• 한국진공학회지
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• 제12권S1호
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• pp.10-14
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• 2003

Coatings of hydroxyapatite (HA) and tricalcium phosphate/HA (TCP/HA) on titanium were fabricated by ion beam assisted deposition (IBAD). Significant effect of the Ca-P coatings on human Gingival Fibroblasts (HGFs) attachment and formation of type I collagen were found by using immunofluorescence microscope. TCP/HA and HA coatings exerted more HGFs attachment and collagen I formation. Comparing with HA coating, TCP/HA coating exhibited better responses during the late period of the tests. This investigation indicated that this surface modification method may enhance the biological seal at the cervical level of the titanium dental implants.

• 한국표면공학회지
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• 제27권1호
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• pp.29-35
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• 1994

The effects of coating of 3$\mu\textrm{m}$ thickness on the mechanical property of alumina after heat treatment at 100$0^{\circ}C$ for 30minutes under $10^{-6}$torr vacuum was quantified in terms of modulus of rupture(MOR) using Weibull plot. While the copper coating did not change MOR of alumina due to the nonwetting behavior of Cu on $Al_2O_3$, the reactive titanium metal coating caused a noticeable 29% reduction in averaged MOr strength. This was related with the combined effects of microcracks in coating formed during heat treatment and good bonding character between Ti and $Al_2O_3$. The effect of cosputtering of Ti and Cu, bilayer coatings of Cu/Ti and Ti/Cu were also investigated. It was found that Ti, cosputtered, Cu/ti and Ti/Cu coatings reduced MOR strength of alumina in the order listed. This was correlated with the amount of Ti at coating/alumina inter-face associated with a coated layer or segregation of Ti during heat treatment.

• 한국표면공학회지
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• 제32권3호
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• pp.265-275
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• 1999

Titanium nitride and related overlayers produced by arc ion plating (AIP) are applied as commercial coatings in world-wide scale since the middle of 80s. Due to the achievements of low temperature deposition (LTD), they begin now to be used as wear and corrosion-resistant coatings for machine parts, besides applications on cemented carbide and high speed steel cutting tools. On the other side, TiN can be now applied successfully to brass, Al-alloy, ZnAl alloy articles as decorative coating through LTD. Various nitrides, carbonitrides, borides and other refractory compounds, such as (Ti, Al)N, TiCN, CrN, are used as the coatings for special heavy-duty working conditions instead of TiN since 90s. More and more multilayer coatings are applied now substituting single layer ones. Duplex processes are under development.

• 대한전자공학회:학술대회논문집
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• 대한전자공학회 2000년도 하계종합학술대회 논문집(2)
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• pp.60-63
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• 2000

We have investigated the relationship between electrical and morphological properties of titanium silicide films. In this study, the C54 titanium silicides were formed by using high temperature sputtering and one-step annealing. From the measurement of electrical and morphological properties, a smooth surface and a relaxed roughness were observed for the titanium silicide film fabricated by high temperature sputtering. And it seems that the previous effect could improve electrical properties.

• Journal of Electrochemical Science and Technology
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• 제8권4호
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• pp.294-306
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• 2017

Stainless steels and titanium alloys are widely used in the medical industry as replacement materials. These materials may be affected by the conditions and type of environment. In the same manner, soft drinks are widely consumed products. It is of interest for dental industry to know the behavior of medical-grade alloys when these are in contact with soft drinks, since any excessive ion release can suppose a risk for human health. In the present study, the electrochemical behavior of three stainless steel alloys and pure titanium was analyzed using three types of cola soft drinks as electrolyte. The objective of this study was to evaluate the response of these metallic materials in each type of solution (cola standard, light and zero). Different electrochemical techniques were used for the evaluation of the alloys, namely potentiodynamic polarization, linear polarization, and open-circuit potential measurements. The corrosion resistance of the stainless-steel alloys and titanium in the cola soft drinks was provided by the formation of a stable passive film formed by metal oxides. Scanning electron microscopy was used as a complementary technique to reveal corrosion phenomena at the surface of the materials evaluated.

