• 한국전기전자재료학회논문지
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• 제23권7호
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• pp.566-570
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• 2010

Electro-optic modulators based on 25 monolayer langmuir-blodgett films of vinylidene fluoride and trifluoroethylene, P(VDF-TrFE), were fabricated. The LB films were prepared by transferring the monolayers on to an ITO coated glass with a surface pressure of 5 dyne/cm by use of the langmuir-schaefer deposition method. Measurement of the electro-optic coefficient has been carried out using a simple reflection techique. The E/O coefficient was found to be 154.9 pm/V and that value remained stable for at least 50 days.

• Fibers and Polymers
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• 제4권4호
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• pp.188-194
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• 2003

Phase behavior and spinodal phase separation kinetics in binary blends of a random copolymer of vinylidene fluoride and trifluoroethylene (75/25) [P(VDF/TrFE)] and poly(l,4-butylene adipate) (PBA) have been investigated by means of optical microscopic observation and time-resolved light scattering. The blends exhibited a typical lower critical solution temperature (LCST)∼${34}^{\circ}C$ above the melting temperature of the P(VDF/TrFE) crystals over the entire blend composition range. P(VDF/TrFE) and PBA were totally miscible in the temperature gap between the melting point of P(VDF/TrFE) and the LCST. Temperature jump experiments of the 3/7 P(VDF/TrFE)/PBA blend were carried out on a light-scattering apparatus from a single-phase melt state (${180}^{\circ}C$) to a two-phase region (205∼${215}^{\circ}C$). Since the late stage of spinodal decomposition (SD) is prevalent in the 3/7 blend, SD was analyzed using a power law scheme. Self-similarity was preserved well in the late stage of SD in the 3/7 blend.

• 비파괴검사학회지
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• 제32권5호
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• pp.585-596
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• 2012

PVDF와 P(VDF-TrFE)로 대별되는 압전고분자는 종래의 대표적인 압전재료인 PZT에 비해 전기음향변환효율이 떨어지며 내부손실이 큰 단점은 있으나, 음향임피던스가 물 또는 생체와 비슷하고 수신효율이 우수하며 광대역 특성을 나타내는 등의 장점을 가진 재료이다. 또한 다른 압전재료에 비해 얇은 막으로의 제작이 쉽고, 그 막은 유연하므로 복잡한 곡면을 갖는 고주파 초음파 트랜스듀서 재료로 유용하다. 그러한 특성은 생의학적 응용에 적합한바, 다양한 형태의 초음파 트랜스듀서가 연구 개발되어져 왔다. 본 논문에서는 먼저, 압전고분자막을 이용하여 초음파 트랜스듀서를 설계 제작하는데 있어서 고려해야할 몇 가지 주요사항을 기술하고, KLM 모델을 사용한 해석을 통하여 그 고려사항들이 트랜스듀서의 동작에 미치는 영향을 파악하였다. 다음으로, 의학적 또는 생물학적 응용을 목적으로 초음파 영상을 얻고 있는 몇몇 주요 응용분야에서 사용되는 압전고분자 트랜스듀서의 구조와 그것을 이용하여 얻은 영상의 특징에 대하여 간략히 해설하였다.

• 반도체디스플레이기술학회지
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• 제19권4호
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• pp.84-87
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• 2020

The properties of ultra-thin two-dimensional (2D) organic ferroelectric Langmuir-Blodgett (LB) films of the poly(vinylidene fluoride-trifluoroethylene) [P(VDF-TrFE)] were investigated to find possible applicability in flexible and wearable electronics applications. In the C-V characteristics of the MFM capacitor of 2-monolayer of 5 nm films, a butterfly hysteresis curve due to the ferroelectricity of P(VDF-TrFE) was confirmed. Typical residual polarization value was measured at 2μC/㎠. When the MFM capacitor with ultra-thin ferroelectric film was measured by applying a 10 Hz bipolar pulse, it was shown that 65% of the initial polarization value in 105 cycles deteriorated the polarization. The leakage current density of the 2-monolayer film was maintained at about 5 × 10-8 A/㎠ for the case at a 5MV/cm electric field. The resistivity of the 2-monolayer film in the case at an electric field at 5 MV/cm was more than 2.35 × 1013 Ω·cm.

