• 제목/요약/키워드: value gap

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비정질 SeGe 박막의 PL 특성과 광흑화 효과에 관한 연구 (The Photoluminescence(PL) Spectroscopy and the Photo-Darkening(PD) Effect of the Amorphous SeGe Thin Films)

  • 김진우;이현용;정홍배
    • 한국전기전자재료학회논문지
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    • 제15권5호
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    • pp.435-440
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    • 2002
  • In this study, we have investigated photo-induced changes of optical energy gap( $E_{OP)}$ and photoluminescence (PL) in amorphous ($\alpha$-) S $e_{100-x}$G $e_{x}$ (x=5, 25 and 33) thin films prepared by conventional thermal evaporation method. In the $\alpha$-S $e_{100-x}$G $e_{x}$ thin film, the $E_{OP}$ is obtained by a linear extrapolation of the ($\alpha$hν)$^{\frac{1}{2}}$ versus hν plot to the energy axis using the optical absorption coefficient ($\alpha$) calculated from the extinction coefficient k measured in the wavelength range of 290~900nm. Although the values of $\Delta$ $E_{OP}$ are very different, all films exhibit photo-induced photo-darkening (PD) effect that is a red shift of $E_{OP}$ . In particular, $\Delta$ $E_{OP}$ in $\alpha$-S $e_{75}$ G $e_{25}$ thin film exhibits the largest value (i, e., $\Delta$ $E^{OP}$ ~40meV for $\alpha$-S $e_{95}$ G $e_{5}$ , $\Delta$ $E_{OP}$ ~200meV for $\alpha$-S $e_{75}$ G $e_{25}$ , $\Delta$ $E_{OP}$ ~130meV for $\alpha$-S $e_{67}$ G $e_{33}$ ). PL spectra in $\alpha$-SeGe by hν$_{HeCd}$ have no-Stokes shift (SS) and show a tendency dependent on both composition and illumination time. We explain the energy-induced phenomena such as the PD and thermal bleaching, the native charged-defect generation and the no-SS PL, etc..the PD and thermal bleaching, the native charged-defect generation and the no-SS PL, etc..tc..

산화 아연에서의 질소 용해도에 대한 알루미늄의 효과 : 밀도 범함수 이론 (Effect of Aluminum on Nitrogen Solubility in Zinc Oxide: Density Functional Theory)

  • 김대희;이가원;김영철
    • 한국재료학회지
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    • 제21권12호
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    • pp.639-643
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    • 2011
  • Zinc oxide as an optoelectronic device material was studied to utilize its wide band gap of 3.37 eV and high exciton biding energy of 60 meV. Using anti-site nitrogen to generate p-type zinc oxide has shown a deep acceptor level and low solubility. To increase the nitrogen solubility in zinc oxide, group 13 elements (aluminum, gallium, and indium) was co-added to nitrogen. The effect of aluminum on nitrogen solubility in a $3{\times}3{\times}2$ zinc oxide super cell containing 72 atoms was investigated using density functional theory with hybrid functionals of Heyd, Scuseria, and Ernzerhof (HSE). Aluminum and nitrogen were substituted for zinc and oxygen sites in the super cell, respectively. The band gap of the undoped super cell was calculated to be 3.36 eV from the density of states, and was in good agreement with the experimentally obtained value. Formation energies of a nitrogen molecule and nitric oxide in the zinc oxide super cell in zinc-rich conditions were lower than those in oxygen-rich conditions. When the number of nitrogen molecules near the aluminum increased from one to four in the super cell, their formation energies decreased to approach the valence band maximum to some degree. However, the acceptor level of nitrogen in zinc oxide with the co-incorporation of aluminum was still deep.

