• Title/Summary/Keyword: the high higher surface

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A Study on Carbonization Characteristics of Indonesian and Korean Bamboo for Production of Bamboo Charcoal and Vinegar (죽탄 및 죽초액 제조를 위한 인도네시아산 및 국내산 대나무의 탄화특성 비교 연구)

  • Yang, Won;Kim, Hui-Yeol;Chae, Tae-Young;Ibik, K.;Pohan, H.G.
    • Journal of the Korean Society of Combustion
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    • v.15 no.1
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    • pp.30-37
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    • 2010
  • Carbonization characteristics of Indonesian bamboos were investigated using lab-scale tube furnace, in order to find optimum design temperature of a carbonizer for producing bamboo charcoal and vinegar. The bamboo samples used in this study are local bamboos from Damyang in Korea, Andong and Petung in Indonesia. Correlation of electric resistance, specific surface area and pH of bamboo vinegar with pyrolysis temperature has been investigated. Electric resistance of the charcoal increased for higher pyrolysis temperature the specific surface area was also increased as carbonization temperature got higher. Charcoal which has specific surface area of over $300\;m^2/g$ could be produced at $700^{\circ}C$. pH of bamboo vinegar was decreased for highter carbonization temperature and vinegar under pH 3 could be produced for all bamboo samples. In this experimental condition, it was found that lower carbonization temperature is better for producing bamboo vinegar of high quality, while higher temperature is better for obtaining bamboo charcoal with larger surface.

Platinum Decoration of a 3D Oxidized Graphitic Carbon Nitride/Graphene Aerogel for Enhanced Visible-Light Photocatalytic Hydrogen Evolution

  • Thi Kieu Oanh Nguyen;Thanh Truong Dang;Tahereh Mahvelati-Shamsabadi;Jin Suk Chung
    • Korean Chemical Engineering Research
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    • v.61 no.4
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    • pp.627-634
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    • 2023
  • Graphitic carbon nitride (g-C3N4) has attracted considerable attention since its discovery for its catalysis of water splitting to hydrogen and oxygen under visible light irradiation. However, pristine g-C3N4 confers only low photocatalytic efficiency and requires surface cocatalysts to reach moderate activity due to a lack of accessible surface active sites. Inspired by the high specific surface area and superior electron transfer of graphene, we developed a strongly coupled binary structure of graphene and g-C3N4 aerogel with 3D porous skeleton. The as-prepared 3D structure photocatalysts achieve a high surface area that favors efficient photogenerated charge separation and transfer, enhances the light-harvesting efficiency, and significantly improves the photocatalytic hydrogen evolution rate as well. The photocatalyst performance is observed to be optimized at the ratio 3:7 (g-C3N4:GO), leading to photocatalytic H2 evolution of 16125.1 mmol. g-1. h-1 under visible light irradiation, more than 161 times higher than the rate achieved by bulk g-C3N4.

Analysis of Numerical Meteorological Fields due to the Detailed Surface Data in Complex Coastal Area (복잡 연안지역의 지표면 자료 상세화에 따른 수치 기상장 분석)

  • Lee, Hwa-Woon;Jeon, Won-Bae;Lee, Soon-Hwan;Choi, Hyun-Jung
    • Journal of Korean Society for Atmospheric Environment
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    • v.24 no.6
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    • pp.649-661
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    • 2008
  • The impact of the detailed surface data on regional meteorological fields in complex coastal area is studied using RAMS. Resolutions of topography and land use data are very important to numerical modeling, because high resolution data can reflect correct terrain height and detail characteristics of the surface. Especially, in complex coastal region such as Gwangyang area, southern area in Korean Peninsula, high resolution topography and land use data are indispensable for accurate modeling results. This study investigated the effect of resolutions of terrain data using SRTM with 3 second resolution topography and KLU with 1 second resolution land use data. Case HR was the experiment using high resolution data, whereas Case LR used low resolution data. In Case HR, computed surface temperature was higher than Case LR along the coastline and wind speed was $1{\sim}2m/s$ weaker than Case LR. Time series of temperature and wind speed indicated great agreement with the observation data. Moreover, Case HR indicated outstanding results on statistical analysis such as regression, root mean square error, index of agreement.

