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http://dx.doi.org/10.5322/JESI.2020.29.8.827

Adsorption Kinetic and Isotherm Characteristics of Mn Ions with Zeolitic Materials Synthesized from Industrial Solid Waste  

Choi, Jeong-Hak (Department of Environmental Engineering, Catholic University of Pusan)
Lee, Chang-Han (Department of Environmental Adminstration, Catholic University of Pusan)
Publication Information
Journal of Environmental Science International / v.29, no.8, 2020 , pp. 827-835 More about this Journal
Abstract
Zeolite material having XRD peaks of Na-A zeolite in the 2θ range of 7.18 to 34.18 can be synthesized from the waste catalyst using a fusion/hydrothermal method. The adsorption rate of Mn ions by a commercial Na-A zeolite and the synthesized zeolitic material increased as the adsorption temperature increased in the range of 10 ~ 40℃. The adsorption of Mn ion were very rapid in the first 30 min and then reached to the equilibrium state after approximately 60 min. The adsorption kinetics of Mn ions by the commercial Na-A zeolite and the zeolitic material were found to be well fitted to the pseudo-2nd order kinetic model. Equilibrium data by the commercial Na-A zeolite and the zeolitic material fit the Langmuir, Koble-Corrigan, and Redlich-Peterson isotherm models well rather than Freundlich isotherm model. The removal capacity of the Mn ions by the commercial Na-A zeolite and the zeolitic material obtained from the Langmuir model was 135.2 mg/g and 128.9 mg/g at 30℃, respectively. The adsorption capacity of Mn ions by the synthesized zeolitic material was almost similar to that of commercial Na-A zeolite. The synthesized zeolitic material could be applied as an economically feasible commercial adsorbent.
Keywords
Adsorption; Isotherm; Industrial solid waste; Zeolitic materials; Manganese;
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Times Cited By KSCI : 4  (Citation Analysis)
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