• 제목/요약/키워드: waste material

검색결과 1,693건 처리시간 0.028초

산업폐기물로부터 합성된 제올라이트 물질의 망간 이온 흡착속도 및 등온흡착 특성 (Adsorption Kinetic and Isotherm Characteristics of Mn Ions with Zeolitic Materials Synthesized from Industrial Solid Waste)

  • 최정학;이창한
    • 한국환경과학회지
    • /
    • 제29권8호
    • /
    • pp.827-835
    • /
    • 2020
  • Zeolite material having XRD peaks of Na-A zeolite in the 2θ range of 7.18 to 34.18 can be synthesized from the waste catalyst using a fusion/hydrothermal method. The adsorption rate of Mn ions by a commercial Na-A zeolite and the synthesized zeolitic material increased as the adsorption temperature increased in the range of 10 ~ 40℃. The adsorption of Mn ion were very rapid in the first 30 min and then reached to the equilibrium state after approximately 60 min. The adsorption kinetics of Mn ions by the commercial Na-A zeolite and the zeolitic material were found to be well fitted to the pseudo-2nd order kinetic model. Equilibrium data by the commercial Na-A zeolite and the zeolitic material fit the Langmuir, Koble-Corrigan, and Redlich-Peterson isotherm models well rather than Freundlich isotherm model. The removal capacity of the Mn ions by the commercial Na-A zeolite and the zeolitic material obtained from the Langmuir model was 135.2 mg/g and 128.9 mg/g at 30℃, respectively. The adsorption capacity of Mn ions by the synthesized zeolitic material was almost similar to that of commercial Na-A zeolite. The synthesized zeolitic material could be applied as an economically feasible commercial adsorbent.

Chinese buffer material for high-level radiawaste disposal --Basic features of GMZ-l

  • WEN Zhijian
    • 한국방사성폐기물학회:학술대회논문집
    • /
    • 한국방사성폐기물학회 2005년도 Proceedings of The 6th korea-china joint workshop on nuclear waste management
    • /
    • pp.236-244
    • /
    • 2005
  • Radioactive wastes arising from a wide range of human activities are in many different physical and chemical forms, contaminated with varying radioactivity. Their common feature is the potential hazard associated with their radioactivity and the need to manage them in such a way as to protect the human environment. The geological disposal is regarded as the most reasonable and effective way to safely disposal high-level radioactive wastes in the world. The conceptual model of geological disposal in China is based on a multi-barrier system that combines an isolating geological environment with an engineered barrier system. The buffer is one of the main engineered barriers for HLW repository. The buffer material is expected to maintain its low water permeability, self-sealing property, radio nuclides adsorption and retardation property, thermal conductivity, chemical buffering property, overpack supporting property, stress buffering property over a long period of time. Benotite is selected as the main content of buffer material that can satisfy above. GMZ deposit is selected as the candidate supplier for Chinese buffer material of High Level Radioactive waste repository. This paper presents geological features of GMZ deposit and basic property of GMZ Na bentonite. GMZ bentonite deposit is a super large scale deposits with high content of Montmorillonite (about $75\%$) and GMZ-l, which is Na-bentonite produced from GMZ deposit is selected as reference material for Chinese buffer material study.

  • PDF

Waste Disposal Models for Manufacturing Firm and Disposal Firm

  • Tsai, Chi-Yang;Nagaraj, Sugarla Edwin
    • Industrial Engineering and Management Systems
    • /
    • 제10권2호
    • /
    • pp.115-122
    • /
    • 2011
  • This research considers a system containing a manufacturing firm who generates waste material during manufacturing process, and a disposal firm who collects and disposes the waste material. Identification of the optimal number of pick ups and the amount of waste to be disposed at certain period of time in terms of cost minimization is studied. Two types of waste accumulation rates, constant and linearly increasing, are discussed and mathematical models are developed. It can be shown that the results for these two different types of waste accumulation differ in a wide range because of the difference in the way of how waste is accumulated, which disturbs the storage cost. An integrated model is also developed and discussed in which both the manufacturing firm and the disposal firm benefit from the coordination between the two parties. It is shown that the optimal policy adopted by the integrated approach can provide a strong and consistent cost-minimizing effect for both the manufacturing firm and the disposal firm over the existing approach. Finally, all the models are verified by a numerical example and the results are compared.