• Korean Membrane Journal
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• 제10권1호
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• pp.20-25
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• 2008

Proton conducting composite membranes were prepared by solution blending of poly(vinylidene fluoride-co-chlorotrifluoroethylene)-graft-poly(sulfopropyl methacrylate) (P(VDF-CTFE)-g-PSPMA) graft copolymer and heteropolyacid (HPA). The P(VDF-CTFE)-g-PSPMA graft copolymer was synthesized by atom transfer radical polymerization (ATRP) using direct initiation of the secondary chlorines of P(VDF-CTFE). FT-IR spectroscopy revealed that HPA nanoparticles were incorporated into the graft copolymer via hydrogen bonding interactions. The water uptake of membranes continuously decreased with increasing HP A concentration up to 45wt%, after which it slightly increased. It is presumably due to the decrease in number of water absorption sites due to hydrogen bonding interaction between the HP A particles and the polymer matrix. The proton conductivity of membranes increased with increasing HPA concentration up to 45wt%, resulting from both the intrinsic conductivity of HP A particles and the enhanced acidity of the sulfonic acid of the graft copolymer.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1996년도 하계학술대회 논문집 C
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• pp.1472-1475
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• 1996

D-E hysteresis loops have been measured for the 65/35 mole % copolymer of vinylidene fluoride and trifIuoroethyIene over wide temperature range. The results were analyzed and discussed. The remanent polarization and the coercive field at room termperature were estimated to be 75 $mC/m^3$ and 55 MV/m respectively. D-E hysteresis loops were observed even below the glass transiation temperature$-20^{\circ}C$) and the remanent polarization and the coercive field were larger than larger, as the temperature lower. It seems that the remanent polarization and the coercive field depend on the amorphous region as well as crystalline region in this copolymer. And the ferroelectric-to-paraelectric phase transition was observed at $90^{\circ}C$ on heating and $80^{\circ}C$ on cooling. Double hysteresis loops were observed at the temperature($85^{\circ}C$) of paraelectric phase.

• 한국전기전자재료학회논문지
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• 제27권3호
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• pp.184-188
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• 2014

The electro-optic properties in Langmuir Blodgett films of poly (vinylidene fluoride trifluoroethylene) are investigated in the crossover region between two and three dimensions. The absence of finite size effect is observed in the films thinner than 20 nm, which confirms that these films are two dimensional ferroelectrics. The copolymer LB film of P(VDF-TrFE) exhibits the largest electro-optic response(26 pm/V) at 10 layer thickness. The cross-over behavior of electro-optic effect around the 10 layer thickness was discussed with the formation of nanomesa after thermal annealing.

• E2M - 전기 전자와 첨단 소재
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• 제10권2호
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• pp.156-165
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• 1997

D-E hysteresis loops have been measured for the 65/35 mole % copolymer of vinylidene fluoride and trifluoroethylene over wide temperature range. The remanent polarization and the coercive field at room temperature were estimated to be 75 mC/m$^{2}$ and 55 MV/m respectively. D-E hysteresis loops were observed even below the glass transition temperature(-20.deg. C) and the remanent polarization and the coercive field were larger, as the temperature lower. It seems that the remanent polarization and the coercive field depend on the amorphous region as well as crystalline region in this copolymer. And the ferroelectric-to-paraelectric phase transition was observed at 90.deg. C on heating and 80'C on cooling. Double hysteresis loops were observed at the temperature(85.deg. C) of paraelectric phase.

• Composites Research
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• 제17권4호
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• pp.61-67
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• 2004

Micromechanical 시험법과 음향방출을 이용하여 단일 basalt 섬유 강화 에폭시 복합재료의 비파괴 손상감지능을 평가하였다. 음향방출 센서로는 PZT 및 고분자 PVDF와 P(VDF-TrFE)를 사용하였고 단섬유 강화 시험법에서 각 센서 종류에 따른 손상감지능을 상호 비교하였다. 고분자 센서는 시편 표면에 부착시키거나 내부에 함침시켜 사용하였지만 PZT 센서는 표면에 부착하여 사용하였다. 고분자 센서를 시편 표면에 부착시킨 경우와 함침시킨 경우 감지능은 비슷하였지만 부착의 경우 debonding 신호가 많아 함침 시키는 방법이 손상감지에 더 효과적이었다. 손상 감지능은 PZT센서가 가장 높았고, 함침 및 부착 모두에서 PVDF와 P(VDF-TrFE) 센서의 손상감지능은 거의 비슷하였다.

• 멤브레인
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• 제20권1호
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• pp.1-7
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• 2010

원자전달 라디칼 중합을 이용하여 poly(styrene sulfonic acid) 47 wt%를 가진 poly(vinylidene fluoride-co-chlorotrifluoroethylene)-g-poly(styrene sulfonic acid) (P(VDF-co-CTFE)-g-PSSA) 가지형 공중합체를 합성하였다. 티타늄 아이소프로폭사이드(TTIP)와 가지형 공중합체를 졸-겔 공정을 통하여 $TiO_2$/가지형 공중합체 복합막을 제조하였다. TTIP는 가지형 공중합체의 친수성을 가진 PSSA 영역에만 선택적으로 결합하였으며 그곳에 $TiO_2$ 나노 입자가 형성되어 성장하였다. 이와 같은 결과를 적외선과 자외선 분광학으로 확인할 수 있다. 함수량과 이온 교환 능력 (IEC)는 TTIP의 함량에 따라 감소하였고 이것은 막이 가진 술폰산의 수가 감소하기 때문이었다. TTIP가 5 중량%일 때, 막의 기계적 강도는 증가하고 수소이온 전도도도 유지되었다.