• 제목/요약/키워드: temperature-sensitivity

검색결과 1,737건 처리시간 0.029초

Redox Reaction on Polarization Curve Variations of Polymer with Enzymes

  • Park, Chil-Nam
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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    • 제4권3호
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    • pp.165-171
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    • 2000
  • Experiments were carried out to measure variations in the oxidation potential and current density using the polarization curves of polycarbonate. The results were then examined to identify the influences affecting the oxidation potential related to various conditions, such as temperature, pH, and oxydase(citrate and lipase). The lines representing the active anodic and cathodic dissolution shifted only slightly in the potential direction relative to temperature, pH, and the effect of the enzyme. The Tafel slope for the anodic and cathodic dissolution was determined such that the reversibility polarization was indicated as being effected by various conditions. The slope of the polarization curves describing the active-to-passive transition region shifted noticeably in their direction. Also, by varying the conditions, the optimum conditions for the most ready transform were identified, including temperature, pH, oxidation rate, and resistance of oxidation potential. The critical oxidation sensitivity(I(sub)r/I(sub)f) of the anodic current density peak and maximum passive current density was also determined, which is used in measuring the critical corrosion sensitivity of a polycarbonate.

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$LiBr-H_2O$계 흡수식냉동기의 부식에 미치는 온도의 영향 (The Effect of Temperature on Corrosion of Absorption Refrigeration Systems Using $LiBr-H_2O$ Working Fluids)

  • 임우조;정기철
    • Journal of Advanced Marine Engineering and Technology
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    • 제26권1호
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    • pp.125-131
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    • 2002
  • This paper was studied on the effect of temperature on corrosion of absorption refrigeration systems using $LiBr-H_2O$ working fluids. In the fresh water and 62 % lithium bromide solution at $70^{\circ}C$, polarization test of SS 400, Cu(C1220T-OL) and Al-Ni bronze was carried out. And polarization behavior, polarization resistance characteristics, corrosion rate(mmpy) and corrosion sensitivity of materials forming absorption refrigeration systems was considered. The main results are as following: (1) As the experimental temperature increase, the change of corrosion rate of Al-Ni bronze become duller than SS 400 and Cu in 62% lithium bromide solution. (2) According as corrosion environment is changed from fresh water to 62% lithium bromide solution, potential change of Cu and Al-Ni bronze become less noble than SS 400. (3) The corrosion sensitivity of Al-Ni bronze was duller than that of Cu and SS 400 in 62% LiBr solution.

Spectroscopic properties of Er3+/Yb3+ co-doped fluorophosphate glasses for NIR luminescence and optical temperature sensor applications

  • Linganna, K.;Agawane, G.L.;In, Jung-Hwan;Park, June;Choi, Ju H.
    • Journal of Industrial and Engineering Chemistry
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    • 제67권
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    • pp.236-243
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    • 2018
  • A series of $Er^{3+}/Yb^{3+}$ co-doped fluorophosphate glasses with varying $YbF_3$ concentration were prepared by a high temperature melt quenching technique. Absorption and emission cross-sections were determined by using the McCumber theory. The larger emission cross-section ($9.86{\times}10^{-21}cm^2$) and longer fluorescence lifetime (12.37 ms) were obtained for the $^4I_{13/2}{\rightarrow}^4I_{15/2}$ transition of ABS3Er4Yb glass. The sensitivity and temperature of the maximum sensitivity were evaluated by the fluorescence intensity ratio method from the measured upconversion spectra. The results were discussed and compared to the other reported glasses.

국내산저서단각류 Mandibulophoxus mai와 Monocorophium acherusicum의 생존, 성장 및 민감도에 대한 온도의 영향 (Influence of Temperature on the Survival, Growth and Sensitivity of Benthic Amphipods, Mandibulophoxus mai and Monocorophium acherusicum)

