• Title/Summary/Keyword: thermal vapor deposition

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Density control and field emission characteristics of carbon nanotubes grown by thermal chemical vapor deposition (열화학기상합성법을 이용한 탄소 나노튜브의 밀도 제어 및 전계방출 특성)

  • 공병윤;김범권;선전영;이내성;김원석;허정나;김종민
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.03a
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    • pp.122-122
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    • 2003
  • 1991년 일본 NEC의 Iijima가 탄소 나노튜브를 발견한 이후, 1995년 Smalley와 De Heer에 의해 탄소 나노튜브의 우수한 전폐방출 특성이 보고되면서 탄소 나노튜브를 새로운 전계방출 물질로 응용하기 위한 연구가 세계적으로 활발히 진행되고 있다. 탄소 나노튜브의 전계방출 연구는 대부분 시장규모가 클 것으로 예상되는 field emission display(FEED)의 cathode에 집중되고 있다. FED cathode는 현재 탄소 나노튜브 페이스트를 스크린 프린팅하여 대면적화를 이루고자 하는 방향과 탄소 나노튜브를 기판 위에 chemical vapor deposition(CVD)로 증착하여 고정세화와 저전압 구동을 이루고자 하는 방향으로 진행되고있다.

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Study for an BF3 Specialty Gas Production (BF3 생산에 관한 연구)

  • Lee, Taeck-Hong;Kim, Jae-Young
    • Journal of the Korean Institute of Gas
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    • v.15 no.3
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    • pp.74-78
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    • 2011
  • $BF_3$ gas has been used for semiconductor manufacturing process and applied in plasma etching, chemical vapor deposition, chamber cleaning processes etc,. $BF_3$ provides Boron and acts as a p-type doping in electrode in semiconductor. In this study, we investigate thermaldecomposition of alkali-boron complexes and suggest a simple way to produce $BF_3$ from $NaBF_4$ and $KBF_4$.

A study on the electric breakdown of polyimide thin film fabricated by vapor deposition polymerization (진공증착중합법에 의해 제조된 폴리이미드박막의 절연파괴특성)

  • 이붕주;김형권;김종석;한상옥;박강식;김영봉;이덕출
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1997.04a
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    • pp.293-296
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    • 1997
  • The experimental system used for vapor deposition polymerization (VDP) from PMDA (Pyromellitic dianhydride) and DDE (4, 4-diaminodiphenyl ether) were changed to PI (polyimide) thin films by thermal curing. The curing temperatures were 20$0^{\circ}C$, 25$0^{\circ}C$, 30$0^{\circ}C$, 35$0^{\circ}C$. When test number was 40, the electric breakdown strengths of PI were 1.21MV/cm, 3.94MV/cm, 4.61MV/cm, 4.55MV/cm according to curing temperatures.

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A Study on the curing characteristics of 6FDA/4-4' DDE Polyimide thin film fabricated by vapor deposition polymerization (진공증착중합에 의해 제조된 6FDA/4-4' DDE 폴리이미드 박막의 열처리 특성에 관한 연구)

  • Hwang, S.Y.;Lee, B.J.;Kim, H.G.;Kim, J.T.;Kim, Y.B.;Park, K.S.;Lee, D.C.
    • Proceedings of the KIEE Conference
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    • 1998.11c
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    • pp.816-818
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    • 1998
  • In this paper Polyimide(PI) thin film are fabricated by vapor deposition polymerization(VDP) of dry process which are easy to control the film's thickness and hard to pollute due to volatile solvent. The FT-IR spectrum show that PAA thin films fabricated by VDP are changed to PI thin film by thermal curing. From AFM(Atomic Force Microscopy) experimental as the higher curing temperature. the thin film thickness decreases and roughness decresse.

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Fabrication of ZnO thin film gas sensor for detecting $(CH_3)_3N$ gas ($(CH_3)_3N$ 가스 감지용 ZnO 박막 가스 센서의 제조)

  • 신현우;박현수;윤동현;홍형기;권철한;이규정
    • Electrical & Electronic Materials
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    • v.8 no.1
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    • pp.21-26
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    • 1995
  • Highly sensitive and mechanically stable gas sensors have been fabricated using the microfabrication and micromaching techniques. The sensing material used to detect the offensive trimethylarnine ((CH$_{3}$)$_{3}$N) gas is 6 wt% $Al_{2}$O$_{3}$-doped, 1000.angs.-thick ZnO deposited by r. f. magnetron sputtering. The optimum operating temperature of the sensor is 350.deg.C and the corresponding heater power is about 85mW. Excellent thermal insulation is achieved by the use of a double-layer structure of 0.2.mu.m -thick silicon nitride and 1.4.mu.m-thick phosphosilicate glass(PSG) prepared by low pressure chemical vapor deposition(LPCVD) and atmospheric pressure chemical vapor deposition(APCVD), respectively. The sensors are mechanically stable enough to endure at least 43, 200 heat cycles between room temperature and 350.deg. C.