류별 살풀이춤에 나타난 미적 특이성에 관한 고찰 -호남지역을 중심으로 (A Study on the Aesthetic Singularity in the Salpuri Dance by Types - Focused on Honam Region)

  • 최지원
    • 한국콘텐츠학회논문지
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    • 제21권5호
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    • pp.170-181
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    • 2021
  • 본 연구는 예향 호남지역에서 전승되고 있는 전통춤 중에 류별 살풀이춤들은 호남 지역의 문화적 양상에 어떠한 영향을 받았는가를 도출하고 그 미적 특이성을 제시하는데 본 연구의 목적이 있다. 연구방법으로는 호남춤의 지역적 특성과 호남지역 교방에 뿌리를 두고 계승·발전되고 있는 이매방, 최선, 장금도, 조갑녀 살풀이춤의 구성 형태를 살펴보고 작품구성에 대한 분석을 통해 호남춤의 정통성과 춤 성향을 알아보고 이를 통해 호남지역 살풀이춤의 예술적 독창성과 호남춤으로서의 명맥, 그리고 전승과 창조적인 발전을 지역적 특수성과 연관 지어 보고자 진행하였다. 이러한 호남 지역의 대표적인 살풀이춤을 통해 지역문화의 배경을 이해하고 문화적 가치를 생성해 내는 작업은 지역의 무형유산으로서 본질적 가치를 높이기 위한 성찰의 시도라고 할 수 있다.

Issues on Particular Market Situation to Calculate Dumping Margin of Korean Steel Products by the USA

  • Wang, Jingjing;Choi, Chang Hwan
    • Journal of Korea Trade
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    • 제25권1호
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    • pp.89-111
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    • 2021
  • Purpose - The U.S. Trade Preference Expansion Act (TPEA) of 2015 enables the US Department of Commerce (DOC) to inflate dumping margin when the particular market situation (PMS) exists in the exporter's home market. DOC applied PMS provisions to the steel products from Korea. This paper analyzes whether DOC's calculation by using the regression analysis is consistent with WTO rules. Design/methodology - This paper analyzes the PMS application in law and regression analysis that extends the data period from 10 years to 18 years using the same economic model with DOC, and changes the country group according to the quantities of steelmaking capacity. Findings - Results show that DOC's argument conflating the sales-based with cost-based PMS designed to inflate dumping margins might not be consistent with WTO Antidumping Agreement Article 2.2 and 2.2.1.1 in which costs shall normally be calculated on the basis of records kept by the exporter, providing generally accepted accounting principles and reasonably reflection of the costs and PMS that exists in the Korean steel product markets. Even if it will be consistent, DOC's calculated margin by the regression analysis using a 10-year data is a big gap (5 times) compared with an 18-year data projection and different countries' data through the same methodology, which is a huge gap of regression coefficient. It means that dumping margin would be very wide range from 7.8% to 38.54% and unstable to calculate. Inflating dumping margin by DOC using regression analysis would not only be inconsistent with WTO rules, but also projection result is unreliable. Originality/value - Literature papers have mainly analyzed WTO law itself. This paper however, would be the first attempt to analyze the DOC's new way of dumping margin calculation in both manners of law and an empirical methodology perspective at the same time.

타설시간차에 의한 고로슬래그 미분말의 치환율별 매스콘크리트의 온도특성 (Effect of Various Partial Replacements of Cement with Blast Furnace Slag and Different Placing Times on Thermal Properties of Mass Concrete and Modeling Work)

  • 김종
    • 대한건축학회논문집:구조계
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    • 제35권10호
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    • pp.207-215
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    • 2019
  • The aim of the research is analyzing the simple adiabatic temperature rising properties and the heat of hydration based on different placing timing of the mass concrete depending on various replacing ratios of blast furnace slag to comparative analyze the thermal cracking index and cracking possibility. As a result from the experiment, a suggested adiabatic temperature rising equation based on various blast furnace slag replacing ratios can be provide favorable correlation with over 0.99 of $R^2$ value by applying the initial induction period. With this relationship, more accurate prediction of the amount of the hydration heat rising and heating timing, and it is known that there is an approximately $13.1^{\circ}C$ of gap between plain concrete without blast furnace slag and concrete with 80 % of replacing blast furnace slag. To control the setting time and heat rising gap, the mix designs between top and bottom concrete casts were changed 15 cases, and D, E, H, I, and L models of controlling the heat of hydration showed 41.23 to $46.88^{\circ}C$ of core temperature and 0.98 to 1.27 of thermal cracking index. Therefore the cracking possibility was 15 to 52 % of favorable results of possibly controlling both the cracking due to the internal and external retainment and concrete temperature at early age.