  • 이규태;이정석;김동훈;김찬국;박건호;강성길;박경수
    • 한국해양환경ㆍ에너지학회지
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    • 제8권1호
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    • pp.9-16
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    • 2005
  • 본 연구는 최근 한국에서 퇴적물 독성 실험생물로 개발되고 있는 저서 단각류 Mandibulophoxus mai와 Monocorophium acherusicum의 생존과 성장 및 민감도(sensitivity)에 대한 온도의 영향를 평가하기 위한 일련의 실험으로 수행되었다. 본 연구에 사용된 각 실험 단각류의 생물학적 영향으로 각기 다른 수온 조건에서의 생존과 성장률을 통해 결정하였다. 표준 독성물질인 카트뮴(Cd)을 평가하는데 있어서 독성 민감도에 대한 온도의 영향은 각기 다른 온도에서 카드뮴이 첨가되지 않은 해수와 카드뮴이 첨가된 해수에 노출된 단각류의 생존률을 비교하여 결정하였다. 연구결과, 온도는 두 실험 단각규 모두의 생존, 성장 및 카드뮴 민감도에 영향을 미치는 것으로 평가되었다(p<0.05). 두 실험종 모두 80%이상의 생존율을 보인 온도범위는 13-22℃인 것으로 확인되었다. 두 실험종의 일일 성장률은 M. mai의 경우 20℃, M. acherusicum의 경우 25℃에서 다른 온도 조건에 비해 상대적으로 높게 나타났다. 반면, Cd 민감노에 대한 영향은 M. mai는 20℃, M. acherusicum은 15℃가 다른 온도 조건에 비해 상대적으로 큰 것으로 평가되었다. 이상의 연구 결과에 근거할 때, 온도는 단각규를 이용한 치사 및 반치사 생물 검정 연구에 있어 매우 중요한 변수인 것으로 판단되었다. 따라서, 독성평가에 활용되는 생물종에 대한 적절한 실험 온도 범위를 결정하는 것은 표준 독성시험법을 개발하는데 우선적으로 고려되어야 학 사항인 것으로 사료된다.

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휘발성유기화합물가스에 대한 폴리아닐린 센서의 감도 향상 (Sensitivity Enhancement of Polyaniline Sensor to Volatile Organic Compounds)

  • 유준부;유비;임정옥;변형기;허증수
    • 한국재료학회지
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    • 제17권8호
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    • pp.433-436
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    • 2007
  • Nano-structured polyaniline have been synthesized by interfacial polymerization method at room temperature. An aqueous solution of aniline in chloroform and another solution of ammonium peroxydisulfate in doping acid were prepared at different times terminated with methanol at room temperature. SEM, UV-vis were used to characterize the polyaniline with regard to their morphology and structure. The diameter and length of polyaniline can be controlled by the reaction time. Nano-structured polyaniline were found to have superior sensitivity for volatile organic compounds(VOCs). As the reaction time to increase from 30minute to 2hours the sensitivity were decreased to VOCs vapors. The sensitivity of Nano-structured polyaniline sensor appeared to VOCs better than the sensitivity of chemical synthesis sensors. The sensitivity of Nano-structured polyaniline sensor improved benzene vapors.

동전위 분극저항 측정에서의 불확도 (Uncertainty in Potentiodynamic Polarization Resistance Measurement)

  • 김종집
    • Corrosion Science and Technology
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    • 제8권5호
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    • pp.193-196
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    • 2009
  • For the estimation of uncertainty in potentiodynamic polarization resistance measurement, the type A uncertainty was measured using type 316 stainless steel in an acidified NaCl solution. Sensitivity coefficients were determined for measurand such as scan rate of potential, temperature of solution, concentration of NaCl, concentration of HCl, surface roughness of specimen and flow rate of purging gas. Sensitivity coefficients were large for the measurand such as the scan rate of potential, temperature of solution and roughness of specimen. However, the sensitivity coefficients were not the major factors influencing the combined standard uncertainty of polarization resistance due to the low values of uncertainty in measurements of the measurands. A major influencing factor was the concentration of NaCl. The value of type A uncertainty was 1.1 times the value of type B uncertainty, and the combined standard uncertainty was 10.5 % of the average value of polarization resistance.

