• Title/Summary/Keyword: type of a ring

Search Result 900, Processing Time 0.022 seconds

Characteristics and Ring-Opening Isomerization Polymerization of 2-(1,3,3-Trimethyl-6-azabicyclo[3,2,1]-oct-6-yl)-4,5-dihydro-1,3-oxazoline (TAO) (2-(1,3,3-Trimethyl-6-azabicyclo[3,2,1]-oct-6-yl)-4,5-dihydro-1,3-oxazoline(TAO)의 개환이성화중합과 특성평가)

  • Lee, Chan-Woo;Chung, Jin-Do
    • Polymer(Korea)
    • /
    • v.36 no.3
    • /
    • pp.262-267
    • /
    • 2012
  • 2-(1,3,3-Trimethyl-6-azabicyclo [3,2,1]-oct-6-yl)-4,5-dihydro-1,3-oxazoline (TAO) was polymerized at several conditions to clarify the influence of initiators, alkyl halide ($PhCH_2Br$, $PhCH_2Cl$, MeI) and sulfonate (MeOTf). The reactions were conducted at $100^{\circ}C$ for 24 h. The resultant polymer forms several kinds of structures with different combination of initiators. The sole MeOTf initiator caused chain transfer reaction to form the one-order structure for which the resultant polymer exclusively formed pendant structure, while alkyl halide and MeOTf formed two kinds of structures, pendant and main chain, which is caused by partly-proceeded double isomerization polymerization by highly reactive nucleophilic counter anion of halogen. Merrifield polymer was also utilized as an intiator and copolymerized with TAO, which produced a graft structure.

Design of a Linear Ultrasonic Actuator for Small Lens Actuation (초소형 렌즈 구동을 위한 선형 초음파 구동기 설계)

  • Kwon, Tae-Seong;Choi, Yo-Han;Lee, Seung-Yop
    • Transactions of the Society of Information Storage Systems
    • /
    • v.2 no.4
    • /
    • pp.251-256
    • /
    • 2006
  • There is a great demand of micro-actuators for mobile information devices such as SFF optical drives and mobile phone cameras. However, the magnetic coils used in conventional electromagnetic motors are a major obstacle for the miniaturization because of their complicated structures and large power consumption. In this paper, a linear ultrasonic motor to actuate focusing lens of mobile devices is proposed. The new actuator uses a ring type bimorph piezoelectric material, and $d_{31}$ mode is adopted for applying linear motion. The interaction between inertia force and friction force makes linear motion by high-frequency saw signal input. The saw signal gives steady forces on the one direction by asymmetric inclination property of the signal itself on time domain. A commercial FEM(ANSYS) was used in this investigation for simulating structural analysis, identification of dynamic property, such as resultant displacement and coupled analysis with piezoelectric material. To evaluate the performance of the new design, a prototype was manufactured and experiments were carried out. Experimental results show the actuator motion of 5.4 mm/s at 10V saw signal of 41 kHz.

  • PDF

HILBERT FUNCTIONS OF STANDARD k-ALGEBRAS DEFINED BY SKEW-SYMMETRIZABLE MATRICES

  • Kang, Oh-Jin
    • Journal of the Korean Mathematical Society
    • /
    • v.54 no.5
    • /
    • pp.1379-1410
    • /
    • 2017
  • Kang and Ko introduced a skew-symmetrizable matrix to describe a structure theorem for complete intersections of grade 4. Let $R=k[w_0,\;w_1,\;w_2,\;{\ldots},\;w_m]$ be the polynomial ring over an algebraically closed field k with indetermiantes $w_l$ and deg $w_l=1$, and $I_i$ a homogeneous perfect ideal of grade 3 with type $t_i$ defined by a skew-symmetrizable matrix $G_i(1{\leq}t_i{\leq}4)$. We show that for m = 2 the Hilbert function of the zero dimensional standard k-algebra $R/I_i$ is determined by CI-sequences and a Gorenstein sequence. As an application of this result we show that for i = 1, 2, 3 and for m = 3 a Gorenstein sequence $h(R/H_i)=(1,\;4,\;h_2,\;{\ldots},\;h_s)$ is unimodal, where $H_i$ is the sum of homogeneous perfect ideals $I_i$ and $J_i$ which are geometrically linked by a homogeneous regular sequence z in $I_i{\cap}J_i$.

