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Effect of Chemical Foaming Process on the Cellular Structure Development and Correlation with the Mechanical and Physical Property of PBAT (화학적 발포 공정이 PBAT 발포 셀 구조 발달에 미치는 영향과 기계적, 물리적 특성과의 상관관계 연구)

  • Yeong ho Ji;Tae Hyeong Park;Ji Eun Choo;Sung Wook Hwang
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.30 no.1
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    • pp.63-72
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    • 2024
  • Poly (butylene adipate-co-terephthalate) (PBAT) is one of the representative biodegradable polymers with high ductility and processability to replace petroleum-based polymers. Many investigations have been conducted to broaden the applications of PBAT in a variety of industries, including the food packaging, agricultural mulching film, and logistics and distribution fields. Foaming process is widely known technique to generate the cell structure within the polymer matrix, offering the insulation and light weight properties. However, there was no commercially feasible foam product based on biodegradable polymers, especially PBAT, and maintaining a proper melt viscosity of the polymer would be a key parameter for the foaming process. In this study, chemical foaming agent and cross-linking agent were introduced to PBAT, and a compression molding process was applied to prepare a foam sheet. The correlation between cell morphological structures and mechanical and physical properties was evaluated. It was found that PBAT with foam structures effectively reduced the density and thermal conductivity, allowing them to be suitable for applications such as insulation and lightweight packaging or cushion materials.

Estimation of Air Void System and Permeability of Latex-Modified Concretes by Image Analysis Method (화상분석법을 이용한 라텍스개질 콘크리트의 공극 구조와 투수성의 상관성 분석)

  • Jeong Won-Kyong;Yun Kyong-Ku;Hong Seung-Ho
    • Journal of the Korea Concrete Institute
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    • v.17 no.5 s.89
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    • pp.695-702
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    • 2005
  • It is known that latex-modified concretes were increased their durability and permeability by added latex. The purpose of this study was to analysis the air void systems in latex-modified concretes using a reasonable and objective image analysis method with main experimental variables such as water-cement ratios, latex contents(0%, 15%) and cement types(ordinary portland cement, high-early strength cement and very-early strength cement). The results are analyzed spacing factor, air volume after hardened, air distribution and structure. Also, air void systems and permeability of latex-modified concretes were compared with correlation. The results are as follows; The same w/c ratio LMC showed better air entraining effect than OPC with AE water reducer. The VES-LMC showed that the number of entrained air below $100{\mu}m$ increased more than four times. In the HES-LMC, micro entraining air having range from 50 to $500{\mu}m$ increased above 7 times without antifoamer. Though spacing factor was measured low, latex-modified concretes were showed that permeability was good. It is considered that air void system does not have an effect on the property of latex-modified concretes but latex film is more influenced in the their durability.

Development of Gradient Centrifugal Partition Chromatography Method and Its Application for the Isolation of 3,5-Dimethoxyphenanthrene-2,7-diol and Batatasin-I from Dioscorea opposita

  • Yoon, Kee-Dong;Yang, Min-Hye;Chin, Young-Won;Kim, Yoen-Jun;Kim, Hye-Ryung;Choi, Ki-Ri;Park, Ju-Hyun;Kim, Jin-Woong
    • Natural Product Sciences
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    • v.15 no.3
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    • pp.144-150
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    • 2009
  • Gradient centrifugal partition chromatography (GCPC) method was developed and applied to isolate 3,5-dimethoxyphenanthrene-2,7-diol (DMP) and batatasin-I (BA-I) from the dichloromethane soluble extract of Dioscorea opposita. In this method, the lower phase of n-hexane-methanol-water system (HMW, 10 : 9 : 1, v/v) was used as a mobile phase A (MpA) and water was used as a mobile phase B (MpB). This gradient CPC method is comparable to that of reversed-phase HPLC method in that the stationary upper-phase of HMW (10 : 9 : 1 v/v) works as if it were reversed-phase silica gel due to its hydrophobic property, while the lower phase (MpA) and water (MpB) functioned as hydrophilic mobile phases. The initial condition of the mobile phase was 20% MpA/80% MpB and maintained for 150 min to obtain DMP (1.2 mg), and then MpA was increased up to 50% to elute BA-I (1.7 mg). The purities of DMP and BA-I were 94.1% and 98.3% with the recovery yields of 83% and 86%, respectively. Similar results were obtained by linear-gradient CPC. The CPC peak fractions were identified by comparing their retention time to those of authentic samples of DMP and BA-I and their spectroscopic data ($^1$H NMR and $^{13}$C NMR) to those of literature values.

