as a pretreatment process. And manganese is thought to be due to the adsorption on the membrane surface as an adsorbate in feed water component during filtration step. For the efficient maintenance of the membrane filtration facilities, optimization of chemical concentration and CIP conditions is very important when finding the abnormal level of influent including foulants such as manganese.

Assessment of Water Quality Characteristics in the Middle and Upper Watershed of the Geumho River Using Multivariate Statistical Analysis and Watershed Environmental Model (다변량통계분석 및 유역환경모델을 이용한 금호강 중·상류 유역의 수질특성평가)

  • Seo, Youngmin;Kwon, Kooho;Choi, Yun Young;Lee, Byung Joon
    • Journal of Korean Society on Water Environment
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    • v.37 no.6
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    • pp.520-530
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    • 2021
  • Multivariate statistical analysis and an environmental hydrological model were applied for investigating the causes of water pollution and providing best management practices for water quality improvement in urban and agricultural watersheds. Principal component analysis (PCA) and cluster analysis (CA) for water quality time series data show that chemical oxygen demand (COD), total organic carbon (TOC), suspended solids (SS) and total phosphorus (T-P) are classified as non-point source pollutants that are highly correlated with river discharge. Total nitrogen (T-N), which has no correlation with river discharge and inverse relationship with water temperature, behaves like a point source with slow and consistent release. Biochemical oxygen demand (BOD) shows intermediate characteristics between point and non-point source pollutants. The results of the PCA and CA for the spatial water quality data indicate that the cluster 1 of the watersheds was characterized as upstream watersheds with good water quality and high proportion of forest. The cluster 3 shows however indicates the most polluted watersheds with substantial discharge of BOD and nutrients from urban sewage, agricultural and industrial activities. The cluster 2 shows intermediate characteristics between the clusters 1 and 3. The results of hydrological simulation program-Fortran (HSPF) model simulation indicated that the seasonal patterns of BOD, T-N and T-P are affected substantially by agricultural and livestock farming activities, untreated wastewater, and environmental flow. The spatial analysis on the model results indicates that the highly-populated watersheds are the prior contributors to the water quality degradation of the river.

Dehydrogenase Activity and Physico-chemical Characteristics of Golf Course Soils in Kyonggi Province (경기도 골프장 토양의 탈수소효소 활성과 물리화학적 특성)

  • Lee, In-Sook;Kim, Ok-Kyung
    • The Korean Journal of Ecology
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    • v.17 no.2
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    • pp.143-148
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    • 1994
  • The relationships between microbial activity and physico-KDICical characteristics of soils were investigated in three golf courses of Kwanak, Gold and Korea Country Clubs, with different open years. The soil samples were collected in tee, fairway and rough. There were ranges of 4.80-5.55 in pH, $25.55-98.50{\mu}S$ / cm in conductivity, 10.96-16.73% in moisture content, 0.18-0.36g / g in water holding capacity, 3.68-5.39% in organic matter, and 0.10-0.25% in total nitrogen. Dehydrogenase activity(DHA) as an index of soil microbial activity was determined. DHA values of soil were $69.83-314.43{\mu}$g / g in three courses and showed the order of Kwanak>Gold>Korea Country Club with open year. This indicates that DHA was affected by several fertilizer treatments rather than herbicide and pesticide treatments. DHA was significantly different with golf clubs as well as golf courses and positively correlated with water holding capacity and total nitrogen.

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An Investigation on the Effect of Stabilization Methods and Leaching characteristics of Heavy Metals in Paddy Soils contaminated by Heavy Metal under Submerged Condition (담수조건에 따른 토양 내 중금속 용출특성과 안정화공법의 효과 검토)

  • Yu, Chan;Yun, Sung-Wook;Kang, Sin-Il;Jin, Hae-Geun
    • Proceedings of the Korean Geotechical Society Conference
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    • 2010.09a
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    • pp.1201-1212
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    • 2010
  • In order to investigate on the effect of stabilization methods for rice paddies contaminated by heavy metals, a series of lab-scale model test was carried out by applying the characteristics of submerged Paddy soil. To perform the lab-scale model test, columns were made by acrylic with the dimension of diameter=10cm, thickness=0.5cm and were filled with soils which was contaminated were mixed with stabilization agents(lime stone 5% and steel refining slag 5% respectively). To manipulate the reduction condition, soils in the columns were submerged with distilled water. And then soil water and subsurface water in each column were sampled in the regular term and analysed the various physical and chemical properties.