폐본차이나를 활용한 도자기 소지 개발 (Development of Ceramics Body using Waste Bone China)

  • 이제일;이용석;이병하
    • 한국세라믹학회지
    • /
    • 제48권1호
    • /
    • pp.46-51
    • /
    • 2011
  • The influx of Western culture and the food culture have altered the tableware of Korea, increasing the amount of using tableware. The representative tableware is known as bone china. Considering not only the amount of bone china waste generated from broken tableware at homes and but also faulty bone china products at factories, the bone china waste disposed in simple landfills is to be a serious environmental problem to solve. In this study, following "the research on development of ceramics body using waste celadon" of which the possibility was confirmed, development of ceramics body is conducted by recycling waste bone china. From the result of the study, it was understood that maximum addition of waste bone china was 20% of the whole material on the basis of measurement of plasticity. So 20% of pulverized bone china was added and the characteristics were evaluated, and the result was that porosity, water absorptivity and plasticity were 0.756%, 0.339% and 24.13%, respectively. Bending strength was $672\;kgf/cm^2$, which showed a good sintering condition. Therefore, it was considered that waste bone china could be utilized for development of new porcelain material.

폐석회를 이용한 매립지 차수재 개발 (A Development of Landfill Liner by Utilizing Waste Lime)

  • 김준섭;이승학;박준범
    • 한국지반공학회:학술대회논문집
    • /
    • 한국지반공학회 1999년도 봄 학술발표회 논문집
    • /
    • pp.521-528
    • /
    • 1999
  • As the size of our industry and population inclose, the byproducts such as municipal solid wastes, industrial wastes are in the increasing phase. The treatment of such things is rising as a social problem. Today, the final disposal of these wastes depends mostly on the landfill, and the sanitary landfill is required and designed for preventing soil and groundwater contamination. Clays have been used for a liner material of a sanitary landfill, however, the high quality clay is hard to come by and quite expensive as a lining material in our country. Using the waste lime produced abundantly every year from chemical processes was studied here, made from the proper mixing of the bentonite and the waste lime meets the regulations from the USEPA. The soil property index tests (sieve analysis, specific gravity test Atterberg limit test) were performed, and at last to confirm the sorption characteristics of the bentonite and the waste lime the sorption isotherm equilibrium test and the sorption isotherm were performed with Toluene and Ethylbenzene which are the main components of the leachate from the landfill.

  • PDF

AN ANALYSIS OF THE FACTORS AFFECTING THE HYDRAULIC CONDUCTIVITY AND SWELLING PRESSURE OF KYUNGJU CA-BENTONITE FOR USE AS A CLAY-BASED SEALING MATERIAL FOR A HIGH-LEVEL WASTE REPOSITORY

  • Cho, Won-Jin;Lee, Jae-Owan;Kwon, Sang-Ki
    • Nuclear Engineering and Technology
    • /
    • 제44권1호
    • /
    • pp.89-102
    • /
    • 2012
  • The buffer and backfill are important components of the engineered barrier system in a high-level waste repository, which should be constructed in a hard rock formation at a depth of several hundred meters below the ground surface. The primary function of the buffer and backfill is to seal the underground excavation as a preferred flow path for radionuclide migration from the deposited high-level waste. This study investigates the hydraulic conductivity and swelling pressure of Kyungju Ca-bentonite, which is the candidate material for the buffer and backfill in the Korean reference high-level waste disposal system. The factors that influence the hydraulic conductivity and swelling pressure of the buffer and backfill are analyzed. The factors considered are the dry density, the temperature, the sand content, the salinity and the organic carbon content. The possibility of deterioration in the sealing performance of the buffer and backfill is also assessed.