Effect of Rosemary Powder on the Physicochemical Characteristics of Sponge Cake during Storage (로즈마리 분말이 스폰지 케이크의 저장 중 이화학적 특성에 미치는 영향)

  • Kang, Byung-Sun;Moon, Sung-Won
    • Food Science and Preservation
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    • v.16 no.2
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    • pp.155-159
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    • 2009
  • Physicochemical properties of sponge cakes prepared using various amounts of rosemary powder were evaluated. Rosemary powder was used at 0, 0.1, 0.3, 0.5, and 0.7%(w/w). The second-stage specific densities of batter increased from 0.49 to 0.54 as the amount of rosemary powder rose from 0% to 0.7%(w/w). All specific densities were within the normal range. The pH of sponge cake batters increased as rosemary powder proportion rose, with statistical significance(p<0.05). The moisture contents of cake showed no difference on the first day but significantly decreased to 38.5-39.7% after 3 days. The acid values and peroxide values fell as the proportion of rosemary powder increased. With rising rosemary powder level, antioxidative capacity increased but physiological properties were not affected in the range of rosemary powder concentrations used in this study.

Structural and Optical Characterizations of VO2 Film on Graphene/Sapphire Substrate by Post-annealing after Sputtering (그래핀/사파이어 기판상에 스퍼터링 후 열처리된 VO2박막의 구조 및 광학적 특성변화 연구)

  • Kim, Keun Soo;Kim, Hyeongkeun;Kim, Yena;Han, Seung-Ho;Bae, Dong Jae;Yang, Woo Seok
    • Journal of the Korean Vacuum Society
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    • v.22 no.2
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    • pp.98-104
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    • 2013
  • $VO_2$ is an attractive thermochromic material, in which its electrical and optical properties can be switched by the structural phase-transition about $68^{\circ}C$. Recently, graphene is also a rising material which is researched as a transparent electrode because of its superior electrical and optical characteristics. In this respect, we try to fabricate the hybridized films using $VO_2$ and graphene on transparent sapphire substrate and then we investigate a structure and characterize an optical property for the samples as a function of temperature. According to the result of IR-transmittance analysis of $VO_2$ films as a function of temperature, the graphene-supported sapphire substrates are better about 10% than the bare sapphire substrates. The mean phase transition temperatures are also decreased as the number of graphene-layers increased and the hysteresis of phase transitions are narrowed.

Reuse of Waste Activated Sludge from Livestock Wastewater Treatment Process using Thermal and Ozone Oxidation Treatment Method (열처리 및 오존산화처리를 이용한 축산폐수처리장 폐활성오니의 재활용)

  • Kim, Young-Kee;Nam, Se-Yong;Kim, Kyung-Sub
    • Applied Chemistry for Engineering
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    • v.17 no.1
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    • pp.22-27
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    • 2006
  • Thermal treatment and ozone oxidation methods were examined to reuse waste activated sludge (WAS) produced from a livestock wastewater treatment plant. Analysis of WAS property was made to study usefulness of the recycled waste as fertilizer. From the results of quantitative analysis, WAS particles were found to be composed of 44.25 wt% carbon, 8.43 wt% nitrogen, and 1.35 wt% phosphorus. It was confirmed that the inactivation of pathogenic microorganism was required from the quantitative analysis of microbes. From the results of TSS, COD, SCOD, and pathogenic microorganism measurement, the optimal operating conditions of thermal treatment and ozone oxidation were determined to be 70, 10 min and $0.6L\;O_3/L\;solution{\cdot}min$, 60 min, respectively. The optimized thermal treatment and ozone oxidation represented the efficient pathogen inactivation and particle dissolution, respectively. However, the two methods examined were not themselves sufficient but they need to combine with another treatment for the effective reuse of wastes.

Conceptual Design of Damage Assessment Inventory in Response to Disaster Risk for Infrastructures Close to River (수변구조물 재해 위험에 대응하기 위한 피해 평가 인벤토리 개념 설계)

  • Jo, Yun-Won;Choi, Hyeoung-Wook;Choi, Soo-Young;Jo, Myung-Hee
    • Journal of the Korean Association of Geographic Information Studies
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    • v.17 no.1
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    • pp.144-158
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    • 2014
  • This research presented a conceptual design of damage assessment inventory for efficient response to natural disaster damage of infrastructure close to the river. It consists of classification and categorization of facilities for accomplishing the conceptual design of inventory for damage of infrastructure close to the river. However, there are arising problems of efficient management on disaster, such as poor management of data facilities and constructions which is managed by the different types of government departments. Therefore, this research presented conceptual models of damage assessment inventory on risks of damage infrastructure close to the river using the United states' HAZUS-MH to analyze damage facilities, type of asset classification, classification of domestic facilities and guidelines for computing the value of assets. Conceptual models of inventory this research presented is to be used on the data for damage response on protected inland damage assessment and to increase efficiency for evaluating detailed damage amount of private property by natural disaster and to establish a restoration plan.