Emulsion Polymerization of Octamethylcyclotetrasiloxane under Ultrasonic Irradiation (고강도 초음파를 이용한 Octamethylcyclotetrasiloxane의 에멀전 중합)

  • Kim, Jihye;Kim, Yubin;Kim, Hyungsu
    • Applied Chemistry for Engineering
    • /
    • v.20 no.3
    • /
    • pp.322-328
    • /
    • 2009
  • Emulsion polymerization of octamethylcyclotetrasiloxane (OMCTS) was conducted under ultrasonic irradiation. Two sources of ultrasound with different intensities and frequencies of 20 KHz and 40 KHz were used for horn and bath type reactor, respectively. A combined process of horn and bath was also investigated. The effectiveness of the reaction systems was investigated by measuring conversion as well as intrinsic viscosity of the products. The influence of reaction temperature and sonication time on the progress of sonochemical polymerization was examined. It was found that conversion of greater than 80% and high viscosity were achieved within a few minutes of sonication in a horn type reactor, however, conversion and viscosity showed maximum values depending upon the sonication time. In a bath type reactor where a relatively weak intensity was maintained, longer duration time of more than one hour of sonication was required to reach a high level of conversion and viscosity. Compared with the horn type system, the conversion and viscosity in the bath type reactor were increased along with the sonication time. When the polymerization was carried out in a combined system of horn and bath, the evolution of conversion and molecular weight was quite different from the other cases. For the given geometry of reaction system, acoustic analysis using a commercial software was carried out and the results were correlated with experimental observation.

Design of a FFR-typed High Power Deep-water Sonar Transducer using a Coupled FE-BEM (결합형 유한요소-경계요소 기법에 의한 FFR 형태의 고출력 심해저용 쏘나 변환기 설계)

  • Jarng Soon Suck;Lee Je Hyeong;Ahn Heung Gu;Choi Heun Ho
    • Proceedings of the Acoustical Society of Korea Conference
    • /
    • spring
    • /
    • pp.224-227
    • /
    • 1999
  • A high power deep-water sonar transducer of FFR (Free Flooded Ring) type has been designed using a coupled FE-BEM. The present sonar transducer is composed of rectangular piezoelectric ceramics and pie-shaped steels (or the advantage of simple fabrication. The dynamics of the sonar transducer is modelled in three dimensions and is analyzed with external electrical excitation conditions. Different results are available such as steady-state frequency response for TX and RX displacement modes, directivity patterns, back-scattering patterns, bandwidths, transmitting voltage responses and receiving sensitivity responses. The TV response shows a very high acoustic pressure of 150 dB/lV (ref $1{\mu}Pa$ at 1m) at 1900 Hz. This ultra high power response of the sonar transducer indicates a new possibility of the sonar transducer development.

  • PDF

Quantum-chemical Study of Effects of Alkoxy Substitution on the Conformations and Electronic Properties of Poly(p-phenylenevinylenes)

  • Hong, Sung Y.
    • Bulletin of the Korean Chemical Society
    • /
    • v.20 no.1
    • /
    • pp.42-48
    • /
    • 1999
  • We have performed a quantum-chemical investigation on the conformations and electronic properties of a variety of methoxy-substituted poly(p-phenylenevinylenes) (PPVs) to elucidate the effects of alkoxy substitution. Geometrical parameters for the polymers were fully optimized through Austin Model I (AM I) semi-empirical Hartree-Fock (HF) band calculations. Electronic properties of the polymers were obtained by applying the AM I optimized structures to the modified extended Huckel method. To confirm validity of the AM I conformational results, we also carried out ab initio HF calculations with the 6-31G (d) basis set for a variety of methoxy-substituted divinylbenzenes. It is found that the potential energy surfaces of alkoxy-substituted PPVs are quite shallow around the planar conformations, suggesting that the prepared films possess a variety of conformations with different torsion angle in the solid state, depending on the synthetic conditions. When two alkoxy groups are concurrently substituted at the adjacent sites in the phenylene ring, these groups are subject to rotating around the C(sp2)-O bonds by 70-80° to avoid the strong steric repulsion between them. Consequently, the overlap between the π-type p orbital of oxygen and the π molecular orbitals of the polymer decreases. This leads to a wide gap and a high oxidation potential for tetramethoxy-substituted PPV, compared to those of dialkoxy-substituted PPV.