LANDFILL STABILIZATION WITH LANDFILL MINING AND THERMAL TREATMENT PROCESS

  • Gust, Micheal A.
    • 한국지하수토양환경학회:학술대회논문집
    • /
    • 한국지하수토양환경학회 1996년도 사용종료 매립지의 안정화 에 관한 국제 세미나
    • /
    • pp.97-101
    • /
    • 1996
  • Municipal and sanitary landfills can pose environmental problems due to leachate, landfill gas md unstable geotechnical properties. Most governmental bodies delay the correction of landfill problems or landfill replacement until a crises stage is reached. The replacement of a landfill is often made difficult due to costly regulatory controls, public opposition to siting and the high cost of closure for the previous landfill unit. Solutions to extending landfill life and capacity Involve waste minimization by recycling, refuse compaction and waste-to-energy incineration. Incineration can reduce the volume of refuse by 50-95%. The largest installed bases of municipal waste Incinerators are located in Japan and the U.S. The volume of waste contained in a landfill can be estimated by load count tabulations, weight-and-volume measurements or a material balance analysis based on the trash profile of user categories. for an existing landfill, core samples may be collected and analyzed for use in a material balance analysis. Newly generated refuse contains approximately 50% of the heating value of coal. However, landfill properties vary significantly due to the waste profile of the contributors and biodegradation due to time and weathering. The volume of the Nanji-do landfill

  • PDF

펄프.제지산업의 환경적 특성과 대책 (Environmental Features and Actions of Pulp & Paper Industry)

  • 조준형
    • 펄프종이기술
    • /
    • 제41권3호
    • /
    • pp.13-21
    • /
    • 2009
  • Pulp and paper industry is a typical plant industry which usually consume lots of water and energy. Recently, environmental issues have become more important due to climate changes around the world, and reinforcement in the regulatory content in transfer and management of chemical material and that in environmental regulations for waste water and air. Paper industry is a source material recycle industry which recycle or reuse waste paper, recyclable wood, planned plantation or lumber from thinning and waste wood. Hence it can be said that paper industry is the representative industry for earth environment and of 21th century.

A study on the effect of material impurity concentration on radioactive waste levels for plans for decommissioning of nuclear power plant

  • Gilyong Cha;Minhye Lee;Soonyoung Kim;Minchul Kim;Hyunmin Kim
    • Nuclear Engineering and Technology
    • /
    • 제55권7호
    • /
    • pp.2489-2497
    • /
    • 2023
  • Co and Eu impurities in the SSCs are nuclides that dominantly influence the neutron-induced radioactive inventory in metal and concrete radwastes (radioactive wastes) during NPP decommission. The impurity concentrations provided by NUREG/CR-3474 were used for the practical range of Co and Eu impurity concentrations to be applied to the code calculations. Metal structures near the core were evaluated to be ILW (intermediate-level waste) for the whole range of Co impurity concentration, so the boundary line between ILW and LLW (low-level waste) has no change for the whole concentration range provided by NUREG/CR-3474. Also, the boundary line between VLLW (very low-level waste) and CW (clearance waste) in the concrete shield could alter a little depending on the Eu impurity concentration within the range provided by NUREG/CR-3474. From this work, it is found that the concentration of material impurities of SSCs gives no critical impact on determining radwaste levels.

물질흐름분석(MFA)을 활용한 주방 음식물쓰레기 저감 전문가시스템 (A Study on the Expert System for Food Wastes Reduction using MFA)

  • 김광만
    • 대한안전경영과학회지
    • /
    • 제15권4호
    • /
    • pp.245-251
    • /
    • 2013
  • In this paper, the expert system to reduce the amount of food waste is proposed. The method of material flow analysis (MFA) is applied. Proper handling of waste beyond the terms of the need for proactive research been mentioned before, but actually cause the waste generator research focuses on consumer behavior and the business community to analyze the flow of materials within the study are insufficient. In this paper, the type of food consumption and food waste, look at the relationship between the occurrence of secondary schools in the diet is provided for students to examine the preferences of the target model diet expert system was reconfigured. Preference for leaving the food in the diet leads to the important information that is Each diet recipes that make up the target material flow analysis (MFA) was constructed to perform all the database. This database is currently being generated from the rain while cooking diet edible plants and materials to reflect the self-esteem following the recommended diet is used to create. Reducing food waste is actually being used currently in research knowledge to the knowledge base was constructed. Future Home Smart System was developed in conjunction with the system to the user, by providing guidelines for the utilization can be expected.