• Title/Summary/Keyword: thermal history

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Study on the physical properties of nylon66/glass fiber composites as a function of extrusion number (나일론66/유리섬유 복합체의 압출횟수에 따른 특성 연구)

  • Lee, Bom Yi;Kim, Youn Cheol
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.15 no.6
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    • pp.3990-3996
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    • 2014
  • Because the physical properties can be decreased when a Nylon 66/glass fiber composite is injected into a mold over $300^{\circ}C$, a systematic study of the thermal history in the case of re-use is needed. Nylon 66/glass fiber extrudates as a function of the extrusion number were prepared using a twin screw extruder at 305/290/273/268/265/$260^{\circ}C$. The chemical structure, thermal properties, melt index, crystal structure, Izod impact strength, and rheological properties were measured by Fourier transform infra-red (FT-IR), melt indexer, DSC, TGA, XRD, Izod impact tester, and dynamic rheometer. The FT-IR spectra indicated that the number of extrusions did not affect the chemical structure. The decrease in molecular weight with increasing extrusion number was confirmed by the melt index and the complex viscosity of extrudates. Based on the DSC and TGA results, the thermal history had no effect on the melting temperature, regardless of the number of extrusions, but the degradation temperature decreased up to $20^{\circ}C$ with increasing extrusion number. The Izod impact strengths of the extrudates were found to decrease with increasing extrusion number. No structural change after extrusion was also confirmed because there was no change in the slope and shape of the G'-G" plot.

Effect of Thermal History on the Physical Properties of Nylon66 (열 이력이 나일론66의 물성에 미치는 영향)

  • Lee, Bom Yi;Jo, Chan Woo;Shim, Chang Up;Lim, Su Jung;Kim, Youn Cheol
    • Applied Chemistry for Engineering
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    • v.25 no.1
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    • pp.90-95
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    • 2014
  • Nylon66 extrudates as a function of the extrusion number were prepared by a twin screw extruder. Chemical structures, thermal properties, melt index, crystal structures, mechanical properties such as the tensile strength, elongation at break and impact strength, and rheological property were measured by FT-IR, $^1H$-NMR, melt indexer, DSC, TGA, XRD, universal tensile tester, Izod impact tester, and rheometer. FT-IR and $^1H$-NMR characterizations indicated that the number of extrusions did not affect the chemical structure. The decrease in the molecular weight was checked by the melt index of extrudates. There were no effects of the thermal history on the melting and degradation temperature. The tensile and impact strength and modulus were found to be similar, regardless of the number of extrusions, but the elongation decreased significantly. The complex viscosity of extrudates at low frequencies decreased with the extrusion number. No structural changes after extrusion were confirmed from the fact that there was no change in the slope and shape of G'-G" plot.

Loading Effects on Thermal Conductivity of Soils: Particle-Scale Study (하중 조건이 지반의 열전도도에 미치는 영향: 입자 스케일에서의 연구)

  • Lee, Jung-Hwoon;Choo, Jin-Hyun;Yun, Tae-Sup;Lee, Jang-Guen;Kim, Young-Seok
    • Journal of the Korean Geotechnical Society
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    • v.27 no.9
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    • pp.77-86
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    • 2011
  • The stress condition mainly dominates the thermal conductivity of soils whereas governing factors such as unit weight and porosity suggested by empirical correlations are still valid. The 3D thermal network model enables evaluation of the stress-dependent thermal conductivity of particulate materials generated by discrete element method (DEM). The relationship among dominant factors is analyzed based on the coordination number and porosity determined by stress condition and thermal conductivity of pore fluid. Results show that the variation of thermal conductivity is strongly attributed to the enlargement of inter-particle contact area by loading history and pore fluid conductivity. This study highlights that the anisotropic evolution of thermal conductivity depends on the directional load and that the particle-scale mechanism mainly dictates the heat transfer in soils.

Applications of Non-Thermal Atmospheric Pressure Plasma in Dentistry (상온 대기압 플라즈마의 치의학적 응용)

  • Uhm, Soo-Hyuk;Kwon, Jae-Sung;Lee, Eun-Jung;Lee, Jung-Hwan;Kim, Kyoung-Nam
    • The Journal of the Korean dental association
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    • v.52 no.12
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    • pp.783-794
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    • 2014
  • Since the introduction of non-thermal atmospheric pressure plasma in the field of the dentistry, numerous applications have been investigated. Especially with its advantages over existing vacuum plasma in terms of portability, low cost, and non-thermal damage, it can be directly applied in the oral cavity, giving number of potentials for dental application. First, possible application of non-thermal atmospheric pressure plasma in the field of dentistry is relation to dental caries and periodontal diseases. Teeth and alveolar bones are one of the strongest bony structures in our body, but it cannot be regenerated when they are damaged by dental caries or periodontal disease. Hence many studies to prevent such diseases have been carried out, though no perfect solution has been found yet. With recent studies of modifying surfaces through non-thermal atmospheric pressure application that can prevent attachment of bacteria, or studies on bactericidal effects of non-thermal atmospheric pressure plasma can be applied here to prevent oral pathogen and 'biofilm' attachment to the surface of teeth or directly eliminate the dental caries/periodontal disease causing germs. Secondly, non-thermal atmospheric pressure application will be useful on the surface of dental implant. It is well known that the success of dental implant surgery depends on the process known as 'osseointegration' that result from osteoblast attachment, proliferation and differentiation. As the application of non-thermal atmospheric pressure plasma on the surface of dental implant just before its introduction by the chair-side of dental surgery. Despite its long history, the generation of non-thermal atmospheric pressure plasma has been greatly increased with its application in dentistry.