다공질 ZnO의 전기적 특성, 환원성 가스 감응 특성 및 습도의 영향 (Electrical Conductivity, Flammable Gas Response and Humidity Effect of Pporous ZnO)

  • 윤당혁;최경만
    • 한국세라믹학회지
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    • 제32권11호
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    • pp.1283-1291
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    • 1995
  • The electrical conductivity, flammable gas response and their humidity effect of porous ZnO, added with 5wt% corn starch as the fugitive phase, were examined. Porous ZnO showed different conductivity curves during increasing and decreasing temperature, and its electrical conductivity decreased rapidly by desorption of OH- between 20$0^{\circ}C$ and 35$0^{\circ}C$ when the temperature increased in dry air. The CO gas sensitivity of starchadded ZnO samples was higher than that of ZnO without starch addition. The sensitivity of porous, starchadded ZnO to 200ppm CO gas was much less in humid atmosphere than in dry atmosphere since water vapor increased the conductivity of porous ZnO in air, but decreased the conductivity in CO. Maximum sensitivity to 200 ppm CO gas balanced by air was about 100 in dry atmosphere and about 15 in RH 23% atmosphere.

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입력변수의 조건에 따른 대기확산모델의 민감도 분석 (Sensitivity Analysis of the Atmospheric Dispersion Modeling through the Condition of Input Variable)

  • 정진도;김장우;김정태
    • 한국환경과학회지
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    • 제14권9호
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    • pp.851-860
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    • 2005
  • In order to how well predict ISCST3(lndustrial Source Complex Short Term version 3) model dispersion of air pollutant at point source, sensitivity was analysed necessary parameters change. ISCST3 model is Gaussian plume model. Model calculation was performed with change of the wind speed, atmospheric stability and mixing height while the wind direction and ambient temperature are fixed. Fixed factors are wind direction as the south wind(l80") and temperature as 298 K(25 "C). Model's sensitivity is analyzed as wind speed, atmospheric stability and mixing height change. Data of stack are input by inner diameter of 2m, stack height of 30m, emission temperature of 40 "C, outlet velocity of 10m/s. On the whole, main factor which affects in atmospheric dispersion is wind speed and atmospheric stability at ISCST3 model. However it is effect of atmospheric stability rather than effect of distance downwind. Factor that exert big influence in determining point of maximum concentration is wind speed. Meanwhile, influence of mixing height is a little or almost not.

증발산량 산정에 있어서 기상학적 요인들의 민감도 해석 (Sensitivity Analyses of the Meteorological Factors in the Estimation of Evapotranspiration Rates)

  • 임창수
    • 한국환경과학회지
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    • 제5권5호
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    • pp.657-662
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    • 1996
  • 여름과 겨울철에 준건조 유역들 (Lucky Hills and Kendall)로부터 측정되어진 기상학적 그리고 flux data를 이용하여 증발산 산정을 위한 변수들의 민감도를 연구하였다. 상대적 민감도 분석을 이용하여 Pen농an의 잠재증발산 산정에 필요한 네 가지 기상학적 그리고 flux변수(순방사, 풍속, 공기온도 그리고 상대습도)들의 중요도가 검증되어졌다. 두 다른 유역으로부터의 연구 결과에 의하면, 여름철에 Pen-mim의 잠재증발산략의 변화는 공기 온도와 순방사에 의해서 지배되어지고, 겨울철에는 상대습도와 공기온도에 의해서 지배되어지는 것으로 나타났다.

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SiC 마이크로 히터가 내장된 극한 환경용 NO 센서의 제작과 특성 (Fabrication of NO sensor integrated SiC micro heaters for harsh environments and its characteristics)

  • 김강산;정귀상
    • 센서학회지
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    • 제19권3호
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    • pp.197-201
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    • 2010
  • This paper describes the fabrication and characteristics of a NO sensor using ZnO thin film integrated 3C-SiC micro heater based on polycrystalline 3C-SiC thin film of operation in harsh environments. The sensitivity, response time, and operating properties in high temperature and voltages of NO sensors based SiC MEMS are measured and analyzed. The sensitivity of device with pure ZnO thin film at the heater operating power of 13.5 mW ($300^{\circ}C$) is 0.875 in NO gas concentration of 0.046 ppm. In the case of Pt doping, the sensitivity of at power consumption of 5.9 mW ($250^{\circ}C$) was 1.92 at same gas flow rate. The ZnO with doped Pt was showed higher sensitivity, lower working temperature and faster adsorption characteristics to NO gas than pure ZnO thin film. The NO gas sensor integrated SiC micro heater is more strength than others in high voltage and temperature environments.