• Title/Summary/Keyword: thick water layer

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Wear Mechanism of Inconel Alloys in Room Temperature Water (물분위기에서의 인코넬 합금의 마멸기구)

  • 이영호;김인섭
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2001.11a
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    • pp.103-108
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    • 2001
  • Wear test has been performed to evaluate the wear mechanism of Inconel alloys against ferritic stainless steels in room temperature water. By means of scanning electron microscopy (SEM), the worn surface and microstructure of subsurface layer have been examined. The wear at steady state conditions result in the formation of 5∼7${\mu}$m thick layers with fragmented microstructure. The thickness of these layers seems to depend on the ability of work hardening and deformation accommodation at the contact areas during wear. Therefore, in room temperature water, the wear rate is closely related with the wear resistance of these fragment microstructure which are generated after severe subsurface deformation.

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Spatial Pattern of Copper Phosphate Precipitation Involves in Copper Accumulation and Resistance of Unsaturated Pseudomonas putida CZ1 Biofilm

  • Chen, Guangcun;Lin, Huirong;Chen, Xincai
    • Journal of Microbiology and Biotechnology
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    • v.26 no.12
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    • pp.2116-2126
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    • 2016
  • Bacterial biofilms are spatially structured communities that contain bacterial cells with a wide range of physiological states. The spatial distribution and speciation of copper in unsaturated Pseudomonas putida CZ1 biofilms that accumulated 147.0 mg copper per g dry weight were determined by transmission electron microscopy coupled with energy dispersive X-ray analysis, and micro-X-ray fluorescence microscopy coupled with micro-X-ray absorption near edge structure (micro-XANES) analysis. It was found that copper was mainly precipitated in a $75{\mu}m$ thick layer as copper phosphate in the middle of the biofilm, while there were two living cell layers in the air-biofilm and biofilm-medium interfaces, respectively, distinguished from the copper precipitation layer by two interfaces. The X-ray absorption fine structure analysis of biofilm revealed that species resembling $Cu_3(PO_4)_2$ predominated in biofilm, followed by Cu-Citrate- and Cu-Glutathione-like species. Further analysis by micro-XANES revealed that 94.4% of copper were $Cu_3(PO_4)_2$-like species in the layer next to the air interface, whereas the copper species of the layer next to the medium interface were composed by 75.4% $Cu_3(PO_4)_2$, 10.9% Cu-Citrate-like species, and 11.2% Cu-Glutathione-like species. Thereby, it was suggested that copper was initially acquired by cells in the biofilm-air interface as a citrate complex, and then transported out and bound by out membranes of cells, released from the copper-bound membranes, and finally precipitated with phosphate in the extracellular matrix of the biofilm. These results revealed a clear spatial pattern of copper precipitation in unsaturated biofilm, which was responsible for the high copper tolerance and accumulation of the biofilm.

Simplified Ground-type Single-plate Electrowetting Device for Droplet Transport

  • Chang, Jong-Hyeon;Kim, Dong-Sik;Pak, James Jung-Ho
    • Journal of Electrical Engineering and Technology
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    • v.6 no.3
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    • pp.402-407
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    • 2011
  • The current paper describes a simpler ground-type, single-plate electrowetting configuration for droplet transport in digital microfluidics without performance degradation. The simplified fabrication process is achieved with two photolithography steps. The first step simultaneously patterns both a control electrode array and a reference electrode on a substrate. The second step patterns a dielectric layer at the top to expose the reference electrode for grounding the liquid droplet. In the experiment, a $5{\mu}m$ thick photo-imageable polyimide, with a 3.3 dielectric constant, is used as the dielectric layer. A 10 nm Teflon-AF is coated to obtain a hydrophobic surface with a high water advancing angle of $116^{\circ}$ and a small contact angle hysteresis of $5^{\circ}$. The droplet movement of 1 mM methylene blue on this simplified device is successfully demonstrated at control voltages above the required 45 V to overcome the contact angle hysteresis.

