• Title/Summary/Keyword: thermal factor

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A Study on Reaction Rate of Solid SCR for NOx Reduction of Exhaust Emissions in Diesel Engine (디젤엔진 배출가스 질소산화물 저감을 위한 Solid SCR의 반응률에 관한 연구)

  • Lee, Hoyeol;Yoon, Cheon Seog;Kim, Hongsuk
    • Transactions of the Korean Society of Automotive Engineers
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    • v.21 no.6
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    • pp.183-194
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    • 2013
  • Liquid urea based SCR has been used in the market to reduce NOx in the exhaust emission of the diesel engine vehicle. This system has several problems at low temperature, which are freezing below $-12^{\circ}C$, solid deposit formation in the exhaust, and difficulties in dosing system at exhaust temperature below $200^{\circ}C$. Also, it is required complicated exhaust packaging equipment and mixer due to supply uniform ammonia concentration. In order to solve these issues, solid urea, ammonium carbonate, and ammonium carbamate are selected as ammonia sources for the application of solid SCR. In this paper, basic research on reaction rate of three ammonia-transporting materials was performed. TGA (Thermogravimetric Analysis) and DTA (Differential Thermal Analysis) tests for these materials are carried out for various heating conditions. From the results, chemical kinetic parameters such as activation energy and frequency factor are obtained from the Arrhenius plot. Additionally, from test results of DSC (Differential Scanning Calorimeter) for these materials, chemical kinetic parameters using the Kissinger method are calculated. Activation energies of solid SCR from this experiment are compared with proper data of literature study, then obtained data of this experiment are used for the design of reactor and dosing system for candidate vehicle.

The Degradation of the Effect of Drag Reduction in Synthetic Polymer Solution (합성고분자 첨가제에 의한 마찰저항감소효과의 퇴화에 관한 연구)

  • 윤석만;최형진;김종보
    • Journal of Energy Engineering
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    • v.7 no.2
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    • pp.163-171
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    • 1998
  • Degradation of polymer additives is enhanced at higher temperature of the test solutions. The degradation of Co-polymer solution was investigated experimentally in a closed loop at the temperature of 6$0^{\circ}C$ and 8$0^{\circ}C$ with various polymer concentrations of 100, 200, 400, 600 ppm in order to see the effect of temperature and polymer concentration with time. The degradation effect were found to be more dependent on temperature than mechanical shear. The friction factor versus Reynolds number curves show that in the range of Reynolds number number 50,000~150,000 the friction was decreased as Reynolds number increased and the friction of solution at low temperature approached to Virk's maximum drag reduction asymptote. For constant flowrates and temperatures the degradation effect was found to be less likely in higher polymer concentration. For constant flowrates and polymer concentrations the degradation rates are affected mainly by temperature. At the temperature of 8$0^{\circ}C$ and polymer concentration of 100 ppm, drag reduction effect was disappeared after 4 hours. However, this thermal degradation could be avoided with additional materials such as surfactants which are supposed to enhance the bonding forces between polymer molecules.

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The Preparation and the Gas Permeation Characteristics of the Soluble Polyimides (용해성 폴리이미드의 제조 및 기체투과특성)

  • Chun, Kyoung-Yong;Kim, Han-Sung;Han, Hak-Soo;Joe, Yung-il
    • Applied Chemistry for Engineering
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    • v.9 no.2
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    • pp.306-310
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    • 1998
  • The soluble polyimides(PMDA/diamine/dianhydride) were prepared and investigated. After coating the prepared PMDA/diamine/dianhydride solution into the commercial tubular alumina ceramic membranes, gas permeation characteristics was investigated. $T_g{\prime}s$ of the polyimides were in the range of $337{\sim}358^{\circ}C$ and thermal stability was good. The polymer was soluble in NMP, DMAc, DMSO, THF, and m-cresol. The adhesion between the alumina membrane and the soluble polyimide was excellent. The soluble polyimide/alumina membranes containing 6FDA showed the highest permeability among others. The permeability of nitrogen of PMDA/1,3PDA/6FDA-alumina membrane was about $7.6{\times}10^{-7}(mol/m^2{\cdot}Pa{\cdot}s)$ in the gas permeation experiments. The ideal separation factor of $O_2/N_2$ and $H_2/N_2$ in PMDA/1,3PDA/6FDA-alumina membrane were 6.19, and 70.0, respectively.

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Kinetics of Pyrolysis Degradation of Cured Phenol Resin (SC-1008) (I). (경화된 페놀 수지 (SC-1008)의 열분해 반응에 관한 연구(I).)

