• 제목/요약/키워드: unsymmetrical form

검색결과 12건 처리시간 0.025초

Synthesis and Catalytic Properties of Ruthenium(Ⅲ) Unsymmetrical Schiff Base Complexes

  • Yeo Hwhan-Jin;Lim Jong-Wan
    • Bulletin of the Korean Chemical Society
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    • 제13권3호
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    • pp.265-268
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    • 1992
  • Ruthenium(III) unsymmetrical Schiff base complexes, $[Ru(CHBPH-TP)Cl_2]$ and $K[Ru(CHBPH-HB)Cl_2]$ were synthesized, where CHBPH-TP and CHBPH-HB are 5-chloro-2-hydroxybenzophenonethiophencarba aldehydephenylenediimine and 5-chloro-2-hydroxybenzophenonehydroxybenzophe nonephenylenediimine. These Schiff bases were obtained from the reactions of 5-chloro-2-hydroxybenzophenone (CHB) and 2-thiophenecarbaldehyde (TP) or hyroxybenzophenone (HB) and 1,2-diaminobenzene. Elemental analysis, conductivity and infrared studies of the complexes suggest an octahedral geometry around ruthenium. Magnetic moments of the complexes indicate a single unpaired electron in alow spin $d^5$ configuration. The complexes are capable of catalyzing the oxidation of styrene with sodium hypochlorite in the presence of phase transfer agent. Oxidative cleavage of C=C bond is the major reaction pathway to form benzaldehyde for styrene oxidation.

의상 전문잡지를 통해 본 해체적 의상디자인 (A Study on Deconstructional Fashion Design Through Fashion Magazine)

  • 이순자;권미정;김주현
    • 한국의류산업학회지
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    • 제1권4호
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    • pp.349-357
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    • 1999
  • The purpose of this study was to examine how deconstruction, which currently had a great deal of influence on fashion, was actually accepted in view of fashion form or material. In order to track the tendency of deconstructional fashion, an attempt to find out what deconstructional methods were used in fashion design for each formative element was made by looking into earlier studies. Then an analysis was made over the recent fashion magazines. As a result of analyzing four fashion magazines, the most distinctive feature was found to be the use of seethrough cloth. In addition, unsymmetrical form also was immensely used. The next most frequently appeared form was layering, followed by slash or making a hole, lingerie look, padded cloth, indeterminate form, wrinkled cloth and patchworked cloth in the order named. The dominant layering style, the most widely used deconstructional fashion, was that inner cloth could be seen through outer seethrough cloth. The most frequently employed deconstructional cloth was seethrough cloth. Rather than complete seethrough cloth, the shape of lace, net or pattern was employed largely, in which the body could be partially hidden. The most largely used deconstructional method was a slash or making a hole. Most slashes appeared on the front part of the body, to which seethrough stuff was attached in many cases. Based on the above mentional finding. 10 kinds of deconstructional design were proposed for each method.

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유기광전도재료 (OPC)용 비대칭 Squarylium계 색소의 합성과 광안전성 (Syntheses and Photostability of Unsymmetrical Squarylium Dyes for Organic Photoconductors(OPC))

  • 김성훈
    • 한국인쇄학회지
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    • 제12권1호
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    • pp.133-143
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    • 1994
  • A new photochromic spiroxazine dye having a pyridinium s-triazine moiety has been prepared. It shows a reversible photochemical color change from colorless to reddish-purple in ethanol solution. In ethanol solution the half life time of the open form was 150sec, which was shortened by raising temperature. Silica-immobilized spiroxazine(6). Fine power of silica-immobilized spiroxazine was changed intensely blue from colorless by U.V. light or sunlight.

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Bending and stability analysis of size-dependent compositionally graded Timoshenko nanobeams with porosities

  • Bensaid, Ismail;Guenanou, Ahmed
    • Advances in materials Research
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    • 제6권1호
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    • pp.45-63
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    • 2017
  • In this article, static deflection and buckling of functionally graded (FG) nanoscale beams made of porous material are carried out based on the nonlocal Timoshenko beam model which captures the small scale influences. The exact position of neutral axis is fixed, to eliminate the stretching and bending coupling due to the unsymmetrical material change along the FG nanobeams thickness. The material properties of FG beam are graded through the thickness on the basis of the power-law form, which is modified to approximate the material properties with two models of porosity phases. By employing Hamilton's principle, the nonlocal governing equations of FG nanobeams are obtained and solved analytically for simply-supported boundary conditions via the Navier-type procedure. Numerical results for deflection and buckling of FG nanoscale beams are presented and validated with those existing in the literature. The influences of small scale parameter, power law index, porosity distribution and slenderness ratio on the static and stability responses of the FG nanobeams are all explored.