Thermal and uplift histories of Mesozoic granites in Southeast Korea: new fission track evidences

  • Shin, Seong-Cheon;Susumu Nishimura
    • The Journal of the Petrological Society of Korea
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    • v.2 no.2
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    • pp.104-121
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    • 1993
  • Fission track (FT) thermochronological analyses on Mesozoic granites provide new information about cooling and uplift histories in Southeast Korea. Twenty-nine new FT sphene, zircon and apatite ages and seven track length measurements are presented for eleven granite samples. Measured mineral ages against assumed closure temperatures yield cooling rates for each sample. Relatively rapid (7-$15^{\circ}C$/Ma) and simple cooling patterns from the middle Cretaceouss (ca. 90-100 Ma) granites are caused mainly by a high thermal contrast between the intruding magma and country rocks at shallow crustal levels (ca. 1-2.5 km-depths). On the contrary, a slow overall cooling (1-$4^{\circ}C$/Ma) of the Triassic to Jurassic granites (ca. 250-200 Ma), emplaced at deep depths (>>9 km), may mainly depend upon very slow denudation of the overlying crust. The uplift history of the Triassic Yeongdeog Pluton in the Yeongyang Subbasin, west of the Yangsan Fault, is characterized by a relatively rapid uplift (~0.4 mm/a) before the total unroofing of the pluton in the earliest Cretaceous (~140 Ma) followed by a subsidence (~0.2mm/a) during the Hayang Group sedimentation. Stability of original FT zircon ages (156 Ma) and complete erasure of apatite ages suggest a range of 3 to 5.5 km for the basin subsidence. Since 120 Ma up to present, the Yeongyang Subbasin has been slowly uplifted (~0.04 mm/a). The FT age patterns of Jurassic granites both from the northeastern wing of the Ryeongnam Massif and from the northern edge of the Pohang-Kampo Block indicate that the two geologic units have been slowly uplifted with a same mean rate (~0.04 mm/a) since early Cretaceous. Estimates of Cenozoic total uplifts since 100 Ma are different: Ryeongnam Massif (~6 km)=Pohang-Kampo Block (~6 km)>Yeongyang Subbasin(~4 km).

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Geochrononlogy and thermal history of the Chuncheon granite in the Gyeonggi massif, South Korea

  • Jin, Myung-Shik;Shin, Seong-Cheon;Kim, Seong-Jae;Choo, Seung-Hwan
    • The Journal of the Petrological Society of Korea
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    • v.2 no.2
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    • pp.122-129
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    • 1993
  • We report Rb-Sr whole rock, K-Ar and fission track mineral ages for the Chuncheon granite in the Precambrian Gyeonggi massif. The Rb-Sr whole rock define an age of $196{\pm}9$ Ma with an initial ratio of $0.7159{\pm}0.0006$, suggesting that the granitic magma might have been generated from crustal sources (S-type), or probably mixed mantle and crustal materials, and emplaced into the massif in the late Triassic or the early Jurassic. K-Ar mineral ages of hornblende, muscovite and biotite are ~210 Ma, ~180 Ma and 166-170 Ma respectively, and fission track zircon and apatite ages are 65-70 Ma, ~35 Ma respectively. These ages indicate that the granitic magma might have been emplaced at about 7 to 9 km from the paleosurface, and rapidly cooled down up to $300^{\circ}C$ until middle Jurassic (~170 Ma) with a rate of about $10^{\circ}C$/Ma, due to thermal difference between the magma and the wall rock. During middle Jurassic to late Cretaceous (about 170-70 Ma), the granite pluton is assumed to have uplifted to 4 to 6 km level under the paleosurface with a rate of 30 m/Ma and slowly cooled down with a rate of about $1^{\circ}C$/Ma owing to relatively slow denudation of the massif. In late Cretaceous to the present, the pluton might have more rapidly uplifted to the present level with a rate of 85 m/Ma and rapidly cooled down with a rate of about $3^{\circ}C$/Ma compared to those of middle Jurassic to late Cretaceous time because of extensive igneous activities accompanied by tectonism in the Gyeonggi massif.