  • 김연철;강희철;예병한;배주찬
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 1996.11a
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    • pp.137-144
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    • 1996
  • The kinetic coefficients far decomposition of the cured phenol resin (SC-1008) using a modified Arrhenius relationship have been determined from thermogavimetric analyses (TGA). The kinetic parameters were determined by multiple heating rate technique developed by Freideman and Henderson. Weight loss (decomposition) and weight loss rate (decomposition rate)were measured and recorded for three heating rates; $5^{\circ}C$/min ,$10^{\circ}C$/min, and $20^{\circ}C$/min. Relatively good agreement was obtained between measured and calculated decomposition as a function of temperature. By separating the reaction, the reaction order and pre exponential factor become empirical parameters which provide a "best fit" of the data. However, this method yields an extremely accurate reproduction of the thermograms over a wide range of heating rates. This is the desired result for kinetic parameters used in thermal models.al models.

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APPLICATION OF REMOTE SENSING IMAGERY ON THE ESTIMATE OF EVAPOTRANSPIRATION OVER PADDY FIELD

  • Chang, Tzu-Yin;Chien, Tzu-Chieh;Liou, Yuei-An
    • Proceedings of the KSRS Conference
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    • v.2
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    • pp.752-755
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    • 2006
  • Evaportranspiration is an important factor in hydrology cycle. Traditionally, it is measured by using basin or empirical formula with meteorology data, while it does not represent the evaportranspiration over a regional area. With the advent of improved remote sensing technology, it becomes a surface parameter of research interest in the field of remote sensing. Airborne and satellite imagery are utilized in this study. The high resolution airborne images include visible, near infrared, and thermal infrared bands and the satellite images are acquired by MODIS. Surface heat fluxes such as latent heat flux and sensible heat flux are estimate by using airborne and satellite images with surface meteorological measurements. We develop a new method to estimate the evaportranspiration over the rice paddy. The surface heat fluxes are initialized with a surface energy balance concept and iterated for convergent solution with atmospheric correct functions associated with aerodynamic resistance of heat transport. Furthermore, we redistribute the total net energy into sensible heat and latent heat fluxes. The result reveals that radiation and evaporation controlled extremes can be properly decided with both airborne and satellite images. The correlation coefficient of latent heat flux and sensible heat flux with corresponding in situ observations are 0.66 and 0.76, respectively. The relative root mean squared errors (RMSEs) for latent heat flux and sensible heat flux are 97.81 $(W/m^2)$ and 124.33 $(W/m^2)$, respectively. It is also shown that the newly developed retrieval scheme performs well when it is tested by using MODIS date.

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An inquiry into the distribution and application plan of new-renewable energy in Military facilities (군 시설 신재생에너지 보급동향과 적용방향 고찰)

  • Kim, Chul;Kyung, Seo-Kyung;Cho, Woo-Seok;Oh, Myung-Won;Kim, Byung-Seon
    • 한국태양에너지학회:학술대회논문집
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    • 2009.04a
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    • pp.269-276
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    • 2009
  • South Korea having military power within the $10^{th}$ in world ranking is the biggest single institution among public institutions in Korea and comprises force of over seven hundred thousand soldiers. However, outworn equipments and efficiency problem have issued. So, this study is to search the distribution state of new-renewable energy and to analyze application plan on the basis of interview with a official in charge in military. Analysis process is the first, classify surveyed military facilities into troops and the geographical factor. Second, classify a scale and type of facilities that new-renewable energy is supplied. Third, find consideration facts on the basis of interview with a official in charge. On the results of the survey, new-renewable energy applied to the military facility is photovoltaic, solar heat, wind power and geo-thermal energy. Also, divide military into the army, navy, air force and marine, visit 14 units and analyze the official's opinion. This study will deduce LCCA(Life cycle cost analysis) considered expenses for the installation and maintenance, and will be basic research that suggest an appropriate new-renewable energy model in military.

