• Applied Biological Chemistry
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• v.41 no.8
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• pp.611-612
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• 1998

The transition state analog for metal catalyzed hydrolysis of an ester through cooperative interactions between metal ions as Lewis acid and peroxide was discussed.

• Nuclear Engineering and Technology
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• v.41 no.1
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• pp.79-90
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• 2009

Verification of programmable logic controller (PLC) programs written in IEC 61131-3 function block diagram (FBD) is essential in the transition from the use of traditional relay-based analog systems to PLC-based digital systems. This paper describes effective use of the well-known verification tool VIS for automatic verification of behavioral equivalences between successive FBD revisions. We formally defined FBD semantics as a state-transition system, developed semantic-preserving translation rules from FBD to Verilog programs, implemented a software tool to support the process, and conducted a case study on a subset of FBDs for APR-1400 reactor protection system design.

• Journal of Life Science
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• v.9 no.2
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• pp.44-48
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• 1999

The ionization of tyrosine residue is known to be involved in the stabilization of transition-state in catalysis of astacin based upon the astacin-transition state analog structure. Two tyrosine residues, Tyr-216 and Tyr-219, are conserved in all MMPs related with astacin family, We replaced Tyr-216 and Tyr-219 into phenylalanine, respectively and the zinc binding properties, kinetic parameters, and pH dependence of each mutant are determined in order to examine the role of tyrosine residue in matrilysin catalysis. Both mutants contain two zinc atoms per mol of enzyme, indicating that either tyrosime does not affect the zinc binding property of the enzyme. Y216F and Y219F mutants are highly active and the kcat/Km values are only decreased 1.1-1.5-fold compared to the wild-type enzyme. The decrease in the activity of the mutants is essentially due to the increase in Km value. The pH dependencies of the kcat/Km values for both mutants are similar to the corresponding dependencies obtained with the wild type enzyme. The pKa values at the alkaline side of both mutants are not changed. These kinetic and pH dependence results indicate that the ionization of active site tyrosine residue of matrilysin is not reflected in the kinetics of peptide hydrolysin as catalyzed by astacin.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.17 no.2
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• pp.73-80
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• 2003

This Paper Proposes instantaneous following control method to control pulse modulation switching converter by using principle that reset time of integrator is inverse proportion in size of integrator input voltage. proposed control method acts of fixed frequency and control switch calculates time of become turn on and turn off using analog integrator. Duty ratio that express switching time of converter is depended on mean value of switching variable and following time consists in one cycle. Follow to do order exactly stationary state as well as transition state, and controller corrects mean value of control variable and control reference value and control as control error gets into zero. Proposed control method could experimented and know that experiment result and theory are agreeing well through this using the buck converter.

• KIEE International Transactions on Power Engineering
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• v.4A no.2
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• pp.79-83
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• 2004

A new small signal stability analysis method for eigenvalue analysis is presented. This method utilizes the Resistive Companion Form (RCF) for the computation of the transition matrix over a specified time interval, which corresponds to a single cycle operation of the system. This method is applicable to any system, with or without switching element. An illustrative example of the method is presented and the eigenvalues are compared with those of the conventional state space method (analog) in order to demonstrate the accuracy of the proposed eigenvalue analysis method. Also, the variations of oscillation modes that are caused by the switching operation can be precisely analyzed using this method.

• Journal of the Microelectronics and Packaging Society
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• v.26 no.1
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• pp.1-7
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• 2019

Recently, memristor (anion-based memristor) is referred to as the fourth circuit element which resistance state can be gradually changed by the electric pulse signals that have been applied to it. And the stored information in a memristor is non-volatile and also the resistance of a memristor can vary, through intermediate states, between high and low resistance states, by tuning the voltage and current. Therefore the memristor can be applied for analogue memory and/or learning device. Usually, memristive behavior is easily observed in the most transition metal oxide system, and it is explained by electrochemical migration motion of anion with electric field, electron scattering and joule heating. This paper reports the latest trends and issues of anion-based memristor.

• Journal of the Institute of Electronics Engineers of Korea SC
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• v.37 no.3
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• pp.55-62
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• 2000

This paper presents an analysis of the chaotic behavior in the discrete-time voltage mode chaotic generator fabricated using 0.8${\mu}{\textrm}{m}$ single poly CMOS technology. An approximated empirical equation is extracted from the measurement data of a nonlinear function block. Then the bifurcation diagram is simulated according to input variables and Lyapunov exponent λ which represent a dependence on an initial value is calculated. We show the interrelations among time waveforms, state transition, and power spectra for the state condition of chaotic circuit, such as equilibrium, periodic, and chaotic state. And results of experiments in the chaotic circuit with the $\pm$2.5V power supply and sampling clock frequency of 10KHz are shown and compared with the simulated results.

• Journal of the Institute of Electronics Engineers of Korea SD
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• v.41 no.11
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• pp.79-85
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• 2004

A digitally-controlled analog-block inevitably undergoes the bang-bang oscillations which may cause a big amplitudes of the glitches if the oscillation occurs at the MSB transition points of a binary counter. The glitch results into the jitter noise for the case of the DLL. In this paper, we devise a new counter code that has the hysteresis in the bit transitions in order to prevent the transitions of the significant counter-bits at the locking state. The maximum clock jitter is simulated to considerably reduce over the voltage-temperature range guaranteed by specifications. The counter is employed to implement the high speed packet-base DRAM and contributes to the maximized valid data-window.

