• 한국분말재료학회지
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• 제12권3호
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• pp.186-191
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• 2005

A formation of aluminum hydroxide by hydrolysis of nano and micro aluminum powder has been studied. The nano aluminum powder of 80 to 100 nm in diameter was fabricated by a pulsed wire evaporation (PWE) method. The micro powder was commercial product with more than $10\;{\mu}m$ in diameter. The hydroxide type and morphology depending on size of the aluminum powder were examined by several analyses such as XRD, TEM, and BET. The hydrolysis procedure of micro aluminum powder was different from that of nano aluminum powder. The nano aluminum powder after immersing in the water was transformed rapidly to a nano fibrous boehmite, accompanying with a remarkable temperature increase, and then further transformed slowly to a stable bayerite. However, the micro powder was changed to the stable bayerite slowly and directly. The formation of fibrous aluminum hydroxide from nano aluminum powder might be due to the fine cracks which were formed by hydrogen gas pressure on the surface hydroxide layer during hydrolysis. The nano powder with large specific surface area and small size reacted more actively and faster than the micro powder, and transformed to meta-stable hydroxide in relatively short reaction time. Therefore, the formation of fibrous boehmite is special characteristic of hydrolysis of nano aluminum powder.

• Journal of the Korean Data and Information Science Society
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• 제23권4호
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• pp.683-691
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• 2012

$4{\times}4$ 그레코라틴방격모형은 모집단의 분포에 상관없이 주효과 검정을 위한 순위변환 통계량의 검정력이 모수적 통계량의 검정력보다 전체적으로 높은 우위성을 갖는다. 효과크기가 균등간격이 아닌 경우에 주효과 검정을 위한 순위변환 통계량의 검정력은 효과크기가 균등간격인 경우보다 다소 낮지만 모수적 통계량의 검정력에 비하여 월등한 비교우위를 갖는다. 순위변환 통계량의 검정력은 블럭효과의 수가 줄어들거나 효과크기가 작아질수록 모수적 통계량의 검정력보다 월등히 우세함을 보인다. 블럭효과들이 존재할 때는 주효과에 비하여 블럭효과들이 모두 작거나 하나의 블럭효과에 편중된 경우에 순위변화 통계량의 검정력이 모수적 통계량의 검정력보다 더욱 우수하다. 이는 상호작용없이 다인자인 네 개의 주인자 및 블럭인자만으로 구성된 그레코라틴방격모형의 특성에 의한 결과로, 앞으로 구체화하지 못한 다인자로 구성된 요인실험계획모형 등에 확대 적용할 순위변환기법의 가능성을 제시한다.

• 대한전자공학회논문지SD
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• 제39권2호
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• pp.27-38
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• 2002

양자 우물 반도체 소자 모델링에 있어서 양자 우물의 다중 에너지 부준위 각각에 대한 Boltzmann 방정식의 해를 직접적으로 구하는 self-consistent한 방법을 개발하였다 양자 우물의 특성을 고려하여 Schrodinger 방정식과 Poisson 방정식 및 Boltzmann 방정식으로 구성된 양자 우물 소자 모델을 설정하였으며 이들의 직접적인 해를 유한 차분법과 Gummel-type iteration scheme에 의해 구하였다. Si MOSFET의 inversion 영역에 형성되는 양자 우물에 적용하여 그 시뮬레이션 결과로부터 본 방법의 타당성 및 효율성을 보여 주었다.