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Characteristics of a Solder-Clad FBG Temperature Sensor (땜납이 용융 부착된 FBG 온도 센서의 특성)

  • Pyoung, Jae-Hyub;Lee, Sang-Bae;Shin, Jong-Dug
    • Journal of the Korean Institute of Telematics and Electronics D
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    • v.36D no.10
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    • pp.45-50
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    • 1999
  • We report a solder-clad fiber Bragg grating(FBG) temperature sensor in order to obtain better Bragg wavelength sensitivity to temperature than a bare FBG sensor. The solder-clad FBG sensor shows a wavelength sensitivity improvement by a factor of four compared to the case of a bare FBG sensor at temperatures below $110^{\circ}C$. However, it has a sensitivity of 0.01 $nm/^{\circ}C$ at temperatures over $110^{\circ}C$, which is identical to that of a bare FBG sensor. Bragg wavelength of the sensor shows a blue-shift below $110^{\circ}C$ because the sensor is fabricated above melting temperature of solder. The thermal stress at the FBG-solder interface has been relieved by annealing, which results in a stable operation.

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Round robin analysis of vessel failure probabilities for PTS events in Korea

  • Jhung, Myung Jo;Oh, Chang-Sik;Choi, Youngin;Kang, Sung-Sik;Kim, Maan-Won;Kim, Tae-Hyeon;Kim, Jong-Min;Kim, Min Chul;Lee, Bong Sang;Kim, Jong-Min;Kim, Kyuwan
    • Nuclear Engineering and Technology
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    • v.52 no.8
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    • pp.1871-1880
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    • 2020
  • Round robin analyses for vessel failure probabilities due to PTS events are proposed for plant-specific analyses of all types of reactors developed in Korea. Four organizations, that are responsible for regulation, operation, research and design of the nuclear power plant in Korea, participated in the round robin analysis. The vessel failure probabilities from the probabilistic fracture mechanics analyses are calculated to assure the structural integrity of the reactor pressure vessel during transients that are expected to initiate PTS events. The failure probabilities due to various parameters are compared with each other. All results are obtained based on several assumptions about material properties, flaw distribution data, and transient data such as pressure, temperature, and heat transfer coefficient. The realistic input data can be used to obtain more realistic failure probabilities. The various results presented in this study will be helpful not only for benchmark calculations, result comparisons, and verification of PFM codes developed but also as a contribution to knowledge management for the future generation.

Fabrication of Field Emission Device Using Carbon Nanotubes Synthesized by Thermal Chemical Vapor Deposition (열 화학 기상 증착법을 이용한 탄소 나노 튜브 전계 방출 소자의 제조)

  • Yu, W.J.;Cho, Y.S.;Choi, G.S.;Kim, D.J.;Kim, H.Y.;Yoon, S.K.
    • Korean Journal of Materials Research
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    • v.13 no.5
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    • pp.333-337
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    • 2003
  • We report a new fabrication process for carbon nanotube field emitters with high performance. The key of the fabrication process is trim-and-leveling the carbon nanotubes grown in trench structures by employing a planarization process, which leads to a uniform distance from the carbon nanotube tip to the electrode. In order to enable this processing, spin-on-glass liquid is applied over the CNTs grown in trench to have them stubborn adhesion among themselves as well as to the substrate. Thus fabricated emitters reveal an extremely stable emission and aging characteristics with a large current density of 40 ㎃/$\textrm{cm}^2$ at 4.5 V/$\mu\textrm{m}$. The field enhancement factor calculated from the F-N plot is $1.83${\times}$10^{5}$ $cm^{-1}$ , which is a very high value and indicates a superior quality of the emitter originating from the nature of open-tip and high stability of the carbon nanotubes obtained new process.

Slow Mass Movement on a Subalpine Slope of Mount Halla, Jeju Island (한라산 아고산대에서의 사면 물질 이동)

  • Kim, Tae-Ho
    • Journal of the Korean Geographical Society
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    • v.45 no.3
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    • pp.375-389
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    • 2010
  • In order to investigate the rates and factors of slow mass movement on a subalpine slope of Mount Halla, two painted stone lines were monitored in a bare patch at 1,710 m a.s.l. The mean movement of surface gravels is 58.2 cm, equivalent to 0.24 cm/day. However, the rates of movement vary with seasons. Compared with 0.05 cm/day of a non-frozen season, a frozen season shows 0.3 cm/day. It implies that the movement of surface gravels could be largely controlled by periglacial processes during a frozen season. In particular, frost creep including needle ice creep plays a main role in the movement of gravels under the thermal and soil conditions which are favorable for needle ice development. Since line II is located at a steeper slope than line I, the movement of line II was always larger than that of line I. However, slope gradient is not the most dominant factor contributing the movement of gravels, which can be interrupted by downslope big gravels and vegetation patches. The size and specific weight of gravels also can influence the movement of gravels. Porous and light scoriae result in relatively quick movement of gravels on the subalpine slope of Mount Halla.