지식정보화사회에서 SNS의 사회적 기능 향상에 따른 부작용 해결방안을 위한 멀티미디어 -리터러시 교육 법제화의 당위성에 관한 연구(Ajzen의 계획된 행위 이론을 기반으로) (Study on Justification of the Legislation of Multimedia -Literacy Education to Solve Side Effects of Improving Social Functions of SNS in the knowledge Information Society (Based on Ajzen's Theory of Planned Behavior))

  • 신승용
    • 문화기술의 융합
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    • 제7권3호
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    • pp.89-94
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    • 2021
  • 최근 우리나라는 정보통신기술의 발달 및 스마트폰 보급의 일반화로 인해 전통적인 매스미디어(신문, 라디오, 텔레비전)때와 달리 콘텐츠를 생산하고 소비하는 사람간의 경계가 사라지고 있으며, 개방형 서비스 플랫폼을 통해 개인마다 문제의식은 동일하지만 서비스유형이 다원화되면서 문제해결방법 또한 다양해지고 있다. 이처럼 뉴미디어 플랫폼 산업의 성장을 통한 부가가치 창출은 우리인간의 삶을 풍요롭게 만들어 줄 것으로 기대되고 있는 가운데, 이로인해 발생되는 사회적 부작용도 만만치 않을 것으로 예상되고 있다. 대표적인 예로 최근 정보격차로 인한 사회 계층간의 소통문제는 또 세대 간의 갈등으로 까지 이어지고 있으며, 이 같은 문제가 지속될 경우 국가·사회적 손실을 불러일으킬 수 있다. 따라서 본 논문에서는 정보격차 해결을 위한 정책적 노력 및 시너지 효과 극대화를 위한 멀티미디어 리터러시 교육 법제화 필요성을 심리적 모형을 통해 분석해보았다.

공중합 아라미드 중합체의 점도에 따른 기격습식 방사구금 유동 해석 연구 (A Study on the Flow Analysis of Air-gap Wet Spinneret according to the Viscosity of Copolymerized Aramid Polymer)

  • 여동현;이종혁;이준희;유성훈;박용태;성정훈;심지현
    • 한국염색가공학회지
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    • 제34권1호
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    • pp.27-37
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    • 2022
  • In this study, a study and interpretation of the spinning process in copolymerized aramid spinning was conducted. In order to proceed with the spinning process modeling and analysis, the spinning process was modeled through the physical property modeling of the spinning solution and the structural modeling of the spinneret, and structural stability and flow of the spinneret for this spinning were analyzed. After modeling the spinning solution and the spinneret in a virtual space, the pack pressure and flow rate when the spinning solution was discharged were simulated. Macroscopically, the structural stability of the spinneret was confirmed at the standard pack pressure (100 kg·f/cm2), and microscopically, the flow rate and pressure drop data of the spinning solution according to the L/D(Length (L)/Diameter (D)) value were analyzed. Based on the research and development of virtual engineering modeling and analysis, we present the possibility of changing the shape and mechanical properties of copolymer aramid fibers according to the spinning process.