한국산 Epistylis속 섬모충류의 2미기록종(섬모충문: 소막충강: 주모목) (Two Newly Recorded Epistylis Ciliate Species (Ciliophora: Oligohymenophora: Peritrichida) from Korea)

  • Youn Kyung Cho;Mann Kyoon Shin
    • Animal Systematics, Evolution and Diversity
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    • 제19권2호
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    • pp.237-244
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    • 2003
  • 울산 인근의 연못 가장자리 수초에서 채집된 섬모충류가 겹가지섬모충과 (Epistylidae)에 속하는 겹가지섬모충(Epistylis plicatilis Ehrenberg, 1831)과 빈겹가지섬모충 (E. hentscheli Kahl, 1935)으로 각각 동정되어 재기재하였다. 이 종들은 한국에서 처음 보고되는 종들로서 생체표본과 protargol로 염색한 표본에 근거하여 재기재하였다. 원기재와 유사종들과 비교하였는데 겹가지섬모충 (E. plicatilis)은 가늘고 긴 깔대기 형태를 가지며 줄기는 근섬유로 속이 찬 형태이다. 반면에 빈겹가지섬모충 (E. hentscheli)는 비대칭의 종 모양을 띠며 줄기는 속이 텅 빈 형태이다.

수면상 단분자막의 변위전류 (Displacement current of monolayer film on the water surface)

  • 송경호;박태곤;박근호
    • E2M - 전기 전자와 첨단 소재
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    • 제9권7호
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    • pp.674-679
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    • 1996
  • Using the home made Kuhn type LB (Langmuir - Blodgett) film's deposition apparatus, We measured the displacement current of monolayer film on the water surface. The obtained displacement current had each different pattern by the kind of solution while varying pressure of the monolayer. Solution of 4 - octyl - 4' - (5 - carboxyl - pentamethyleneoxy ) - azobenzene (8A5H) and stearic acid (CH$_{3}$(CH$_{2}$)$_{16}$COOH) (C18) were spreaded at the air water interface respectively, and the current induced by the dynamic behavior of molecules were pressed by barrier. Displacement current of 8A5H measured small current than C18 at same condition and it was positive direction when increasing pressure but it was negative direction when decreasing pressure. Also, Two patterns of displacement current were symmetrical form and appeared repeatedly. The C18 has unsymmetrical form of displacement current and weak current when decreasing pressure (expansion). The C18 molecules have two distinct peak values of displacement current that show that the orientations of molecules were changed largely at this points. From these results, we obtained that the 8A5H has more elasticity than the C18.8.C18.

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현대 복식 디자인에 나타난 해체주의적 표현과 그 수용에 관한 연구 (A Study on Deconstructional Methods in Mordern Fashion Design and Consumer Acceptance)

  • 김주현;권미정;이순자
    • 복식문화연구
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    • 제7권4호
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    • pp.80-98
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    • 1999
  • The purpose of this study was to examine what consumers virtyally thought about deconstructional method used in fashion and its cloths. For attaining the purpose, earlier studies were reviewed to see what kind of deconstructional methods were used in fashion and its cloth, and questionnaire survey was carried out based on the result. 10 kinds of deconstructional method were surveyed : indeterminate form, lingerie look, layering, unsymmetrical form, seethrough cloth, slash or making a hole, fray, padded cloth, patchworked cloth, and wrinkled cloth. There appeared 6 kinds of image for deconstructional fashion, esthetics, womanliness, youth, elegance, uniqueness, and fashionability. Consumers considered most deconstructional fashion to be unique but unique but lack elegance. However, they didn\`t feel indeterminate form, fray or padded cloth was unique, and one notable thing was that they had an impression wrinkled cloth was graceful. The design assessed to be generally esthetic was lingerie look, laying, seethrough cloth and wrinkled cloth. Those who were older set more esthetic value on layering, seethrough cloth, fray, padded cloth and wrinkled cloth. On the contrary, they didn\`t have a good impression from slash, making a hole or patchworked cloth. As a result of investigating the subjects\` willingness to wear deconstructional design, there was deconstructional design which they might possibly put on, and those who were older found more difficulties in wearing ir. Toward indeterminate and layering fashion, younger people whose age was ranged from 18 to 22 or from 18 to 22 or from 23 to 27 showed particularly better response. Married woman wanted to wear wrinkled cloth, and considered it possible to put on seethrough design more than unmarried women. Rather, younger people were more unwilling to wear seethrough design.