Electrochemical Characteristics of Pt/PEM/Pt-Ru MEA for Water Electrolysis (수전해용 Pt/PEM/Pt-Ru MEA의 전기화학적 특성)

  • Kweon, Oh-Hwan;Kim, Kyung-Eon;Jang, In-Young;Hwang, Yong-Koo;Chung, Jang-Hoon;Moon, Sang-Bong;Kang, An-Soo
    • Transactions of the Korean hydrogen and new energy society
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    • v.19 no.1
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    • pp.18-25
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    • 2008
  • The membrane electrode assembly(MEA) was prepared by a nonequilibrium impregnation- reduction (I-R) method. Nafion 117 and covalently cross-linked sulfonated polyetherether with tungsto- phosphoric acid (CL-SPEEK/TPA30) prepared by our laboratory, were chosen as polymer electrolyte membrane(PEM). $Pt(NH_3)_4Cl_2$, $RuCl_3$ and reducing agent $(NaBH_4)$ were used as electrocatalytic materials. Electrochemical activity surface area(ESA) and specific surface area(SSA) of Pt cathodic electrode with Nafion 117 were $22.48m^2/g$ and $23.50m^2/g$ respectively under the condition of 0.8 M $NaBH_4$. But Pt electrode prepared by CL-SPEEK/TPA30 membrane exhibited higher ESA $23.46m^2/g$ than that of Nafion 117. In case of Pt-Ru anodic electrode, the higher concentration of Ru was, the lower potential of oxygen reduction and region of hydrogen desorption was, and Pt-Ru electrode using 10 mM $RuCl_3$ showed best properties of SSA $34.09m^2/g$ with Nafion 117. In water electrolysis performance, the cell voltage of Pt/PEM/Pt-Ru MEA with Nafion 117 showed cell property of 1.75 V at $1A/cm^2$ and $80{\circ}C$. On the same condition, the cell voltage with CL-SPEEK/TPA30 was the best of 1.73 V at $1A/cm^2$.

Evaluation of Flexural Properties of Indirect Gum-Shade Composite Resin for Esthetic Improvement (심미성 향상을 위한 간접수복용 Gum-Shade 복합레진의 굽힘 특성 평가)

  • Im, Yong-Woon;Hwang, Seong-Sig
    • Journal of dental hygiene science
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    • v.15 no.4
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    • pp.407-412
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    • 2015
  • This study investigated flexural properties of indirect Gum-shade composite resins for esthetic improvement. The material utilized in this study was Crea.lign, Twiny flow and Twiny paste (TP). Ten specimens were fabricated with a dimension of $25{\times}2{\times}2mm$ according to the ISO 4049. After fabrications, specimens were stored in the distilled water for 24 hours at the temperature of $37^{\circ}C$. Three-point bending test was performed in universal testing machine (Instron 3344; Instron, USA) at a crosshead speed of 1 mm/min until the failure occurred. TP exhibited a higher flexural strength (FS) and flexural modulus (FM) compared to the flowable materials. There were significant differences among the three materials in FS and FM. However, there was no significant difference in work of fracture (WOF) in all tested materials (p>0.05). In Weibull analysis, TP showed the greatest Weibull modulus which means a higher reliability of the materials. Also, Gum-shade composite resins revealed a strong correlation in all flexural properties. There was a positive correlation in FS-FM ($r^2=0.99$) and a negative correlation between FS-WOF and FM-WOF ($r^2>0.97$). Therefore, this confirmed that flexural property was important for mechanical behavior evaluation and useful information. To addition, this improved among mechanical properties correlation of materials as important factor.

Molecular Cloning of Plasmodium vivax Calcium-Dependent Protein Kinase 4

  • Choi, Kyung-Mi;Kim, Jung-Yeon;Moon, Sung-Ung;Lee, Hyeong-Woo;Sattabongkot, Jetsumon;Na, Byoung-Kuk;Kim, Dae-Won;Suh, Eun-Jung;Kim, Yeon-Joo;Cho, Shin-Hyeong;Lee, Ho-Sa;Rhie, Ho-Gun;Kim, Tong-Soo
    • Parasites, Hosts and Diseases
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    • v.48 no.4
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    • pp.319-324
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    • 2010
  • A family of calcium-dependent protein kinases (CDPKs) is a unique enzyme which plays crucial roles in intracellular calcium signaling in plants, algae, and protozoa. CDPKs of malaria parasites are known to be key regulators for stage-specific cellular responses to calcium, a widespread secondary messenger that controls the progression of the parasite. In our study, we identified a gene encoding Plasmodium vivax CDPK4 (PvCDPK4) and characterized its molecular property and cellular localization. PvCDPK4 was a typical CDPK which had well-conserved N-terminal kinase domain and C-terminal calmodulin-like structure with 4-EF hand motifs for calcium-binding. The recombinant protein of EF hand domain of PvCDPK4 was expressed in Echerichia coli and a 34 kDa product was obtained. Immunofluorescence assay by confocal laser microscopy revealed that the protein was expressed at the mature schizont of P. vivax. The expression of PvCDPK4-EF in schizont suggests that it may participate in the proliferation or egress process in the life cycle of this parasite.