음원 내 보컬 주파수 대역 분석에 기반한 음향기기 추천시스템 (A system for recommending audio devices based on frequency band analysis of vocal component in sound source)

  • 김정현;석철민;김민주;김수연
    • 한국산업정보학회논문지
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    • 제27권6호
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    • pp.1-12
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    • 2022
  • 음원 스트리밍 서비스와 Hi-Fi 시장이 성장함에 따라 다양한 음향기기들이 출시되고 있다. 이로 인해 소비자들의 제품 선택에 대한 폭은 넓어졌지만 자신의 음악적 취향과 일치하는 제품을 찾기는 더욱 어려워졌다. 본 연구에서는 사용자가 선호하는 음원으로부터 보컬 성분을 추출하고 이를 토대로 사용자에게 가장 적합한 음향기기를 추천하는 시스템을 제안하였다. 이를 위해 먼저 원본 음원을 Python의 Spleeter Library를 통해 분리하여 보컬 음원을 추출하고 제조사의 음향기기의 주파수 대역 데이터를 수집한 결과를 각각 격자 그래프로 나타내었다. 추출한 보컬 음원의 주파수 대역과 음향기기의 주파수 대역 측정치 데이터를 비교하기 위한 지표로서 Matching Gap Index(MGI)를 제안하였다. 산출된 MGI 값을 토대로 사용자 선호와의 유사도가 가장 높은 음향기기를 추천한다. 추천 결과는 음향 전문업체에서 제공하는 장르별 Equalizer 데이터를 이용하여 검증하였다.

STI의 Top Profile 개선 및 Gap-Fill HLD 두께 평가 (STI Top Profile Improvement and Gap-Fill HLD Thickness Evaluation)

  • 강성준;정양희
    • 한국전자통신학회논문지
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    • 제17권6호
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    • pp.1175-1180
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    • 2022
  • STI는 반도체 소자의 소형화 및 고집적화에 따른 광역 평탄화를 위한 공정 기술로써 많은 연구가 이루어져 왔다. 본 연구에서는 STI의 profile 개선을 위한 방법으로 STI 건식각 후 HF 용액에 의한 pad oxide 습식각과 O2+CF4 건식각을 제안하였다. 이 공정 기술은 기존의 방법보다 소자의 밀집도에 따른 패턴간의 프로파일 불균형과 누설전류의 개선을 나타내었다. 또한 동일한 STI 깊이와 HLD 증착를 갖는 디바이스에 대하여 CMP 후 HLD 두께를 측정한 결과 디바이스 밀도에 따라 측정값이 다르게 나타났고 이는 CMP 후 디바이스 밀도에 따른 질화막의 두께 차이 및 슬러리의 선택비에 기인됨을 확인하였다.

Growth and Characterization of a-Si :H and a-SiC:H Thin Films Grown by RF-PECVD

  • Kim, Y.T.;Suh, S.J.;Yoon, D.H.;Park, M.G.;Choi, W.S.;Kim, M.C.;Boo, J.-H.;Hong, B.;Jang, G.E.;Oh, M.H.
    • 한국표면공학회지
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    • 제34권5호
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    • pp.503-509
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    • 2001
  • Thin films of hydrogenated amorphous silicon (a-Si : H) and hydrogenated amorphous silicon carbide (a-SiC:H) of different compositions were deposited on Si(100) wafer and glass by RF plasma-enhanced chemical vapor deposition (RF-PECVD). In the present work, we have investigated the effects of the RF power on the properties, such as optical band gap, transmittance and crystallinity. The Raman data show that the a-Si:H material consists of an amorphous and crystalline phase for the co-presence of two peaks centered at 480 and $520 cm^{-1}$ . The UV-VIS data suggested that the optical energy band gap ($E_{g}$ ) is not changed effectively with RF power and the obtained $E_{g}$(1.80eV) of the $\mu$c-Si:H thin film has almost the same value of a-Si:H thin film (1.75eV), indicating that the crystallity of hydrogenated amorphous silicon thin film can mainly not affected to their optical properties. However, the experimental results have shown that$ E_{g}$ of the a-SiC:H thin films changed little on the annealing temperature while $E_{g}$ increased with the RF power. The Raman spectrum of the a-SiC:H thin films annealed at high temperatures showed that graphitization of carbon clusters and microcrystalline silicon occurs.

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