Evaluation of the Vickers hardness on denture acrylic resins by glaze color (글레이즈 컬러를 적용한 의치상 레진의 비커스 경도 평가)

  • Yong-Woon Im
    • Journal of Technologic Dentistry
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    • v.44 no.4
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    • pp.111-117
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    • 2022
  • Purpose: This study was conducted to compare the Vickers hardness on the denture acrylic resins using the glaze color system. Methods: The specimens (20×2 mm) were prepared by mixing according to the manufacturer's protocols through thermal polymerization and self-polymerization. The surface roughness was measured using a testing machine after water-soaking for 48 hours. For the Vickers hardness measurement, the completed specimen was soaked in water for 48 hours and then applied at 200 gf for 30 seconds. Was the specimen immersed after being soaked in water for 48 hours at temperatures of 5℃ and 55℃, respectively, for 30 seconds for the thermos-cycling treatment, and it was carried out 5,000 times. Results: Surface roughness was higher in the more glazing group than in the control group. A significant difference was observed in all groups, except for the Retec Don 2000 and Luciton 199 groups (p<0.05). As a result of measuring the Vickers hardness, the treatment by glaze color showed slightly lower but the thermo-cycling treatment group appeared higher than control group in all. Conclusion: Therefore, the glaze color was found to affect the surface roughness and showed a significant difference. The surface glaze color showed a very high Vickers hardness after the thermo-cycling treatment, indicating that the surface-strengthening effect is greater in the oral environment.

Development of Inexpensive High Energetic Electrodes Ni-Cu and Ni-CeO2-Cu for Renewable Energy through Direct Ethanol Fuel Cell

  • Guchhait, Sujit Kumar;Paul, Subir
    • Journal of Electrochemical Science and Technology
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    • v.7 no.3
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    • pp.190-198
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    • 2016
  • Application of fuel cell to produce renewable energy for commercial purpose is limited by the high cost of Pt based electrode materials. Development of inexpensive, high energetic electrode is the need of the hour to produce pollution free energy using bio-fuel through a fuel cell. Ni-Cu and Ni-CeO2-Cu electrode materials, electro synthesized by pulse current have been developed. The surface morphology of the electrode materials is controlled by different deposition parameters in order to produce a high current from the electro-oxidation of the fuel, the ethanol. The developed materials are electrochemically characterized by Cyclic Voltammetry (CV), Chronoamperometry (CA) and Potentiodynamic polarization tests. The results confirm that the high current is due to their enhanced catalytic properties viz. high exchange current density (i0), low polarization resistance (Rp) and low impedance. It is worthwhile to mention here that the addition of CeO2 to Ni-Cu has outperformed Pt as far as the high electro catalytic properties are concerned; the exchange current density is about eight times higher than the same on Pt surface. The morphology of the electrode surface examined by SEM and FESEM exhibits that the grains are narrow and sub spherical with 3D surface, containing vacancies in between the elongated grains. The fact has enhanced more surface area for electro oxidation of the fuel, giving rise to an increase in current. Presence of Ni, CeO2, and Cu is confirmed by the XRD and EDXS. Fuel cell fabricated with Ni-CeO2-Cu material electrode is expected to produce clean electrical energy at cheaper rates than conventional one, using bio fuel the derived from biomass.

On the Surface Moisture Availability Parameters to Estimate the Surface Evaporation (증발량 추정을 위한 지표면 가용 수분 계수)

  • 황병화;황수진
    • Journal of Environmental Science International
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    • v.4 no.5
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    • pp.427-435
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    • 1995
  • In order to discuss the differences among the SMP(Surface Moisture Availability Parameter), by previous researchers on the basis of their own theoretical and empirical background, we assessed the SMP according to the soil types and volumetric soil water contents. The results are as follows. There are differences among all the five SMAPs. There's a tendency that the larger grain size, the higher value of parameters. And they divided into two groups for their value: one group has parameters with exponential function and the other with cosine and linear function. The maximum difference between the two groups appears when the volumetric soil water contents are 0.07m3m-3 for sand, 0.l1m3m-3 for loam, 0.12 for clay, and 0.13m3m-3 for silt loam. So, these differences must be considered when we estimate the surface evaporation rate. From field data, the paddy field soil around Junam reservoir is classified as a silt has high wetness, 0.56. So, the parameter obtained from the field measurement is much higher than that of Clapp and Hornberger(1978)'s Table. This study treated the SMP for a certain point of time in winter season. But if we measured the soil water contents continuously, we could obtain better time-dependent parameter. Key words : SMAP(Surface Moisture Availability Parameter), Paddy field, Volumetric soil water content, Evaporation, Capillary potential.

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Low Temperature Plasma Nitriding Process of AISI 304L Austenitic Stainless Steels for Improving Surface Hardness and Corrosion Resistance (내식성 및 표면경도 향상을 위한 AISI 304L 스테인리스강의 저온 플라즈마질화 프로세스)

  • Lee, In-Sup
    • Korean Journal of Metals and Materials
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    • v.47 no.10
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    • pp.629-634
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    • 2009
  • The effects of processing parameters on the surface properties of the hardened layers processed by the low temperature plasma nitrocarburizing and the low temperature two-step plama treatment (carburizing+nitriding) were investigated. The nitrogen-enriched expanded austenite structure (${\gamma}_N$) or S phase was formed on all of the treated surface. The surface hardness reached up to 1200 $HV_{0.025}$, which is about 5 times higher than that of untreated sample (250 $HV_{0.1}$). The thickness of hardened layer of the low temperature plasma nitrocarburized layer treated at $400^{\circ}C$ for 40 hour was only $15{\mu}m$, while the layer thicknesss in the two-step plama treatment for the 30 hour treatment increased up to about $30{\mu}m$. The surface thickness and hardness increased with increasing treatment temperature and time. In addition, the corrosion resistance was enhanced than untreated samples due to a high concentration of N on the surface. However, higher treatment temperature and longer treatment time resulted in the formation of $Cr_2N$ precipitates, which causes the degradation of corrosion resistance.

