• Title/Summary/Keyword: waste glass

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Preparation and Properties of Polyorganosiloxane Modified Maleated EPDM/EPDM Rubber Vibration Isolator (Polyorganosiloxane 변성 말레화 EPDM/EPDM 방진고무의 제조와 그 특성)

  • Kang, Doo-Whan;Kim, So-Mi
    • Applied Chemistry for Engineering
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    • v.21 no.5
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    • pp.581-585
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    • 2010
  • The surface of Alnico, one of the industrial dust waste, was treated with 1,3,5-trivinyl-1,3,5-trimethylcyclotrisilazane (VMS) as a surface treating agent and used as the filler for vibration isolator rubber. Maleated EPDM prepared from bulk polymerization of EPDM with maleic anhydride was copolymerized with ${\alpha},{\omega}$-bis(3-aminopropyl)polydimethylsiloxane to obtain maleated EPDM-polydimethylsiloxane copolymer (MEPDM-PDMS). EPDM/Alnico/MEPDM-PDMS vibration isolator rubber was prepared from compounding with Alnico treated with surface treating agent, 25 and 50 phrs to EPDM, respectvely based on 1 to 10 wt% of MEPDM-PDMS to EPDM. From the measurement of the thermal properties to the rubber, the glass transition temperatures (Tg) for the rubber containing maleated EPDM-PDMS copolymer was slightly lower temperature, $33^{\circ}C$ than EPDM rubber, and also DMA results showed higher tan ${\delta}$ peak to the rubber prepared from compounding with EPDM-PDMS copolymer. From the results, rubber prepared using EPDM-PDMS copolymer had better vibration isolator property.

A pplication of $CO_2$ Technolgy in Nuclear Decontamination (원자력 제염에서 $CO_2$ 기술 응용)

  • Park, K.H.;Kim, H.W.;Kim, H.D.;Koh, M.S.;Ryu, J.D.;Kim, Y.E.;Lee, B.S.;Park, H.T.
    • Journal of the Korean institute of surface engineering
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    • v.34 no.1
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    • pp.62-67
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    • 2001
  • Green technology is being developed up to a point that is feasible not only in an environmental sense, but also in an economical viewpoint. This paper introduces two case studies that applied $CO_2$ technology into nuclear industry. 1) Nuclear laundry : A laundry machine that uses liquid and supercritical $CO_2$ as a solvent for decontamination of contaminated working dresses in nuclear power plants was developed. The machine consists of a 16 liter reactor, a recovery system with compressors, and storage tanks. All $CO_2$ used in cleaning is fully recovered and reused in next cleaning, resulting in no production of secondary nuclear waste. Decontamination factor is still lower than that in the methods currently used in the plant. Nuclear laundry using $CO_2$ looks promising with technical improvements-surfactants and mechanical agitation. 2) $CO_2$ nozzle decontamination : An adjustable nozzle for controlling the size of dry ice snow was developed. Using the developed nozzle, a surface decontamination device was made. Human oils like fingerprints on glass were easy to remove. Decontamination ability was tested using a contaminated pump-housing surface. About 40 to 80% of radioactivity was removed. This device is effective in surface-decontamination of any electrical devices like detector, controllers which cannot be cleaned in aqueous solution.

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Study on compatibility of cellulose ester/poly(ethylene-co-isosorbide terephthalate) solution blends (셀룰로오스 에스터와 Poly(ethylene-co-isosorbide terephthalate) 용액 블렌드의 상용성에 관한 연구)

  • Kim, Yeon-Hee;Nam, Byeong-Uk
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.15 no.5
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    • pp.3351-3356
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    • 2014
  • Recently, Importance of studying based on biomass materials have increased due to the concern about plastic waste problems. Cellulose acetate butyrate (CAB) is a potential alternative to petroleum-based plastics because of its biodegradable property. Poly(ethylene-co-isosorbide terephthalate) (PEIT) is bio-based plastic, produced by isosorbide monomer. In this study, CAB/PEIT blends were prepared by solution blending to improve thermal stability of CAB. CAB and PEIT were dissolved in chloroform, and then precipitated in ethanol. To evaluate the compatibility of CAB/PEIT blends, the morphology and glass transition behaviors were analyzed by FE-SEM and DMA, respectively. TGA results revealed the improved thermal stabilities of the PEIT-rich and 50:50 compositions. No new or changed crystal structures were observed in the XRD result. Finally, CAB/PEIT solution blends showed good compatibility in overall compositions.

