• Proceedings of the Korea Association of Crystal Growth Conference
• /
• 2000.06a
• /
• pp.179-193
• /
• 2000

Aluminium titanate (Al₂TiO5) with an excellent thermal shock resistant and a low the expansion coefficient was obtained by solid solution with MgO, SiO₂, and ZrO₂ in the Al₂TiO5 lattice or in the grain boundary solution through electrofusion in an arc furnace. However, these materials have low mechanical strength due to the presence of microcracks developed by a large difference in thermal expansion coefficients along crystallographic axes. Pure Al₂TiO5 tends to decompose into α-Al₂O₃ and TiO₂-rutile in the temperature range of 750-1300℃ that rendered it apparently useless for industrial applications. Several thermal shock tests were performed: Long therm thermal annealing test at 1100℃ for 100h; and water quenching from 950 to room temperature (RT). Cyclic thermal expansion coefficients up to 1500℃ before and after decomposition tests was also measured using a dilatometer, changes in the microstructure, thermal expansion coefficients, Young's modulus and strengths were determined. The role of microcracks in relation to thermal shock resistance and thermal expansion coefficient is discussed.

• Korean Journal of Materials Research
• /
• v.24 no.10
• /
• pp.515-519
• /
• 2014

The aim of this paper is to consider the effect of annealing on the coefficient of thermal expansion (CTE) of electroplated Invar Fe-Ni alloy. The CTE of the as-electroplated alloy is lower than those of alloys annealed at $400^{\circ}C$ and $800^{\circ}C$. XRD peaks become sharper as the as-electroplated alloy is annealed, which means the grain growth. The average grain sizes of as-electroplated and as-annealed alloys at $400^{\circ}C$ and $800^{\circ}C$ are 10 nm, 70 nm, and $2{\mu}m$, respectively, as determined by TEM and EBSD analyses. The CTE variation for the various grain sizes after annealing may come from the magnetostriction effect, which generates strain due to changes in the magnetization state of the alloys. The thermal expansion coefficient is considered to be affected by nano grain size in electroplated Fe-Ni Invar alloys. As grain size decreases, ferromagnetic forces might change to paramagnetic forces. The effect of lattice vibration damping of nano grain boundaries could lead to the decrease of CTE.

• Journal of the Korean Ceramic Society
• /
• v.53 no.1
• /
• pp.43-49
• /
• 2016

This analyzed a Young's modulus (E), a thermal expansion coefficient (TEC, ${\beta}$) and a thermal conductivity (${\kappa}$) of the material with simple cubic particulate inclusion using two model structures: a parallel structure and a series structure of laminated layers. The derived ${\beta}$ equations were applied to calculate the ${\beta}$ value of the W-MgO system. The accuracy was higher for the series model structure than for the parallel model structure. Young's moduli ($E_c$) of sintered porous alumina compacts were theoretically related to the development of neck growth of grain boundary between sintered two particles and expressed as a function of porosity. The series structure model with cubic pores explained well the increased tendency of $E_c$ with neck growth rather than the parallel structure model. The thermal conductivity of the three phase system of alumina-mullite-pore was calculated by a theoretical equation developed in this research group, and compared with the experimental results. The pores in the sintered composite were treated as one phase. The measured thermal conductivity of the composite with 0.5-25% porosity (open and closed pores) was in accordance with the theoretical prediction based on the parallel structure model.

• Journal of the Korean Crystal Growth and Crystal Technology
• /
• v.14 no.4
• /
• pp.174-186
• /
• 2004

Striations are growth-induced inhomogeneities which hamper the applications of solid-solution crystals and of doped crystals in numerous technologies. Thus the optimized performance of solid solutions often can not be exploited. The inhomogeneity problem can be solved in specific cases by achieving a distribution coefficient one in growth from melts and from solutions. Macrostep-induced striations can be suppressed by controlling the growth mode, by achieving growth on facets thereby preventing step bunching. Thermal striations are commonly assumed to be caused by convective instabilities so that reduced convection by microgravity or by damping magnetic fields was and is widely attempted to reduce such inhomogeneities. Here it will be shown that temperature fluctuations at the growth interface cause striations, and that hydrodynamic fluctuations in a quasi-isothermal growth system do not cause striations. The theoretically derived conditions were experimentally established and allowed the growth of striation-free crystals of $KTa_{1-x}Nb_xO_3$"KTN" solid solutions. Hydrodynamic variations from the accelerated crucible rotation technique ACRT did not cause striations as long as the temperature was controlled within $0.03^{\circ}$ at $1200^{\circ}C$ growth temperature. Alternative approaches to solve or reduce the segregation and striation problems in growth from melts and from solutions are discussed as well.