• Journal of the Korean Chemical Society
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• v.48 no.5
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• pp.473-482
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• 2004

The homobimetallic anion, $M^+({\eta}^5-MeCp)Mn(CO)_2Mn(CO)_5^-(M^+=Na^+,\;PPN^+)$was disrupted by CH2CHCH2Cl in THF at various temperatures ($20^{\circ}C~50^{\circ}C$) under the pseudo 1st order reaction conditions where excess of allyl chloride was employed under a nitrogen atmosphere. This homobimetallic anion seems to be involved in a concerted reaction mechanism in which a four-centered transition state is proposed. After undergoing the transition state, this reaction eventually leads to (MeCp)Mn$(CO)_3$ on addition of CO and $({\eta}^1-allyl)Mn(CO)_5$, respectively. However, in case of $Na^+$ analog, $Na^+$ may play a novel counter ion effect on the disruption reaction either by transferring one terminal CO from the $Mn(CO)_5$ moiety on to the $({\eta}^5-MeCp)Mn(CO)_2$of the corresponding homobimetallic complex, eventually resulting in $({\eta}^5-MeCp)Mn(CO)_3$ or through the interaction between $Na^+$ and the leaving group (Cl) of allyl chloride. This reaction is of overall second order with respect to homobimetallic complex with the activation parameters (${\Delta}H^{\neq}=17.15{\pm}0.17kcal/mol,\;{\Delta}S^{\neq}=-9.63{\pm}0.10$ e.u. for $Na^+$ analog; ${\Delta}H^{\neq}=22.13{\pm}0.21 kcal/mol,\;{\Delta}S^{\neq}=9.74{\pm}0.19$ e.u. for $PPN^+$ analog reaction).

• Journal of Global Scholars of Marketing Science
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• v.18 no.2
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• pp.223-252
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• 2008

In this study, we attempt to propose a choice-based diffusion model with switching cost, which can be used to forecast the dynamic substitution and competition among previous and new products at both individual-level and aggregate level, especially when market data for new products is insufficient. Additionally, we apply the proposed model to the empirical case of substitution and competition among Analog Cable TV that represents previous fixed charged broadcasting service and Digital Cable TV and Internet Protocol TV (IPTV) that are new ones, verify the validities of our proposed model, and finally derive related empirical implications. For empirical application, we obtained data from survey conducted as follows. Survey was administered by Dongseo Research to 1,000 adults aging from 20 to 60 living in Seoul, Korea, in May of 2007, under the title of 'Demand analysis of next generation fixed interactive broadcasting services'. Conjoint survey modified as follows, was used. First, as the traditional approach in conjoint analysis, we extracted 16 hypothetical alternative cards from the orthogonal design using important attributes and levels of next generation interactive broadcasting services which were determined by previous literature review and experts' comments. Again, we divided 16 conjoint cards into 4 groups, and thus composed 4 choice sets with 4 alternatives each. Therefore, each respondent faces 4 different hypothetical choice situations. In addition to this, we added two ways of modification. First, we asked the respondents to include the status-quo broadcasting services they subscribe to, as another alternative in each choice set. As a result, respondents choose the most preferred alternative among 5 alternatives consisting of 1 alternative with current subscription and 4 hypothetical alternatives in 4 choice sets. Modification of traditional conjoint survey in this way enabled us to estimate the factors related to switching cost or switching threshold in addition to the effects of attributes. Also, by using both revealed preference data(1 alternative with current subscription) and stated preference data (4 hypothetical alternatives), additional advantages in terms of the estimation properties and more conservative and realistic forecast, can be achieved. Second, we asked the respondents to choose the most preferred alternative while considering their expected adoption timing or switching timing. Respondents are asked to report their expected adoption or switching timing among 14 half-year points after the introduction of next generation broadcasting services. As a result, for each respondent, 14 observations with 5 alternatives for each period, are obtained, which results in panel-type data. Finally, this panel-type data consisting of $4{\ast}14{\ast}1000=56000$observations is used for estimation of the individual-level consumer adoption model. From the results obtained by empirical application, in case of forecasting the demand of new products without considering existence of previous product(s) and(or) switching cost factors, it is found that overestimated speed of diffusion at introductory stage or distorted predictions can be obtained, and as such, validities of our proposed model in which both existence of previous products and switching cost factors are properly considered, are verified. Also, it is found that proposed model can produce flexible patterns of market evolution depending on the degree of the effects of consumer preferences for the attributes of the alternatives on individual-level state transition, rather than following S-shaped curve assumed a priori. Empirically, it is found that in various scenarios with diverse combinations of prices, IPTV is more likely to take advantageous positions over Digital Cable TV in obtaining subscribers. Meanwhile, despite inferiorities in many technological attributes, Analog Cable TV, which is regarded as previous product in our analysis, is likely to be substituted by new services gradually rather than abruptly thanks to the advantage in low service charge and existence of high switching cost in fixed charged broadcasting service market.