Recycling of End-of-Life Photovoltaic Silicon Modules (사용 후 태양광 실리콘 모듈의 리싸이클링)

  • Kim, Joon Soo;Cho, Jae Young;Lee, Jae Kyung;Park, Areum;Park, Jin Hyuk;Yun, Hyun Mok;Jun, Yun-Su
    • Resources Recycling
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    • v.28 no.5
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    • pp.19-29
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    • 2019
  • Recently, it is increasing a amount of installized solar-cell rapidly, and waste Solar cell module are generated in according to the reduction of efficiency largely. Therefore, it is concerned at the environmental problems and recycling of valuable materials, greatly. The treatment processes of end-of-life photovoltaic modules are composed the disassembly of Aluminum frames, separation of Tempered glass, removal of Ethylene Vinyl Acetate and recovery of valuable Metals. For the efficient recycling, we are considered to the treatment technology seriously. And we are proposed on the general opinions according to the developing technology, EPR (Extended Producer Responsibility) problems and promotion plans for the activation of recycling industry.

Comparative study of individual and co-application of biochar and wood vinegar on growth of perilla (Perilla frutescens var.) and soil quality

  • Yun-Gu Kang;Nam-Ho Kim;Jun-Ho Kim;Da-Hee Ko;Jae-Han Lee;Jin-Hyuk Chun;Taek-Keun Oh
    • Korean Journal of Agricultural Science
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    • v.49 no.2
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    • pp.357-366
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    • 2022
  • Biochar can be obtained by using various types of biomass under an oxygen-limited condition. Biochar can be utilized for various applications such as soil improvement, waste management, growth promotion, and adsorption. Wood vinegar is produced by the process of pyrolysis wood biomass and is used as a growth promoter, for soil improvement, and as a feed additive. When wood vinegar is treated on soil, it acts to control soil pH, improve nutrient availability, and alleviate N2O and NH3 volatilization. The objective of this study was to evaluate the effect of biochar and wood vinegar on the growth of perilla and soil quality. The experiment was conducted by using a Wagner pot (1·5,000 a-1) in a glass greenhouse. The biochar was produced by pyrolysis at 450℃ for 30 minutes using rice husk and rice straw. Wood vinegar was diluted to 1 : 500 (v·v-1) and used in this experiement. In the results of a cultivation experiment, co-application of biochar and wood vinegar enhanced the growth of perilla. In particular, rice husk biochar affected the leaves of the perilla, and rice straw biochar influenced the stems of the perilla. In addition, soil quality after treatment with biochar and wood vinegar applied together was highest compared to other units. Therefore, it is anticipated that co-application of biochar and wood vinegar will be more productive and improve soil quality compared to individual utilization of biochar and wood vinegar.

Nanoscale Pattern Formation of Li2CO3 for Lithium-Ion Battery Anode Material by Pattern Transfer Printing (패턴전사 프린팅을 활용한 리튬이온 배터리 양극 기초소재 Li2CO3의 나노스케일 패턴화 방법)

  • Kang, Young Lim;Park, Tae Wan;Park, Eun-Soo;Lee, Junghoon;Wang, Jei-Pil;Park, Woon Ik
    • Journal of the Microelectronics and Packaging Society
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    • v.27 no.4
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    • pp.83-89
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    • 2020
  • For the past few decades, as part of efforts to protect the environment where fossil fuels, which have been a key energy resource for mankind, are becoming increasingly depleted and pollution due to industrial development, ecofriendly secondary batteries, hydrogen generating energy devices, energy storage systems, and many other new energy technologies are being developed. Among them, the lithium-ion battery (LIB) is considered to be a next-generation energy device suitable for application as a large-capacity battery and capable of industrial application due to its high energy density and long lifespan. However, considering the growing battery market such as eco-friendly electric vehicles and drones, it is expected that a large amount of battery waste will spill out from some point due to the end of life. In order to prepare for this situation, development of a process for recovering lithium and various valuable metals from waste batteries is required, and at the same time, a plan to recycle them is socially required. In this study, we introduce a nanoscale pattern transfer printing (NTP) process of Li2CO3, a representative anode material for lithium ion batteries, one of the strategic materials for recycling waste batteries. First, Li2CO3 powder was formed by pressing in a vacuum, and a 3-inch sputter target for very pure Li2CO3 thin film deposition was successfully produced through high-temperature sintering. The target was mounted on a sputtering device, and a well-ordered Li2CO3 line pattern with a width of 250 nm was successfully obtained on the Si substrate using the NTP process. In addition, based on the nTP method, the periodic Li2CO3 line patterns were formed on the surfaces of metal, glass, flexible polymer substrates, and even curved goggles. These results are expected to be applied to the thin films of various functional materials used in battery devices in the future, and is also expected to be particularly helpful in improving the performance of lithium-ion battery devices on various substrates.