Basic and Mechanical Properties by Film Type to Minimize the Sound Pressure Level of PTFE Laminated Vapor-permeable Water-repellent Fabrics (PTFE(Polytetrafluoroethylene) 라미네이팅 투습발수직물의 총음압 최소화를 위한 필름 타입 별 기본 특성과 역학 특성)

  • Lee, Kyu-Lin;Lee, Jee-Hyun;Jin, Eun-Jung;Yang, Youn-Jung;Cho, Gil-Soo
    • Fashion & Textile Research Journal
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    • v.14 no.4
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    • pp.641-647
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    • 2012
  • This study investigates the sound properties of fabric frictional sound (SPL, ${\Delta}L$, ${\Delta}f$) according to the film type of PTFE laminated vapor-permeable water-repellent fabrics in order to understand the relationship between SPL and the basic properties of fabrics such as layer, yarn type, and thickness of fiber. This study accesses their mechanical properties and determines how to control them to minimize SPL. Eight PTFE laminated water-repellent fabrics, composed of four different film types (A, B, C, D) and with two different fabrics, were used as test specimens. Frictional sounds generated at 1.21m/s were recorded by using a fabric sound generator and SPLs were analyzed through Fast Fourier Transformation (FFT). The mechanical properties of fabrics were measured by KES-FB. The SPL value was lowest at 74.4dB in film type A and highest as 85.5dB in type D. Based on ANOVA and post-hoc test, specimens were classified into less Loud Group (A, B) and Loud Group (C, D). It was shown that SPL was lower when 2 layer (instead of 3 layer), filament yarn than staple, and thin fiber than thick were used. In Group I, shearing properties (G, 2HG5), geometrical roughness (SMD), compressional properties (LC, RC) and weight (W) showed high correlation with SPL however, elongation (EM) and shear stiffness (G) did with SPL in Group II.

Corrosion of Fe-(8.5~36.9) wt% Cr Alloys at 600~800℃ in (N2, H2S, H2O)-Mixed Gases (Fe-(8.5~36.9) wt% Cr합금의 600~800℃, (N2,H2S,수증기)-혼합 가스분위기에서의 부식)

  • Kim, Min Jung;Lee, Dong Bok
    • Korean Journal of Metals and Materials
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    • v.50 no.3
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    • pp.218-223
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    • 2012
  • Fe-(8.5, 18.5, 28.3, 36.9) wt% Cr alloys were corroded between 600 and $800^{\circ}C$ for up to 70 h in a 1 atm gas mixture that consisted of 0.0242 atm of $H_2S$, 0.031 atm of water vapor, and 0.9448 atm of nitrogen gas. Their corrosion resistance increased with an increment in the Cr content. The Fe-8.5%Cr alloy corroded fast, forming thick, fragile, nonadherent scales that consisted primarily of an outer FeS layer and an inner (Fe, Cr, O, S)-mixed layer. The outer FeS layer grew into the air by the outward diffusion of $Fe^{2+}$ ions, whereas the inner mixed layer grew by the inward diffusion of oxygen and sulfur ions. At the interface of the outer and inner scales, voids developed and cracking occurred. The Fe-(18.5, 28.3, 36.9)% Cr alloys displayed much better corrosion resistance than the Fe-8.5Cr alloy, because thin $Cr_2O_3$ or $Cr_2S_3$ scales formed.

Electrospun Magnetic Nanofiber as Multifunctional Flexible EMI-Shielding Layer and its Optimization on the Effectiveness

  • Yu, Jiwoo;Nam, Dae-Hyun;Lee, Young-Joo;Joo, Young-Chang
    • Journal of the Microelectronics and Packaging Society
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    • v.23 no.2
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    • pp.57-63
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    • 2016
  • We developed a flexible and micro-thick electromagnetic interference (EMI) shielding nanofabric layer that also functions as a water resisting and heat sinking material. Electrospinning followed by a simple heat treatment process was carried on to produce the EMI-shielding Ni/C hybrid nanofibers. The ambient oxygen partial pressure ($pO_2$ = 0.1, 0.7, 1.3 Torr) applied during the heat treatment was varied in order to optimize the effectiveness of EMI-shielding by modifying the size and crystallinity of the magnetic Ni nanoparticles distributed throughout the C nanofibers. Permittivity and permeability of the nanofibers under the electromagnetic (EM) wave frequency range of 300 MHz~1 GHz were measured, which implied the EMI-shielding effectiveness (SE) optimization at $pO_2$ = 0.7 Torr during the heat treatment. The materials' heat diffusivity for both in-plane direction and vertical direction was measured to confirm the anisotropic thermal diffusivity that can effectively deliver and sink the local heat produced during device operations. Also, the nanofibers were aged at room temperature in oxygen ambient for water resisting function.