• Journal of the Korean Ceramic Society
• /
• v.30 no.5
• /
• pp.381-388
• /
• 1993

Due to the anisotropy of thermal expansion, LAS system which has low thermal expansion property is hard to obtain a dense sintered body. Therefore, the thermal expansion coefficient and the mechanical strength were decreased. In this study, mullite, which has good mechanical properties in high temperature and comparatively low thmeral expansion coefficient, was taken as a additive in LAS system. And then, sintering, thermal, and mechanical properties were investigated. The results are follows; When mullite is added in eucryptite composition (Li2O.Al2O3.2SiO2) of LAS system, the creation of liquid phase results in the densification of sintered body and the specimen sintered at 136$0^{\circ}C$ for 2 hours shows optimum sintering condition. With the addition of mullite in eucryptite composition, mechanical strength is increased by the control of grain growth. Especially, flexual strength of EM0 specimen was about double value than the basic composition. Thermal expansion coefficients of EM0 and EM15 specimens sintered at 136$0^{\circ}C$ were -8.23$\times$10-6/$^{\circ}C$ and -4.90$\times$10-6/$^{\circ}C$ in the temperature range of RT.~80$0^{\circ}C$. As the mullite content are increased, negative thermal expansion ratios are decreased.

• Journal of the Korean institute of surface engineering
• /
• v.47 no.6
• /
• pp.293-296
• /
• 2014

Fe-Ni has been of great interest because it is known as one of low thermal expansion alloys as various application areas. This alloy was fabricated by electroforming process, and effect of heat treatment on thermal expansion and hardness was investigated. Nano-crystalline structure of 13.3 - 63.5 nm in size was observed in the as-deposited alloy. To investigate the effect of heat treatment on grain growth and mechanical/thermal properties, we conducted hardness and coefficient of thermal expansion (CTE). From this, we confirmed these properties were varied by heat treatment. In this nano-crystalline alloy, we could observe abnormal behavior in thermal expansion between $350-400^{\circ}C$. Additionally, an abrupt change in hardness has also been observed. However, once the grains grow up to micro-sized the mechanical and thermal properties mentioned above were stabilized similar to those of bulk alloys due to heat treatment.

• Journal of the Korean Society for Heat Treatment
• /
• v.34 no.2
• /
• pp.75-80
• /
• 2021

The crystal grains of polycrystalline diamond vary depending on deposition conditions and growth thickness. The diamond thin film deposited by the CVD method has a very rough growth surface. On average, the surface roughness of a diamond thin film deposited by CVD is in the range of 1-100 um. However, the high surface roughness of diamond is unsuitable for application in industrial applications, so the surface roughness must be lowered. As the surface roughness decreases, the scattering of incident light is reduced, the heat conduction is improved, the mechanical surface friction coefficient can be lowered, and the transmittance can also be improved. In addition, diamond-coated cutting tools have the advantage of enabling ultra-precise machining. In this study, the surface roughness of diamond was improved by thermal diffusion reaction between diamond carbon atoms and ferrous metals at high temperature for diamond thin films deposited by MPCVD.

• Journal of Energy Engineering
• /
• v.15 no.3 s.47
• /
• pp.194-201
• /
• 2006

Greenhouses should be heated during nights and cold days in order to fit growth conditions in greenhouses. Ground source heat pump (GSHP) systems are recognized to be outstanding heating and cooling systems. A horizontal GSHP system with thermal storage tank was installed in greenhouse and investigated the performance characteristics. The reasons for using thermal storage tank were discussed in detail. Thermal storage tank can provide heat for heating load that is larger than GSHP system heating capacity. The results of study showed that the heating coefficient of performance of the heat pump system was 2.69.

• 한국신재생에너지학회:학술대회논문집
• /
• 2007.11a
• /
• pp.505-510
• /
• 2007

Greenhouses should be heated during nights and co Id days in order to fit growth conditions in greenhouses. Ground source heat pump(GSHP) or geothermal heat pump system(GHPs) is recognized to be outstanding heating and cooling system. Horizontal GSHP system is typically less expensive than vertical GSHP system but requires wide ground area to bury ground heat exchanger (GHE). In this study, a horizontal GSHP system with thermal storage tank was installed in greenhouse and investigated as performance characteristics. In the daytime, heating load of greenhouse is very small or needless because solar radiation increases inner air temperature. The results of study showed that the heating coefficient of performance of the heat pump($COP_h$) was 2.9 and the overall heating coefficient of performance of the system($COP_{sys}$) was 2.4. Heating energy cost was saved 76% using the horizontal GSHP system with thermal storage tank.

• International Journal of Advanced Culture Technology
• /
• v.11 no.2
• /
• pp.375-380
• /
• 2023

The study was conducted in Manu-stream, located in Paju, Gyeonggi-do, from January 2021 to December 2021. The survey points were selected in the upper and lower streams based on where thermal discharged to investigate water temperature and fish species and biological community analysis and growth rate were analyzed. The average annual water temperature difference between the upper and lower stream is about 11.0℃, and in the case of the lower stream area, the water temperature is maintained at 20.0℃ or more per year. Fish that appeared during the survey period decreased lower stream compared to the upper stream, which is believed to be the result of a decrease in temperature-sensitive species as the simple riverbed structure and water temperature increased compared to the upper stream. As a result of biological community analysis, it showed a relatively stable community state at the upper stream. The growth rate of fish has a high regression coefficient b value in lower streams throughout the four seasons. It showed relatively good growth lower stream, with a high water temperature. However, the results of each survey point are similar from season to season. The indicator species is a resistant intermediate species, and the range of resistance to water temperature is wide, so it is judged that water temperature's effect on the indicator species' growth is low.