Engineering Geological Implications of Fault Zone in Deep Drill Cores: Microtextural Characterization of Pseudotachylite and Seismic Activity (시추코어 단층대에서의 지질공학적 의미: 슈도타킬라이트의 미세조직의 특징과 지진활동)

  • Choo, Chang-Oh;Jeong, Gyo-Cheol
    • The Journal of Engineering Geology
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    • v.27 no.4
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    • pp.489-500
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    • 2017
  • It is not rare that pseudotachylite, dark colored rock with glassy texture, is recognizable in deep core samples drilled up to 900 m from the surface. Pseudotachylite with widths varying few to 20 cm is sharply contacted or interlayered with the host rocks composed of Jurassic granite and Precambrian amphibolite gneiss, showing moderately ductile deformation or slight folding. Pseudotachylite occurring at varying depths in the deep drill core are slightly different in texture and thickness. There is evidence of fault gouge at shallower depths, although brittle deformation is pervasive in most drill cores and pseudotachylite is identified at random depth intervals. Under scanning electron microscope (SEM), it is evident that the surface of pseudotachylite is characterized by a smooth, glassy matrix even at micrometer scale and there is little residual fragments in the glass matrix except microcrystals of quartz with embayed shape. Such textural evidence strongly supports the idea that the pseudotachylite was generated through the friction melting related to strong seismic events. Based on X-ray diffraction (XRD) quantitative analysis, it consists of primary minerals such as quartz, feldspars, biotite, amphibole and secondary minerals including clay minerals, calcite and glassy materials. Such mineralogical features of fractured materials including pseudotachylite indicate that the fractured zone might form at low temperatures possibly below $300^{\circ}C$, which implies that the seismic activity related to the formation of pseudotachylite took place at shallow depths, possibly at most 10 km. Identification and characterization of pseudotachylite provide insight into a better understanding of the paleoseismic activity of deep grounds and fundamental information on the stability of candidate disposal sites for high-level radioactive waste.

Characteristics of Marine Debris collected from the Coastline of Sandbar in the Nakdong River Estuary (낙동강 하구 사주 해안에서 수거한 쓰레기 종류 및 분포량 추정)

  • Lee, Y.B.;Park, S.;Ryu, C.R.;Kim, H.T.;Yoon, H.S.
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.10 no.3
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    • pp.148-154
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    • 2007
  • This study investigated the spatial distribution of the marine debris in Jinudo in the Nakdong river estuary. Types of marine debris in Jinudo are analyzed through sampling around some portion of its sandbar shoreline. The present study and its main results are summarized as follow: 1) Monitoring system, for evaluating the volume of marine debris, was established in the coastal region of $50\;m\;{\times}\;50\;m\;(=0.002\;km^2)$ over the southern part of Jinudo. All the marine debris of conceivable form are collected and their amount was also estimated. 2) During the $1^{st}$ collection in May 2007, the total weight of the marine debris was 1,110 kg in this site, which means the density of marine debris around the shoreline is $444\;ton/km^2$. After one month later, the collected marine debris was 23.75 kg and so we have the average density of $9.5\;ton/km^2$. From these results, it is suggested that the marine debris of 316.67kg was being accumulated per day over unit area($1\;km^2$). 3) The most frequent marine debris collected during monitoring campaigns was wooden material amounting to 85.86% of the whole collection; the rest were fishing gears such as nets and buoys(5.13%), household waste(2.34%), glass(0.94%) and metals(0.27%).

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An Analysis of Hydrophobic Characteristics of Concrete Surfaces by Antifouling Coating Agent using Cellulose Nonofiber and Alkyl Ketene Dimer (셀룰로오스 나노 섬유와 AKD를 활용한 방오 코팅제에 의한 콘크리트 표면의 소수 특성 분석)

  • Nag-Seop Jang;Chi-Hoon Noh;Hongseob Oh
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.11 no.2
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    • pp.120-129
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    • 2023
  • Marine structures are subject to damage not only from sea salt but also from the adhesion of marine microorganisms and suspended particles, which cause additional damages. In order to prevent this, periodic coating is employed in the case of vessels to maintain the necessary performance. However, it is true that periodic coating is difficult for concrete or steel support structures, and there is a risk of marine environmental pollution. In this study, authors developed an anti-fouling coating agent using eco-friendly materials that possess hydrophilic cellulose nanofibers and AKD(alkyl ketene dimer). To achieve a homogeneous mixture, the content of cellulose nanofibers was fixed at 1 %, and AKD, distilled water, and waste glass were mixed using a digital mixer and homogenizer. The contact angle of the prepared coated surface was observed to be over 130°, indicating sufficient performance even in a water droplet flow test with a 15° slope, suggesting self-cleaning capability. Furthermore, through the analysis of viscosity characteristics at different temperatures, it was confirmed that the application is feasible at room temperature. Microstructure analysis also verified that the coating agent is uniformly applied to the concrete surface.