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유한요소법을 이용한 브러시레스 DC 모터의 특성 해석에 관한 연구 (A Study on the Characteristic Analysis of Brushless DC Motor Using FEM)

  • 정신영;송유석;이주;장석중;박건희
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2002년도 하계학술대회 논문집 B
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    • pp.920-922
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    • 2002
  • This paper investigates the cogging torque reduction in a brushless DC(BLDC) motor having an inner-rotor with surface-mounted segment-type permanent magnets. The kind of magnets for the BLDC motor could have different waveforms of magnetization such as square, trapezoidal and sinusoidal form. This paper discusses the effect of the unsymmetrical magnetization distribution in the segment-type permanent magnet, which is able to obtain through a segment structure that the number of poles per segments is 2 ($N_p/N_s$), on the cogging torque and EMF waveform. Where the existing magnetizer fixture for the square-type magnetization is used to magnetize the magnets in two segment structures of $N_p/N_s$ = 1 and 2. The effectiveness of the proposed designs had been confirmed by comparing cogging torque, and EMF waveform between conventional and new models which are analyzed by Finite Element Method (FEM).

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투명성을 이용한 현대 패션디자인의 미적 특성 (Aesthetic Characteristics of Modern Fashion Design with Emphasis on Transparency)

  • 김선영
    • 대한가정학회지
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    • 제46권8호
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    • pp.17-26
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    • 2008
  • The purpose of this study was to identify the aesthetic characteristics of modern fashion design use with a particular focus on transparency, and to help create future vision and feature. As part of the methodology for this study, I examined the concept of transparency, its characteristics and how it was expressed through art, architecture and other designs using literature research. Furthermore, I performed justifiable analysis on modern fashion design which used transparency from the 1990s till present. The following concepts were deciphered from information: Firstly, the concept of purity was highlighted. The emphasis here was to enhance the body's natural beauty with simple silhouettes that do not restrict its curves, using light materials such as clear vinyl, semi-clear materials or thin chiffon. Secondly, to express sensuality by exposing the body's curves with tight wrapping using clear materials, or with indirect and symbolic see-through techniques using contrasting clear, semi-clear and opaque materials. Thirdly, to express futurism through cyber and electronic images using high tech or shiny materials such as metal or holograms. Mechanical movements or effects of light are also used. Fourthly, to express playful characteristic by promoting surprises and disharmony that contradict with traditional techniques. This is carried out by intentionally exaggerating certain portions of clothes through disorder elements or confusion, and unsymmetrical shapes which destruct the human body's normal form.

면외변형하의 압전재료에 대한 침투 쐐기균열 (A Permeable Wedge Crack in a Piezoelectric Material Under Antiplane Deformation)

  • 최성렬;박재학
    • 대한기계학회논문집A
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    • 제39권9호
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    • pp.859-869
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    • 2015
  • 횡등방성 압전재료에 기하학적 비대칭인 쐐기균열문제를 해석하였다. 기계적 집중면외하중과 전기적 집중 면내하중이 쐐기표면 점에 작용하고 있고, 반면에 균열면 한점에는 기계적 집중하중만 작용한다. 균열면은 침투형 얇은 슬릿으로 가정하여, 전기변위의 수직성분 및 전위가 균열면을 가로질러 연속으로 두었다. Mellin 변환을 사용하여 문제를 수식화하고, Wiener-Hopf 식을 유도하였다. 이 식을 풀므로써 폐형으로 주어지는 해를 얻었다. 임의 균열길이나 경사각, 쐐기각에 대해서도 적용이 가능한 응력 및 전기변위 강도계수를 구하였다. 장의 강도계수들은 전기적 하중에는 무관하고, 전기변위강도계수는 응력강도계수만의 함수로 표현되었다. 전기장 강도계수는 영으로 계산되었다. 또한 에너지방출률을 얻었다. 이 해는 중첩에 의하여 임의로 분포하는 전기기계하중문제에 대한 해를 제공하는 기본해로 사용될 수 있다.