Surface pressure measurements in translating tornado-like vortices

  • Kassab, Aya;Jubayer, Chowdhury;Ashrafi, Arash;Hangan, Horia
    • Wind and Structures
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    • v.33 no.6
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    • pp.447-462
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    • 2021
  • High spatial and temporal surface pressure measurements were carried out in the state-of-the-art tornado simulator, the Wind Engineering, Energy and Environment (WindEEE) Dome, to explore the characteristics of stationary and translating tornado-like vortices (TLV) for a wide range of swirl ratios (S=0.21 to 1.03). The translational speed of the TLV and the surface roughness were varied to examine their effects on tornado ground pressures, wandering, and vortex structure. It was found that wandering is more pronounced at low swirl ratios and has a substantial effect on the peak pressure magnitude for stationary TLV (error percentage ≤ 35%). A new method for removing wandering was proposed which is applicable for a wide range of swirl ratios. For translating TLV, the near-surface part lagged behind the top of the vortex, resulting in a tilt of the tornado vertical axis at higher translating speeds. Also, a veering motion of the tornado base towards the left of the direction of the translation was observed. Wandering was less pronounced for higher translation speeds. Increasing the surface roughness caused an analogous effect as lowering the swirl ratio.

The Influence of the Wafer Resistivity for Dopant-Free Silicon Heterojunction Solar Cell (실리콘 웨이퍼 비저항에 따른 Dopant-Free Silicon Heterojunction 태양전지 특성 연구)

  • Kim, Sung Hae;Lee, Jung-Ho
    • Journal of the Korean institute of surface engineering
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    • v.51 no.3
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    • pp.185-190
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    • 2018
  • Dopant-free silicon heterojunction solar cells using Transition Metal Oxide(TMO) such as Molybdenum Oxide($MoO_X$) and Vanadium Oxide($V_2O_X$) have been focused on to increase the work function of TMO in order to maximize the work function difference between TMO and n-Si for a high-efficiency solar cell. One another way to increase the work function difference is to control the silicon wafer resistivity. In this paper, dopant-free silicon heterojunction solar cells were fabricated using the wafer with the various resistivity and analyzed to understand the effect of n-Si work function. As a result, it is shown that the high passivation and junction quality when $V_2O_X$ deposited on the wafer with low work function compared to the high work function wafer, inducing the increase of higher collection probability, especially at long wavelength region. the solar cell efficiency of 15.28% was measured in low work function wafer, which is 34% higher value than the high work function solar cells.

The Relationship Between the Quality of Surface Layer of Concrete Floor and the Defect of Self-Leveling Material - Evaluation Method about Surface Layer Quality of Concrete Floor Groundwork Corresponding to Defect in Self-leveling Material (Part II) - (콘크리트 표층부 품질이 SL재의 하자에 미치는 영향 - SL재의 하자 발생에 영향을 미치는 콘크리트 표층부의 품질 평가방법(II) -)

  • Kim, Doo-Ho;Choi, Soo-Kyung
    • Journal of the Korea Institute of Building Construction
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    • v.7 no.4
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    • pp.125-132
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    • 2007
  • The use of Self-Leveling material is increasing recently. This paper assesses the quality of surface layer of concrete floor when Self-Leveling material is defective. The paper shows how to predict the defect of SL material before construction begins. The relationship between the quality of surface layer of concrete floor and the defect of SL material was determined and the quality of surface layer of concrete floor was then estimated. The relations between the quality of surface layer and the defect of SL material were determine considering surface strength, moisture, and consistency of surface layer. Absorbing amount was used as the indicator of consistency and the absorbing amount of test material was measured. Then the relations between the test material and surface strength were determined. Generally concrete floor with greater consistency has greater surface strength, however in this study, we hound that high impact concrete floor could have lower surface strength as the consistency gets bigger. The relations between the level of defect occurred in SL material and the quality of surface layer were examined and we clarified that the surface layer with lower consistency gets higher possibility to occur exfoliation in early stage, one or two weeks after constructing SL material. When the consistency is sufficient, the occurring situation of defect depends upon the moisture of surface layer. Little amount of moisture gets higher possibility not to occur the defect. As the amount increases, fissure generates and early exfoliation may occur. In addition, the level of fissure is highly related with the surface strength.