• Journal of Microbiology and Biotechnology
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• 제26권5호
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• pp.846-853
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• 2016

We displayed four types of Solanum nigrum metallothionein (SMT) for the first time on the surface of Saccharomyces cerevisiae using an α-agglutinin-based display system. The SMT genes were amplified by RT-PCR. The plasmid pYES2 was used to construct the expression vector. Transformed yeast strains were confirmed by PCR amplification and custom sequencing. Surface-expressed metallothioneins were indirectly indicated by the enhanced cadmium sorption capacity. Flame atomic absorption spectrophotometry was used to examine the concentration of Cd²⁺ in this study. The transformed yeast strains showed much higher resistance ability to Cd²⁺ compared with the control. Strikingly, their Cd²⁺ accumulation was almost twice as much as that of the wild-type yeast cells. Furthermore, surface-engineered yeast strains could effectively adsorb ultra-trace cadmium and accumulate Cd²⁺ under a wide range of pH levels, from 3 to 7, without disturbing the Cu²⁺ and Hg²⁺. Four types of surfaceengineered Saccharomyces cerevisiae strains were constructed and they could be used to purify Cd²⁺-contaminated water and adsorb ultra-trace cadmium effectively. The surface-engineered Saccharomyces cerevisiae strains would be useful tools for the bioremediation and biosorption of environmental cadmium contaminants.

• 한국분말재료학회지
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• 제10권5호
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• pp.305-309
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• 2003

We report on the formation and chemical leaching of non-equilibrium $Al_{0.6}(Fe_{75}Co_{25})$ alloy produced by rod milling. X-ray diffractometry, transmission electron microscopy, differential scanning calorimetry, scanning electron microscopy, and vibrating sample magnetometry were used to characterize the as-milled and leached specimens. After 400 h, only the $Al_{0.4}Fe_{0.6}$ peak of the body-centered cubic type was present in the XRD pattern. The entire rod milling process could be divided into three different stages of milling: agglomeration, disintegration, and homogenization. The saturation magnetization, $M_s$ decreased with increased milling time, the $M_s$ of the powders before milling was about 113.8 emu/g, the $M_s$ after milling for 400 h was about 11.55 emu/g. Leaching of the Al in KOH of the Al at room temperature from the as-milled powders did not induce any significant change in the diffraction pattern. After the leached specimen had been annealed at $600^{\circ}C$ for 1 hour, the nanoscale crystalline phases were transformed into the bcc Fe, cubic Co, and $CoFe_2O_4$ phases. On cooling the specimen from 85$0^{\circ}C$, the degree of magnetization increased slightly, then increased sharply at approximately 364.8$^{\circ}C$, indicating that the bcc $Al_{0.4}Fe_{0.6}$ phase had been transformed to the Fe and Co phases.

• 한국재료학회지
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• 제12권12호
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• pp.947-954
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• 2002

HCl concentration and reaction time are the decisive factors in determining the structure of precipitates in the process of synthesis of $TiO_2$ particles from aqueous $TiOCl_2$ solution by precipitation and the volumetric proportion of brookite phase in $TiO_2$ particles can be controlled by these two factors. As reaction rate increases with increase of reaction temperature, the reaction time, at which maximum volumetric proportion of brookite phase in $TiO_2$ particles was obtained, was reduced. The brookite was transformed directly to rutile phase with only increase of reaction time. And precipitation was delayed with increase of HCl concentration because the amount of $H_2$O, which is necessary source of oxygen for conversion of $Ti^{+4}$ to $TiO_2$, was relatively reduced with increase of that. Brookite in the mixture phase powder was finally transformed to rutile phase via anatase through heat-treatment.

• Journal of Welding and Joining
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• 제12권2호
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• pp.87-96
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• 1994

Correlation between microstructural features and segregation of elements (Si, Mn, P and S) near the mid of thickness in the base metal and the synthetic HAZ was investigated. Furthermore, the relationship between the degree of center segregation and weld cold cracking susceptibility in the thickness direction was also conducted by evaluating the effect of P concentration on the critical applied stress. The results obtained are as follows: 1) Pearlite band, containing the MnS type inclusion and a locally transformed structure with a higher hardness, was observed in the center segregation region. 2) By the weld thermal cycle, center segregation region was transformed to the white band which had a higher hardness than that of base metal due to a greater hardenability of concentrated Mn, P etc.. 3) Weld cold cracking susceptibility in the thickness direction was mainly dependent on the concentration of impurity elements rather than on the number of the segregated particles near the mid of thickness. 4) During welding, the higher concentrated region was easily changed into white band. Therefore, it could be predicted that the initiation and propagation of a cold crack would be promoted by increasing the restraint stress and hydrogen content.