Effect of Channel Variation on Switching Characteristics of LDMOSFET

  • Lee, Chan-Soo;Cui, Zhi-Yuan;Kim, Kyoung-Won
    • Journal of Semiconductor Engineering
    • /
    • v.3 no.2
    • /
    • pp.161-167
    • /
    • 2022
  • Electrical characteristics of LDMOS power device with LDD(Lightly Doped Drain) structure is studied with variation of the region of channel and LDD. The channel in LDMOSFET encloses a junction-type source and is believed to be an important parameter for determining the circuit operation of CMOS inverter. Two-dimensional TCAD MEDICI simulation is used to study hot-carrier effect, on-resistance Ron, breakdown voltage, and transient switching characteristic. The voltage-transfer characteristics and on-off switching properties are studied as a function of the channel length and doping levels. The digital logic levels of the output and input voltages are analyzed from the transfer curves and circuit operation. Study indicates that drain current significantly depends on the channel length rather than the LDD region, while the switching transient time is almost independent of the channel length. The high and low logic levels of the input voltage showed a strong dependency on the channel length, while the lateral substrate resistance from a latch-up path in the CMOS inverter was comparable to that of a typical CMOS inverter with a guard ring.

Experimental Distillation of Ethanol-Propanol Mixture Using a Horizontal Column (수평증류를 이용한 에탄올-프로판올 혼합물의 증류실험)

  • Kim, Byoung Chul;Kim, Young Han
    • Korean Chemical Engineering Research
    • /
    • v.51 no.1
    • /
    • pp.93-97
    • /
    • 2013
  • A lab-sized distillation experiment was conducted using small-size packings and a horizontal distillation column. The 6.7 mm Raschig ring type packings of stainless steel and a 40 mm glass column were used, and five independent electric heaters were installed in the axial direction to adjust the column inside temperature separately. The temperature was continuously distributed along the column length to provide equivalent equilibrium to the temperature for the separation. From the experimental results, a larger HETP of the column than the vertical distillation column was obtained, but it was found that the practical separation with proper processing capacity and separation efficiency was available.

Construction and Characterization of Travelling Wave Type Single Mode Fiber Laser Using a Fiber Grating (광섬유격자를 이용하는 진행파형 단일모드 광섬유레이저의 제작과 특성 측성)

  • 김택중;박희갑;이동한
    • Korean Journal of Optics and Photonics
    • /
    • v.6 no.4
    • /
    • pp.296-301
    • /
    • 1995
  • A single-mode erbium-doped fiber laser is constructed by using a intracore fiber Bragg grating and a unidirectional fiber loop mirror. The laser cavity is designed in such a way that the laser beam forms a travelling wave in the gain medium by placing the erbium-doped fiber inside the unidirectional loop and that the wavelength-selective feedback is made from the outside of the loop by a fiber grating with 0.2 nm reflection linewidth. An additional fiber ring resonator is constructed and used as an optical spectrum analyzer to observe the variation of the laser mode spectra. As the result, relatively stable single mode, single polarization output is observed for the most of the time except some mode hoppings in minute scale due to enviommental temperature variations. tions.

  • PDF

A Study on the 80V BICMOS Device Fabrication Technology (80V BICMOS 소자의 공정개발에 관한 연구)

  • Park, Chi-Sun;Cha, Seung-Ik;Choi, Yearn-Ik;Jung, Won-Young;Park, Yong
    • Journal of the Korean Institute of Telematics and Electronics A
    • /
    • v.28A no.10
    • /
    • pp.821-829
    • /
    • 1991
  • In this paper, a BICMOS technology that has CMOS devices for digital application and bipolar devices for high voltage (80V) analog applications is presented. Basic concept to design BICMOS device is simple process technology without making too many performance trade-offs. The base line process is poly gate p-well CMOS process and three additional masking steps are added to improve bipolar characteristics. The key ingredients of bipolar integration are n+ buried layer process, up/down isolation process and p-well base process. The bipolar base region is formed simultaneously with the region of CMOS p-well area to reduce mask and heat cycle steps. As a result, hFE value of NPN bipolar transistor is 100-150(Ic=1mA). Collector resistance value is 138 ohm in case of bent type collector structure. Breakdown voltage of BVebo, BVcbo and BVceo are 21V, 115V and78V respectively. Threshold voltage is ${\pm}$1.0V for NMOS and PMOS transistor. Breakdown voltage of NMOS and PMOS transistor is obtained 22V and 19V respectively. 41 stage CMOS ring oscillator has 0.8ns delay time.

  • PDF