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Improvement Study on Vertical Growth of Carbon Nanotubes and their Field Emission Properties at ICPCVD (유도결합형 플라즈마 화학기상증착법에서 탄소나노튜브의 수직성장과 전계방출 특성 향상 연구)

  • 김광식;류호진;장건익
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.15 no.8
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    • pp.713-719
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    • 2002
  • In this study, the vertically well-aligned CNTs were synthesized by DC bias-assisted inductively coupled plasma hot-filament chemical vapor deposition (ICPHFCVD) using radio-frequence plasma of high density and that CNTs were vertically grown on Ni(300 )/Cr(200 )-deposited glass substrates at 58$0^{\circ}C$. This system(ICPHFCVD) added to tungsten filament in order to get thermal decompound and DC bias in order to vertically grow to general Inductively Coupled Plasma CVD. The grown CNTs by ICPHFCVD were developed to higher graphitization and fewer field emission properties than those by general ICPCVD. In this system, DC bias was effect of vortical alignment to growing CNTs. The measured turn-on fields of field emission property by general ICPCVD and DC bias-assisted ICPHFCVD were 5 V/${\mu}{\textrm}{m}$ and 3 V/${\mu}{\textrm}{m}$, respectively.

ZnO Nanowires Fabricated by Pulsed Laser Deposition using Gold Catalyst (PLD-Furnace로 증착시킨 금촉매를 이용한 ZnO 나노와이어 합성)

  • Son, Hyo-Jeong;Jeon, Kyung-Ah;Lee, Sang-Yeol
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.11a
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    • pp.5-6
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    • 2005
  • ZnO nanowlres (NWs) were fabricated using Au as catalyst for a method combining laser ablation cluster formation and vapor-liquid-solid (VLS) growth. The target used in synthesis was pure ZnO ceramics. Two different substrates were used; (0001)-oriented sapphires and Au-coated sapphires. The Au thin film was deposited by thermal evaporation and the thickness was about 50 ${\AA}$. ZnO NWs were only formed in case of that used catalyst metal. Field effect scanning electron microscopic (FESEM) investigation showed that the average diameter of ZnO NWs was about 70 nm and the typical lengths varied from $3{\sim}4{\mu}m$.

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Field Emission Properties of Flat Lamp using Carbon Nanotubes Grownon Glass Substrate (유리기판 위에 성장된 탄소나노튜브를 이용한 평판 램프의 전계방출 특성)

  • Lee, Yang-Doo;Moon, Seung-Il;Han, Jong-Hun;Lee, Yun-Hi;Ju, Byeong-Kwon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.17 no.6
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    • pp.647-651
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    • 2004
  • We fabricated the 1-inch diode type flat lamp using CNTs, which were grown directly on soda-lime glass substrate at 600 ∼ 650 $^{\circ}C$ by thermal chemical vapor deposition(CVD) of acetylene gas. Turn- on field was about 2.8 V/${\mu}{\textrm}{m}$. We observed that uniform and high brightness had been obtained. The brightness of CNT flat lamp was measured up to about 14 kcd/$m^2$ at 2000V in spacing of 500 ${\mu}{\textrm}{m}$. The results showed that the CNTs were very good emission source and suitable for application in the lamp.

Fabrication of micro carbon structures using laser-induced chemical vapor deposition and Raman spectroscopic analysis (레이저 국소증착에 의한 탄소 미세 구조물 제조 및 분광분석)

  • ;;J. Senthil Selvan
    • Laser Solutions
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    • v.5 no.2
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    • pp.17-22
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    • 2002
  • Characteristics of micro carbon structures fabricated with laser-induced chemical vapor deposition (LCVD) are investigated. An argon ion laser (λ=514.5nm) and ethylene gas were utilized as the energy source and precursor, respectively. The laser beam was focused onto a graphite substrate to produce carbon deposit through thermal decomposition of the precursor. Average growth rate of a carbon rod increased for increasing laser power and pressure. Micro carbon rods with good surface quality were obtained at near the threshold condition. Micro carbon rods with aspect ratio of about 100 and micro tubular structures were fabricated to demonstrate the possible application of this method to the fabrication of three-dimensional microstructures. Laser Raman spectroscopic analysis of the micro carbon structures revealed that the carbon rods are consisting of amorphous carbon.

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The effect of various parameters for few-layered graphene synthesis using methane and acetylene

  • Kim, Jungrok;Seo, Jihoon;Jung, Hyun Kyung;Kim, Soo H.;Lee, Hyung Woo
    • Journal of Ceramic Processing Research
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    • v.13 no.spc1
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    • pp.42-46
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    • 2012
  • The effect of the parameters for few-layered graphene growth by thermal CVD on nickel substrate was investigated. Graphene can be synthesized by using different strategies. Chemical vapor deposition (CVD) has known as one of the most attractive methods to produce graphene due to its good film uniformity, compatibility and large scale production. The control of parameters such as temperature, growth time and pressure in CVD process has been widely recognized as the most important process in graphene growth. Different carbon precursors, methane and acetylene, were introduced in the quartz tube with a variety of growth conditions. Raman spectroscopy was used to confirm the presence of a few- or multi-layered graphene.