• Bulletin of the Korean Chemical Society
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• 제33권7호
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• pp.2295-2298
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• 2012

We describe herein a three-dimensionally diverse micropatterning of poly(lactic acid), as a biopolymer, using 1-butyl-3-methylimidazolium-based room-temperature ionic liquids (bmim-based RTILs), [bmim]X (X = $SbF_6$, $PF_6$, $NTf_2$, Cl). Utilizing the hydrophobic bmim-based RTILs, [bmim]X (X = $SbF_6$, $PF_6$, $NTf_2$) and a phase separation technique, we were able to produce white and opaque membranes with a three-dimensional structure closely packed with particles ($10-50{\mu}m$ in diameter). The particlulate structure, made by the assistance of [bmim]$NTf_2$ and DCM, interestingly transformed to a fibrous structure by using a cosolvent, e.g., DCM/$CF_3CH_2OH$. When we used an increased amount of [bmim]$NTf_2$, the particles were effectively detached and macrosized ($100-500{\mu}m$ in diameter) and the oval-shaped beads were obtained in a powder form. By varying the counter-anion type of the imidazolium-based RTIL, for example from $NTf_2^-$ to $Cl^-$, the particulate 3D-morphology was once more transformed to a porous structure. These reserch results could be potentially useful, as a method to fabricate particulate scaffolds, fibrous or porous scaffolds, and beads as a biopolymer device in diverse fields including drug delivery, tissue regeneration, and biomedical engineering.

• Journal of Welding and Joining
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• 제31권6호
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• pp.37-43
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• 2013

This study targets to make clear the connection between MS (Martensite start) point and welding shrinkage. We approved that a Martensite-transformed weldment may not yield state under low MS point, but also admitted the limitation of numerical calculation by inherent strain approach or thermal strain approach. Therefore, new thermal strain formulae during cooling stages were made. As a thermal strain is obtained by integrating thermal extension coefficient, a constant of integration should be decided. In our suggested formulae, the origin was based on totally remained austenite, and added strain from volume changes in Martensite transformation was based on totally transformed ferrite. Through the suggested methodology, It is verified that an MS point under a critical temperature can let weld shrinkage relax and the critical value can be obtained. For supporting this process, 15 weld-consumables were made, were tested by fillet type and were measured. As a result, a positive correlation between MS point and level of weld-distortion was obtained, but it was rather weak.

• 자원환경지질
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• 제31권2호
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• pp.101-110
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• 1998

The purpose of this study is to elucidate the source of U anormaly formed in stream water of the drainage system around the Shinbo talc mine area based on the hydrochemical properties of water masses including surface water and groundwater. The hydrochemical properties of water masses in the Shinbo talc mine area are divide into three types; Type I : $Ca(Mg)SO_4$ type with high U content as shown in the stream water flowout from the mine, Type II : $Ca(HCO_3)_2$ type with high U content as in deep groundwater, Type III : $Ca(HCO_3)_2$, type with low U content as in the other stream water and shallow groundwater. It is necessary to emphasize that in deducing the uranium source, a distinct discrimination between type I and type II is showed in their hydrothermal properties in spite of commonly having a high uranium content, which in turn means the occurrence of a different water-rock interaction processes between both type. All evidences suggest that type II groundwater have acted as a primary media in the transport of uranium and that, as the groundwater flows through the talc mineralization zone, water composition of type II was transformed into that of type I water as the results of a secondary water rock interaction process, caused by imposition of new mineralogically controlled thermodynamic constraints. Consequently, in the viewpoint of hydrochemical exploration, the investigation of the hydrologic circulation system and the hydrogeologic properties for the aquifer of type II groundwater shall be done first of all and will provide a crucial clue on tracing the uranium mineralization zone occurred in the Shinbo talc mine area.