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Characteristics of Municipal Solid Wastes Generation in a Small City -For Donghae City- (소규모 도시의 생활폐기물 발생특성 -동해시를 중심으로-)

  • Kim, Seung-Ho;Won, Chul-Hee;Kim, Byoung-Ug;Rim, Jay-Myoung
    • Journal of Industrial Technology
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    • v.22 no.B
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    • pp.103-108
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    • 2002
  • This research was performed to investigate the generation and physico-chemical characteristics of municipal solid wastes. The results were as follows: i) The generation rate and bulk density were 0.157 kg/cap/d and 147.8 g/L in residential zone, respectively. In non-residential zone, the generation and bulk density were 1.71 kg/cap/d and 85.6 g/L, respectively. Consequently, bulk density of non-residential zone was lower than that of residential zone. ii) The wastes consisted of 90% of combustibles and 10% of incombustibles in residential zone. And the wastes from non-residential zone was composed 85% of combustibles and 15% of incombustibles. iii) Water content was estimated at 47~50% in residential zone and restaurants. In non-residential zone, except restaurants, water content was in the range of 10~30%. Ash content was nearly 10% in overall zone.

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Characteristics of Concentration of Pollutants from a Rural Watersheds during Dry Days (평상시 농촌유역에서의 오염물질의 농도특성)

  • Oh, Kwang Young;Kim, Jin Soo;Khan, jong bum;Cho, Jae Won
    • Proceedings of the Korea Water Resources Association Conference
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    • 2004.05b
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    • pp.395-398
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    • 2004
  • Characteristics of concentration of pollutants such as total nitrogen(T-N), total phosphorus(T-P) and chemical oxygen demand(COD) during dry days of $2002\~2003$ were investigated for streamwater from a rural watershed. Water was sampled and discharge was measured at 5-days intervals at outlet of study area. The mean concentrations of pollutants in non-irrigation and irrigation period not significantly different. For increasing discharge in 2002, TN concentration increased but COD concentrations decreases.

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Gas Permeation Characteristics of the Prepared SiC Membrane through Polyimide Carbonization Treatmemt (폴리이미드의 탄화 처리에 의한 SiC 분리막의 가스투과 특성)

  • Choi, Ho-Sang;Hwang, Gab-Jin;Kang, An-Soo
    • Korean Chemical Engineering Research
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    • v.43 no.1
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    • pp.66-70
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    • 2005
  • For the application in HI decomposition reaction of thermochemical water-splitting IS process, the carbonized membranes using the polymer material (polyimide) were prepared, and SiC membrane was also prepared by SiO treatment on those carbonized membranes. The weight change by the carbonation of polyimide was about 50%, and the weight decreased with an increase of carbonation temperature. The gas permeance ($H_2$ or $N_2$) of carbonized membrane decreased with an increase of carbonation temperature led to the pore closing. The gas permeance ($H_2$ or $N_2$) of SiC membrane increased with an increase of SiO treatment concentration, and the gas permeation mechanism was changed from the activiation energy flow to Knudsen flow.

A Study on the Characteristics of Fenton Oxidation of Bisphenol A and Nitrobenzene (비스페놀A와 니트로벤젠의 펜톤 산화분해 특성)

  • Bae, Su-Jin;Kwon, Hee-won;Kim, Ji-young;Hwang, In-Seong;Kim, Young-Hun
    • Journal of Environmental Science International
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    • v.30 no.12
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    • pp.1005-1014
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    • 2021
  • Organic contaminants can be released into water environments due to chemical accidents and exist as dissolved and non-aqueous phase liquids (NAPL). Fenton oxidation was tested for bisphenol A and nitrobenzene as model organic contaminants in dissolved and NAPL states. Fenton oxidation was successfully applied for both of the dissolved and NAPL states of the two pollutants and the results indicated that a quick treatment was needed to reduce the risk from a chemical accidents instead of carrying out oxidation after the contaminants dissolve in water. A set of Fenton reactions were tested under seawater conditions because chemical accidents often occurs in the ocean. Chloride ions act as radical scavengers and inhibit Fenton oxidation. The reaction rate is inversely proportional to salt contents and the reduced reaction rate can be compensated by increasing the quantity of the oxidizing agents. The current study showes that Fenton oxidation could be applied as a quick treatments for organic contaminant in dissolved and NAPL state organic contaminants released as a result of leaks or chemical accidents.

Comparison of Characteristics and Performance of Membrane in Proton Exchange Membrane Fuel Cells (고분자전해질 연료전지 고분자막의 특성 및 성능 비교)

  • Lee, Daewoong;Lim, Daehyun;Oh, Sohyeong;Chung, Hoi-Bum;Yoo, Seung-Eul;Ku, Young-Mo;Park, Kwonpil
    • Korean Chemical Engineering Research
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    • v.58 no.2
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    • pp.171-175
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    • 2020
  • In the proton exchange membrane fuel cells (PEMFC), the development of a reinforced membrane with improved durability by a support is actively in progress in Korea. In this study, the initial performance and characteristics of four types of reinforced membranes were compared. Reinforced membranes with higher amounts of C-F chains in the polymer membrane showed lower water diffusion coefficients due to the hydrophobicity of the C-F chains. The thicker the polymer membrane, the more the hydrogen permeability decreased and the higher the OCV. Membrane with short resistance below 1.5 Ωcm2 showed OCV below 0.9 V and the lowest performance, so short resistance should be above 3.0 Ωcm2. Compared with the current standard membrane, there was a similar domestic membrane, which could confirm the possibility of localization of PEMFC polymer membrane.