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Effects of Superheat and Coating Layer on Interfacial Heat Transfer Coefficient between Copper Mold and Aluminum Melt during Solidification (응고중 구리 주형과 알루미늄 용탕의 계면열전달계수에 미치는 용탕과열도와 도형재의 영향)

  • Kim, Hee-Soo;Shin, Je-Sik;Lee, Sang-Mok;Moon, Byung-Moon
    • Journal of Korea Foundry Society
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    • v.24 no.5
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    • pp.281-289
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    • 2004
  • The present study focused on the estimation of the interfacial heat transfer coefficient as a function of the surface temperature of the aluminum casting at the mold/casting interface to investigate the effects of superheat and coating layer. The casting experiments of aluminum into a cylindrical copper mold were systematically conducted to obtain the thermal history during solidification. The thermal history recorded by four thermocouples embedded both in the mold and the casting was used to solve the inverse heat conduction problem using Beck's method. The effects of superheat and coating on the interfacial heat transfer coefficient in the liquid state, during the solidification, and in the solid state were comparatively discussed. In the liquid state, the interfacial heat transfer coefficient is thought to be affected by the roughness of the mold, the wettability of the casting on the mold surface, and the thermophysical properties of the coating layer. When the solidification begins, the air gap forms between the casting and the mold, and the interfacial heat transfer coefficient becomes a function of the air gap as well as surface roughness and the superheat. In the solid phase, it depends only upon the thermal conductivity and the thickness of the air gap. The coating layer reduces seriously the interfacial heat transfer coefficient in the liquid state and during the solidification.

A Study on the Evaluation of Thermal Stress of Massive Concrete Structure (매스콘크리트구조물의 온도응력평가에 관한 연구)

  • 강석화;정철헌;정한중;이용호;박칠림
    • Magazine of the Korea Concrete Institute
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    • v.7 no.2
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    • pp.126-135
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    • 1995
  • Thermal cracks are occured when thermal stress due to the hydration of cement exceeds the tens~le strength of concrete. Since crackmg causes poor durability of concrete, the effect of ther ma1 cracking should be includod for the design and construction of massive concrete structures. In this study, an experiment is performed for the investigation of time dependent thermal stress history. In order to evaluate thermal stress. two methods are employed. One 1s the evaluation method of thermal stress based on the measurement from embedment stram gauge with non-stress strain gauge and the other 1s based on the measurement from concrete stress gauge. As a result of this study, the value corrected by the former shows good agreement with the latter. The validity of the proposed method for the evaluation of thermal stress 1s explored.

LARGE EDDY SIMULATION OF THERMAL STRIPING IN THE UPPER PLENUM OF FAST REACTOR (대와동모사법을 사용한 고속로 상부플레넘에서의 thermal sriping 해석)

  • Choi, S.K.;Han, J.W.;Kim, D.;Lee, T.H.
    • Journal of computational fluids engineering
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    • v.19 no.4
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    • pp.29-36
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    • 2014
  • A computational study of a thermal striping in the upper plenum of PGSFR(Prototype Generation-IV Sodium-cooled Fast Reactor) being developed at the KAERI(Korea Atomic Energy Research Institute) is presented. The LES(Large Eddy Simulation) approach is employed for the simulation of thermal striping in the upper plenum of the PGSFR. The LES is performed using the WALE (Wall-Adapting Local Eddy-viscosity) model. More than 19.7 million unstructured elements are generated in upper plenum region of the PGSFR using the CFX-Mesh commercial code. The time-averaged velocity components and temperature field in the complicated upper plenum of the PGSFR are presented. The time history of temperature fluctuation at the eight locations of solid walls of UIS(Upper Internal Structure) and IHX(Intermediate Heat eXchanger) are additionally stored. It has been confirmed that the most vulnerable regions to thermal striping are the first plate of UIS. From the temporal variation of temperature at the solid walls, it was possible to find the locations where the thermal stress is large and need to assess whether the solid structures can endure the thermal stress during the reactor life time.

Microstructure and Thermal Shock Properties of SiC Materials (SiC 재료의 미세조직 및 열충격 특성)

  • Lee, Sang-Pill;Cho, Kyung-Seo;Lee, Hyun-Uk;Son, In-Soo;Lee, Jin-Kyung
    • Journal of Ocean Engineering and Technology
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    • v.25 no.3
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    • pp.28-33
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    • 2011
  • The thermal shock properties of SiC materials were investigated for high temperature applications. In particular, the effect of thermal shock temperature on the flexural strength of SiC materials was evaluated, in conjunction with a detailed analysis of their microstructures. The efficiency of a nondestructive technique using ultrasonic waves was also examined for the characterization of SiC materials suffering from a cyclic thermal shock history. SiC materials were fabricated by a liquid phase sintering process (LPS) associated with hot pressing, using a commercial submicron SiC powder. In the materials, a complex mixture of $Al_2O_3$ and $Y_2O_3$ powders was used as a sintering additive for the densification of the microstructure. Both the microstructure and mechanical properties of the sintered SiC materials were investigated using SEM, XRD, and a three point bending test. The SiC materials had a high density of about 3.12 Mg/m3 and an excellent flexural strength of about 700 MPa, accompanying the creation of a secondary phase in the microstructure. The SiC materials exhibited a rapid propagation of cracks with an increase in the thermal shock temperature. The flexural strength of the SiC materials was greatly decreased at thermal shock temperatures higher than $700^{\circ}C$, due to the creation of microcracks and their propagation. In addition, the SiC materials had a clear tendency for a variation in the attenuation coefficient in ultrasonic waves with an increase in thermal shock cycles.