Selection of the optimum mixture condition for stabilization of Songdo silty clay (송도 지역 해양성 점토 고화처리를 위한 최적배합 조건의 선정)

  • Kim, Jun-Young;Jang, Eui-Ryong;Chung, Choong-Ki;Lee, Yong-Jun;Jang, Soon-Ho;Choi, Jung-Yeul
    • Proceedings of the Korean Geotechical Society Conference
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    • 2009.09a
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    • pp.412-419
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    • 2009
  • Large quantity of extra soils discharged from excavation site in Songdo area can be treated by hardening agents and utilized in surface stabilized layer overlying thick reclaimed soft soil deposit. Though surface layer stabilization method using cement or lime for very soft soils has been studied in recent years, but studies on moderately soft clayey silt has not been tried. The purpose of this research is to investigate optimum mixing condition for stabilizing Songdo marine soil with low plasiticity. The optimum mixing conditions of hardening agents with Songdo soil such as kind of agents, mixing ratio, initial water content and curing time are investigated by uniaxial compression test and laboratory vane test. The results indicate that strength increases with high mixing ratio and long curing time, while decreases drastically under certain water content before mixing. Finally, optimum mixing condition considering economic efficiency and workability with test results was proposed.

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Tribochemical Mechanism of Borate of Triethanolamine in Water Solution by XPS

  • Du, Da-Chang;Kim, Seock-Sam;Suh, Chang-Min
    • KSTLE International Journal
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    • v.2 no.2
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    • pp.138-141
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    • 2001
  • Tribological behaviors of a borate of triethanolamine in water solution were evaluated using a four-ball wear tester. X-ray photoelectron spectroscopy (XPS) was employed to study tribochemical species on worn scars of steel balls. Results show that a thick deposit layer was produced on the worn scars, which came from the decomposition of the borate. The surface film on the worn scars was mostly consisted with H$_3$BO$_3$, B$_2$O$_3$and large amounts of ferricyanides.

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Tribochemical Mechanism of Borate of Triethanolamine in Water Solution by XPS

  • Du, Da-Chang;Kim, Seock-Sam;Suh, Chang-Min
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2001.11a
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    • pp.374-379
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    • 2001
  • Tribochmical behaviors of a borate of triethanolamine in water solution were evaluated using a four-ball wear tester. X-ray photoelectron spectroscopy (XPS) was employed to study tribochemical species on worn scars of steel balls. Results show that a thick deposit layer was produced on the worn scars, which came from the decomposition of the borate. The surface film on the worn scars was mostly consisted with H$_{3}$BO$_{3}$, B$_{2}$O$_{3}$ and large amounts of ferricyanides.

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Study On Effect of Fe Density on Electrolyte Exfoliation of Chromium Plating Layer (전해액의 Fe 농도에 의한 크롬도금 탈락 연구)

  • Park, Jin-Saeng
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.39 no.12
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    • pp.1297-1303
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    • 2015
  • The internal chromium plating of a long-axis tube is widely used in military and industrial application, with the thick hard plating formed using a mixed solution of Chromium acid and catalytic $H_2SO_4$. A large-caliber gun can endure a high explosive force as a result of the increased stiffness and wear resistance provided by this internal hard chromium surface. The internal chromium layer of a tube is prone to exfoliation caused by the high kinetic energy of the projectile and high pressure of the explosion. Therefore, we reviewed the plating process. Chromium plating comprises many steps, including the removal of Grease, water cleaning, electrolytic abrasion, etching, plating, water cleaning, and hydrogen brittleness removal. The exfoliated chromium plating layer is affected by the adhesion property of the plating. In particular, the Fe concentration of the electrolyte affects the adhesion property. The optimum Fe concentration for effectively suppressing the exfoliation of the plating layer was established by using a scanning electron microscope to determine the surface roughness, and the effectiveness was proved in an adhesion test, etc.