• 소성∙가공
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• 제19권1호
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• pp.50-58
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• 2010

In order to successfully implement hot die forging process for the large-size titanium alloy products, it is necessary to devise a customized heating method for the billets and the die tools, as well as the die tool design. This study aims at establishing a hot die forging process of the large-size titanium alloy container products by applying the warm die, semi-hot die and hot die forging process step-wise. To accomplish this purpose, forging mechanism and the die tools were designed considering the strength of die materials at the given die heating temperature. The movable heating devices for the billet and the die tools were also introduced to prevent overcooling of billet and die tools. To verify the applicability of the designed forging process, real-size forging tests were carried out and the quality of forged products, including dimension, surface condition, microstructure and the mechanical properties was evaluated.

• 대한기계학회논문집B
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• 제29권7호
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• pp.854-860
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• 2005

Pool boiling heat transfer characteristics of R-134a were investigated in titanium plain and low finned tubes. The diameter of test tube was 15.88 mm and the fin density was 33 fpi. Tests were conducted at saturation temperatures of $20^{\circ}C$ and $30^{\circ}C$. Heat fluxes varied from 5000 W/$m^2$ to 50,000 W/$m^2$ based on surface area of the plain tube. The pool boiling heat transfer coefficients of the titanium horizontal plain tube are lower than those of the copper plain tube by $8.2\%$. The boiling heat transfer coefficients of the low finned tube are averagely higher than those of the plain tubes by $34\%$. The average deviation of the Slipcevic correlation from the present data for the low finned tube is $20\%$.

• Bulletin of the Korean Chemical Society
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• 제30권8호
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• pp.1798-1804
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• 2009

In this study, we have studied on improved performance of carbon nanotubes/titanium (CNT/TiO2) structure electrode for methylene blue (MB). The composite electrodes consisting of CNTs and a titanium oxide matrix with phenol resin binder was fabricated with a mixture method. The chemical and morphological structure of CNT/Ti$O_2$ composites were characterized by means of BET surface area, X-ray diffraction (XRD), scanning electron microscopy (SEM), UV-Vis absorption technique, Raman spectroscopy and energy dispersive X-ray (EDX). The electrode showed a remarkably enhanced performance for MB oxidation under UV illumination with or without electro-chemical reaction (ECR). Such a remarkably improved performance of the CNT/Ti$O_2$ structure electrode might be due to the enhanced MB oxidation by electro- and photo-generated electrons and holes in the CNTs and Ti$O_2$ under UV illumination with or without ECR.

• Elastomers and Composites
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• 제49권4호
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• pp.336-340
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• 2014

본 연구에서는 광촉매 작용을 하는 이산화티타늄 광촉매를 polyester 섬유에 코팅하여 탈취, 항균 및 자외선 차폐에 대한 기능을 부여하고 그 특성을 알아보았다. 그 결과 탈취성능은 세탁 전과 반복 20회 세탁 후에도 97%이상 저감되는 것으로 나타났으며, 항균성은 균수가 99.9%이상 감소되는 것으로 나타났다. 그리고 Polyester 섬유를 20회 반복 세탁을 행하여도 이산화티타늄 광촉매의 이탈 없이 표면에 견고하게 부착되어 있음을 확인하였으며, 또한 가스분해성능도 세탁전과 20회 반복 세탁 후에도 유지하는 것으로 나타나 세탁내구성이 우수함을 확인하였다. 자외선 차폐성도 세탁 전과 비교하여 20회 반복 세탁 후에도 83%이상 차단되는 것으로 나타났다.

• Bulletin of the Korean Chemical Society
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• 제34권1호
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• pp.143-148
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• 2013

Novel titanium containing solid core mesoporous shell silica has been synthesized by using octadecyltrichloro silane and triethylamine. The synthesized material was characterized by various physicochemical techniques. The mesoporous character of the material has been revealed from PXRD studies. The presence of octadecyltrichloro silane and triethylamine in the sample has been confirmed from EDAX studies. TG/DTA analysis reveals the thermal characteristics of the synthesized material. The presence of titanium in the frame work and its coordination state has been studies by UV-vis DR studies and XPS analysis. Chemical environment of Si in the framework of the material has been studied by $^{29}SiMASNMR$ studies. The surface area of the material is found to be around $550\;m^2g^{-1}$ and pore radius is of nano range from BET analysis. The spherical morphology and particle size of the core as well as shell has been found to be 300 nm and 50 nm respectively from TEM analysis. The catalytic application of this material towards the synthesis of caprolactam from cyclohexanone in presence of hydrogen peroxide through ammoxidation reaction has been investigated. The optimum conditions for the reaction have been established. The plausible mechanism for the formation of core silica and conversion of cyclohexanone has been proposed.