• 제목/요약/키워드: thermal vapor deposition

검색결과 539건 처리시간 0.024초

열화학기상증착법에 의한 대면적 실리콘 기판위에서의 탄소나노튜브 성장 (Growth of carbon nanotubes on a large area of Si substrate by the thermal chemical vapor deposition)

  • 김대운;이철진;이태재;박정훈;손권희;강현근;송홍기;최영철;박영수
    • 대한전자공학회:학술대회논문집
    • /
    • 대한전자공학회 1999년도 하계종합학술대회 논문집
    • /
    • pp.954-957
    • /
    • 1999
  • We have synthesized carbon nanotubes by thermal chemical vapor deposition of $C_2$H$_2$ on transition metal-coated silicon substrates. Carbon nanotubes are uniformly synthesized on a large area of the plain Si substrates, different from previously reported porous Si substrates. It is observed that surface modification of transition metals deposited on substrates by either etching with dipping in a HF solution and/or NH$_3$ pretreatment is a crucial step for the nanotube growth prior to the reaction of $C_2$H$_2$gas. We will demonstrate that the diameters of carbon naotubes can be controlled by applying the different transition metals.

  • PDF

Geometry variation for as-grown carbon coils under the minimized sulfur additive condition

  • Lee, Seok-Hee;Kim, Sung-Hoon
    • 한국결정성장학회지
    • /
    • 제22권5호
    • /
    • pp.213-217
    • /
    • 2012
  • Carbon coils could be synthesized on nickel catalyst layer-deposited silicon oxide substrate using $C_2H_2$ and $H_2$ as source gases under thermal chemical vapor deposition system. By the incorporation of $SF_6$ additive in cyclic modulation manner, the dominant formation of the nanosized carbon coils could be achieved with maintaining the minimized sulfur additive amount. The geometry variation of the as-grown carbon coils, such as linear type, microsized coil type, wavelike nanosized coil type, and nanosized coil type, were investigated according to the different cyclic modulation manner of $SF_6$ flow. $SF_6$ gas incorporation develops the coil-type geometry. Furthermore, the higher flow rate of $SF_6$ gas increased the amount of the nanosized carbon coils. The slightly increased etching ability by $SF_6$ addition seems to be the cause for these results.

열 CVD에 의한 탄소나노튜브의 성장 및 구조의 온도 의존성 (Temperature dependence on the growth and structure of carbon nanotubes by thermal chemical vapor deposition)

  • 이철진;손권희;이태재;류승철;최성헌;유재은
    • 대한전기학회:학술대회논문집
    • /
    • 대한전기학회 2000년도 하계학술대회 논문집 C
    • /
    • pp.1494-1496
    • /
    • 2000
  • We have studied the temperature dependence on the growth and structure of carbon nanotubes using thermal chemical vapor deposition. All the carbon nanotubes have bamboo shaped multi walled structure with closed tip. The growth rate and density of carbon nanotubes increase with increasing growth temperature. The numbers of graphite sheet at the wall increase with increasing growth temperature. The crystallinity of graphite sheets become enhanced at the high growth temperature.

  • PDF

RTCVD법을 이용한 Si(111)기판 위에 3C-SiC(111) 박막의 성장 및 분석 (Growth and Analyses of 3C-SiC(111)Thin Films on Si(111)Substrate Using Rapid Thermal Chemical Vapor Deposition)

  • 서영훈;남기석;황용규;서은경;이형재
    • 한국재료학회지
    • /
    • 제7권6호
    • /
    • pp.472-478
    • /
    • 1997
  • TMS(tetramethysilane, Si(CH$_{3}$)$_{4}$)를 이용하여 RTCVD(rapid thermal chemical vapor deposition)장치에서 Si(111) 기판 위에 $\beta$-SiC(111)를 성장시켰다. 실험변수로는 반응온도, TMS유량, 반응시간, H$_{2}$유량을 변화시켰으며, XRD, IR, SEM, RBS, TEM등을 이용하여 성장된 박막을 분석하였다. 성장된 박막은 crystallized Si, C또한 Si-H, C-H결합은 관찰할 수 없었으나 다결정이었다. TMS의 유량이 증가함에 따라, 성장온도가 감소함에 따라서 미려한 박막을 성장시킬 수 있었으며, 반응의 활성화에너지는 20kcal/molㆍK이었다.

  • PDF

Thermal Properties of Diamond Films Deposited by Chemical Vapor Depositon

  • Chae, Hee-Baik;Baik, Young-Joon
    • The Korean Journal of Ceramics
    • /
    • 제3권1호
    • /
    • pp.29-33
    • /
    • 1997
  • Four diamond films were deposited by the microwave plasma assisted chemical vapor deposition method varying CH4 concentration from 2.5 to 10% in the feeding gases. Thermal conductivity was measured on these free standing films by the steady state method from 80 K to 400K. They showed higher thermal conductivity as the film deposited with lower methane concentration. One exception, 7.79% methane concentration deposited film, was observed to be the highest thermal conductivity. Phonon scattering processes were considered to analyze the thermal conductivity with the full Callaway model. The grain size and the concentration of the extended and the point defects were used as the fitting parameters. Microstructure of diamond films was investigated with the scanning electron microscopy and Raman spectroscopy.

  • PDF